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外训“船舶结构”随堂DIY模型教学实践
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作者 张二 闵少松 +1 位作者 滑林 刘聪 《教育教学论坛》 2024年第16期105-108,共4页
以外训船舶与海洋工程专业基础通识课程“船舶结构”为研究对象,从学员成长及体系化教学的角度分析了课程教学目标。结合外训“船舶结构”课堂教学的特点与难点、外训学员教学实践的特点,提出基于构建主义的随堂DIY模型教学实践。参考BO... 以外训船舶与海洋工程专业基础通识课程“船舶结构”为研究对象,从学员成长及体系化教学的角度分析了课程教学目标。结合外训“船舶结构”课堂教学的特点与难点、外训学员教学实践的特点,提出基于构建主义的随堂DIY模型教学实践。参考BOPPPS教学法,提出在“船舶结构”DIY教学实践中采用OBPCA教学方法。选取典型的知识点,给出了可供参考的教学设计案例,以期为我国高校开展“船舶结构”教学改革提供参考。 展开更多
关键词 船舶结构 diy模型 教学实践
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水田动力底盘逆向建模与质心验证——基于Geomagic Design X
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作者 何剑飞 曾志浩 +5 位作者 郭梓游 李贵蓉 钟文能 钟顺 王在满 李庆 《农机化研究》 北大核心 2024年第10期248-253,共6页
针对目前农业机械仿真和优化模型精度不高的问题,提出了一种构建精确模型的逆向建模方法。应用光学扫描仪采集点云数据,基于Geomagic Design X处理点云数据并重构零部件模型,在SolidWorks中完成水田动力底盘的装配。以VP6D-CQ型水田动... 针对目前农业机械仿真和优化模型精度不高的问题,提出了一种构建精确模型的逆向建模方法。应用光学扫描仪采集点云数据,基于Geomagic Design X处理点云数据并重构零部件模型,在SolidWorks中完成水田动力底盘的装配。以VP6D-CQ型水田动力底盘为例,将测得的实际质心位置与所建的模型质心位置进行比较,并对提出的逆向建模方法进行了试验验证以及误差分析。结果表明:总质量、x坐标、y坐标、z坐标的误差值分别为4.55%、3.62%、2.23%、4.81%,误差值均在5%内。此方法可构建准确的三维模型,为后续仿真优化数据精确性奠定了基础,与传统的研发相比较,可缩短农业机械研发周期、降低设计成本。 展开更多
关键词 水田 动力底盘 逆向建模 质心验证 Geomagic design X 数字样机
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“纯天然化妆品DIY”课程思政教学研究
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作者 孙延芳 孙知新 《教育教学论坛》 2024年第23期157-160,共4页
大学课堂是用习近平新时代中国特色社会主义思想凝心铸魂的主营地,开展“全校通识课程”社会大课进行思政教学是高校落实立德树人根本任务的重要举措。立足国家强国战略对新时代人才需求,将思政教育融入“纯天然化妆品DIY”实践课堂,以... 大学课堂是用习近平新时代中国特色社会主义思想凝心铸魂的主营地,开展“全校通识课程”社会大课进行思政教学是高校落实立德树人根本任务的重要举措。立足国家强国战略对新时代人才需求,将思政教育融入“纯天然化妆品DIY”实践课堂,以“家国情怀、工匠精神、时代使命、国际传播和孝文化”为切入点,全面推进课程思政建设,挖掘通识课程思政内涵,实现通识教育课程“知识传授”与“思政引领”相统一,培根铸魂,启智润心,培养新时代创新引领性人才,从而推动高校通识课程思政教学高质量发展。 展开更多
关键词 纯天然化妆品diy 通识课程 思政教学
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App Designer辅助教学方法探索与实践——以软件无线电课程为例
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作者 向新 刘宇峰 +2 位作者 梁源 王瑞 何林远 《中国现代教育装备》 2024年第19期148-151,共4页
软件无线电作为通信学科的必修课程,具有承上启下的重要作用。因课程原理抽象、理论公式复杂,学员在学习过程存在理解掌握难、实践应用难等问题。通过对当前软件无线电教学过程中存在的不足与困难进行分析,提出利用MATLAB App Designer... 软件无线电作为通信学科的必修课程,具有承上启下的重要作用。因课程原理抽象、理论公式复杂,学员在学习过程存在理解掌握难、实践应用难等问题。通过对当前软件无线电教学过程中存在的不足与困难进行分析,提出利用MATLAB App Designer辅助课程教学,从教学准备、课堂互动、自主实验、反馈提升四个方面开展课程教学改革。实践表明,该方法对于提升学员的工程思维、系统思维具有显著效果,同时可以增强学员理论联系实际的能力。 展开更多
关键词 软件无线电 MATLAB App designer 教学方法改革 理实结合
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传统手工艺DIY活动现状分析
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作者 张海晨(文/图) 《中华手工》 2024年第4期102-106,共5页
传统手工技艺凝聚着中华民族深厚的文化内涵,曾在人民的物质生活和精神生活中发挥着重要作用,但因工业化生产的冲击而式微。本文以DIY活动的参与人群和活动条件为主要分析对象,结合以往部分DIY活动组织指导的实践经验,探讨传统手工艺DI... 传统手工技艺凝聚着中华民族深厚的文化内涵,曾在人民的物质生活和精神生活中发挥着重要作用,但因工业化生产的冲击而式微。本文以DIY活动的参与人群和活动条件为主要分析对象,结合以往部分DIY活动组织指导的实践经验,探讨传统手工艺DIY活动现状,以期为更有效促进传统手工艺传承提供思路。 展开更多
关键词 diy 参与人群 活动条件
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敦煌壁画动物形象在校园文化DIY产品的应用思考
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作者 王玉芳 冯美荣 《西部文艺研究》 2024年第2期107-111,共5页
敦煌文化延续近两千年,是世界现存规模最大、延续时间最长、内容最丰富、保存最完整的艺术宝库,是世界文明长河中的一颗璀璨明珠。在举国学习贯彻习近平文化思想的背景下,传承、弘扬敦煌艺术精神,引导学生在校园DIY体验中绘制敦煌艺术... 敦煌文化延续近两千年,是世界现存规模最大、延续时间最长、内容最丰富、保存最完整的艺术宝库,是世界文明长河中的一颗璀璨明珠。在举国学习贯彻习近平文化思想的背景下,传承、弘扬敦煌艺术精神,引导学生在校园DIY体验中绘制敦煌艺术元素的文化产品,激发他们传承和弘扬优秀传统文化的责任感和使命感,具有重要的学术价值和现实意义。 展开更多
关键词 敦煌艺术 动物形象 校园文化 diy
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Integration of uniform design and quantum-behaved particle swarm optimization to the robust design for a railway vehicle suspension system under different wheel conicities and wheel rolling radii 被引量:2
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作者 Yung-Chang Cheng Cheng-Kang Lee 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2017年第5期963-980,共18页
