Recovery of high purity silicon from SoG crystalline silicon cutting slurry waste

The composition and size distribution of cutting waste were characterized. The Si-rich powders were obtained from the cutting waste using a physical sedimentation process, and then further purified by removing impurity using acid leaching. The effects of process parameters such as acid leaching time, temperature and the ratio of solid to liquid on the purification efficiency were investigated, and the parameters were optimized. Afterwards, the high-purity Si ingot was obtained by melting the Si-rich powders in vacuum furnace. Finally, the high purity Si with 99.96%Si, 1.1×10^-6 boron （B）, and 4.0×10^-6 phosphorus （P） were obtained. The results indicate that it is feasible to extract high-purity Si, and further produce SoG-Si from the cutting slurry waste.

Preparation of SiC Porous Ceramics by Crystalline Silicon Cutting Waste

SiC porous ceramics were prepared at 1 400 ℃ for4 h with crystalline silicon cutting waste and activated carbon as main starting materials and NH4HCO3 as the pore-forming agent. Effects of NH4HCO3 additions( 0,20%,30%,40%,by mass) on the phase composition,microstructure,sintering properties,cold compressive strength and thermal shock resistance of as-prepared Si C porous ceramics were investigated. The results show that:( 1) addition of NH4HCO3 remarkably influences the apparent porosity and cold compressive strength of specimens. The apparent porosity achieves its maximum value( 63. 40%) when 40% NH4HCO3 is added,while the minimum cold compressive strength is 4. 77 MPa;( 2) the specimen with 40% NH4HCO3 has the best thermal shock resistance. The thermal cycling times between1 000 ℃ to room temperature reach 62;( 3) the addition of NH4HCO3 does not remarkably affect the phase composition of the specimens;( 4) the specimens include a large number of SiC particles and a small amount of SiC whiskers.

Effects of Pore-forming Agents on Properties of Silicon Carbide Porous Ceramics Prepared from Crystalline Silicon Cutting Waste

SiC powder was rapidly synthesized in an induction furnace with crystalline silicon cutting waste and active carbon as raw materials,and then SiC porous ceramics were prepared at 1600 t for 4 h with carbon embedded using the powder as raw material,the starch and the graphite as pore-forming agents.Effects of additions of different pore-forming agents on the phase composition,microstructures,physical properties,and cold crushing strength of the porous ceramics were investigated.The results show that the main crystalline phases of the synthetic powder areα-S iC(6H-SiC)andβ-SiC(3C-SiC).The phase composition of the porous ceramics includesα-S iC(6H-SiC),β-SiC(3C-SiC),FeSi,quartz and Si2N20.The apparent porosity and closed porosity of the porous ceramics prepared by adding starch are higher,and the cold compressive strength of the porous ceramics added with graphite is higher.As increasing the additions of the starch,the apparent porosity,closed porosity and linear shrinkage ratio of the porous ceramics increase,and the bulk density decreases correspondingly.When 20 mass%starch is added,the apparent porosity,closed porosity,linear shrinkage ratio and cold compressive strength are 57.05%,2.03%,5.10%and 10.20 MPa,respectively.

浅析“无废城市”与“Zero Waste”

2018年底,"无废城市"建设试点工作方案出台,由此开启了中国"无废城市"的建设进程。对"无废城市"提出的国际背景阐述,认识到"推进零废物"城市已成为全球的共识。通过对"零废弃"内涵和"零废弃"层级管理的了解,及纵观城市率先实施"零废弃"战略的原因和温哥华"2040零废弃"实践,提出中国"无废城市"建设目标与国际普遍采用的"零废弃"内涵的差异,中国若实现"零废弃"还需全社会的努力,任重道远。

Zero Waste and Conversion Efficiencies of Various Technologies for Disposal of Municipal Solid Waste

Zero waste is a philosophy and a design principle of dealing with our waste stream for the ~21st century. After reviewing the available information, the goal of zero waste from landfill is considered to be unachievable by using known and proven methods and ~approaches . The comparison of various technologies shows that the conversion efficiencies depend upon the type of system chosen for processing residual waste, and the best overall diversion rate of waste management system that can be achieved is about 71%. The maximum achievable overall diversion rate can be increased to approximate 92% if current environmental regulations to permit the routine use of the bottom ash or char for advanced thermal technologies.

