Defect chemistry engineering of Ga-doped garnet electrolyte with high stability for solid-state lithium metal batteries

Ga-doped Li_(7)La_(3)Zr_(2)O_(12)(Ga-LLZO)has long been considered as a promising garnet-type electrolyte candidate for all-solid-state lithium metal batteries(ASSLBs)due to its high room temperature ionic conductivity.However,the typical synthesis of Ga-LLZO is usually accompanied by the formation of undesired LiGaO_(2) impurity phase that causes severe instability of the electrolyte in contact with molten Li metal during half/full cell assembly.In this study,we show that by simply engineering the defect chemistry of Ga-LLZO,namely,the lithium deficiency level,LiGaO_(2) impurity phase is effectively inhibited in the final synthetic product.Consequently,defect chemistry engineered Ga-LLZO exhibits excellent electrochemical stability against lithium metal,while its high room temperature ionic conductivity(~1.9×10^(-3)S·cm^(-1))is well reserved.The assembled Li/Ga-LLZO/Li symmetric cell has a superior critical current density of 0.9 mA·cm^(-2),and cycles stably for 500 hours at a current density of 0.3 mA·cm^(-2).This research facilitates the potential commercial applications of high performance Ga-LLZO solid electrolytes in ASSLBs.

Impact Analysis of Microscopic Defect Types on the Macroscopic Crack Propagation in Sintered Silver Nanoparticles

Sintered silver nanoparticles(AgNPs)arewidely used in high-power electronics due to their exceptional properties.However,the material reliability is significantly affected by various microscopic defects.In this work,the three primary micro-defect types at potential stress concentrations in sintered AgNPs are identified,categorized,and quantified.Molecular dynamics(MD)simulations are employed to observe the failure evolution of different microscopic defects.The dominant mechanisms responsible for this evolution are dislocation nucleation and dislocation motion.At the same time,this paper clarifies the quantitative relationship between the tensile strain amount and the failure mechanism transitions of the three defect types by defining key strain points.The impact of defect types on the failure process is also discussed.Furthermore,traction-separation curves extracted from microscopic defect evolutions serve as a bridge to connect the macro-scale model.The validity of the crack propagation model is confirmed through tensile tests.Finally,we thoroughly analyze how micro-defect types influence macro-crack propagation and attempt to find supporting evidence from the MD model.Our findings provide a multi-perspective reference for the reliability analysis of sintered AgNPs.

Solution of idle LBO problem for high FAR aero combustor

The paper sheds light on the idle lean blow off(LBO)problem for high fuel air ratio(FAR)com⁃bustor,which is impossible to be addressed with traditional aero combustor design.A significant improvement in aero combustor design is required to resolve the idle LBO issue.The authors detailed a practical and efficient solu⁃tion,which not only solved the idle LBO issue but also defined the aero-thermal design for high-FAR combustor.The design will usher in a new era of aero combustor.

An Arbitrarily High Order and Asymptotic Preserving Kinetic Scheme in Compressible Fluid Dynamic

We present a class of arbitrarily high order fully explicit kinetic numerical methods in compressible fluid dynamics,both in time and space,which include the relaxation schemes by Jin and Xin.These methods can use the CFL number larger or equal to unity on regular Cartesian meshes for the multi-dimensional case.These kinetic models depend on a small parameter that can be seen as a"Knudsen"number.The method is asymptotic preserving in this Knudsen number.Also,the computational costs of the method are of the same order of a fully explicit scheme.This work is the extension of Abgrall et al.(2022)[3]to multidimensional systems.We have assessed our method on several problems for two-dimensional scalar problems and Euler equations and the scheme has proven to be robust and to achieve the theoretically predicted high order of accuracy on smooth solutions.

