Investigation of hydroxyl-terminated polybutadiene propellant breaking characteristics and mechanism impacted by submerged cavitation water jet

A submerged cavitation water jet(SCWJ)is an effective method to recycle solid propellant from obsolete solid engines by the breaking method.Solid propellant's breaking modes and mechanical process under SCWJ impact are unclear.This study aims to understand those impact breaking mechanisms.The hydroxyl-terminated polybutadiene(HTPB)propellant was chosen as the research material,and a self-designed test system was used to conduct impact tests at four different working pressures.The high-speed camera characterized crack propagation,and the DIC method calculated strain change during the impact process.Besides,micro and macro fracture morphologies were characterized by scanning electron microscope(SEM)and computed tomography(CT)scanning.The results reveal that the compressive strain concentration region locates right below the nozzle,and the shear strain region distributes symmetrically with the jet axis,which increases to 4% at first 16th ms,the compressive strain rises to 2% and 6% in the axial and transverse direction,respectively.The two tensile cracks formed first at the compression strain concentrate region,and there generate many shear cracks around the tensile cracks,and those shear cracks that develop and aggregate cause the cracks to become wider and cut through the tensile cracks,forming the tensile-shear cracks and the impact parts eventually fail.The HTPB propellant forms a breaking hole shaped conical after impact 10 s.The mass loss increases by 17 times at maximum,with the working pressure increasing by three times.Meanwhile,the damage value of the breaking hole remaining on the surface increases by 7.8 times while 2.9 times in the depth of the breaking hole.The breaking efficiency is closely affected by working pressures.The failure modes of HTPB impacted by SCWJ are classified as tensile crack-dominated and tensile-shear crack-dominated damage mechanisms.

Observation of Zero-Energy Modes with Possible Time-Reversal Symmetry Breaking on Step Edge of CaKFe_(4)As_(4)

Topologically nontrivial Fe-based superconductors attract extensive attentions due to their ability of hosting Majorana zero modes(MZMs)which could be used for topological quantum computation.Topological defects such as vortex lines are required to generate MZMs.Here,we observe the robust edge states along the surface steps of CaKFe_(4)As_(4).Remarkably,the tunneling spectra show a sharp zero-bias peak(ZBP)with multiple integerquantized states at the step edge under zero magnetic field.We propose that the increasing hole doping around step edges may drive the local superconductivity into a state with possible spontaneous time-reversal symmetry breaking.Consequently,the ZBP can be interpreted as an MZM in an effective vortex in the superconducting topological surface state by proximity to the center of a tri-junction with different superconducting order parameters.Our results provide new insights into the interplay between topology and unconventional superconductivity,and pave a new path to generate MZMs without magnetic field.

Numerical Simulation of Spatial Lag Between Wave Breaking Point and Location of Maximum Wave-Induced Current

A quasi three-dimensional numerical model of wave-driven coastal currents with the effects of surface rollers is developed for the study of the spatial lag between the location of the maximum wave-induced current and the wave breaking point. The governing equations are derived from Navier-Stokes equations and solved by the hybrid method combining the fractional step finite different method in the horizontal plane with a Galerkin finite element method in the vertical direc- tion. The surface rollers effects are considered through incorporating the creation and evolution of the roller area into the free surface shear stress. An energy equation facilitates the computation process which transfers the wave breaking energy dissipation to the surface roller energy. The wave driver model is a phase-averaged wave model based on the wave action balance equation. Two sets of laboratory experiments producing breaking waves that generated longshore currents on a planar beach am used to evaluate the model＇s performance. The present wave-driven coastal current model with the roller effect in the surface shear stress term can produce satisfactory results by increasing the wave-induced nearshore current velocity inside the surf zone and shifting the location of the maximum longshore current velocity landward.