Mathematical Model and Simulation of Cutting Layer Geometry in Orthogonal Turn⁃Milling with Zero Eccentricity

Orthogonal turn-milling is a high-efficiency and precision machining method.Its cutting layer directly affects chip formation,cutting forces,and chatter,and further affects tool life,machining quality,etc.We studied The cutting layer geometry(CLG)in orthogonal turn-milling with zero eccentricity(OTMZE)is studied to explore orthogonal turn-milling cutting layer formation process.OTMZE principles of motion and formation processes are analyzed statically without considering kinetic influences.Mathematical models of the entrance and exit angles,cutting thickness,and cutting depth are established.In addition,these models are validated experimentally and some influences of cutting parameters on the tool cutting layer are analyzed.The results show that OTMZE cutting layer formation can be divided into two stages,chip shapes are nearly consistent with the simulated CLGs,and the most influencial parameter in affecting the cutting layer is found to be the tool feed per revolation of workpiece fa,followed by the ratio of the tool and workpiece speedsλand the cutting depth ap.These models and results can provide theoretical guidance to clarify formation processes and quantitatively analyze changes in cutting layer geometry during OTMZE.In addition,they offer theoretical guidelines for cutting forces and chatter.

The Six Sigma Approach to Solid Waste Management and Minimization： Moving towards Zero Landfill Facilities

This article provides an overview of an eleven step solid waste analysis and minimization process that is based on the six sigma approach to problem solving that may be applied at a wide variety of organizations. The six sigma approach provides a holistic process that focuses on minimizing defects, in this case, eliminating waste disposed at landfills. As many organizations are moving towards ＂zero landfill＂ facilities, such a process is needed to aid in achieving these goals. The eleven step processes provides details on establishing goals, creating process flowcharts, conducting waste sorts, data collection, establishing baseline data, identifying improvement opportunities, cost justification, executing improvement plans and validating results. The article also includes a case study that applies that eleven step process. The goal of the article is to provide the audience with a structured process to evaluate and minimize solid waste generation based on cost justified improvement opportunities.

Solidification and utilization of water-based drill cuttings to prepare ceramsite proppant with low-density and high performance

Water-based drill cuttings(WBDC)and bauxite are used as raw materials to prepare proppants with low density and high performance.The effects of sintering temperature,sintering period,mixture ratios of materials,doping with iron oxide,and acid modification of WBDC on the properties of proppants are discussed.The proppant performance is evaluated according to the national standard SY/T5108-2014.The morphology of the proppant is analyzed using scanning electron microscopy(SEM).The crystal phase structure of the proppant is studied using X-ray diffraction(XRD).Thermal analysis of the proppant sintering process is performed using thermogravimetry(TG).Proppant Z-23 completely satisfied the SY/T5108-2014 standard.This study provides a new perspective for the resource utilization of water-based drill cuttings and preparation of low-density proppants.

Taper Angle Correction in Cutting of Complex Micro-mechanical Contours with Ultra-Short Pulse Laser

The objective of this work was to investigate the possibility of taper angle correction in cutting of complex micro-mechanical contours using a TruMicro ultra-short pulse laser in combination with the SCANLAB precSYS micro machining sub system. In a first step, the influence of the process parameters on the kerftaper angle of metallic alloys was systematically investigated without beam inclination. A set of base parameters was derived for the subsequent investigations. In a second step, the kerftaper angle was controlled by static beam inclination. In a third step, the same optics was used in its dynamic precession mode to fabricate micro-mechanical components of complex contours with perpendicular 0~ taper angles. It was found that taper angle adjustments of up to 7.5~ are possible with the used setup for cutting applications. Taper angle control is possible both in the static beam inclination mode and in the dynamic precession mode. The static mode could be interesting for contours with sharp inner radii and for achieving faster cutting times similar to results with fixed optics, but would require excellent synchronization of beam inclination and axis motion. The dynamic precession mode would allow an easier integration of the optics into a laser machine but will result in longer cutting times and limitations with respect to achievable inner radii.

