In this article, we study the smoothing effect of the Cauchy problem for the spatially homogeneous non-cutoff Boltzmann equation for hard potentials. It has long been suspected that the non-cutoff Boltzmann equation e...In this article, we study the smoothing effect of the Cauchy problem for the spatially homogeneous non-cutoff Boltzmann equation for hard potentials. It has long been suspected that the non-cutoff Boltzmann equation enjoys similar regularity properties as to whose of the fractional heat equation. We prove that any solution with mild regularity will become smooth in Gevrey class at positive time, with a sharp Gevrey index, depending on the angular singularity. Our proof relies on the elementary L^(2) weighted estimates.展开更多
Sodium-ion batteries (SIBs) have great potential to be the next major energy storage devices due to their obvious advantages and developing advanced electrodes and electrolytes is urgently necessary to promote its fut...Sodium-ion batteries (SIBs) have great potential to be the next major energy storage devices due to their obvious advantages and developing advanced electrodes and electrolytes is urgently necessary to promote its future industrialization.However,hard carbon as a state-of-the-art anode of SIBs still suffers from the low initial Coulomb efficiency and unsatisfactory rate capability,which could be improved by forming desirable solid electrolyte interphases (SEI) to some extent.Indeed,the chemistry and morphology of these interfacial layers are fundamental parameters affecting the overall battery operation,and optimizing the electrolyte to dictate the quality of SEI on hard carbon is a key strategy.Hence,this review summarizes the recent research on SEI design by electrolyte manipulation from solvents,salts,and additives.It also presents some potential mechanisms of SEI formation in various electrolyte systems.Besides,the current advanced characterization techniques for electrolyte and SEI structure analyses have been comprehensively discussed.Lastly,current challenges and future perspectives of SEI formation on hard carbon anode for SIBs are provided from the viewpoints of its compositions,evolution processes,structures,and characterization techniques,which will promote SEI efficient manipulation and improve the performance of hard carbon,and further contribute to the development of SIBs.展开更多
Carbon nanofiber(CNF)was widely utilized in the field of electrochemical energy storage due to its superiority of conductivity and mechanics.However,CNF was generally prepared at relatively high temperature.Herein,nit...Carbon nanofiber(CNF)was widely utilized in the field of electrochemical energy storage due to its superiority of conductivity and mechanics.However,CNF was generally prepared at relatively high temperature.Herein,nitrogen-doped hard carbon nanofibers(NHCNFs)were prepared by a lowtemperature carbonization treatment assisted with electrospinning technology.Density functional theory analysis elucidates the incorporation of nitrogen heteroatoms with various chemical states into carbon matrix would significantly alter the total electronic configurations,leading to the robust adsorption and efficient diffusion of Na atoms on electrode interface.The obtained material carbonized at 600°C(NHCNF-600)presented a reversible specific capacity of 191.0 mAh g^(−1)and no capacity decay after 200 cycles at 1 A g^(−1).It was found that the sodium-intercalated degree had a correlation with the electrochemical impedance.A sodium-intercalated potential of 0.2 V was adopted to lower the electrochemical impedance.The constructed sodium-ion capacitor with activated carbon cathode and presodiated NHCNF-600 anode can present an energy power density of 82.1 Wh kg^(−1)and a power density of 7.0 kW kg^(−1).展开更多
Hard carbons are promising anode materials for sodium-ion batteries.To meet practical requirements,searching for durable and conductive carbon with a stable interface is of great importance.Here,we prepare a series of...Hard carbons are promising anode materials for sodium-ion batteries.To meet practical requirements,searching for durable and conductive carbon with a stable interface is of great importance.Here,we prepare a series of vanadiummodified hard carbon submicrospheres by using hydrothermal carbonization followed by high-temperature pyrolysis.Significantly,the introduction of vanadium can facilitate the nucleation and uniform growth of carbon spheres and generate abundant V-O-C interface bonds,thus optimizing the reaction kinetic.Meanwhile,the optimized hard carbon spheres modified by vanadium carbide,with sufficient pseudographitic domains,provide more active sites for Na ion migration and storage.As a result,the HC/VC-1300 electrode exhibits excellent Na storage performance,including a high capacity of 420 mAh g^(-1) at 50mA g^(-1) and good rate capability at 1 A g^(-1).This study proposes a new strategy for the synthesis of hard carbon spheres with high tap density and emphasizes the key role of pseudographitic structure for Na storage and interface stabilization.展开更多
