Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonetheless,the intricate energy storage mechanisms in aqueous electrolytes place stringent require-ments on the host materials.Prussian blue analogs(PBAs),with their open three-dimensional framework and facile synthesis,stand out as leading candidates for aqueous energy storage.However,PBAs possess a swift capacity fade and limited cycle longevity,for their structural integrity is compromised by the pronounced dis-solution of transition metal(TM)ions in the aqueous milieu.This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs.The dissolution mechanisms of TM ions in PBAs,informed by their structural attributes and redox processes,are thoroughly examined.Moreover,this study delves into innovative design tactics to alleviate the dissolution issue of TM ions.In conclusion,the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries.

Transitions of Normal Universities and Strategies of Talents Cultivation

Transitions of normal universities in our country are inexorable trends with the development of the times. In this process, normal universities should actively reform models of talents cultivation, establish teachers＇ profession with distinguishing features, construct new strategies of talents cultivation so as to improve all-round capacities of normal universities in running schools.

Productive functional evolution of rural settlements:analysis of livelihood strategy and land use transition in eastern China

In China, rural settlements are usually multifunctional complex of natural societies and they also play important productive function. This study explored the spatiotemporal evolution of the productive function of three rural settlements, i.e.,Hetaoyuan, Dawengshan, and Gaoqiao, in the Yimeng Mountain in Shandong province of eastern China.Residents lived in this three types of rural settlements were all involved in agricultural production(i.e., grain threshing, drying and storage), which had remained dominant in Hetaoyuan. Dawengshan became an industrial-oriented settlement, while Gaoqiao became a commercial-oriented settlement. This evolution was reflected in the livelihood strategy changes of rural households and the transition of rural settlements changes. The choice of livelihood strategy was affected by the livelihood assets and policies, which resulted in the spatiotemporal evolution of the productive function of rural settlements. This study can provide references for the implementation and adjustment of rural residential land consolidation policies and the improvement of production and the quality of rural life in future.

Application of Variable Strategies in the Low-cost and Energy-saving Rural Residences in Transitional Areas

Changeful and complex rural family structure and climatic features of transitional areas in China make the application of variable strategy in energy-saving rural residence designs possible.Aiming at the low cost,several effective and reasonable variable strategies were proposed for the design of interior spaces,main bedroom,sunshine room,staircase,west wall,door and window design to satisfy changing structure of a family during different periods and their different thermo-technical requirements in winter and summer.In this way,thermal comfort of rural indoor spaces will be improved,more energy saved,useful experience and thoughts provided for the energy-saving residence design in cold regions and regions hot in summer and cold in winter.

“Transition States” Testing America's Global Strategy

Elexible variety has all along been a hallmark of America’s global strategy withdifferentiated treatment for specific nations. In the new century, Washingtondivides the major world forces into four categories in light of a comprehensive crite-rion of whether they have been fused into the international system, are going to-ward democracy or benefit world stability. They include: insiders or allies (Europeand Japan), marginalized ones (some underdeveloped African nations), outsidersor "rogues" (Iraq, North Korea) and finally, travelers on the way or "transitionstates". Interpretations by U.S. strategic reports define the "transition states"

Strategies of Transition to IPv6

The paper briefly describes the necessity of introducing IPv6 into networks and the fact that IPv4 and IPv6 will coexist in operators' networks for a long time. It also introduces Dual Stack, Tunneling and Translation technologies for the transition from IPv4 to IPv6 and their coexistence. Moreover, it makes a brief analysis of transition strategies of operators' networks to IPv6 networks.

Design Strategy of Highway Speed Transition Section

In this paper,combined with the relevant speed theory and characteristics of the law,the current highway speed transition design problems are studied and analyzed.In the process of specific analysis,mainly combined with the characteristics of different types of highway speed changes and road section design requirements,this paper studies and analyzes the design methods of different types of highway speed transition section.And on this basis,according to the design principles and requirements of highway operation speed transition section,the paper summarizes the matters needing attention in the design of highway operation speed transition section,in order to provide certain reference value for relevant personnel.

Transition from Metastablity to Instability in Dynamics for the Precipitation of δ'(Al_3Li)

A computer simulation study on dynamics for the precipitation of δ'(Al_3Li) ordered particles from a disor- dered matrix (α) in binary Al-Li alloys is performed using the microscopic Langevin equation. A unique precipitation mechanism is found near the ordering spinodal line. Different from the classical nucleation mechanism in the me- tastable region and the congruent ordering followed by spinodal decomposition in the instable region, a nonstoichi- ometric single ordered phase with composition fluctuations is formed by non-classical nucleation, and this ordered phase decomposes spinodally. It can be concluded that the precipitation dynamics of δ' phase from metastability to instability is gradual, and no sharp transition occurs near the mean-field spinodal line as the mean-field theory pre- dicts.