Recovery of Tungsten and Cobalt from Wasted Tungsten Carbide

The collected tungsten carbide/cobalt scrapped waste typically contains approximately 90% tungsten carbide and 10% cobalt.A nitric method is used to extract tungsten and cobalt from tungsten-containing waste.The waste is first dissolved in nitric acid,which then makes cobalt soluble and becomes cobalt nitrate solution.The waste also oxidizes tungsten carbide to insoluble tungstenic acid precipitate.If tungsten carbide scraps are obtained from leftover of LCD glass cutting,after applying the same process as above,the remaining glass also needs to be separated from the tungstenic acid.XRF analysis shows that 93.8% of cobalt and 97.72% of tungsten can be obtained separately by this wet chemical method.By ICP analysis,no more tungsten ion remains after 2 h reaction in the cobalt recovery when 12 N of nitric acid is used for oxidation.The recovery materials obtained for tungsten are tungsten oxide and for cobalt a mixture of Co3O4 and CoO.

Design and development of large-scale in-situ PRACLAY heater test and horizontal high-level radioactive waste disposal gallery seal test in Belgian HADES

In Belgium,the Boom clay was selected as a potential host formation for the disposal of high-level radioactive waste（HLW）.To demonstrate the suitability of Boom clay for bearing thermal load induced by the HLW,a large-scale in-situ heater test,called PRACLAY heater test,will be conducted in the underground research laboratory（URL） in Mol.Owing to the limitations of the test（a short period of time compared with that considered in a real repository,different boundary conditions,etc.）,the test is designed to simulate,in a conservative way,the most critical state and phenomena that could occur in the host rock.The PRACLAY gallery was excavated at the end of 2007;the heating phase will begin in 2010 and will last for at least 10 years.The PRACLAY gallery itself leaves an opportunity to study the possibilities of sealing a disposal drift in Boom clay and testing the feasibility of hydraulic cut-off of any preferential pathway to the main access gallery through the excavation damage zone（EDZ） and the lining with a seal in a horizontal drift（horizontal seal）.Indeed,this is a generic problem for all deep geological disposal facilities for HLW.An annular seal made of compacted swelling bentonite will be installed in the front of the heated part of the PRACLAY gallery for these purposes.This paper provides detailed considerations on the thermo-hydro-mechanical（THM） boundary conditions for the design of the PRACLAY heater test and the seal test with the support of numerical calculations.It is believed that these important items considered in the PRACLAY heater test design also constitute key issues for the repository design.The outcome of the PRACLAY heater test will be an important milestone for the Belgian repository design.

Valorization of Solid Waste Recovery in an Institution of Higher Education

One of the biggest challenges for organizations, cities and countries is waste management. Currently, 1.3 million tons of solid wastes are generated in the cities and by 2025 it is estimated that this volume will increase up to 2.2 billion tons. Considering this, it is clear that strategies for the reduction of waste generation are needed. In order to achieve this arduous and critic task changes in education, culture and public policy are required and one of the strategies that emerge as one of the most effective is the “zero waste” programs. This paper shows the foundation of a zero waste program based on previous and successful experiences in institutions of higher education. It presents the characterization and quantification of waste, as well as the valorization of it and potential environmental and economic benefits of the implementation of this kind of programs in higher education institutions. Results show that reduction and valorization of waste generation is possible in academic sectors while other outcomes emerge, such as the generation of human capital for the implementation of this kind of programs in different sectors of society and, in that way, contribute in the transition towards sustainable development.