Physical dormancy(PY) commonly present in the seeds of higher plants is believed to be responsible for the germination failure by impermeable seed coat in hard seeds of legume species, instead of physiological dormanc...Physical dormancy(PY) commonly present in the seeds of higher plants is believed to be responsible for the germination failure by impermeable seed coat in hard seeds of legume species, instead of physiological dormancy(PD). In this study, a non-destructive approach involving multispectral imaging was used to successfully identify hard seeds from non-hard seeds in Medicago sativa, with accuracy as high as96.8%–99.0%. We further adopted multiple-omics strategies to investigate the differences of physiology,metabolomics, methylomics, and transcriptomics in alfalfa hard seeds, with non-hard seeds as control.The hard seeds showed dramatically increased antioxidants and 125 metabolites of significant differences in non-targeted metabolomics analysis, which are enriched in the biosynthesis pathways of flavonoids, lipids and hormones, especially with significantly higher ABA, a hormone known to induce dormancy. In our transcriptomics results, the enrichment pathway of “response to abscisic acid” of differential expressed genes(DEG) supported the key role of ABA in metabolomics results. The methylome analysis identified 54,899, 46,216 and 54,452 differential methylation regions for contexts of CpG, CHG and CHH, and 344 DEGs might be regulated by hypermethylation and hypomethylation of promoter and exon regions, including four ABA-and JA-responsive genes. Among 8% hard seeds in seed lots,24.5% still did not germinate after scarifying seed coat, and were named as non-PY hard seeds.Compared to hard seeds, significantly higher contents of ABA/IAA and ABA/JA were identified in nonPY hard seeds, which indicated the potential presence of PD. In summary, the significantly changed metabolites, gene expressions, and methylations all suggested involvement of ABA responses in hard seeds, and germination failure of alfalfa hard seeds was caused by combinational dormancy(PY + PD),rather than PY alone.展开更多
Evaluating the adaptability of cantilever boring machine(CBM) through in-depth excavation and analysis of tunnel excavation data and rock mass parameters is the premise of mechanical design and efficient excavation in...Evaluating the adaptability of cantilever boring machine(CBM) through in-depth excavation and analysis of tunnel excavation data and rock mass parameters is the premise of mechanical design and efficient excavation in the field of underground space engineering.This paper presented a case study of tunnelling performance prediction method of CBM in sedimentary hard-rock tunnel of Karst landform type by using tunneling data and surrounding rock parameters.The uniaxial compressive strength(UCS),rock integrity factor(Kv),basic quality index([BQ]),rock quality index RQD,brazilian tensile strength(BTS) and brittleness index(BI) were introduced to construct a performance prediction database based on the hard-rock tunnel of Guiyang Metro Line 1 and Line 3,and then established the performance prediction model of cantilever boring machine.Then the deep belief network(DBN) was introduced into the performance prediction model,and the reliability of performance prediction model was verified by combining with engineering data.The study showed that the influence degree of surrounding rock parameters on the tunneling performance of the cantilever boring machine is UCS > [BQ] > BTS >RQD > Kv > BI.The performance prediction model shows that the instantaneous cutting rate(ICR) has a good correlation with the surrounding rock parameters,and the predicting model accuracy is related to the reliability of construction data.The prediction of limestone and dolomite sections of Line 3 based on the DBN performance prediction model shows that the measured ICR and predicted ICR is consistent and the built performance prediction model is reliable.The research results have theoretical reference significance for the applicability analysis and mechanical selection of cantilever boring machine for hard rock tunnel.展开更多