This paper proposes a systematic method, integrating the uniform design (UD) of experiments and quantum-behaved particle swarm optimization (QPSO), to solve the problem of a robust design for a railway vehicle suspens... This paper proposes a systematic method, integrating the uniform design (UD) of experiments and quantum-behaved particle swarm optimization (QPSO), to solve the problem of a robust design for a railway vehicle suspension system. Based on the new nonlinear creep model derived from combining Hertz contact theory, Kalker's linear theory and a heuristic nonlinear creep model, the modeling and dynamic analysis of a 24 degree-of-freedom railway vehicle system were investigated. The Lyapunov indirect method was used to examine the effects of suspension parameters, wheel conicities and wheel rolling radii on critical hunting speeds. Generally, the critical hunting speeds of a vehicle system resulting from worn wheels with different wheel rolling radii are lower than those of a vehicle system having original wheels without different wheel rolling radii. Because of worn wheels, the critical hunting speed of a running railway vehicle substantially declines over the long term. For safety reasons, it is necessary to design the suspension system parameters to increase the robustness of the system and decrease the sensitive of wheel noises. By applying UD and QPSO, the nominal-the-best signal-to-noise ratio of the system was increased from -48.17 to -34.05 dB. The rate of improvement was 29.31%. This study has demonstrated that the integration of UD and QPSO can successfully reveal the optimal solution of suspension parameters for solving the robust design problem of a railway vehicle suspension system. 展开更多
关键词 Speed-dependent nonlinear creep model Quantum-behaved particle swarm optimization Uniform design Wheel rolling radius Hunting stability
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神经示踪染料DiI影响溃疡性结肠炎小鼠背根神经节神经元电学特性
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作者 雒炜 刘永斌 +3 位作者 刘坤 刘允 高昕妍 乔海法 《中国疼痛医学杂志》 CAS CSCD 北大核心 2024年第5期331-340,共10页
目的:探究在神经示踪结合膜片钳全细胞记录的实验中,示踪染料DiI是否会对小鼠背根神经节(dorsal root ganglion,DRG)神经元兴奋性产生影响。方法:采用SPF级雄性C57BL/6J小鼠,经5%葡聚糖硫酸钠(dextran sulfate sodium,DSS)诱导溃疡性结... 目的:探究在神经示踪结合膜片钳全细胞记录的实验中,示踪染料DiI是否会对小鼠背根神经节(dorsal root ganglion,DRG)神经元兴奋性产生影响。方法:采用SPF级雄性C57BL/6J小鼠,经5%葡聚糖硫酸钠(dextran sulfate sodium,DSS)诱导溃疡性结肠炎(ulcerative colitis,UC)模型,在T12~L2皮节多点注射DiI逆向示踪躯体感觉神经元,分离全组织DRG并进行全细胞膜片钳记录。结果:HE染色结果显示模型诱导成功。膜片钳记录未经标记的小鼠DRG神经元,模型组小鼠膜电位兴奋性高于正常组小鼠。两组小鼠示踪后,正常示踪组和模型示踪组DiI+神经元兴奋性均低于本组DiI-神经元;与两未示踪组的神经元相比较,两示踪组的DiI-神经元兴奋性分别升高。结论:本实验结果明确了示踪剂DiI会降低DRG神经元的兴奋性,提示相关实验设计中应注意示踪剂的应用对神经元兴奋性的影响,以保证实验结果的可靠性。 展开更多
关键词 神经示踪 背根神经节 兴奋性 DII 膜片钳
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Alloy design for laser powder bed fusion additive manufacturing:a critical review 被引量:3
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作者 Zhuangzhuang Liu Qihang Zhou +4 位作者 Xiaokang Liang Xiebin Wang Guichuan Li Kim Vanmeensel Jianxin Xie 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第2期29-63,共35页
Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using exi... Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using existing alloys for laser powder bed fusion(L-PBF)AM have persisted.These challenges arise because commercial alloys are primarily designed for conventional casting or forging processes,overlooking the fast cooling rates,steep temperature gradients and multiple thermal cycles of L-PBF.To address this,there is an urgent need to develop novel alloys specifically tailored for L-PBF technologies.This review provides a comprehensive summary of the strategies employed in alloy design for L-PBF.It aims to guide future research on designing novel alloys dedicated to L-PBF instead of adapting existing alloys.The review begins by discussing the features of the L-PBF processes,focusing on rapid solidification and intrinsic heat treatment.Next,the printability of the four main existing alloys(Fe-,Ni-,Al-and Ti-based alloys)is critically assessed,with a comparison of their conventional weldability.It was found that the weldability criteria are not always applicable in estimating printability.Furthermore,the review presents recent advances in alloy development and associated strategies,categorizing them into crack mitigation-oriented,microstructure manipulation-oriented and machine learning-assisted approaches.Lastly,an outlook and suggestions are given to highlight the issues that need to be addressed in future work. 展开更多
关键词 laser powder bed fusion alloy design PRINTABILITY crack mitigation
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Web Layout Design of Large Cavity Structures Based on Topology Optimization 被引量:1