法舒地尔缓解β-淀粉样蛋白1-42诱导的SH-SY5Y细胞凋亡

背景:法舒地尔对阿尔茨海默病小鼠脑内的线粒体动力学有调节作用,并且可以抑制神经炎症,但能否调节线粒体自噬和NLRP3炎症小体进而减轻β-淀粉样蛋白毒性尚不清楚。目的:探究法舒地尔对β-淀粉样蛋白1-42诱导的人源神经母细胞瘤细胞株SH-SY5Y凋亡和线粒体自噬以及NLRP3炎症小体的调节作用。方法:将SH-SY5Y细胞接种于孔板内,细胞贴壁后分3组干预:对照组不加入任何药物,模型组加入20μmol/L β-淀粉样蛋白1-42,法舒地尔组同时加入20μmol/L β-淀粉样蛋白1-42与15 mg/L法舒地尔,干预24 h后,采用MTT法检测细胞活性,TUNEL染色检测细胞凋亡,qRT-PCR和Western blot检测凋亡相关蛋白表达,免疫荧光染色和Western blot检测线粒体自噬相关蛋白表达,免疫荧光染色和Western blot检测NLRP3炎症小体相关蛋白表达。结果与结论:(1)与对照组比较,模型组细胞活性降低、凋亡率升高(P<0.05);与模型组比较,法舒地尔组细胞活性升高、凋亡率降低(P<0.05);(2)qRT-PCR和Western blot检测结果显示,与对照组比较,模型组细胞Bax mRNA与蛋白表达升高(P<0.05),Bcl-2 mRNA与蛋白表达降低(P<0.05);与模型组比较,法舒地尔组细胞Bax mRNA与蛋白表达降低(P<0.05),Bcl-2 mRNA与蛋白表达升高(P<0.05);(3)免疫荧光染色和Western blot检测结果显示,与对照组相比,模型组细胞PINK1、帕金森病蛋白和LC3蛋白表达降低(P<0.05),p62蛋白表达升高(P<0.05);与模型组相比,法舒地尔组细胞PINK1、帕金森病蛋白和LC3蛋白表达升高(P<0.05),p62蛋白表达降低(P<0.05);(4)免疫荧光染色和Western blot检测结果显示,与对照组相比,模型组细胞NLRP3、ASC、Caspase-1和白细胞介素1β蛋白表达升高(P<0.05);与模型组相比,法舒地尔组细胞NLRP3、ASC、Caspase-1和白细胞介素1β蛋白表达降低(P<0.05);(5)结果表明,法舒地尔可以减轻β-淀粉样蛋白1-42诱导的SH-SY5Y细胞凋亡,其机制可能与激活线粒体自噬且抑制NLRP3炎症小体激活有关。

Circulation Features Associated with the Record-breaking Typhoon Silence in August 2014

Climatologically, August is the month with the most tropical cyclone(TC) formation over the western North Pacific(WNP) during the typhoon season. In this study, the reason for abnormal TC activity during August is discussed—especially August 2014, when no TCs formed. The large-scale background of August 2014 is presented, with low-level large-scale easterly anomalies and anticyclonic anomalies dominating over the main TC genesis region, a weak monsoon trough system,and a strong WNP subtropical high(WPSH), leading to significantly reduced low-level convergence, upper-level divergence,and mid-level upward motion. These unfavorable large-scale conditions suppressed convection and cyclogenesis. In August2014, equatorial waves were inactive within the negative phase of the Madden–Julian Oscillation(MJO), with fewer tropical disturbances. Although the low-level vorticity and convection of those disturbances were partly promoted by the convective envelopes of equatorial waves, the integral evolution of disturbances, as well as the equatorial waves, were suppressed when propagating into the negative MJO phase. Moreover, the upper-level potential vorticity(PV) streamers associated with anticyclonic Rossby wave breaking events imported extratropical cold and dry air into the tropics. The peripheral tropospheric dryness and enhanced vertical wind shear by PV streamer intrusion combined with the negative MJO phase were responsible for the absence of TC formation over the WNP in August 2014.

One-Dimensional Horizontal Boussinesq Model Enhanced for Non-Breaking and Breaking Waves

Based on a set of fully nonlinear Boussinesq equations up to the order of O（μ^2, ε^3μ^2） （where ε is the ratio of wave amplitude to water depth and ,μ is the ratio of water depth to wave length） a numerical wave model is formulated. The model＇s linear dispersion is acceptably accurate to μ ≌ 1.0, which is confirmed by comparisons between the simulat- ed and measured time series of the regular waves propagating on a submerged bar. The moving shoreline is treated numer- ically by replacing the solid beach with a permeable beach. Run-up of nonbreaking waves is verified against the analytical solution for nonlinear shallow water waves. The inclusion of wave breaking is fulfilled by introducing an eddy term in the momentum equation to serve as the breaking wave force term to dissipate wave energy in the surf zone. The model is applied to cross-shore motions of regular waves including various types of breaking on plane sloping beaches. Comparisons of the model test results comprising spatial distribution of wave height and mean water level with experimental data are presented.

