In this paper, we investigate the Toeplitz operators with positive measure symbols on the Bergman spaces of bounded multi-connected domains and show that a Toeplitz operator is bounded or compact if and only if the sy...In this paper, we investigate the Toeplitz operators with positive measure symbols on the Bergman spaces of bounded multi-connected domains and show that a Toeplitz operator is bounded or compact if and only if the symbol measure is a Carleson or vanishing Carleson measure respectively.展开更多
目的:对比三维多回波恢复梯度回波(3D MERGE)、三维可变反转角快速自旋回波(3D SPACE STIR)序列在腰椎间盘突出症(LDH)检查中的应用效果。方法:选择2020年1月~2022年11月收治的135例LDH患者,回顾性分析患者临床和磁共振成像(MRI)资料,...目的:对比三维多回波恢复梯度回波(3D MERGE)、三维可变反转角快速自旋回波(3D SPACE STIR)序列在腰椎间盘突出症(LDH)检查中的应用效果。方法:选择2020年1月~2022年11月收治的135例LDH患者,回顾性分析患者临床和磁共振成像(MRI)资料,所有患者均接受常规MRI扫描及3D MERGE、3D SPACE STIR序列扫描,对比3D MERGE、3D SPACE STIR序列测量神经根直径的一致性,评价两种序列的图像质量参数[信噪比(SNR)、对比噪声比(CNR)]、图像清晰度评分。结果:3D MERGE和3D SPACE STIR序列测量的L3~S1神经根直径比较差异无统计学意义(P>0.05),且两组序列测量的L3、L4、L5和S1直径均显示出较高相关性(r=0.957,0.986,0.975,0.972,P<0.05);3D MERGE序列的SNR及CNR均高于3D SPACE STIR序列,神经根显示分级、图像清晰度评分优于3D SPACE STIR序列,差异有统计学意义(P<0.05)。结论:3D MERGE、3D SPACE STIR序列在LDH神经根直径测量中具有极高一致性,3D MERGE序列较3D SPACE STIR序列能够更清晰显示神经跟的解剖形态,图像质量更好。展开更多
螺旋藻(Spirulina)藻蓝蛋白具有独特的理化特性及生理功能,是药物、食品和化妆品的天然原料,具有较大的开发潜力。为探讨螺旋藻藻蓝蛋白的研究现状与发展前景,对中国知网和Web of Science数据库中1990—2023年发表的文献进行检索并筛选...螺旋藻(Spirulina)藻蓝蛋白具有独特的理化特性及生理功能,是药物、食品和化妆品的天然原料,具有较大的开发潜力。为探讨螺旋藻藻蓝蛋白的研究现状与发展前景,对中国知网和Web of Science数据库中1990—2023年发表的文献进行检索并筛选,使用Cite Space软件对文章发文量、研究团队及研究热点进行图谱分析。综合分析可知,国内年发文量偏少,呈平稳趋势;国外年发文量持续上升,尤其近几年发文量迅速增长,且发文量超过了100篇;国外研究热点集中于藻蓝蛋白在食品、医药行业的应用方面,而国内研究热点集中在提取纯化、稳定性、功能活性的研究与应用,下一步应结合研究现状开发适合规模化生产的提取纯化工艺,进一步加强藻蓝蛋白研究的广度与深度;国内外研究群体主要是高校的相关生物技术学院或研究机构等,总体来讲,学者间存在较为密切的合作,但研究机构间尚未形成紧密的合作关系,在地域上比较分散,各大高校和研究机构应突破地区或机构间的各种限制,促进该研究领域的深度融合和快速发展,深入挖掘藻蓝蛋白在各个领域的潜在应用。展开更多
A new 2-D Bi(3+) coordination polymer {Bi4(μ3-O)2(μ4-O)2(C7H3NO4)2}n(1,C7H3NO4 = pyridine-2,6-dicarboxylate) containing(6,5)-connected topological sheet with the Schl?fli symbol of(4~4·6~3·8...A new 2-D Bi(3+) coordination polymer {Bi4(μ3-O)2(μ4-O)2(C7H3NO4)2}n(1,C7H3NO4 = pyridine-2,6-dicarboxylate) containing(6,5)-connected topological sheet with the Schl?fli symbol of(4~4·6~3·8~4·12~4)(4~5·6~4·8) has been synthesized by an ionothermal method using the ionic liquid 1-ethyl-3-methylimidazolium bromide([Emim]Br) as solvent,and characterized by C,H and N elemental analysis,energy-dispersive X-ray spectroscopy(EDS),infrared spectrum(IR spectrum) and single-crystal X-ray diffraction.The results indicate that 1 belongs to the monoclinic system,space group P21/n with a = 13.766(7),b = 4.142(2),c = 16.439(8) ?,β = 99.099(9)°,Z = 2,V = 925.6(8) ?~3,Dc = 4.414 g·cm^(-3),F(000) = 1064,μ = 37.985 mm-1,the final R = 0.0326,wR = 0.0727 and S = 1.022.The molecular structural units [Bi4(μ3-O)2(μ4-O)2(C7H3NO4)2] are connected to each other via bridging O atoms,extending into an interesting 2-D layered structure.These resulting layers are further assembled by weak C-H…O hydrogen bonds into a 3-D supramolecular architecture.Moreover,its thermal stability and the luminescent properties have been also studied.展开更多