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作者 Xiaoqiao Yang Jialiang Sun Dongping Jin 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第3期2665-2689,共25页
Large cavity structures are widely employed in aerospace engineering, such as thin-walled cylinders, blades andwings. Enhancing performance of aerial vehicles while reducing manufacturing costs and fuel consumptionhas... Large cavity structures are widely employed in aerospace engineering, such as thin-walled cylinders, blades andwings. Enhancing performance of aerial vehicles while reducing manufacturing costs and fuel consumptionhas become a focal point for contemporary researchers. Therefore, this paper aims to investigate the topologyoptimization of large cavity structures as a means to enhance their performance, safety, and efficiency. By usingthe variable density method, lightweight design is achieved without compromising structural strength. Theoptimization model considers both concentrated and distributed loads, and utilizes techniques like sensitivityfiltering and projection to obtain a robust optimized configuration. The mechanical properties are checked bycomparing the stress distribution and displacement of the unoptimized and optimized structures under the sameload. The results confirm that the optimized structures exhibit improved mechanical properties, thus offering keyinsights for engineering lightweight, high-strength large cavity structures. 展开更多
关键词 Topology optimization lightweight design web layout design cavity structure
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Design Principles and Mechanistic Understandings of Non-Noble-Metal Bifunctional Electrocatalysts for Zinc-Air Batteries 被引量:2
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作者 Yunnan Gao Ling Liu +10 位作者 Yi Jiang Dexin Yu Xiaomei Zheng Jiayi Wang Jingwei Liu Dan Luo Yongguang Zhang Zhenjia Shi Xin Wang Ya‑Ping Deng Zhongwei Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期13-48,共36页
Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-... Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ZABs.Therefore,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic reaction.In this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this field.Then,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic engineering.We also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox reactions.Finally,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs. 展开更多
关键词 Zinc-air batteries Bifunctional electrocatalysts design principles Mechanistic understandings
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Accelerated design of high-performance Mg-Mn-based magnesium alloys based on novel bayesian optimization 被引量:2
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作者 Xiaoxi Mi Lili Dai +4 位作者 Xuerui Jing Jia She Bjørn Holmedal Aitao Tang Fusheng Pan 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第2期750-766,共17页
Magnesium(Mg),being the lightest structural metal,holds immense potential for widespread applications in various fields.The development of high-performance and cost-effective Mg alloys is crucial to further advancing ... Magnesium(Mg),being the lightest structural metal,holds immense potential for widespread applications in various fields.The development of high-performance and cost-effective Mg alloys is crucial to further advancing their commercial utilization.With the rapid advancement of machine learning(ML)technology in recent years,the“data-driven''approach for alloy design has provided new perspectives and opportunities for enhancing the performance of Mg alloys.This paper introduces a novel regression-based Bayesian optimization active learning model(RBOALM)for the development of high-performance Mg-Mn-based wrought alloys.RBOALM employs active learning to automatically explore optimal alloy compositions and process parameters within predefined ranges,facilitating the discovery of superior alloy combinations.This model further integrates pre-established regression models as surrogate functions in Bayesian optimization,significantly enhancing the precision of the design process.Leveraging RBOALM,several new high-performance alloys have been successfully designed and prepared.Notably,after mechanical property testing of the designed alloys,the Mg-2.1Zn-2.0Mn-0.5Sn-0.1Ca alloy demonstrates exceptional mechanical properties,including an ultimate tensile strength of 406 MPa,a yield strength of 287 MPa,and a 23%fracture elongation.Furthermore,the Mg-2.7Mn-0.5Al-0.1Ca alloy exhibits an ultimate tensile strength of 211 MPa,coupled with a remarkable 41%fracture elongation. 展开更多