Rock Breaking Performance of a Pick Assisted by High-pressure Water Jet under Different Configuration Modes

In the process of rock breaking, the conical pick bears great cutting force and wear, as a result, high-pressure water jet technology is used to assist with cutting. However, the effect of the water jet position has not been studied for rock breaking using a pick. Therefore, the models of rock breaking with different configuration modes of the water jet are established based on SPH combined with FEM. The effect of the water jet pressure, distance between the jet and the pick bit, and cutting depth on the rock breaking performance as well as a comparison of the tension and compression stress are studied via simulation; the simulation results are verified by experiments. The numerical and experimental results indicate that the decrease in the rates of the pick force obviously increases from 25 MPa to 40 MPa, but slowly after 40 MPa, and the optimal distance between the jet and the pick bit is 2 mm under the JFP and JSP modes. The JCP mode is proved the best, followed by the modes of JRP and JFP, and the worst mode is JSP. The decrease in the rates of the pick force of the JCP, JRP, JFP, and JSP modes are up to 30.96%, 28.96%, 33.46%, 28.17%, and 25.42%, respectively, in experiment. Moreover, the JSP mode can be regarded as a special JFP model when the distance between the pick-tip and the jet impact point is 0 mm. This paper has a dominant capability in introducing new numerical and experimental method for the study of rock breaking assisted by water jet and electing the best water jet position from four different configuration modes.

Vibrating-Rocking Motion of Caisson Breakwater Under Breaking Wave Impact

The possible motions of a caisson breakwater under dynamic load excitation include vibrating, vibrating-sliding and vibrating- rocking motions. The models of vibrating motion and vibrating-sliding motion have been proposed in an early paper. In this paper, a model of vibrating- rocking motion of caisson breakwaters under breaking wave impact is presented, which can be used to simulate the histories of vibrating-rocking motion of caisson breakwaters. The effect of rocking motion on the displacement, rotation, sliding force and overturning moment of breakwaters is investigated, In case the overturning moment exceeds the stability moment of a caisson, the caisson may only rock. The caisson overturns only in case the rocking angle exceeds the critical angle, It is shown that the sliding force and overturning moment of breakwaters can be reduced effectively due to the rocking motion, It is proposed that some rocking motion should be allowed in breakwater design.

A Boussinesq Equation-Based Model for Nearshore Wave Breaking

Based on the wave breaking model by Li and Wang (1999), this work is to apply Dally's analytical solution to the wave-height decay instead of the empirical and semi-empirical hypotheses of wave-height distribution within the wave breaking zone. This enhances the applicability of the model. Computational results of shoaling, location of wave breaking, wave-height decay after wave breaking, set-down and set-up for incident regular waves are shown to have good agreement with experimental and field data.

Integrated transcriptome and proteome analysis provides insight into chilling-induced dormancy breaking in Chimonanthus praecox

Chilling has a critical role in the growth and development of perennial plants.The chilling requirement(CR)for dormancy breaking largely depends on the species.However,global warming is expected to negatively affect chilling accumulation and dormancy release in a wide range of perennial plants.Here,we used Chimonanthus praecox as a model to investigate the CR for dormancy breaking under natural and artificial conditions.We determined the minimum CR(570 chill units,CU)needed for chilling-induced dormancy breaking and analyzed the transcriptomes and proteomes of flowering and non-flowering flower buds(FBs,anther and ovary differentiation completed)with different CRs.The concentrations of ABA and GA3 in the FBs were also determined using HPLC.The results indicate that chilling induced an upregulation of ABA levels and significant downregulation of SHORT VEGETATIVE PHASE(SVP)and FLOWERING LOCUS T(FT)homologs at the transcript level in FBs when the accumulated CR reached 570 CU(IB570)compared to FBs in November(FB.Nov,CK)and nF16(non-flowering FBs after treatment at 16℃for−300 CU),which suggested that dormancy breaking of FBs could be regulated by the ABA-mediated SVP-FT module.Overexpression in Arabidopsis was used to confirm the function of candidate genes,and early flowering was induced in 35S::CpFT1 transgenic lines.Our data provide insight into the minimum CR(570 CU)needed for chilling-induced dormancy breaking and its underlying regulatory mechanism in C.praecox,which provides a new tool for the artificial regulation of flowering time and a rich gene resource for controlling chilling-induced blooming.