Characteristics and origin of abnormally high porosity zones in buried Paleogene clastic reservoirs in the Shengtuo area, Dongying Sag, East China

There are three abnormally high porosity zones developed in buried Paleogene nearshore subaqueous fan and sublacustrine fan clastic＇reservoirs at 2,800-3,200 m, 3,250-3,700 m and 3,900- 4,400 m, respectively, within the Shengtuo area of the Dongying Sag. Here the porosity of reservoirs buried deeper than 4,000 m can still be greater than 20%. Investigation of these three abnormally high porosity （AHP） zones in the 3rd to 4th member of the Paleogene Shahejie Formation in the Shengtuo area was carried out with utilization of core observation, thin section identification, SEM observation, image analysis, core physical property testing and other technical methods. The results show that, the AHP zones in 2,800-3,200 m and 3,250-3,700 m are visible pores primary AHP zones dominated by significant primary intergranular pores （more than 50% of the total porosity）, while secondary pores and micropores in authigenic clays may develop in some reservoirs. AHP reservoirs in the AHP zone of 3,900-4,400 m are dominated by micropores in matrix, visible pores are mainly grain dissolution pores but with low absolute content （〈 1%）, so this zone belongs to the micropores primary AHP zone. The genesis of the three AHP zones was studied to distinguish between porosity enhancement and porosity preservation. Our research shows that, in deeply buried clastic reservoirs in the Shengtuo area, mineral dissolution occurred in a relatively closed diagenetic system with high temperature and high salinity. Reservoir rocks underwent extensive feldspar dissolution, while detrital carbonate grains and carbonate cements show no evidence of extensive dissolution. Although significant feldspar dissolution pores developed, feldspar dissolution enhanced porosity only a little due to the precipitation of almost isovolumetric dissolution products in the nearby primary intergranular pores in forms of authigenic clays and quartz cements. Net enhanced porosity originating from feldspar dissolution is generally less than 0.25%. Thus, the subsurface dissolution has little impact on the mid-deep buried high porosity reservoirs. Reservoirs in braided channels of middle fans in sublacustrine fans and reservoirs in the middle-front of fan bodies of nearshore subaqueous fans provide the basis for the development of AHP zones. The shallow development of fluid overpressure and early hydrocarbon emplacement have effectively retarded compaction and carbonate cementation, so that the high porosity in the superficial layers is preserved in the mid-deep layers. These are the main controlling factors in the development of AHP zones.

Distribution and genesis of the anomalously high porosity zones in the middle-shallow horizons of the northern Songliao Basin

High-quality reservoirs occur in the middle-shallow horizons of the northern Songliao Basin. The distribution and genesis of their anomalously high porosity zones were studied using measured porosities, examination of ordinary thin sections and blue epoxy resin-impregnated thin sections and by SEM. The results show that there are three anomalously high porosity zones at the depth of 450-900 m, 1,300-1,900 m, 2,050-2,350 m respectively, named zone i, zone ii and zone iii from top to bottom. Horizontally, zone i and zone ii are distributed all over the basin except in the Southeastern Uplift, while zone iii is only distributed in the Central Depression. Zone i was formed by meteoric water leaching as well as organic acid dissolution. Zones ii and iii were dominantly formed by organic acid dissolution. Additionally, clay mineral transformation generating H＋ and hydrocarbon emplacement retarding the cementation of sandstones are also important for the formation of zones ii and iii.

High Temperature Strain Structures and Quartz C-Axis Fabrics from Mylonitic Rocks in the Ailaoshan-Red River Shear Zone,Yunnan,and Their Tectonic Implication

The Ailaoshan-Red River（ASRR） shear zone is one of the major Southeast Asian tectonic discontinuities that have figured the present tectonic framework of the eastern Tibet.Several metamorphic massifs are distributed linearly along the shear zone,e.g.Xuelongshan,Diancangshan, Ailaoshan and Day Nui Con Voi from north to south.They bear a lot of lines of evidence for the tectonic evolution of the eastern Tibetan at different crustal levels in different tectonic stages.Controversy still exists on the deformation structures,microstructures and their relationship with metamorphisms along the ASRR.In this paper detailed microstructural and EBSD（Electron Backscattered Diffraction） fabric analysis of some highly sheared granitic rocks from different massifs along the ASRR are conducted.High temperature structures and microstructures are preserved in unsheared gneisses,in weakly sheared xenoliths or in some parts of the highly sheared rocks（mylonites）.Several types of high temperature quartz c-axis fabrics show symmetrical patterns or transitions from symmetrical to asymmetrical patterns.The former are attributed to coaxial deformation during regional shortening in an early stage of the Indian-Eurasian tectonic interaction and the latter are related to the transitions from coaxial compression to noncoaxial shearing during the post-collisional ASRR left lateral shearing.