关键词 Mg-Mn-based alloys HIGH-PERFORMANCE Alloy design Machine learning Bayesian optimization
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Inverse design of mechanical metamaterial achieving a prescribedconstitutive curve 被引量:1
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作者 Zongliang Du Tanghuai Bian +4 位作者 Xiaoqiang Ren Yibo Jia Shan Tang Tianchen Cui Xu Guo 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2024年第1期16-22,共7页
Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive relations.This is facilitated by switching between di... Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive relations.This is facilitated by switching between different patterns under deformation.However,the related inverse design problem is quite challenging,due to the lack of appropriate mathematical formulation and the convergence issue in the post-buckling analysis of intermediate designs.In this work,periodic unit cells are explicitly described by the moving morphable voids method and effectively analyzed by eliminating the degrees of freedom in void regions.Furthermore,by exploring the Pareto frontiers between error and cost,an inverse design formulation is proposed for unit cells.This formulation aims to achieve a prescribed constitutive curve and is validated through numerical examples and experimental results.The design approach presented here can be extended to the inverse design of other types of mechanical metamaterials with prescribed nonlinear effective properties. 展开更多
关键词 METAMATERIAL Pattern-transformation Constitutive curve Inverse design
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Machine learning for membrane design and discovery 被引量:1
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作者 Haoyu Yin Muzi Xu +4 位作者 Zhiyao Luo Xiaotian Bi Jiali Li Sui Zhang Xiaonan Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期54-70,共17页
Membrane technologies are becoming increasingly versatile and helpful today for sustainable development.Machine Learning(ML),an essential branch of artificial intelligence(AI),has substantially impacted the research an... Membrane technologies are becoming increasingly versatile and helpful today for sustainable development.Machine Learning(ML),an essential branch of artificial intelligence(AI),has substantially impacted the research and development norm of new materials for energy and environment.This review provides an overview and perspectives on ML methodologies and their applications in membrane design and dis-covery.A brief overview of membrane technologies isfirst provided with the current bottlenecks and potential solutions.Through an appli-cations-based perspective of AI-aided membrane design and discovery,we further show how ML strategies are applied to the membrane discovery cycle(including membrane material design,membrane application,membrane process design,and knowledge extraction),in various membrane systems,ranging from gas,liquid,and fuel cell separation membranes.Furthermore,the best practices of integrating ML methods and specific application targets in membrane design and discovery are presented with an ideal paradigm proposed.The challenges to be addressed and prospects of AI applications in membrane discovery are also highlighted in the end. 展开更多
关键词 Machine learning Membranes AI for Membrane DATA-DRIVEN design
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Rationally designing electrolyte additives for highly improving cyclability of LiNi_(0.5)Mn_(1.5)O_(4)/Graphite cells 被引量:2
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作者 Zhiyong Xia Kuan Zhou +8 位作者 Xiaoyan Lin Zhangyating Xie Qiurong Chen Xiaoqing Li Jie Cai Suli Li Hai Wang Mengqing Xu Weishan Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期266-275,共10页