Formation Process of Intermittent Molten Bridge Between Au-Plated Contacts at Super Low Breaking Velocity

This paper presents the molten bridge behaviors of Au-plated material at super low breaking velocity conditions by introducing our new designed test rig. The typical waveforms of the contact voltage and contact force during breaking are investigated under the load of 5- 25 V/0.2-1 A and velocity of 25-150 nm/s. It is shown that the intermittent molten bridge is formed from the competition of multitude contact a-spots for current distribution and the solid- liquid mixing characteristics of a molten bridge. Also, it is proved that the bridge is not composed by the completed melted metal by using FEM thermal simulation and the voltage-temperature relation. The observed surface morphology reveals that the scattered and stacked melted regions are attributed to the intermittent bridge. Finally, the effects of breaking velocity and electrical load on bridge length and duration are also analyzed.

自旋-轨道耦合作用下极化激元凝聚中的调制不稳定性

利用线性稳定性分析方法,对存在自旋-轨道耦合(SOS)作用的二维极化激元玻色-爱因斯坦凝聚(BEC)系统中的调制不稳定性(MI)进行了研究.分析了组分内部,组分之间以及SOC相互作用对系统调制不稳定性的影响.结果显示,当系统内部不存在SOC作用,组分之间的相互作用为0,组分内部存在排斥作用时,不会出现调制不稳定性,组分内部存在吸引作用时,会出现调制不稳定性,并且调制不稳定性区间长度随吸引作用的增强而增加;组分之间相互作用不为0时,组分之间的相互作用以平方形式出现,其正负不会对调制不稳定性产生实质性影响.存在SOC相互作用时,SOC相互作用会引起增益谱曲线的不规则振荡,破坏原来的调制不稳定性区间.

Numerical Simulation of Breaking Wave Based on Higher-Order Mild Slope Equation

The 'surface roller' to simulate wave energy dissipation of wave breaking is introduced into the random wave model based on approximate parabolic mild slope equation in this paper to simulate the random wave transportation in chiding diffraction, refraction and breaking in nearshore areas. The roller breaking random wave higher-order approximate parabolic equation model has been verified by the existing experimental data for a plane slope beach and a circular shoal, and the numerical results of random wave breaking model agree with the experimental data very well, This model can be applied to calculate random wave propagation from deep to shallow water in large areas near the shore over natural topography.

双偶氮苯-二苯并[b,i]噻蒽-[2,3-b]苯-5,7,12,14-四酮衍生物分子的二阶非线性光学性质

使用密度泛函理论(DFT)M06-2X方法、采用6-311+g(d,p)基组,分别对26个双偶氮-二苯并[b,i]噻蒽-[2,3-b]苯-5,7,12,14-四酮衍生物分子进行结构优化与频率计算;使用含时密度泛函理论(TD-DFT)TD-M06-2X方法计算了a1~d6分子的前线分子轨道与电子吸收光谱,采用有效场FF方法研究了二阶非线性光学性质(NLO).研究结果表明,26个噻蒽四酮类衍生物分子的能隙在1.33—2.02 eV范围,归属于有机半导体;最低能量吸收峰波长在601.8~609.5nm范围;在增大分子的二阶非线性光学系数β_(μ)(或β_(0))值方面,含相同偶氮苯基团或含不同偶氮苯基团分别引入到二苯并[b,i]噻蒽-[2,3-b]苯-5,7,12,14-四酮分子两侧的2,10位优于2,9位,在2,10位分别端接含推、拉基团的偶氮苯优于含相同给电子基团的偶氮苯.在偶氮苯苯环对位分别端接强吸电子基(-NO_(2))与强供电子基(如-N(CH_(3))_(2)、-N(Ph)_(3)、-N-苯基咔唑等)可增强体系的二阶非线性光学性能,获得性能良好的非线性光学材料.