目的梳理国内多发伤急救相关研究文献,分析研究现状、热点和趋势,为我国多发伤急救研究提供借鉴和指导。方法检索中国知网数据库中2011—2021年关于多发伤急救的相关文献,使用Cite Space 6.1.R3可视化软件对该领域的年发文量、机构、作...目的梳理国内多发伤急救相关研究文献,分析研究现状、热点和趋势,为我国多发伤急救研究提供借鉴和指导。方法检索中国知网数据库中2011—2021年关于多发伤急救的相关文献,使用Cite Space 6.1.R3可视化软件对该领域的年发文量、机构、作者、关键词进行分析。结果最终纳入多发伤急救研究文献2519篇,整体发文数量较平稳,以2016年为小高峰;发文量最高的机构是华中科技大学附属同济医院。多发伤急救研究热点包括院前急救、并发症护理、风险因素分析和预后效果评估,研究前沿包括不同多发伤人群的诊断、治疗、手术和护理体会等方面。结论本文通过可视化分析国内多发伤急救研究的热点及趋势,指明了多发伤目前研究存在的问题和未来研究发展的方向,为进一步完善多发伤急救卫生服务和管理体系提供指导。展开更多
A chiral lanthanide metal-organic framework based on enantiopure camphoric acid (D-H2cam), [Nd3(D-cam)8(H2O)4Cl]n (1), has been synthesized and characterized by single-crystal X-ray structural analysis, elemen...A chiral lanthanide metal-organic framework based on enantiopure camphoric acid (D-H2cam), [Nd3(D-cam)8(H2O)4Cl]n (1), has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows: orthorhombic system, space group P212121 with a = 13.8287(7), b = 14.0715(7), c = 25.7403(12) A^°, V = 5008.8(4) A^°3, Mr = 1333.08, Z = 4, F(000) = 2644, Dc = 1.768 g/cm^3, μ(MoKα) = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 (I 〉 2σ(I)). Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism (VCD) spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.展开更多
By using "pillaring" strategy, a new Co(Ⅱ)-MOF, [Co_2(abtc)(bimb)_2]·2H_2O(1, H_4abtc = 3,3?,5,5?-azobenzenetetracarboxylic acid, bimb = 4,4?-bis(imidazole-1-ylmethyl)biphenyl), has been solvother...By using "pillaring" strategy, a new Co(Ⅱ)-MOF, [Co_2(abtc)(bimb)_2]·2H_2O(1, H_4abtc = 3,3?,5,5?-azobenzenetetracarboxylic acid, bimb = 4,4?-bis(imidazole-1-ylmethyl)biphenyl), has been solvothermally synthesized and structurally characterized. The structural determination revealed that 1 features a 3D pillar-layered framework with(4,8)-connected {4^4.6^2}{4^8.6^(20)} topology based on dinuclear Co(Ⅱ)-SBUs. The magnetic investigation shows that the dominant antiferromagnetic coupling is observed in compound 1.展开更多
In wind power generation system the grid-connected inverter is an important section for energy conversion and transmission, of which the performance has a direct influence on the entire wind power generation system. T...In wind power generation system the grid-connected inverter is an important section for energy conversion and transmission, of which the performance has a direct influence on the entire wind power generation system. The mathematical model of the grid-connected inverter is deduced firstly. Then, the space vector pulse width modulation (SVPWM) is analyzed. The power factor can be controlled close to unity, leading or lagging, which is realized based on H-type current controller and grid voltage vector-oriented control. The control strategy is verified by the simulation and experimental results with a good sinusoidal current, a small harmonic component and a fast dynamic response.展开更多