RESOURCE RECOVERY AND MATERIALS FLOW IN THE CITY Zero Waste and Sustainable Consumption as Paradigm in Urban Development

Beyond energy efficiency,there are now urgent challenges around the supply of resources,materials,food and water.After debating energy-efficiency for the last decade,the focus has shifted to include resource and material-efficiency.In this context,urban farming has emerged as a valid urban design strategy in Europe,where food is produced and consumed locally within city boundaries,turning disused sites into productive urban landscapes and community gardens.Agricultural activities allow for effective composting of organic waste,returning nutrients to the soil and improving biodiversity in the urban environment.Urban farming will help to feed the 9 billion by 2050(predicted population growth,UN-Habitat forecast 2009).This paper reports on best practice of urban design principles in regard to materials flow,material recovery,adaptive re-use of building elements and components(‘design for disassembly’;prefabrication of modular building components),and other relevant strategies to implement zero waste by avoiding waste creation,reducing harmful consumption and changing behaviour.The paper touches on two important issues in regard to the rapid depletion of the world’s natural resources:the construction sector and the education of architects and designers.The construction sector:Prefabricated multi-story timber buildings for inner-city living can set new benchmarks for minimizing construction wastage and for sustainable on-site assembly.Today,the construction and demolition(C&D)sector is one of the main producers of waste;it does not engage enough with waste minimization,waste avoidance and recycling.Education and research:It’s still unclear how best to introduce a holistic understanding of these challenges and to better teach practical and affordable solutions to architects,urban designers,industrial designers,and so on.One of the findings of this paper is that embedding‘zero-waste’requires strong industry leadership,new policies and effective education curricula,as well as raising awareness(education)and refocusing research agendas to bring about attitudinal change and the reduction of wasteful consumption.

Acceleration of floc-water separation and floc reduction with magnetic nanoparticles during demulsification of complex waste cutting emulsions

Waste cutting emulsions are difficult to treat efficiently owing to their complex composition and stable emulsified structure.As an important treatment method for emulsions,chemical demulsification is faced with challenges such as low flocs-water separation rates and high sludge production.Hence,in this study,Fe3O4 magnetic nanoparticles(MNPs)were used to enhance chemical demulsification performance for treating waste cutting emulsions under a magnetic field.The addition of MNPs significantly decreased the time required to attain sludge-water separation and sludge compression equilibrium,from 210 to 20 min.In addition,the volume percentage of sludge produced at the equilibrium state was reduced from 45% to 10%.This excellent flocculation-separation performance was stable over a pH range of 3-11.The magnetization of the flocculants and oil droplets to form a flocculant-MNP-oil droplet composite,and the magnetic transfer of the composite were two key processes that enhanced the separation of cutting emulsions.Specifically,the interactions among MNPs,flocculants,and oil droplets were important in the magnetization process,which was controlled by the structures and properties of the three components.Under the magnetic field,the magnetized flocculant-MNP-oil droplet composites were considerably accelerated and separated from water,and the sludge was simultaneously compressed.Thus,this study expands the applicability of magnetic separation techniques in the treatment of complex waste cutting emulsions.

Coupling magnetic particles with flocculants to enhance demulsification and separation of waste cutting emulsion for engineering applications

Magnetic particles were coupled with a flocculant to enhance the demulsification and separation of waste cutting emulsions.The optimal magnetic particle size and critical magnetic field conditions were investigated to achieve large-scale engineering application of magnetic demulsification separation for waste cutting emulsion treatment.The micro-scale magnetic particles were found to show comparable effects to nano-scale magnetic particles on enhancing the demulsification and separation of cutting emulsions,which are beneficial for broadening the selectivity of low-cost magnetic particles.The critical magnetic separation region was determined to be an area 40 mm from the magnetic field source.Compared to the flocculant demulsification,the magnetic demulsification separation exhibited a significant advantage in accelerating flocs-water separation by decreasing the separation time of flocs from 180-240 min to less than 15 min,compressing the flocs by reducing the floc volume ratio from 60%-90%to lower than 20%,and showing excellent adaptability to the variable properties of waste cutting emulsions.Coupled with the design of the magnetic disk separator,continuous demulsification separation of the waste cutting emulsion was achieved at 1.0 t/hr for at least 10 hr to obtain clear effluent with 81%chemical oxygen demand removal and 89%turbidity reduction.This study demonstrates the feasibility of applying magnetic demulsification separation to large-scale continuous treatment of waste emulsion.Moreover,it addresses the flocs-water separation problems that occur in practical flocculant demulsification engineering applications.

