This paper experimentally and theoretically investigates the effect of the underlayer medium on tuning of the surface plasmon resonance （SPR） wavelength of silver island films, and the effect of substrate temperatur...This paper experimentally and theoretically investigates the effect of the underlayer medium on tuning of the surface plasmon resonance （SPR） wavelength of silver island films, and the effect of substrate temperature on the morphologies and optical properties of the films. From the absorption spectra of single Ag with various thickness and overcoated （Ag/TiO2） films deposited on glass substrates at various substrate temperatures by RF magnetron sputtering, we demonstrate that the surface plasmon resonance wavelength can be made tunable by changing the underlayer medium, the thickness of metal layer and the substrate temperature. By varying substrate temperatures, the interparticle coupling effects on plasmon resonances of nanosilver particles enhance as the spacing between the particles reduces. When the substrate temperature is up to 500 ℃, the absorption peak decreases sharply and shifts to shorter wavelength side due to the severe coalescence between silver islands in the film.展开更多
ZnO（002） films with different thicknesses ranging from 7 to 300 nm were grown on sapphire（006） substrates via metal-organic chemical vapor deposition （MOCVD）. The two-dimensional（2D） planar layer and the three...ZnO（002） films with different thicknesses ranging from 7 to 300 nm were grown on sapphire（006） substrates via metal-organic chemical vapor deposition （MOCVD）. The two-dimensional（2D） planar layer and the three-dimensional（3D） island layer were studied by using of X-ray diffraction（XRD） rocking curves and atomic force microscopy （AFM）. The room temperature photoluminescence （PL） spectra show a blue shift of the peak positions of the uhraviolet（UV） emission with increasing film thickness. The blue shift is remarkably high（393-380 nm） when an increase in film thickness（7-15 nm） is accompanied by the change of structure from a 2D planar layer to a 3D island layer. The PL spectra at 77 K also indicate that there are different transition mechanisms in the film thickness from a 2D planar layer to a 3D island layer near the 2D layer region.展开更多
Internal solitary waves （ISWs） are frequently observed in the area between Dongsha Island （DI） and Taiwan Island. However, there have been few in-situ observations southwest of DI. To improve our knowledge of ISWs...Internal solitary waves （ISWs） are frequently observed in the area between Dongsha Island （DI） and Taiwan Island. However, there have been few in-situ observations southwest of DI. To improve our knowledge of ISWs in this area, we observed the ISWs over the continental shelf （115.4°E, 20.3°N） from Aug. 29 to Oct. 10, 2011 with temperature sensors and an acoustic Doppler current profiler （ADCP）. The observations showed that the a fully developed ISW produced a current whose maximum westward velocity was 0.92 rrds and maximum northward velocity was 0.47 m/s. During the 41-day observation period the ISWs appeared for three periods with about 7-day gaps between each period. During each day, two types of ISWs were observed. The first type of wave arrived regularly diurnally at the same time each day, with a similar pattern to that of the type-a wave identified by Ramp et al. （2004）. The second type arrived about 12 h after the first type and was delayed about 1 hour each day; this wave type was related to the type-b wave. Thus, our observations confirmed that both type-a and type-b waves can reach the area southwest of the DI. Moreover, the waves observed by the mooring propagated toward the directions of 270°-315° clockwise from true north, indicating obvious refraction from uneven topography around DI.展开更多
Due to their particular optical characteristics,metallic island films have the potential to significantly increase the energy conversion efficiency of solar cell.We experimentally and theoretically investigated the ef...Due to their particular optical characteristics,metallic island films have the potential to significantly increase the energy conversion efficiency of solar cell.We experimentally and theoretically investigated the effect of substrate temperature on the morphologies and optical properties of the silver island films.At low temperature,below 300 ℃,as the substrate temperature increases.Compared to the films prepared at room temperature,the sizes of nanoparticles decrease and the Absorption peaks shift to shorter wavelength accompanied by an increase density resulting in a 150% Absorption efficiency.As the substrate temperature goes up to 300 ℃,nanoparticles with larger in-plan(X-Y)dimensions are formed,the number density decreases and the Absorption peaks redshift but the Absorption efficiency is still 10% higher.Numerical simulation reveals that these behaviors are a consequence of morphologies transformation.展开更多
Surface wave dynamics of falling film on the surface of periodic rectangular wall under monochromatic-frequency flowrate forcing disturbances is studied via numerical simulation. Waveforms formed on the periodic recta...Surface wave dynamics of falling film on the surface of periodic rectangular wall under monochromatic-frequency flowrate forcing disturbances is studied via numerical simulation. Waveforms formed on the periodic rectangular wall are different from those on the flat plate. At low frequency, the perturbation introduced at the inlet first undergoes a steady flow region and then develops into solitary waves. When the frequency becomes higher, solitary waves disappear. Film deformations in the steady flow region and characteristics of solitary waves are studied as the film travels down. There are circulations at the depression of periodic wall which are dependent on the local film characteristics and geometry of the corrugation. Moreover, the flow rate and geometry of the corrugations can also affect the evolvement of the monochromatic perturbation.展开更多
基金Project supported by the Distinguished Youth Foundation of Hunan Province,China (Grant No. 03JJY1008)the Science Foundation for Post-doctorate of China,(Grant No. 2004035083)the Natural Science Foundation of Hunan Province,China(Grant No. 06JJ2034)
文摘This paper experimentally and theoretically investigates the effect of the underlayer medium on tuning of the surface plasmon resonance （SPR） wavelength of silver island films, and the effect of substrate temperature on the morphologies and optical properties of the films. From the absorption spectra of single Ag with various thickness and overcoated （Ag/TiO2） films deposited on glass substrates at various substrate temperatures by RF magnetron sputtering, we demonstrate that the surface plasmon resonance wavelength can be made tunable by changing the underlayer medium, the thickness of metal layer and the substrate temperature. By varying substrate temperatures, the interparticle coupling effects on plasmon resonances of nanosilver particles enhance as the spacing between the particles reduces. When the substrate temperature is up to 500 ℃, the absorption peak decreases sharply and shifts to shorter wavelength side due to the severe coalescence between silver islands in the film.