为了解国内外近10年护理不良事件的研究热点与前沿,为医院管理和临床护士提供参考,保障患者安全,通过检索中国期刊全文数据库(CNKI)和Web of Science(WOS)数据库,检索时限为2012年1月—2022年8月,导入CiteSpace进行可视化分析。研究显示...为了解国内外近10年护理不良事件的研究热点与前沿,为医院管理和临床护士提供参考,保障患者安全,通过检索中国期刊全文数据库(CNKI)和Web of Science(WOS)数据库,检索时限为2012年1月—2022年8月,导入CiteSpace进行可视化分析。研究显示,从发文量看,国内外学者对护理不良事件的关注度整体较高,可视化分析结果并未发现作者之间、机构之间的联系。未来减少护理不良事件的方法一定会越来越紧贴科学技术,越来越多的新型信息化平台、App等会用于医疗行业,降低护理不良事件预防的难度,但护理人员仍要重视护理安全。展开更多
Two new metal-organic frameworks(MOFs), namely, [Co_2(L_1)(bix)(μ_3-OH)]·2H_2O(1) and [Co_2(L_2)(bix)(μ_3-OH)]·2.5H_2O(2)(H_3L_1 = 5-oxyacetate isophthalic acid, H_3L_2 = 3,5-bis-oxyacet...Two new metal-organic frameworks(MOFs), namely, [Co_2(L_1)(bix)(μ_3-OH)]·2H_2O(1) and [Co_2(L_2)(bix)(μ_3-OH)]·2.5H_2O(2)(H_3L_1 = 5-oxyacetate isophthalic acid, H_3L_2 = 3,5-bis-oxyacetate-benzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), have been synthesized under hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra, and powder X-ray diffraction(PXRD) analysis. Both complexes 1 and 2 demonstrate identical three-dimensional(3D)(3,8)-connected tfz-d nets with(4~3)_2(4~6·6^(18)·8~4) topologies, where the tetranuclear [Co_4(μ_3-OH)_2] clusters act as 8-connected nodes and aromatic multicarboxylic ligands as 3-connected nodes. The results show that the ligands with different geometrical conformations can form products with the same topological structures. Their thermal and magnetic properties were also investigated.展开更多
A new metal-organic framework, {[Cd(DPA)(OBA)]'(HzO)}n (1, DPA = 4,4"-dipyri- dylamine, H2OBA = 4,4"-oxybisbenzoic acid), has been synthesized and characterized by elemental analysis, IR and single-crystal ...A new metal-organic framework, {[Cd(DPA)(OBA)]'(HzO)}n (1, DPA = 4,4"-dipyri- dylamine, H2OBA = 4,4"-oxybisbenzoic acid), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Single-crystal X-ray analysis shows that it is a 3-D framework. Complex 1 crystallizes in monoclinic, space group C2/c with a = 21.699(7), b = 12.192(4), c = 17.566(5) A, β = 105.254(5)°, V = 4483.43 A3, Z = 8, Dc = 1.653 g/cm3, p = 1.021 mm^-1], F(000) = 2240, the final R = 0.0307, wR = 0.0867 (I 〉 2σ(I)). Complex I exhibits a rare three-dimensional highly 8-connected LOMFOI topology with a point symbol of {424"64}. Thermogravimetric analysis shows that the decomposition temperature of the host framework of the complex is above 400 ℃.展开更多
基金This work was supported by the NSF (19971061) of China and the Science Foundation ofFushun Petroleum Institute.
文摘In this paper, we investigate the Toeplitz operators with positive measure symbols on the Bergman spaces of bounded multi-connected domains and show that a Toeplitz operator is bounded or compact if and only if the symbol measure is a Carleson or vanishing Carleson measure respectively.
