The severe environmental problems and the demand for energy urgently require electrocatalysis to replace Haber-Bosch for the nitrogen reduction reaction(NRR).The descriptors and important properties of single-atom and...The severe environmental problems and the demand for energy urgently require electrocatalysis to replace Haber-Bosch for the nitrogen reduction reaction(NRR).The descriptors and important properties of single-atom and homonuclear double-atom catalysts have been preliminarily explored,but the relationship between the inherent properties and catalytic activity of heteronuclear double-atom catalysts with better performance remains unclear.Therefore,it is very significant to explore the prediction expressions of catalytic activity of heteronuclear double-atom catalysts based on their inherent properties and find the rule for selecting catalytic centers.Herein,by summarizing the free energy for the key steps of NRR on 55 catalysts calculated through the first-principle,the expressions of predicting the free energy and the corresponding descriptors are deduced by the machine learning,and the strategy for selecting the appropriate catalytic center is proposed.The selection strategy for the central atom of heteronuclear double-atom catalysts is that the atomic number of central B atom should be between group VB and VIIIB,and the electron difference between central A atom and B atom should be large enough,and the selectivity of NRR or hydrogen evolution reaction(HER)could be calculated through the prediction formula.Moreover,five catalysts are screened to have low limiting potential and excellent selectivity,and are further analyzed by electron transfer.This work explores the relationship between the inherent properties of heteronuclear double-atom catalysts and the catalytic activity,and puts forward the rules for selecting the heteronuclear double-atom catalytic center,which has guiding significance for the experiment.展开更多
The liberty of expression is one of the most important values in the human society, and a tolerant, unconstrained social atmosphere can provide personal development with a healthy and harmonious environment. Since the...The liberty of expression is one of the most important values in the human society, and a tolerant, unconstrained social atmosphere can provide personal development with a healthy and harmonious environment. Since the modern times, the liberty of expression has been gradually deemed by academic circles and all walks of life as a basic human right, and also has been fixed as a basic right of citizens through the legal form. The purpose of this paper is to clearly analyze the kernel and value of the liberty of expression through a historical review, so as to specifically sort out the development course of the liberty of expression and also excavate its implied meanings. In addition, the embodiment of the liberty of expression in both theory and practice since the modern times is analyzed around the limit theory of the liberty of expression, and then the opinions of the author are drawn up. Thus, some new ideas and views are provided for the future development of the liberty of expression from a new perspective.展开更多
Based on the Prototype Theory,the prototypical feature of advertisement is found to be the combination of three language functions:the informative function,the expressive function,and the vocative function.The adverti...Based on the Prototype Theory,the prototypical feature of advertisement is found to be the combination of three language functions:the informative function,the expressive function,and the vocative function.The advertisement translation means the adjustment of the informative function and the expressive function according to the differences between languages or cultures in order to maximize the vocative function.The faithful translation is the closest to the prototype of the source text but not necessarily the best translation.展开更多
In this paper, the Martin-Hou equation of state is derived by using a power series representation of radial distribution function and an analytic representation of multi-section potential based on the Barker-Henderso...In this paper, the Martin-Hou equation of state is derived by using a power series representation of radial distribution function and an analytic representation of multi-section potential based on the Barker-Henderson hard-particle perturbation theory including high-order terms. In the derivation, a theoretical form of Martin-Hou equation was obtained. It had a similar form and the same capability to predict P-V-T properties as the Martin-Hou equation and no additional data were required for evaluating the constants. The characteristic constants of the theoretical expression have certain relationships with the molecular parameters.展开更多
Theory is necessary to science and science grounds legitimate and essential practice. This is true for Nursing as a discipline of knowledge and a practicing profession. Nevertheless, should all science or research wit...Theory is necessary to science and science grounds legitimate and essential practice. This is true for Nursing as a discipline of knowledge and a practicing profession. Nevertheless, should all science or research within a scientific field be focused on theoretical development and testing? Currently, various nursing theories exist to describe and explain the phenomena of nursing. Often, the development of nursing theory is in response to advancing ontologies and epistemologies of nursing. The advent of technology is one of these advances challenging the professional practice of nursing. How will nursing practice be made visible and realistic in the face of traditional nursing care practice? Nursing practice processes, derived from theories of nursing, provide opportunities for demonstrating practice grounded in the science of nursing. The purpose of this article is to describe the development of the emergent theory of Aesthetic Nursing Practice, focus on illuminating caring for person through the process of encountering, co-creating caring relationships, and meaningful engaging between the nurse and nursed through caring encounters occurring in caring situations. Five assumptions and a model of practice are described. As a contemporary theory of Nursing, it describes caring for persons who remain wholes and enhance their well-being.展开更多