Estimation method for a skip-stop operation strategy for urban rail transit in China

The skip-stop operation strategy （SOS） is rarely applied to Chinese urban rail transit networks because it is a simple scheme and a less universally popular transportation service. However, the SOS has performance advantages, in that the total trip time can be reduced depending on the number of skipped stations, crowds of passengers can be rapidly evacuated at congested stations in peak periods, and the cost to transit companies is reduced. There is a contradiction between reducing the trip time under the SOS and increasing the passengers＇ waiting times under an all-stop scheme. Given this situation, the three objectives of our study were to minimize the waiting and trip times of all passengers and the travel times of trains. A comprehensive estimation model is presented for the SOS. The mechanism through which the trip time for all passengers is affected by the SOS is analyzed in detail. A 0-I integer programming formulation is established for the three objectives, and is solved using a tabu search algorithm. Finally, an example is presented to demonstrate that the estimation method for the SOS is capable of optimizing the timetable and operation schemes for a Chinese urban rail transit network.

Engineering transition metal-based nanomaterials for high-performance electrocatalysis

Transition metal(TM)based electrocatalysts attract increasing attention in energy conversion reactions,and current effects focus on material engineering strategies to tailor physicochemical properties of TM based electrocatalysts for improved performance.This review provides a summary about the recent advances of engineering TM based nanomaterials for electrocatalytic reactions,which include hydrogen evolution reaction(HER),oxygen evolution reaction(OER),CO2 reduction reaction(CO2RR),and nitrate reduction reaction(NO3RR).We highlight four engineering strategies,namely,size engineering,facet engineering,composition engineering,and crystal structure engineering for TM based electrocatalysts,and pay a special emphasis on exploring the relationship between their physicochemical properties and catalytic activities.We outline the opportunities in this research field,in particular,the strategy of rationally combining in-situ and operando techniques and theoretical predication to design efficient electrocatalysts.Finally,issues that deserve attention and consideration for practical applications are discussed.

Boundedness and liveness enforcement for labeled Petri nets using transition priority

This paper deals with the supervisory control problem of discrete event systems modeled by labeled Petri nets. The system is originally unbounded. First, the solvability of the problem is confirmed. A necessary condition is given and proven for the existence of a feasible priority-based controller based on the notions of liveness and transition invariants. Next, a cyclic behavior graph is constructed, which shows the reachable markings that guarantee the maximum liveness of the system within a given bound vector. Finally, an on-line control strategy is proposed to enforce boundedness and liveness to the given system by appending priority relations to transitions. The dynamic priority relation changes flexibly according to the current state of the system and enforces the system evolving in a bounded and live manner. In addition, numerical examples are studied to verify the validity of the proposed approach that remains the structure of the plant net and is efficient for on-line control.

Design Strategy of Underground Space of Urban Rail Transit Complex Based on Integration Concept

With the accelerated development and utilization of urban underground space,the underground space design of complex based on rail transit has attracted much attention.By sorting out the integration concept and constructing the logical framework of integrated design,the integrated design strategy is proposed from the aspects of function,transportation,space and environment on the urban scale,and the evaluation points of integrated design effect are put forward from the aspects of accessibility,coordination,openness and symbolism.

China＇s Industrial Transition and Upgrade to Sustainable Growth Model

China＇s transition to sustainable growth model in the coming years depends on the ability of its industrial sector to adapt and innovate. In the llth Five-Year Plan period, China entered the intermediate stage of industrialization and crossed the threshold to become a middle-income country. China＇s current industrial structure, therefore, which is still characteristic of early-stage industrialization, must transition to support intermediate and advanced industrialization. Although resource constraints will pose certain hurdles for this transition, the pressure of these constraints will ultimately serve to catalyze, rather than impede, sustainable industrial growth. Furthermore, industrial transition and upgrade will mean not only changes for the nation＇s industrial structure as a whole but also rethinking the strategic possibilities and direction of industry at the enterprise level. The key to success rests on China＇s ability to improve indigenous development and boost competitive advantage in international markets through the use of new, advanced technologies.

Advances in doping strategies for sodium transition metal oxides cathodes:A review

The electrochemistry of cathode materials for sodium-ion batteries differs significantly from lithium-ion batteries and offers distinct advantages.Overall,the progress of commercializing sodium-ion batteries is currently impeded by the inherent inefficiencies exhibited by these cathode materials,which include insufficient conductivity,slow kinetics,and substantial volume changes throughout the process of intercalation and deintercalation cycles.Consequently,numerous methodologies have been utilized to tackle these challenges,encompassing structural modulation,surface modification,and elemental doping.This paper aims to highlight fundamental principles and strategies for the development of sodium transition metal oxide cathodes.Specifically,it emphasizes the role of various elemental doping techniques in initiating anionic redox reactions,improving cathode stability,and enhancing the operational voltage of these cathodes,aiming to provide readers with novel perspectives on the design of sodium metal oxide cathodes through the doping approach,as well as address the current obstacles that can be overcome/alleviated through these dopant strategies.