There are over four million miles of two-lane roadways across the United States, of which a substantial portion is low-volume roads (LVR). Traditionally, most traffic safety efforts and countermeasures focus on high-v...There are over four million miles of two-lane roadways across the United States, of which a substantial portion is low-volume roads (LVR). Traditionally, most traffic safety efforts and countermeasures focus on high-volume high-crash urban locations. This is because LVRs cover an extensive area, and the rarity of crashes makes it challenging to use crash data to monitor the safety performance of LVRs regularly. In addition, obtaining up-to-date roadway information, such as pavement or shoulder conditions of an extensive LVR network, can be exceptionally difficult. In recent times, crowdsourced hard-acceleration and braking event data have become commercially available, which can provide precise geolocation information and can be readily acquired from different vendors. The present paper examines the potential use of this data to identify opportunities to monitor the safety of LVRs. This research examined approximately 12 million hard-acceleration and hard-braking events over a 3-months period and 26,743 crashes, including 9373 fatal injuries over the past 5-year period. The study found a moderate correlation between hard acceleration/hard-braking events with historical crash events. This study conducted a hot spot analysis using hard-acceleration/hard-braking and crash datasets. Hotspot analysis detected spatial clusters of high-risk crash locations and detected 848 common high-risk sites. Finally, this paper proposes a combined ranking scheme that simultaneously considers historical crash events and hard-acceleration/hard-braking events. The research concludes by suggesting that agencies can potentially use the hard-acceleration and hard-braking event dataset along with the historical crash dataset to effectively supervise the safety performance of the vast network of LVRs more frequently.展开更多
Cellulose-derived carbon is regarded as one of the most promising candidates for high-performance anode materials in sodium-ion batteries;however,its poor rate performance at higher current density remains a challenge...Cellulose-derived carbon is regarded as one of the most promising candidates for high-performance anode materials in sodium-ion batteries;however,its poor rate performance at higher current density remains a challenge to achieve high power density sodium-ion batteries.The present review comprehensively elucidates the structural characteristics of cellulose-based materials and cellulose-derived carbon materials,explores the limitations in enhancing rate performance arising from ion diffusion and electronic transfer at the level of cellulose-derived carbon materials,and proposes corresponding strategies to improve rate performance targeted at various precursors of cellulose-based materials.This review also presents an update on recent progress in cellulose-based materials and cellulose-derived carbon materials,with particular focuses on their molecular,crystalline,and aggregation structures.Furthermore,the relationship between storage sodium and rate performance the carbon materials is elucidated through theoretical calculations and characterization analyses.Finally,future perspectives regarding challenges and opportunities in the research field of cellulose-derived carbon anodes are briefly highlighted.展开更多
For the performance optimization strategies of hard carbon,heteroatom doping is an effective way to enhance the intrinsic transfer properties of sodium ions and electrons for accelerating the reaction kinetics.However...For the performance optimization strategies of hard carbon,heteroatom doping is an effective way to enhance the intrinsic transfer properties of sodium ions and electrons for accelerating the reaction kinetics.However,the previous work focuses mainly on the intrinsic physicochemical property changes of the material,but little attention has been paid to the resulting interfacial regulation of the electrode surface,namely the formation of solid electrolyte interphase(SEI)film.In this work,element F,which has the highest electronegativity,was chosen as the doping source to,more effectively,tune the electronic structure of the hard carbon.The effect of F-doping on the physicochemical properties of hard carbon was not only systematically analyzed but also investigated with spectroscopy,optics,and in situ characterization techniques to further verify that appropriate F-doping plays a positive role in constructing a homogenous and inorganic-rich SEI film.The experimentally demonstrated link between the electronic structure of the electrode and the SEI film properties can reframe the doping optimization strategy as well as provide a new idea for the design of electrode materials with low reduction kinetics to the electrolyte.As a result,the optimized sample with the appropriate F-doping content exhibits the best electrochemical performance with high capacity(434.53 mA h g^(-1)at 20mA g^(-1))and excellent rate capability(141 mAh g^(-1)at 400 mA g^(-1)).展开更多