Emotion Model is the basis of facial expression recognition system. The constructed emotional model should not only match facial expressions with emotions, but also reflect the location relationship between different ...Emotion Model is the basis of facial expression recognition system. The constructed emotional model should not only match facial expressions with emotions, but also reflect the location relationship between different emotions. In this way, it is easy to understand the current emotion of an individual through the analysis of the acquired facial expression information. This paper constructs an improved three-dimensional model for emotion based on fuzzy theory, which corresponds to the facial features to emotions based on the basic emotions proposed by Ekman. What’s more, the three-dimensional model for motion is able to divide every emotion into three different groups which can show the positional relationship visually and quantitatively and at the same time determine the degree of emotion based on fuzzy theory.展开更多
Language is a special social phenomenon and is always on the changing process with the development of society. During the evolving process of language, new language varieties will continuously emerge due to the change...Language is a special social phenomenon and is always on the changing process with the development of society. During the evolving process of language, new language varieties will continuously emerge due to the changes of some social and cultural factors. Cyber language is universally accepted as one type of the social language varieties. Basically, cyber language can be treated as a complex adaptive system which is influenced by the interaction between users’ cognition, social culture and the surrounding environments. Thus it is safe to say that cyber language is always undergoing a dynamic evolving process. With the usage-based language model as the theoretical foundation, this paper proposes a Complex Adaptive System (CAS) approach to analyze the expression of Appreciation to explore the complex, dynamic and nonlinear development of cyber language from the angle of meaning construction, grammaticalization and functional adaption respectively. It is found that the expression of Appreciation is experiencing adaptively a semantic connotations development and a process of grammatical functions expansion as well. This paper suggests that the emergence and development of cyber language is a novel and trendy social language phenomenon. Network language can achieve its process and evolution under the huge impact of social changes and social promotions. When faced with the changing surroundings, cyber language itself enjoys a timely adaption and responsive development to keep up with the new environments, which reflects the basic principle of language development, namely, language changes with the development of society.展开更多
基金support by National Natural Science Foundation of China(61202354,51507084)Nanjing University of Post and Telecommunications Science Foundation(NUPTSF)(NT214203)
基金supports by the National Natural Science Foundation of China(NSFC,52271113)the Natural Science Foundation of Shaanxi Province,China(2020JM 218)+1 种基金the Fundamental Research Funds for the Central Universities(CHD300102311405)HPC platform,Xi’an Jiaotong University。
文摘The severe environmental problems and the demand for energy urgently require electrocatalysis to replace Haber-Bosch for the nitrogen reduction reaction(NRR).The descriptors and important properties of single-atom and homonuclear double-atom catalysts have been preliminarily explored,but the relationship between the inherent properties and catalytic activity of heteronuclear double-atom catalysts with better performance remains unclear.Therefore,it is very significant to explore the prediction expressions of catalytic activity of heteronuclear double-atom catalysts based on their inherent properties and find the rule for selecting catalytic centers.Herein,by summarizing the free energy for the key steps of NRR on 55 catalysts calculated through the first-principle,the expressions of predicting the free energy and the corresponding descriptors are deduced by the machine learning,and the strategy for selecting the appropriate catalytic center is proposed.The selection strategy for the central atom of heteronuclear double-atom catalysts is that the atomic number of central B atom should be between group VB and VIIIB,and the electron difference between central A atom and B atom should be large enough,and the selectivity of NRR or hydrogen evolution reaction(HER)could be calculated through the prediction formula.Moreover,five catalysts are screened to have low limiting potential and excellent selectivity,and are further analyzed by electron transfer.This work explores the relationship between the inherent properties of heteronuclear double-atom catalysts and the catalytic activity,and puts forward the rules for selecting the heteronuclear double-atom catalytic center,which has guiding significance for the experiment.