Spatial correlation of the high intensity zone in deep-water acoustic field

The spatial correlations of acoustic field have important implications for underwater target detection and other ap- plications in deep water. In this paper, the spatial correlations of the high intensity zone in the deep-water acoustic field are investigated by using the experimental data obtained in the South China Sea. The experimental results show that the structures of the spatial correlation coefficient at different ranges and depths are similar to the transmission loss structure in deep water. The main reason for this phenomenon is analyzed by combining the normal mode theory with the ray theory. It is shown that the received signals in the high intensity zone mainly include one or two main pulses which are contributed by the interference of a group of waterbome modes with similar phases. The horizontal-longitudinal correlations at the same receiver depth but in different high intensity zones are analyzed. At some positions, more pulses are received in the arrival structure of the signal due to bottom reflection and the horizontal-longitudinal correlation coefficient decreases accordingly. The multi-path arrival structure of receiving signal becomes more complex with increasing receiver depth.

Technical foundation research on high resolution remote sensing system of China's coastal zone

China's coastal zone is a region with a highly developed economy that contrasts clearly with the slow paced regular investigation on its natural environment,which cannot keep pace with the requirement of economic development and modern management.Laying a theoretical foundation for the modern management of China's costal zone is aimed at. This research focuses on the following processing and analyzing technologies for coastal zone high-resolution remote sensing data: organization and management of large amounts of high-resolution remote sensing data, quick and precise spatial positioning system,algorithms for image fusion in feature level and coastal zone feature extraction. They will form a technical foundation of the system. And, if combined with other research results such as coastal zone remote sensing classification system and its mapping subsystem, an advanced technical frame for remote sensing investigation of coastal zone resource will be constructed.

TDFAD APPROACH TO HIGH TEMPERATURE DEFECT ASSESSMENT AND ITS ENGINEERING APPLICATION

From the idea of failure of defective structures at high temperature beingcontrolled by two mechanisms: fast fracture due to creep crack growth initiating at the crack tipand creep rupture on the weakened section, a time-dependent failure assessment diagram (TDFAD) isdeveloped on the basis of the time dependent crack tip parameter J integral. According to theproposed TDFAD method, detailed crack initiation and creep crack growth analysis is avoided insafety assessments of high temperature structures by performing simple calculations of stressintensity factor and limit load. To evaluate the creep toughness parameter K_(mat), three differentexpressions are suggested on the basis of experimental load-line displacement, creep crackinitiation and growth parameters as well as the isochronous stress-strain curve. The influence ofservice factors such as temperature and service-time on the proposed TDFAD is discussed by using theproperties of 2.25CrlMo steel and an example is also presented to illustrate the approach.

Quantizing and analyzing the feature information of coastal zone based on high-resolution remote sensing image

On the basis of realization of beach information and its differentiating of high-resolution remote sensing image on coastal zone, extracting objects are carried through RS multi-scale diagnostic analysis, and fast information extraction methods and key technologies are put forward. Meanwhile image segmentation methods are set forth for objects of coastal zone. And through the application of Otsu2D to the segmentation of water area and dock and the applying of Gabor filter to the separation and extraction of construction, some typical applications of high-resolution RS image are presented in the field of coastal zone surface objects＇ recognition. Quantizing high-resolution RS information on the coastal zone proved to be of great scientific and practical significance for coastal development and management.

Production of High Purity Metals: A Review on Zone Refining Process

Purification is a primary application of zone melting, in which the improvement of efficiency, production yield and minimum achievable impurity level are always the research focus due to the increasing demand for high purity metals. This paper has systematically outlined the whole development of related research on zone refining of metals including basic theories, variants of zone refining, parametric optimization, numerical models, and high purity analytical methods. The collection of this information could be of good value to improve the refining efficiency and the production of high purity metals by zone refining.

Ultrasonic Analysis of Cracking Propagation Morphology in the Fusion Zone of High Strength Steel

Cracking morphology in the fusion zone of HQ130 high strength steel was researched by 'the y-slit test' and 'three-point bend test', ultrasonic test and microscope. HQ130 and QJ63 high strength steel was welded by Ar+CO2 gas shielded arc welding under the condition without preheating. Experimental results indicated that welding cracks were produced in the partially melted zone of the weld root of HQ130 steel side and propagated parallel to the fusion zone. The cracks were developed alternatively between the weld and the partially melted zone, and are not strictly ruptured at W/F (weld metal/fusion zone) boundary surface. Controlling weld heat input (E) about 16 kJ/cm could make the cracking rate lowest and satisfy the performance requirement of welded joint zone.