The hard X-ray nanoprobe beamline BL13U is a phase-II beamline project at the Shanghai Synchrotron Radiation Facility.The beamline aims to enable comprehensive experiments at high spatial resolutions ranging from 50 t...The hard X-ray nanoprobe beamline BL13U is a phase-II beamline project at the Shanghai Synchrotron Radiation Facility.The beamline aims to enable comprehensive experiments at high spatial resolutions ranging from 50 to 10 nm.The X-ray energy range of the beamline,5-25 keV,can detect most elements in the periodic table.Two operating modes were designed to accommodate the experimental requirements of high-energy resolution or high photon flux,respectively.X-ray nanofluorescence,nanodiffraction,and coherent diffraction imaging are developed as the main experimental techniques for BL13U.This paper describes the beamline optics,end station configurations,experimental methods under development,and preliminary test results.This comprehensive overview aims to provide a clear understanding of the beamline capabilities and potential applications.展开更多
The compaction characteristics of gravelly soil are affected by gravel hardness.To investigate the evolution and influencing mechanism of different gravel hardness on the compaction characteristics of gravelly soil,he...The compaction characteristics of gravelly soil are affected by gravel hardness.To investigate the evolution and influencing mechanism of different gravel hardness on the compaction characteristics of gravelly soil,heavy compaction tests and crushing tests were conducted on gravelly soils with gravels originated from hard,soft and extremely soft rocks.According to orthogonal experiments and variance analysis,it was found that hardness has a significant impact on the maximum dry density of gravelly soil,followed by gravel content,and lastly,moisture content.For gravel compositions with an average saturated uniaxial compressive strength less than 60 MPa,the order of compacted maximum dry density is soft gravels>hard gravels>extremely soft gravels.Each type of gravelly soil has a threshold for gravel content,with 60%for hard and soft gravels and 50%for extremely soft gravels.Beyond these thresholds,the compacted dry density decreases significantly.There is a certain interaction between hardness,gravel content,and moisture content.Higher hardness increases the influence of gravel content,whereas lower hardness increases the influence of moisture content.Gravelly soils with the coarse aggregate(CA)between 0.7 and 0.8 typically achieve higher dry densities after compaction.In addition,the prediction equations for the particle breakage rate and CA ratio in the Bailey method were proposed to estimate the compaction performance of gravelly soil preliminarily.The results further revealed the compaction mechanism of different gravelly soils and can provide reference for subgrade filling construction.展开更多
基金supported by the NSFC(12101012)the PhD Scientific Research Start-up Foundation of Anhui Normal University.Zeng’s research was supported by the NSFC(11961160716,11871054,12131017).
文摘In this article, we study the smoothing effect of the Cauchy problem for the spatially homogeneous non-cutoff Boltzmann equation for hard potentials. It has long been suspected that the non-cutoff Boltzmann equation enjoys similar regularity properties as to whose of the fractional heat equation. We prove that any solution with mild regularity will become smooth in Gevrey class at positive time, with a sharp Gevrey index, depending on the angular singularity. Our proof relies on the elementary L^(2) weighted estimates.
基金financially supported by the Ministry of Higher Education through the Fundamental Research Grant Scheme (FRGS/1/2022/STG05/UM/01/2) awarded to Ramesh T Subramaniamby Technology Development Fund 1 (TeD1)from the Ministry of Science,Technology,and Innovation (MOSTI),Malaysia (MOSTI002-2021TED1)supported by the Key Research Program of Yichang City(2023KYPT0303)
文摘Sodium-ion batteries (SIBs) have great potential to be the next major energy storage devices due to their obvious advantages and developing advanced electrodes and electrolytes is urgently necessary to promote its future industrialization.However,hard carbon as a state-of-the-art anode of SIBs still suffers from the low initial Coulomb efficiency and unsatisfactory rate capability,which could be improved by forming desirable solid electrolyte interphases (SEI) to some extent.Indeed,the chemistry and morphology of these interfacial layers are fundamental parameters affecting the overall battery operation,and optimizing the electrolyte to dictate the quality of SEI on hard carbon is a key strategy.Hence,this review summarizes the recent research on SEI design by electrolyte manipulation from solvents,salts,and additives.It also presents some potential mechanisms of SEI formation in various electrolyte systems.Besides,the current advanced characterization techniques for electrolyte and SEI structure analyses have been comprehensively discussed.Lastly,current challenges and future perspectives of SEI formation on hard carbon anode for SIBs are provided from the viewpoints of its compositions,evolution processes,structures,and characterization techniques,which will promote SEI efficient manipulation and improve the performance of hard carbon,and further contribute to the development of SIBs.