The rock breaking and ROP increase mechanisms for single-tooth torsional impact cutting using DEM

Torsional impact drilling is a new technology which has the advantages of high rock-breaking efficiency and a high rate of penetration(ROP).So far,there is no in-depth understanding of the rock-breaking mechanism for the ROP increase from torsional impact tools.Therefore,it has practical engineering significance to study the rock-breaking mechanism of torsional impact.In this paper,discrete element method(DEM)software(PFC2 D)is used to compare granite breaking under the steady and torsional impacting conditions.Meanwhile,the energy consumption to break rock,microscopic crushing process and chip characteristics as well as the relationship among these three factors for granite under different impacting frequencies and amplitudes are discussed.It is found that the average cutting force is smaller in the case of torsional impact cutting(TIC)than that in the case of steady loading.The mechanical specific energy(MSE)and the ratio of brittle energy consumption to total energy are negatively correlated;rock-breaking efficiency is related to the mode of action between the cutting tooth and rock.Furthermore,the ROP increase mechanism of torsional impact drilling technology is that the ratio of brittle energy consumption under the TIC condition is larger than that under a steady load;the degree of repeated fragmentation of rock chips under the TIC condition is lower than that under the steady load,and the TIC load promotes the formation of a transverse cracking network near the free surface and inhibits the formation of a deep longitudinal cracking network.

Annihilation Solitons and Chaotic Solitons for the （2＋1）-Dimensional Breaking Soliton System

By means of an improved mapping method and a variable separation method, a series of variable separation solutions including solitary wave solutions, periodic wave solutions and rational function solutions） to the （2＋1）-dimensional breaking soliton system is derived. Based on the derived solitary wave excitation, we obtain some special annihilation solitons and chaotic solitons in this short note.

Exact Geometric Relationships, Symmetry Breaking and Structural Stability for Single-Walled Carbon Nanotubes

We pioneered a study about how the geometric relationship of single-walled carbon nanotubes(SWCNT) is influenced by curvature factor and non-planar geometry factor in cylindrical coordinate system based on the assumption of complete symmetry. The bond length and angle of every carbon-carbon bonds are determined by using the principle of the minimum energy. The results of the paper include(1) From the calculation result, the symmetry breaking appears for chiral carbon nanotubes, while the part symmetry appears for achiral carbon nanotubes with increasing curvature.(2) The synergistic effect of bond lengths and bond angles is first found.(3) We conclude that the influence of non-planar geometry factor can be completely ignored on bond lengths and bond angles when the curvature parameter has been included in the model.(4)The two fractal dimensions are given from the nanoscale to the macroscale for zigzag topology and armchair topology respectively. Fractal dimensions of SWCNT show special characteristics, varying with the length of SWCNT until the lengths approach infinity. The close and inevitable correlations among curvature, symmetry breaking and stability of SWCNTs can be summed up as: the increase of curvature causes symmetry breaking,and such symmetry breaking will further reduce the structural stability.

A swirling jet from a nozzle with tangential inlets and its characteristics in breaking-up rocks

In order to apply a swirling jet to a PDC drill bit, the nozzle performance influenced by nozzle inlet geometric parameters and rock breaking tests under submerged conditions were studied. Numerical simulation was used to study the influence of the nozzle structure on the swirling intensity and nozzle discharge coefficient. Simulation results indicate that spreading angle of the swirling jet is greater than that of＂ the non-swirling jet, and the swirling intensity of the jet is strongly influenced by the length of the nozzle body but weakly by the number of tangential inlets. Rock breaking tests were conducted to evaluate the performance of the swirling jet. It is found that the swirling jet shows a lower threshold pressure to break the rock samples and could break rock more efficiently compared with the non-swirling jet.

A record-breaking high efficiency facilitated by hierarchical morphology in all polymer solar cells

Organic solar cells(OSCs) especially non-fullerene OSCs(NF-OSCs) are promising to become the next-generation of commercial applications and have received great attention from many researchers due to their typical advantages of low cost,light weight,and flexibility [1,2].

Vibrating-Sliding Motion of Caisson Breakwaters Under Various Breaking Wave Impact Forces

Sliding is one of the principal failure types of caisson breakwaters and is an essential content of stability examination in caisson breakwater design. Herein, the mass-spring-dashpot model of caisson-base system is used to simulate the vibrating-sliding motion of the caisson under various types of breaking wave impact forces, i.e., single peak impact force, double peak impact force, and shock-damping oscillation impact force. The effects of various breaking wave impacts and the sliding motion on the dynamic response behaviors of caisson breakwaters are investigated and the calculation of relevant system parameters is discussed. It is shown that the dynamic responses of the caisson are significantly different under different types of breaking wave impact forces even when the amplitudes of impact forces are equal. The amplitude of dynamic response of the caisson is lower under single peak impact excitation than that under double peak impact or shock-damping oscillation impact excitation. Though the displacement of the caisson is large due to sliding, the rotation, the sliding force and the overturning moment of the caisson are significantly reduced.