Mineralogy and Geochemistry of the High-Cr Podiform Chromitite from the Cuobuzha Ophiolite, Yarlung Zangbo Suture Zone, Western Tibet, China: Implication for its Origin

The Cuobuzha high-Cr chromitites in the western segment of Yarlung Zangbo Suture Zone of Tibet are mainly hosted in the harzburgites as massive type, which are characterized by high concentrations of platinum group elements(PGE) ranging from 380 to 577 ppb, and low Pd/Ir ratios(<0.1). In mid-ocean ridge basalts(MORB)-normalized spidergrams, chromites of the Cuobuzha chromitites are depleted in Al, Ga, V, Mg and Zn, and enriched in Mn and Cr, sharing similar patterns with those of ophiolitic boninites in the Bonin and Thetford Mines. Approximately 20 platinum group mineral(PGM) grains were discovered from the samples, including laurite, erlichmanite, Os-Fe alloy, cuproiridsite, and irarsite. The PGM assemblages indicate that sulfur fugacity was initially low enough to allow the precipitation of Os-Fe alloy and increased thereafter, with the fall in temperature. Primary Fe-Ni and Fe-Cr alloys, which are stable in a highly reduced environment, occur as inclusions within chromites or clinopyroxenes. Calculated results show that the parental magma has an intimate affinity with boninites. Based on our observations, a model is proposed wherein the Cuobuzha chromitites contain high-pressure and low-pressure chromites. Low-pressure chromites were formed via reaction between boninitic melts and peridotites, during which the high-pressure chromites hosting highly reduced minerals were mobilized by melts and were reallocated to podiform chromitites.

Carboniferous Highly Fractionated I-type Granites from the Kalamaili Fault Zone, Eastern Xinjiang, NW China: Petrogenesis and Tectonic Implications

Carboniferous magmatism is one of the most important tectonothermal events in the Central Asian Orogenic Belt(CAOB). However, the final closure time of the Kalamaili Ocean between East Junggar and Harlik Mountain is still debated. Early Carboniferous(332 Ma) and late Carboniferous(307-298 Ma) granitic magmatism from Kalamaili fault zone have been recognized by LA-ICP-MS zircon U-Pb dating. They are both metaluminous highly fractionated I-type and belong to the high-K calc-alkaline. The granitoids for early Carboniferous have zircon εHf(t) values of-5.1 to +8.5 with Hf model ages(TDM2) of 1.78-0.83 Ga, suggesting a mixed magma source of juvenile material with old continental crust. Furthermore, those for late Carboniferous have much younger heterogeneous zircon εHf(t) values(+5.1 to +13.6) with Hf model ages(TDM2=1.03-0.45 Ga) that are also indicative of juvenile components with a small involvement of old continental crust. Based on whole-rock geochemical and zircon isotopic features, these high-K granitoids were derived from melting of heterogeneous crustal sources or through mixing of old continental crust with juvenile components and minor AFC(assimilation and fractional crystallization). The juvenile components probably originated from underplated basaltic magmas in response to asthenospheric upwelling. These Carboniferous highly fractionated granites in the Kalamaili fault zone were probably emplaced in a post-collisional extensional setting and suggested vertical continental crustal growth in the southern CAOB, which is the same or like most granitoids in CAOB. This study provides new evidence for determining the post-accretionary evolution of the southern CAOB. In combination with data from other granitoids in these two terranes, the Early Carboniferous Heiguniangshan pluton represents the initial record of post-collisional environment, suggesting that the final collision between the East Junggar and Harlik Mountain might have occurred before 332 Ma.