High voltage is necessary for high energy lithium-ion batteries but difficult to achieve because of the highly deteriorated cyclability of the batteries.A novel strategy is developed to extend cyclability of a high vo... High voltage is necessary for high energy lithium-ion batteries but difficult to achieve because of the highly deteriorated cyclability of the batteries.A novel strategy is developed to extend cyclability of a high voltage lithium-ion battery,LiNi_(0.5)Mn_(1.5)O_(4)/Graphite(LNMO/Graphite)cell,which emphasizes a rational design of an electrolyte additive that can effectively construct protective interphases on anode and cathode and highly eliminate the effect of hydrogen fluoride(HF).5-Trifluoromethylpyridine-trime thyl lithium borate(LTFMP-TMB),is synthesized,featuring with multi-functionalities.Its anion TFMPTMB-tends to be enriched on cathode and can be preferentially oxidized yielding TMB and radical TFMP-.Both TMB and radical TFMP can combine HF and thus eliminate the detrimental effect of HF on cathode,while the TMB dragged on cathode thus takes a preferential oxidation and constructs a protective cathode interphase.On the other hand,LTFMP-TMB is preferentially reduced on anode and constructs a protective anode interphase.Consequently,a small amount of LTFMP-TMB(0.2%)in 1.0 M LiPF6in EC/DEC/EMC(3/2/5,wt%)results in a highly improved cyclability of LNMO/Graphite cell,with the capacity retention enhanced from 52%to 80%after 150 cycles at 0.5 C between 3.5 and 4.8 V.The as-developed strategy provides a model of designing electrolyte additives for improving cyclability of high voltage batteries. 展开更多
关键词 Electrolyte additive design and synthesis CYCLABILITY High voltage batteries Cathode and anode interphases
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Deep Insight of Design,Mechanism,and Cancer Theranostic Strategy of Nanozymes 被引量:1
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作者 Lu Yang Shuming Dong +6 位作者 Shili Gai Dan Yang He Ding Lili Feng Guixin Yang Ziaur Rehman Piaoping Yang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期165-217,共53页
Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction... Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities. 展开更多
关键词 Nanozymes Classification Prediction and design Catalytic mechanism Tumor theranostics
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基于DIY耳机的注射模数字化设计
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作者 张延杰 张荧 《模具制造》 2024年第8期207-209,共3页
注射模是制造业中不可或缺的一部分,从技术发展层面来看,为生产制造出更精密化、自动化、智能化的模具,将会不断引入新技术、新工艺和新设备,以提高生产效率和质量,减少成本和浪费。目前,数字化设计技术、智能制造技术等已经成为塑料模... 注射模是制造业中不可或缺的一部分,从技术发展层面来看,为生产制造出更精密化、自动化、智能化的模具,将会不断引入新技术、新工艺和新设备,以提高生产效率和质量,减少成本和浪费。目前,数字化设计技术、智能制造技术等已经成为塑料模具生产过程中的重要技术和手段。以DIY耳机为例,介绍了利用MoldFlow、UG等软件对塑件进行三维产品设计、模流分析、模具数字化设计全过程。根据分析结果进行模具优化设计,最终完成耳机上壳注射模设计。 展开更多
关键词 注射模 数字化设计 MOLDFLOW UG
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Electrolyte Design for Low‑Temperature Li‑Metal Batteries:Challenges and Prospects 被引量:1
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作者 Siyu Sun Kehan Wang +3 位作者 Zhanglian Hong Mingjia Zhi Kai Zhang Jijian Xu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期365-382,共18页
Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements ... Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries. 展开更多
关键词 Solid electrolyte interphase Li metal Low temperature Electrolyte design BATTERIES
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Design,test,and verification of in-situ condition preserved coring and analysis system in lunar-based simulation environment 被引量:1
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作者 Haichun Hao Mingzhong Gao +10 位作者 Yan Wu Zheng Gao Yongcheng Li Xuemin Zhou Peng Chu Xuan Wang Jiahua Li Lang Zhou Jie Song Tianxiang Ao Yikun Yang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1259-1272,共14页