文摘目的:对比三维多回波恢复梯度回波(3D MERGE)、三维可变反转角快速自旋回波(3D SPACE STIR)序列在腰椎间盘突出症(LDH)检查中的应用效果。方法:选择2020年1月~2022年11月收治的135例LDH患者,回顾性分析患者临床和磁共振成像(MRI)资料,所有患者均接受常规MRI扫描及3D MERGE、3D SPACE STIR序列扫描,对比3D MERGE、3D SPACE STIR序列测量神经根直径的一致性,评价两种序列的图像质量参数[信噪比(SNR)、对比噪声比(CNR)]、图像清晰度评分。结果:3D MERGE和3D SPACE STIR序列测量的L3~S1神经根直径比较差异无统计学意义(P>0.05),且两组序列测量的L3、L4、L5和S1直径均显示出较高相关性(r=0.957,0.986,0.975,0.972,P<0.05);3D MERGE序列的SNR及CNR均高于3D SPACE STIR序列,神经根显示分级、图像清晰度评分优于3D SPACE STIR序列,差异有统计学意义(P<0.05)。结论:3D MERGE、3D SPACE STIR序列在LDH神经根直径测量中具有极高一致性,3D MERGE序列较3D SPACE STIR序列能够更清晰显示神经跟的解剖形态,图像质量更好。
文摘螺旋藻(Spirulina)藻蓝蛋白具有独特的理化特性及生理功能,是药物、食品和化妆品的天然原料,具有较大的开发潜力。为探讨螺旋藻藻蓝蛋白的研究现状与发展前景,对中国知网和Web of Science数据库中1990—2023年发表的文献进行检索并筛选,使用Cite Space软件对文章发文量、研究团队及研究热点进行图谱分析。综合分析可知,国内年发文量偏少,呈平稳趋势;国外年发文量持续上升,尤其近几年发文量迅速增长,且发文量超过了100篇;国外研究热点集中于藻蓝蛋白在食品、医药行业的应用方面,而国内研究热点集中在提取纯化、稳定性、功能活性的研究与应用,下一步应结合研究现状开发适合规模化生产的提取纯化工艺,进一步加强藻蓝蛋白研究的广度与深度;国内外研究群体主要是高校的相关生物技术学院或研究机构等,总体来讲,学者间存在较为密切的合作,但研究机构间尚未形成紧密的合作关系,在地域上比较分散,各大高校和研究机构应突破地区或机构间的各种限制,促进该研究领域的深度融合和快速发展,深入挖掘藻蓝蛋白在各个领域的潜在应用。
基金Project supported by the National Natural Science Foundation of China(No.21601095)
文摘A new 2-D Bi(3+) coordination polymer {Bi4(μ3-O)2(μ4-O)2(C7H3NO4)2}n(1,C7H3NO4 = pyridine-2,6-dicarboxylate) containing(6,5)-connected topological sheet with the Schl?fli symbol of(4~4·6~3·8~4·12~4)(4~5·6~4·8) has been synthesized by an ionothermal method using the ionic liquid 1-ethyl-3-methylimidazolium bromide([Emim]Br) as solvent,and characterized by C,H and N elemental analysis,energy-dispersive X-ray spectroscopy(EDS),infrared spectrum(IR spectrum) and single-crystal X-ray diffraction.The results indicate that 1 belongs to the monoclinic system,space group P21/n with a = 13.766(7),b = 4.142(2),c = 16.439(8) ?,β = 99.099(9)°,Z = 2,V = 925.6(8) ?~3,Dc = 4.414 g·cm^(-3),F(000) = 1064,μ = 37.985 mm-1,the final R = 0.0326,wR = 0.0727 and S = 1.022.The molecular structural units [Bi4(μ3-O)2(μ4-O)2(C7H3NO4)2] are connected to each other via bridging O atoms,extending into an interesting 2-D layered structure.These resulting layers are further assembled by weak C-H…O hydrogen bonds into a 3-D supramolecular architecture.Moreover,its thermal stability and the luminescent properties have been also studied.
文摘目的梳理国内多发伤急救相关研究文献,分析研究现状、热点和趋势,为我国多发伤急救研究提供借鉴和指导。方法检索中国知网数据库中2011—2021年关于多发伤急救的相关文献,使用Cite Space 6.1.R3可视化软件对该领域的年发文量、机构、作者、关键词进行分析。结果最终纳入多发伤急救研究文献2519篇,整体发文数量较平稳,以2016年为小高峰;发文量最高的机构是华中科技大学附属同济医院。多发伤急救研究热点包括院前急救、并发症护理、风险因素分析和预后效果评估,研究前沿包括不同多发伤人群的诊断、治疗、手术和护理体会等方面。结论本文通过可视化分析国内多发伤急救研究的热点及趋势,指明了多发伤目前研究存在的问题和未来研究发展的方向,为进一步完善多发伤急救卫生服务和管理体系提供指导。
基金supported by National Natural Science Foundation of China(21401147)Basic Research Program of Natural Science from Shaanxi Provincial Government(2015JQ2032)+2 种基金Scientific Research Program from Education Department of Shaanxi Provincial Government(2013JK0654)Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University(201219)the Program for Distinguished Young Scholars of Xi’an Polytechnic University(201403)
文摘A chiral lanthanide metal-organic framework based on enantiopure camphoric acid (D-H2cam), [Nd3(D-cam)8(H2O)4Cl]n (1), has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows: orthorhombic system, space group P212121 with a = 13.8287(7), b = 14.0715(7), c = 25.7403(12) A^°, V = 5008.8(4) A^°3, Mr = 1333.08, Z = 4, F(000) = 2644, Dc = 1.768 g/cm^3, μ(MoKα) = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 (I 〉 2σ(I)). Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism (VCD) spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.