Effect of defects properties on InP-based high electron mobility transistors

The performance damage mechanism of InP-based high electron mobility transistors(HEMTs) after proton irradiation has been investigated comprehensively through induced defects.The effects of the defect type, defect energy level with respect to conduction band ET, and defect concentration on the transfer and output characteristics of the device are discussed based on hydrodynamic model and Shockley–Read–Hall recombination model.The results indicate that only acceptorlike defects have a significant influence on device operation.Meanwhile, as defect energy level ETshifts away from conduction band, the drain current decreases gradually and finally reaches a saturation value with ETabove 0.5 eV.This can be attributed to the fact that at sufficient deep level, acceptor-type defects could not be ionized any more.Additionally,the drain current and transconductance degrade more severely with larger acceptor concentration.These changes of the electrical characteristics with proton radiation could be accounted for by the electron density reduction in the channel region from induced acceptor-like defects.

Defect band formation in high pressure die casting AE44 magnesium alloy

The characteristics of defect bands in the microstructure of high pressure die casting(HPDC)AE44 magnesium alloy were investigated.Special attention was paid to the effects of process parameters during the HPDC process and casting structure on the distribution of defect bands.Results show that the defect bands are solute segregation bands with the enrichment of Al,Ce and La elements,which are basically in the form of Al_(11)RE_(3) phase.There is no obvious aggregation of porosities in the defect bands.The width of the inner defect band is 4-8 times larger than that of the outer one.The variation trends of the distribution of the inner and outer defect bands are not consistent under different process parameters and at different locations of castings.This is due to the discrepancy between the formation mechanisms of double defect bands.The filling and solidification behavior of the melt near the chilling layer is very complicated,which finally leads to a fluctuation of the width and location of the outer defect band.By affecting the content and aggregation degree of externally solidified crystals(ESCs)in the cross section of die castings,the process parameters and casting structure have a great influence on the distribution of the inner defect band.

On the high conductive layer near the Moho and the transitional zone between the crust and mantle in Tianshui region

On the basis of MTS and DSS data in and near Tianshui region,the deep structure contour of the region was expounded.The regional distribution of the high conductive layer near the Moho in the region becomes one of the most obvious characters of the conductivity structure in the crust and mantle,and it is corresponding to the low S wave velocity zone near the Moho and is guessed as the transitional zone between the crust and mantle in the region.In this paper,the behaviour of medium and the thermodynamic circumstance of the conductive low shear velocity layer near the Moho were demonstrated emphatically,and the cause of formation of the layer was roughly explained under specified conditions of geographical environment and deep structure characters in this region.

Investigation of a novel spot defect on a hot dip galvanized high-silicon AHSS sheet

Improving the galvanizability of high silicon advanced high strength steels （AHSS） is a practical technical challenge. In this study, spot defects on an industrial hot dip galvanized （GI） sheet of an AHSS with 1.5 % Si has been studied in-depth. The surface morphologies of spot defects before and after partial and complete removal of the Zn layer, as well as the interface between the outermost coating layer and the sheet substrate were characterized using optical microscopy （ OM）, scanning electron microscopy （ SEM）, a 3-D optical profiler, energy dispersive spectroscopy（ EDS ） and focused ion beam （FIB） analysis. The most outstanding spot defect on the normally coated area of the steel sheet has a diameter of approximately 500μm, with the following characteristics. In the central region of the spot defect,Zn is barely coated and the sheet substrate is covered by a thin silicon oxide film with dispersed Zn-Fe intermetallics. At the periphery of the spot defect, a burst structure of Zn-Fe intermetallics forms on the sheet substrate. Outside the spot defect where the Zn layer is normally coated, there is a continuous Fe2Al5 inhibition layer between the Zn coating and the sheet substrate. These results indicate that a silicon oxide film forms on the substrate during annealing prior to hot dipping, thus preventing the formation of the Fe2Al5 inhibition layer during hot dipping. This causes spot defects on high Si AHSS sheets.

Impact of Native Defects in the High Dielectric Constant Oxide HfSiO_4 on MOS Device Performance

Native dejects in HfSiO4 are investigated by first principles calculations. Transition levels of native detects can be accurately described by employing the nonlocal HSE06 hybrid functional. This methodology overcomes the band gap problem in traditional functionals. By band alignments among the Si, GaAs and HfSiO4. we are able to determine the position of defect levels in Si and GaAs relative to the HfSiO4 band gap. We evaluate the. possibility of these defects acting as fixed charge. Native defects lead to the change of valence and conduction band offsets. Gate leakage current is evaluated by the band offset. In addition, we also investigate diffusions of native defects, and discuss how they affect the MOS device performance.