Formulation of a Net Zero Assessment System for Healthcare Facilities

The international efforts to limit climate change are increasing, that during the COP26 convention, reaching Net Zero Greenhouse Gas emissions became part of the global goals for many countries and entities. One of the sectors that holds the responsibility of addressing the impacts of climate change is the healthcare sector, and accordingly, it is also encouraged to take a leading role in maintaining its sustainability and be a role model for the other sectors. Additionally, the buildings sector, through the World Green Building council, has taken the initiative to launch the Net Zero Carbon Buildings Commitment for the sector. Based on these practices, the work presented aims to introduce and formulate an Approaching Net Zero assessment methodology to be integrated as part of the sustainability criteria and rating system for healthcare facilities in developing countries. The methodology planned is based on four different aspects which are: 1) Approaching Net Zero Energy, 2) Approaching Net Zero Wastewater, 3) Approaching Net Zero Solid Waste, and 4) Approaching Net Zero GHG emissions. The facility should have achieved a Green Building certification through any certification body, and then apply for the aspect on which it requires to be assessed. The assessment methodology follows a systematic approach, where a baseline year of normal operation is determined for existing facilities to act as a base of assessment, and normal design practices for new facilities Based on the assessment and proof of performance enhancement, the facility will either be awarded a basic certificate for achieving continuous savings, or additionally be awarded a best performance certificate compared to other facilities in the same category.

“无废城市”试点政策对企业绿色创新的影响

为推进固体废物治理改革,贯彻落实“双碳”目标及探索区域绿色发展路径,文章以2016—2021年我国试点城市内沪深上市公司为处理组,采用PSM-DID方法进行准自然实验检验。研究发现:相对于非试点地区,“无废城市”试点政策渐进提升了试点地区企业的绿色创新水平和质量;作用机制检验发现,政府环境关注度在试点政策与企业绿色创新之间具有部分中介作用;进一步引入三重差分模型进行异质性检验发现,该政策对工业企业绿色创新质量的提升效应更显著,对国有企业及知识产权保护力度较高地区企业的绿色创新水平和质量提升均更显著。文章为“十四五”期间“无废城市”试点政策的推广提供决策参考。

INTEGRATED DEMAND FORECASTING TO SUPPORT URBAN PLANNING OF LOW-CARBON PRECINCTS:THE WASTE SCENARIO

INTRODUCTION Waste is a symbol of inefficiency in modern society and represents misallocated resources.This paper outlines an ongoing interdisciplinary research project entitled‘Integrated ETWW demand forecasting and scenario planning for low-carbon precincts’and reports on first findings and a literature review.This large multi-stakeholder research project has been designed to develop a shared platform for integrated ETWW(energy,transport,waste,and water)planning in a low-carbon urban future,focusing on synergies and alternative approaches to urban planning.The aim of the project is to develop a holistic integrated software tool for demand forecasting and scenario evaluation for residential precincts covering the four domains(ETWW),using identified commonalities in data requirements and model formulation.The authors of this paper are overseeing the waste domain,while other researchers in the team have expertise in the remaining domains.

Performance comparison of zero-Schottky-barrier and doped contacts carbon nanotube transistors with strain applied

Atomistic quantum simulation is performed to compare the performance of zero-Schottky-barrier and doped source-drain contacts carbon nanotube field effect transistors(CNTFETs) with strain applied. The doped source-drain contact CNTFETs outperform the Schottky contact devices with and without strain applied. The off-state current in both types of contact is similar with and without strain applied. This is because both types of contact offer very similar potential barrier in off-state. However, the on-state current in doped contact devices is much higher due to better modulation of on-state potential profile, and its variation with strain is sensitive to the device contact type. The on/off current ratio and the inverse subthreshold slope are better with doped source-drain contact, and their variations with strain are relatively less sensitive to the device contact type. The channel transconductance and device switching performance are much better with doped source-drain contact, and their variations with strain are sensitive to device contact type.

我国“无废城市”建设进展与成效

文章从“无废城市”的建设背景、建设试点进展等方面分析,总结出创建“无废城市”试点的创新和经验,以供参考。