The lunar surface and its deep layers contain abundant resources and valuable information resources,the exploration and exploitation of which are important for the sustainable development of the human economy and soci... The lunar surface and its deep layers contain abundant resources and valuable information resources,the exploration and exploitation of which are important for the sustainable development of the human economy and society.Technological exploration and research in the field of deep space science,especially lunar-based exploration,is a scientific strategy that has been pursued in China and worldwide.Drilling and sampling are key to accurate exploration of the desirable characteristics of deep lunar resources.In this study,an in-situ condition preserved coring(ICP-Coring)and analysis system,which can be used to test drilling tools and develop effective sampling strategies,was designed.The key features of the system include:(1)capability to replicate the extreme temperature fluctuations of the lunar environment(-185 to 200℃)with intelligent temperature control;(2)ability to maintain a vacuum environment at a scale of 10^(-3) Pa,both under unloaded conditions within Ф580 mm×1000 mm test chamber,and under loaded conditions using Ф400 mm×800 mm lunar rock simulant;(3)application of axial pressures up to 4 MPa and confining pressures up to 3.5 MPa;(4)sample rotation at any angle with a maximum sampling length of 800 mm;and(5)multiple modes of rotary-percussive drilling,controlled by penetration speed and weight on bit(WOB).Experimental studies on the drilling characteristics in the lunar rock simulant-loaded state under different drill bit-percussive-vacuum environment configurations were conducted.The results show that the outgassing rate of the lunar soil simulant is greater than that of the lunar rock simulant and that a low-temperature environment contributes to a reduced vacuum of the lunar-based simulated environment.The rotary-percussive drilling method effectively shortens the sampling time.With increasing sampling depth,the temperature rise of the drilling tools tends to rapidly increase,followed by slow growth or steady fluctuations.The temperature rise energy accumulation of the drill bits under vacuum is more significant than that under atmospheric pressure,approximately 1.47 times higher.The real-time monitored drilling pressure,penetration speed and rotary torque during drilling serve as parameters for discriminating the drilling status.The results of this research can provide a scientific basis for returning samples from lunar rock in extreme lunar-based environments. 展开更多
关键词 Lunar-based Large temperature difference Vacuum Drilling and coring System design
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Molecular Mechanism and Molecular Design of Lubricating Oil Antioxidants 被引量:1
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作者 Su Shuo Long Jun +2 位作者 Duan Qinghua Zhou Han Zhao Yi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期135-145,共11页
To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular me... To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular mechanism of the antioxidant reaction of hindered phenol,diphenylamine,and alkyl sulfide are studied via molecular simulations.Calculation results show that the strong electron-donating ability and high hydrogen-donating activity of the antioxidant molecule and the low hydrogen-abstracting activity of free radicals formed after dehydrogenation are the internal molecular causes of the shielding of phenol and diphenylamine from scavenging peroxy free radicals,and the strong electron-donating ability is the internal molecular cause of the high activity of thioether in decomposing alkyl hydrogen peroxide.Based on this antioxidant molecular mechanism,a molecular design rule of antioxidant is proposed,namely“high EHOMO,large Q(S),low bond dissociation energy BDE(O—H)and BDE(N—H)”.Two new antioxidants,PAS-I and PAS-II,are designed and prepared by chemical bonding of hindered phenol,diphenylamine,and sulfur atoms.Experimental results show that these antioxidants both have excellent antioxidant effects in lubricating oil,and that PAS-II is the superior antioxidant,consistent with theoretical predictions. 展开更多
关键词 lubricating oil ANTIOXIDANT molecular mechanism molecular design antioxidant performance
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