基金supported by the National Natural Science Foundation of China(No.51907193,51822706,and 51777200)the Key Research Program of Frontier Sciences,CAS(No.ZDBS-LY-JSC047)the Youth Innovation Promotion Association,CAS(No.2020145)
文摘Carbon nanofiber(CNF)was widely utilized in the field of electrochemical energy storage due to its superiority of conductivity and mechanics.However,CNF was generally prepared at relatively high temperature.Herein,nitrogen-doped hard carbon nanofibers(NHCNFs)were prepared by a lowtemperature carbonization treatment assisted with electrospinning technology.Density functional theory analysis elucidates the incorporation of nitrogen heteroatoms with various chemical states into carbon matrix would significantly alter the total electronic configurations,leading to the robust adsorption and efficient diffusion of Na atoms on electrode interface.The obtained material carbonized at 600°C(NHCNF-600)presented a reversible specific capacity of 191.0 mAh g^(−1)and no capacity decay after 200 cycles at 1 A g^(−1).It was found that the sodium-intercalated degree had a correlation with the electrochemical impedance.A sodium-intercalated potential of 0.2 V was adopted to lower the electrochemical impedance.The constructed sodium-ion capacitor with activated carbon cathode and presodiated NHCNF-600 anode can present an energy power density of 82.1 Wh kg^(−1)and a power density of 7.0 kW kg^(−1).
基金National Natural Science Foundation of China,Grant/Award Numbers:51874362,51932011,52002407Scientific Research Project of Hunan Provincial Department of Education,Grant/Award Number:21B0815。
文摘Hard carbons are promising anode materials for sodium-ion batteries.To meet practical requirements,searching for durable and conductive carbon with a stable interface is of great importance.Here,we prepare a series of vanadiummodified hard carbon submicrospheres by using hydrothermal carbonization followed by high-temperature pyrolysis.Significantly,the introduction of vanadium can facilitate the nucleation and uniform growth of carbon spheres and generate abundant V-O-C interface bonds,thus optimizing the reaction kinetic.Meanwhile,the optimized hard carbon spheres modified by vanadium carbide,with sufficient pseudographitic domains,provide more active sites for Na ion migration and storage.As a result,the HC/VC-1300 electrode exhibits excellent Na storage performance,including a high capacity of 420 mAh g^(-1) at 50mA g^(-1) and good rate capability at 1 A g^(-1).This study proposes a new strategy for the synthesis of hard carbon spheres with high tap density and emphasizes the key role of pseudographitic structure for Na storage and interface stabilization.
基金supported by the earmarked fund for CARS (CARS-34)National Key Research and Development Program of China (2022YFD1300804)the Key R&D Project of Sichuan Science and Technology Program(2023YFSY0012)。
文摘Physical dormancy(PY) commonly present in the seeds of higher plants is believed to be responsible for the germination failure by impermeable seed coat in hard seeds of legume species, instead of physiological dormancy(PD). In this study, a non-destructive approach involving multispectral imaging was used to successfully identify hard seeds from non-hard seeds in Medicago sativa, with accuracy as high as96.8%–99.0%. We further adopted multiple-omics strategies to investigate the differences of physiology,metabolomics, methylomics, and transcriptomics in alfalfa hard seeds, with non-hard seeds as control.The hard seeds showed dramatically increased antioxidants and 125 metabolites of significant differences in non-targeted metabolomics analysis, which are enriched in the biosynthesis pathways of flavonoids, lipids and hormones, especially with significantly higher ABA, a hormone known to induce dormancy. In our transcriptomics results, the enrichment pathway of “response to abscisic acid” of differential expressed genes(DEG) supported the key role of ABA in metabolomics results. The methylome analysis identified 54,899, 46,216 and 54,452 differential methylation regions for contexts of CpG, CHG and CHH, and 344 DEGs might be regulated by hypermethylation and hypomethylation of promoter and exon regions, including four ABA-and JA-responsive genes. Among 8% hard seeds in seed lots,24.5% still did not germinate after scarifying seed coat, and were named as non-PY hard seeds.Compared to hard seeds, significantly higher contents of ABA/IAA and ABA/JA were identified in nonPY hard seeds, which indicated the potential presence of PD. In summary, the significantly changed metabolites, gene expressions, and methylations all suggested involvement of ABA responses in hard seeds, and germination failure of alfalfa hard seeds was caused by combinational dormancy(PY + PD),rather than PY alone.