基金Supported by the National Natural Science Foundation of China(Nos.21201109,21373122 and 21301106)
文摘By using "pillaring" strategy, a new Co(Ⅱ)-MOF, [Co_2(abtc)(bimb)_2]·2H_2O(1, H_4abtc = 3,3?,5,5?-azobenzenetetracarboxylic acid, bimb = 4,4?-bis(imidazole-1-ylmethyl)biphenyl), has been solvothermally synthesized and structurally characterized. The structural determination revealed that 1 features a 3D pillar-layered framework with(4,8)-connected {4^4.6^2}{4^8.6^(20)} topology based on dinuclear Co(Ⅱ)-SBUs. The magnetic investigation shows that the dominant antiferromagnetic coupling is observed in compound 1.
基金supported by Delta Power Electronic Science and Education Development in 2007 (Grant No.DRES2007002)
文摘In wind power generation system the grid-connected inverter is an important section for energy conversion and transmission, of which the performance has a direct influence on the entire wind power generation system. The mathematical model of the grid-connected inverter is deduced firstly. Then, the space vector pulse width modulation (SVPWM) is analyzed. The power factor can be controlled close to unity, leading or lagging, which is realized based on H-type current controller and grid voltage vector-oriented control. The control strategy is verified by the simulation and experimental results with a good sinusoidal current, a small harmonic component and a fast dynamic response.
文摘为了解国内外近10年护理不良事件的研究热点与前沿,为医院管理和临床护士提供参考,保障患者安全,通过检索中国期刊全文数据库(CNKI)和Web of Science(WOS)数据库,检索时限为2012年1月—2022年8月,导入CiteSpace进行可视化分析。研究显示,从发文量看,国内外学者对护理不良事件的关注度整体较高,可视化分析结果并未发现作者之间、机构之间的联系。未来减少护理不良事件的方法一定会越来越紧贴科学技术,越来越多的新型信息化平台、App等会用于医疗行业,降低护理不良事件预防的难度,但护理人员仍要重视护理安全。
基金supported by the application basis research key project of Yunnan Province science and technology department(201401CB00299)the major project of Qujing Normal University(2012ZD002)
文摘Two new metal-organic frameworks(MOFs), namely, [Co_2(L_1)(bix)(μ_3-OH)]·2H_2O(1) and [Co_2(L_2)(bix)(μ_3-OH)]·2.5H_2O(2)(H_3L_1 = 5-oxyacetate isophthalic acid, H_3L_2 = 3,5-bis-oxyacetate-benzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), have been synthesized under hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra, and powder X-ray diffraction(PXRD) analysis. Both complexes 1 and 2 demonstrate identical three-dimensional(3D)(3,8)-connected tfz-d nets with(4~3)_2(4~6·6^(18)·8~4) topologies, where the tetranuclear [Co_4(μ_3-OH)_2] clusters act as 8-connected nodes and aromatic multicarboxylic ligands as 3-connected nodes. The results show that the ligands with different geometrical conformations can form products with the same topological structures. Their thermal and magnetic properties were also investigated.
基金supported by the National Ministry of Science and Technology of China(2012CB821702)the National Science Foundation of China(21073192,21203194 and 21233009)the Science Foundation of CAS and Fujian Province for research funding support(KJCX2-YW-H20)
文摘A new metal-organic framework, {[Cd(DPA)(OBA)]'(HzO)}n (1, DPA = 4,4"-dipyri- dylamine, H2OBA = 4,4"-oxybisbenzoic acid), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Single-crystal X-ray analysis shows that it is a 3-D framework. Complex 1 crystallizes in monoclinic, space group C2/c with a = 21.699(7), b = 12.192(4), c = 17.566(5) A, β = 105.254(5)°, V = 4483.43 A3, Z = 8, Dc = 1.653 g/cm3, p = 1.021 mm^-1], F(000) = 2240, the final R = 0.0307, wR = 0.0867 (I 〉 2σ(I)). Complex I exhibits a rare three-dimensional highly 8-connected LOMFOI topology with a point symbol of {424"64}. Thermogravimetric analysis shows that the decomposition temperature of the host framework of the complex is above 400 ℃.