基金Supported by the National Natural Science Foundation of China(Nos. 20071013 and 20301007).
文摘ZnO（002） films with different thicknesses ranging from 7 to 300 nm were grown on sapphire（006） substrates via metal-organic chemical vapor deposition （MOCVD）. The two-dimensional（2D） planar layer and the three-dimensional（3D） island layer were studied by using of X-ray diffraction（XRD） rocking curves and atomic force microscopy （AFM）. The room temperature photoluminescence （PL） spectra show a blue shift of the peak positions of the uhraviolet（UV） emission with increasing film thickness. The blue shift is remarkably high（393-380 nm） when an increase in film thickness（7-15 nm） is accompanied by the change of structure from a 2D planar layer to a 3D island layer. The PL spectra at 77 K also indicate that there are different transition mechanisms in the film thickness from a 2D planar layer to a 3D island layer near the 2D layer region.
基金Supported by the National Natural Science Foundation of China(Nos.41030855,U1133001,41376027)National High Technology Research and Development Program of China(863 Program)(No.2013AA09A502)
文摘Internal solitary waves （ISWs） are frequently observed in the area between Dongsha Island （DI） and Taiwan Island. However, there have been few in-situ observations southwest of DI. To improve our knowledge of ISWs in this area, we observed the ISWs over the continental shelf （115.4°E, 20.3°N） from Aug. 29 to Oct. 10, 2011 with temperature sensors and an acoustic Doppler current profiler （ADCP）. The observations showed that the a fully developed ISW produced a current whose maximum westward velocity was 0.92 rrds and maximum northward velocity was 0.47 m/s. During the 41-day observation period the ISWs appeared for three periods with about 7-day gaps between each period. During each day, two types of ISWs were observed. The first type of wave arrived regularly diurnally at the same time each day, with a similar pattern to that of the type-a wave identified by Ramp et al. （2004）. The second type arrived about 12 h after the first type and was delayed about 1 hour each day; this wave type was related to the type-b wave. Thus, our observations confirmed that both type-a and type-b waves can reach the area southwest of the DI. Moreover, the waves observed by the mooring propagated toward the directions of 270°-315° clockwise from true north, indicating obvious refraction from uneven topography around DI.
基金The Distinguished Youth Foundation of Hunan Province(03JJY1008)The Natural Science Foundation of Hunan Province(06JJ2034)
文摘Due to their particular optical characteristics,metallic island films have the potential to significantly increase the energy conversion efficiency of solar cell.We experimentally and theoretically investigated the effect of substrate temperature on the morphologies and optical properties of the silver island films.At low temperature,below 300 ℃,as the substrate temperature increases.Compared to the films prepared at room temperature,the sizes of nanoparticles decrease and the Absorption peaks shift to shorter wavelength accompanied by an increase density resulting in a 150% Absorption efficiency.As the substrate temperature goes up to 300 ℃,nanoparticles with larger in-plan(X-Y)dimensions are formed,the number density decreases and the Absorption peaks redshift but the Absorption efficiency is still 10% higher.Numerical simulation reveals that these behaviors are a consequence of morphologies transformation.
基金Supported by National Natural Science Foundation of China (No. 20976118)
文摘Surface wave dynamics of falling film on the surface of periodic rectangular wall under monochromatic-frequency flowrate forcing disturbances is studied via numerical simulation. Waveforms formed on the periodic rectangular wall are different from those on the flat plate. At low frequency, the perturbation introduced at the inlet first undergoes a steady flow region and then develops into solitary waves. When the frequency becomes higher, solitary waves disappear. Film deformations in the steady flow region and characteristics of solitary waves are studied as the film travels down. There are circulations at the depression of periodic wall which are dependent on the local film characteristics and geometry of the corrugation. Moreover, the flow rate and geometry of the corrugations can also affect the evolvement of the monochromatic perturbation.