基金National Natural Science Foundation of China (Grant No.52178393)the Science and Technology Innovation Team of Shaanxi Innovation Capability Support Plan (Grant No.2020TD005)Science and Technology Innovation Project of China Railway Construction Bridge Engineering Bureau Group Co.,Ltd.(Grant No.DQJ-2020-B07)。
文摘Evaluating the adaptability of cantilever boring machine(CBM) through in-depth excavation and analysis of tunnel excavation data and rock mass parameters is the premise of mechanical design and efficient excavation in the field of underground space engineering.This paper presented a case study of tunnelling performance prediction method of CBM in sedimentary hard-rock tunnel of Karst landform type by using tunneling data and surrounding rock parameters.The uniaxial compressive strength(UCS),rock integrity factor(Kv),basic quality index([BQ]),rock quality index RQD,brazilian tensile strength(BTS) and brittleness index(BI) were introduced to construct a performance prediction database based on the hard-rock tunnel of Guiyang Metro Line 1 and Line 3,and then established the performance prediction model of cantilever boring machine.Then the deep belief network(DBN) was introduced into the performance prediction model,and the reliability of performance prediction model was verified by combining with engineering data.The study showed that the influence degree of surrounding rock parameters on the tunneling performance of the cantilever boring machine is UCS > [BQ] > BTS >RQD > Kv > BI.The performance prediction model shows that the instantaneous cutting rate(ICR) has a good correlation with the surrounding rock parameters,and the predicting model accuracy is related to the reliability of construction data.The prediction of limestone and dolomite sections of Line 3 based on the DBN performance prediction model shows that the measured ICR and predicted ICR is consistent and the built performance prediction model is reliable.The research results have theoretical reference significance for the applicability analysis and mechanical selection of cantilever boring machine for hard rock tunnel.
文摘There are over four million miles of two-lane roadways across the United States, of which a substantial portion is low-volume roads (LVR). Traditionally, most traffic safety efforts and countermeasures focus on high-volume high-crash urban locations. This is because LVRs cover an extensive area, and the rarity of crashes makes it challenging to use crash data to monitor the safety performance of LVRs regularly. In addition, obtaining up-to-date roadway information, such as pavement or shoulder conditions of an extensive LVR network, can be exceptionally difficult. In recent times, crowdsourced hard-acceleration and braking event data have become commercially available, which can provide precise geolocation information and can be readily acquired from different vendors. The present paper examines the potential use of this data to identify opportunities to monitor the safety of LVRs. This research examined approximately 12 million hard-acceleration and hard-braking events over a 3-months period and 26,743 crashes, including 9373 fatal injuries over the past 5-year period. The study found a moderate correlation between hard acceleration/hard-braking events with historical crash events. This study conducted a hot spot analysis using hard-acceleration/hard-braking and crash datasets. Hotspot analysis detected spatial clusters of high-risk crash locations and detected 848 common high-risk sites. Finally, this paper proposes a combined ranking scheme that simultaneously considers historical crash events and hard-acceleration/hard-braking events. The research concludes by suggesting that agencies can potentially use the hard-acceleration and hard-braking event dataset along with the historical crash dataset to effectively supervise the safety performance of the vast network of LVRs more frequently.
基金partly supported by the National Natural Science Foundation of China(51903113,51763014,and 52073133)the China Postdoctoral Science Foundation(2022T150282)+1 种基金Lanzhou Young Science and Technology Talent Innovation Project(2023-QN-101)the Program for Hongliu Excellent and Distinguished Young Scholars at Lanzhou University of Technology.
文摘Cellulose-derived carbon is regarded as one of the most promising candidates for high-performance anode materials in sodium-ion batteries;however,its poor rate performance at higher current density remains a challenge to achieve high power density sodium-ion batteries.The present review comprehensively elucidates the structural characteristics of cellulose-based materials and cellulose-derived carbon materials,explores the limitations in enhancing rate performance arising from ion diffusion and electronic transfer at the level of cellulose-derived carbon materials,and proposes corresponding strategies to improve rate performance targeted at various precursors of cellulose-based materials.This review also presents an update on recent progress in cellulose-based materials and cellulose-derived carbon materials,with particular focuses on their molecular,crystalline,and aggregation structures.Furthermore,the relationship between storage sodium and rate performance the carbon materials is elucidated through theoretical calculations and characterization analyses.Finally,future perspectives regarding challenges and opportunities in the research field of cellulose-derived carbon anodes are briefly highlighted.