文摘The liberty of expression is one of the most important values in the human society, and a tolerant, unconstrained social atmosphere can provide personal development with a healthy and harmonious environment. Since the modern times, the liberty of expression has been gradually deemed by academic circles and all walks of life as a basic human right, and also has been fixed as a basic right of citizens through the legal form. The purpose of this paper is to clearly analyze the kernel and value of the liberty of expression through a historical review, so as to specifically sort out the development course of the liberty of expression and also excavate its implied meanings. In addition, the embodiment of the liberty of expression in both theory and practice since the modern times is analyzed around the limit theory of the liberty of expression, and then the opinions of the author are drawn up. Thus, some new ideas and views are provided for the future development of the liberty of expression from a new perspective.
文摘Based on the Prototype Theory,the prototypical feature of advertisement is found to be the combination of three language functions:the informative function,the expressive function,and the vocative function.The advertisement translation means the adjustment of the informative function and the expressive function according to the differences between languages or cultures in order to maximize the vocative function.The faithful translation is the closest to the prototype of the source text but not necessarily the best translation.
基金Zhejiang Provincial Natural Science Foundation of China!(No. 298013)
文摘In this paper, the Martin-Hou equation of state is derived by using a power series representation of radial distribution function and an analytic representation of multi-section potential based on the Barker-Henderson hard-particle perturbation theory including high-order terms. In the derivation, a theoretical form of Martin-Hou equation was obtained. It had a similar form and the same capability to predict P-V-T properties as the Martin-Hou equation and no additional data were required for evaluating the constants. The characteristic constants of the theoretical expression have certain relationships with the molecular parameters.
文摘Theory is necessary to science and science grounds legitimate and essential practice. This is true for Nursing as a discipline of knowledge and a practicing profession. Nevertheless, should all science or research within a scientific field be focused on theoretical development and testing? Currently, various nursing theories exist to describe and explain the phenomena of nursing. Often, the development of nursing theory is in response to advancing ontologies and epistemologies of nursing. The advent of technology is one of these advances challenging the professional practice of nursing. How will nursing practice be made visible and realistic in the face of traditional nursing care practice? Nursing practice processes, derived from theories of nursing, provide opportunities for demonstrating practice grounded in the science of nursing. The purpose of this article is to describe the development of the emergent theory of Aesthetic Nursing Practice, focus on illuminating caring for person through the process of encountering, co-creating caring relationships, and meaningful engaging between the nurse and nursed through caring encounters occurring in caring situations. Five assumptions and a model of practice are described. As a contemporary theory of Nursing, it describes caring for persons who remain wholes and enhance their well-being.
文摘Emotion Model is the basis of facial expression recognition system. The constructed emotional model should not only match facial expressions with emotions, but also reflect the location relationship between different emotions. In this way, it is easy to understand the current emotion of an individual through the analysis of the acquired facial expression information. This paper constructs an improved three-dimensional model for emotion based on fuzzy theory, which corresponds to the facial features to emotions based on the basic emotions proposed by Ekman. What’s more, the three-dimensional model for motion is able to divide every emotion into three different groups which can show the positional relationship visually and quantitatively and at the same time determine the degree of emotion based on fuzzy theory.
文摘Language is a special social phenomenon and is always on the changing process with the development of society. During the evolving process of language, new language varieties will continuously emerge due to the changes of some social and cultural factors. Cyber language is universally accepted as one type of the social language varieties. Basically, cyber language can be treated as a complex adaptive system which is influenced by the interaction between users’ cognition, social culture and the surrounding environments. Thus it is safe to say that cyber language is always undergoing a dynamic evolving process. With the usage-based language model as the theoretical foundation, this paper proposes a Complex Adaptive System (CAS) approach to analyze the expression of Appreciation to explore the complex, dynamic and nonlinear development of cyber language from the angle of meaning construction, grammaticalization and functional adaption respectively. It is found that the expression of Appreciation is experiencing adaptively a semantic connotations development and a process of grammatical functions expansion as well. This paper suggests that the emergence and development of cyber language is a novel and trendy social language phenomenon. Network language can achieve its process and evolution under the huge impact of social changes and social promotions. When faced with the changing surroundings, cyber language itself enjoys a timely adaption and responsive development to keep up with the new environments, which reflects the basic principle of language development, namely, language changes with the development of society.