Alloy strategy to synthesize Pt-early transition metal oxide interfacial catalysts

Metal oxide supported metal catalysts show promising catalytic performance in many industry-relevant reactions.However,the enhancement of performance is often limited by the insufficient metal/metal oxide interface.In this work,we demonstrate a general synthesis of Pt-early transition metal oxide(Pt-MO_(x),M=Ti,Zr,V,and Y)catalysts with rich interfacial sites,which is based on the air-induced surface segregation and oxidation of M in the supported Pt-M alloy catalysts.Systematic characterizations verify the dynamic structural response of Pt-M alloy catalysts to air and the formation of Pt-MO_(x) catalysts with abundant interfacial sites.The prepared Pt-TiO_(x) interfacial catalysts exhibit improved performance in hydrogenation reactions of benzaldehyde,nitrobenzene,styrene,and furfural,as a result of the heterolytic dissociation of H_(2) at Pt-metal oxide interfacial sites.

Electrocatalytic oxygen evolution activities of metal chalcogenides and phosphides:Fundamentals,origins,and future strategies

The development of inexpensive and efficient electrocatalysts is key to commercializing energy-related electrocatalytic techniques such as water electrolyzers and metal-air batteries.In particular,novel oxygen evolution reaction(OER)pre-catalysts,such as transition metal chalcogenides(TMCs)and phosphides(TMPs),have evolved in recent years from traditional stable OER electrocatalysts,which show superior OER electrocatalytic performance compared with transition metal oxides(TMOs)or(oxy)hydroxides(TMOHs).In this feature article,we summarize recent advances in the development of TMCand TMP-based OER electrocatalysts,as well as approaches to improve the OER performance in terms of morphology,structure,composition,surface engineering,lattice-strained and in-situ transformation in the electrolysis process.In particular,the electrochemical stability of TMCs and TMPs in alkaline electrolytes and the evolution of morphology,structure and composition under OER conditions are discussed.In the last section,we discuss the challenges that need to be addressed in this specific area of research and the implications for further research.

Simultaneous optimization of transit network and public bicycle station network

The traditional manner to design public transportation system is to sequentially design the transit network and public bicycle network. A new public transportation system design problem that simultaneously considers both bus network design and public bicycle network design is proposed. The chemical reaction optimization(CRO) is designed to solve the problem. A shortcoming of CRO is that, when the two-molecule collisions take place, the molecules are randomly picked from the container.Hence, we improve CRO by employing different mating strategies. The computational results confirm the benefits of the mating strategies. Numerical experiments are conducted on the Sioux-Falls network. A comparison with the traditional sequential modeling framework indicates that the proposed approach has a better performance and is more robust. The practical applicability of the approach is proved by employing a real size network.

ESP教学理念下大学英语教师角色转换与发展路径

专门用途英语(English for Specific Purpose,简称ESP)是大学英语教学改革的主要发展方向。ESP教学,师资是关键,大学英语教师的专业素质和专业发展已成为决定ESP教学成败的重要因素。文章以ESP教学理念为依托,探讨大学英语教师向ESP教师转型过程中的角色定位。在ESP教学理念指导下,大学英语教师在教学中扮演着教学的动态需求分析者、具备英语知识和跨专业知识的教学者、以学生为中心的课程设计者和精通ESP教学评估的研究者等多元化角色。以角色转换为基础,文章还提出通过自我发展途径、合作发展途径和校本培训途径来调整和优化大学英语教师发展路径,以完善大学英语教师知识结构,为实现其职业的专业化发展指明方向。

考虑需求不确定的响应式接驳公交自适应发车策略优化

传统公交系统融合网约出行的模式之一是需求响应式接驳公交,它定位于连接枢纽站点(如地铁车站、铁路车站或机场),服务客流的集散,其需求响应服务主要指灵活线路的门到门接送,但在发车策略方面仍主要沿用传统的基于时刻表或频率的运营方案。在乘客到达或需求订单不确定的情形下,固定发车间隔可能导致系统过饱和或低饱和等问题,为此,本文提出自适应发车策略,根据乘客累计到达量动态确定发车决策。具体地,引入载客量目标作为发车阈值,称为固定发车阈值和时变发车阈值,前者的发车阈值固定不变,而后者的发车阈值则随时间逐渐降低,对此,构建以期望广义系统成本最小化为目标的数学规划问题,并利用网格搜索方法获得最优解。数值分析结果表明,时变发车阈值模型相比于传统的等间隔发车模型和固定发车阈值模型在需求均值较低或变异系数较高的场景下优势显著,其广义系统成本节约百分比最高可达18%。灵敏度分析表明上述模型的性能也受到乘客的时间价值影响。自适应发车模型具有较广的应用潜力,适当修改后可用于其他形式的公共交通系统。

西安市轨道交通产业链分析及发展策略研究

在充分研究轨道交通产业链定义、范围和近期研究成果的基础上,通过解析轨道交通产业链所涉及的科技创新、设计咨询、建设施工、装备制造、运营及增值服务等多环节产业构成,并以西安轨道交通产业链作为研究对象,对产业链现存诸多问题如装备制造产业规模小、产业集群效应弱、产业创新能力转化率不高、产业支撑政策有待完善等进行分析。在深入研究西安都市圈轨道交通政策背景、市场发展形式和前景下,提出产业链发展策略。包括充分发挥政府引导作用、强化资源要素配置、以科技创新引领智造装备产业链、提升规模化和集群化发展水平,以及推动产城融合等措施。