基金National Key R&D Program of China,Grant/Award Number:2022YFB4000120Fundamental Research Funds for the Central Universities,Grant/Award Number:2022ZYGXZR101。
文摘For the performance optimization strategies of hard carbon,heteroatom doping is an effective way to enhance the intrinsic transfer properties of sodium ions and electrons for accelerating the reaction kinetics.However,the previous work focuses mainly on the intrinsic physicochemical property changes of the material,but little attention has been paid to the resulting interfacial regulation of the electrode surface,namely the formation of solid electrolyte interphase(SEI)film.In this work,element F,which has the highest electronegativity,was chosen as the doping source to,more effectively,tune the electronic structure of the hard carbon.The effect of F-doping on the physicochemical properties of hard carbon was not only systematically analyzed but also investigated with spectroscopy,optics,and in situ characterization techniques to further verify that appropriate F-doping plays a positive role in constructing a homogenous and inorganic-rich SEI film.The experimentally demonstrated link between the electronic structure of the electrode and the SEI film properties can reframe the doping optimization strategy as well as provide a new idea for the design of electrode materials with low reduction kinetics to the electrolyte.As a result,the optimized sample with the appropriate F-doping content exhibits the best electrochemical performance with high capacity(434.53 mA h g^(-1)at 20mA g^(-1))and excellent rate capability(141 mAh g^(-1)at 400 mA g^(-1)).
基金National Key Research and Development Program(No.2021YFA1601000)National Natural Science Foundation of China(No.12175294)Natural Science Foundation of Shanghai,China(No.21ZR1471500).
文摘The hard X-ray nanoprobe beamline BL13U is a phase-II beamline project at the Shanghai Synchrotron Radiation Facility.The beamline aims to enable comprehensive experiments at high spatial resolutions ranging from 50 to 10 nm.The X-ray energy range of the beamline,5-25 keV,can detect most elements in the periodic table.Two operating modes were designed to accommodate the experimental requirements of high-energy resolution or high photon flux,respectively.X-ray nanofluorescence,nanodiffraction,and coherent diffraction imaging are developed as the main experimental techniques for BL13U.This paper describes the beamline optics,end station configurations,experimental methods under development,and preliminary test results.This comprehensive overview aims to provide a clear understanding of the beamline capabilities and potential applications.
基金supported by the National Natural Science Foundation of China(No.51878127)the Fundamental Research Funds for the Central Universities(N180104013).
文摘The compaction characteristics of gravelly soil are affected by gravel hardness.To investigate the evolution and influencing mechanism of different gravel hardness on the compaction characteristics of gravelly soil,heavy compaction tests and crushing tests were conducted on gravelly soils with gravels originated from hard,soft and extremely soft rocks.According to orthogonal experiments and variance analysis,it was found that hardness has a significant impact on the maximum dry density of gravelly soil,followed by gravel content,and lastly,moisture content.For gravel compositions with an average saturated uniaxial compressive strength less than 60 MPa,the order of compacted maximum dry density is soft gravels>hard gravels>extremely soft gravels.Each type of gravelly soil has a threshold for gravel content,with 60%for hard and soft gravels and 50%for extremely soft gravels.Beyond these thresholds,the compacted dry density decreases significantly.There is a certain interaction between hardness,gravel content,and moisture content.Higher hardness increases the influence of gravel content,whereas lower hardness increases the influence of moisture content.Gravelly soils with the coarse aggregate(CA)between 0.7 and 0.8 typically achieve higher dry densities after compaction.In addition,the prediction equations for the particle breakage rate and CA ratio in the Bailey method were proposed to estimate the compaction performance of gravelly soil preliminarily.The results further revealed the compaction mechanism of different gravelly soils and can provide reference for subgrade filling construction.
