BACKGROUND Alzheimer’s disease(AD)is a neurodegenerative condition characterized by oxidative stress and neuroinflammation.Tanshinone ⅡA(Tan-ⅡA),a bioactive compound isolated from Salvia miltiorrhiza plants,has sho...BACKGROUND Alzheimer’s disease(AD)is a neurodegenerative condition characterized by oxidative stress and neuroinflammation.Tanshinone ⅡA(Tan-ⅡA),a bioactive compound isolated from Salvia miltiorrhiza plants,has shown potential neuroprotective effects;however,the mechanisms underlying such a function remain unclear.AIM To investigate potential Tan-ⅡA neuroprotective effects in AD and to elucidate their underlying mechanisms.METHODS Hematoxylin and eosin staining was utilized to analyze structural brain tissue morphology.To assess changes in oxidative stress and neuroinflammation,we performed enzyme-linked immunosorbent assay and western blotting.Additionally,the effect of Tan-ⅡA on AD cell models was evaluated in vitro using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay.Genetic changes related to the long non-coding RNA(lncRNA)nuclear-enriched abundant transcript 1(NEAT1)/microRNA(miRNA,miR)-291a-3p/member RAS oncogene family Rab22a axis were assessed through reverse transcription quantitative polymerase chain reaction.RESULTS In vivo,Tan-ⅡA treatment improved neuronal morphology and attenuated oxidative stress and neuroinflammation in the brain tissue of AD mice.In vitro experiments showed that Tan-ⅡA dose-dependently ameliorated the amyloid-beta 1-42-induced reduction of neural stem cell viability,apoptosis,oxidative stress,and neuroinflammation.In this process,the lncRNA NEAT1-a potential therapeutic target-is highly expressed in AD mice and downregulated via Tan-ⅡA treatment.Mechanistically,NEAT1 promotes the transcription and translation of Rab22a via miR-291a-3p,which activates nuclear factor kappa-B(NF-κB)signaling,leading to activation of the pro-apoptotic B-cell lymphoma 2-associated X protein and inhibition of the anti-apoptotic B-cell lymphoma 2 protein,which exacerbates AD.Tan-ⅡA intervention effectively blocked this process by inhibiting the NEAT1/miR-291a-3p/Rab22a axis and NF-κB signaling.CONCLUSION This study demonstrates that Tan-ⅡA exerts neuroprotective effects in AD by modulating the NEAT1/miR-291a-3p/Rab22a/NF-κB signaling pathway,serving as a foundation for the development of innovative approaches for AD therapy.展开更多
The South China Sea(SCS)is a marginal sea connecting the Pacific and Indian oceans and has gained much attention in recent decades.The dynamics in the northeast SCS are considerably influenced by topography,monsoons,t...The South China Sea(SCS)is a marginal sea connecting the Pacific and Indian oceans and has gained much attention in recent decades.The dynamics in the northeast SCS are considerably influenced by topography,monsoons,tropical cyclones,the Kuroshio intrusion,and water exchange through the Luzon Strait(LS).展开更多
Thinning is an effective management step for sustainable forest development,yet less attention is paid to the restoration of soil microbiota after thinning.In this study,both abundant and rare soil microbial communiti...Thinning is an effective management step for sustainable forest development,yet less attention is paid to the restoration of soil microbiota after thinning.In this study,both abundant and rare soil microbial communities(i.e.,bacterial,fungal),were evaluated under various thinning treatments in a mixed stand of Cunninghamia lanceolata and Sassafras tzumu using Mi Seq sequencing.Thinning did not significantly change either abundant or rare bacterial and fungal community composition,but affected their alpha diversity.The Shannon–Wiener indexes of rare fungal taxa under medium thinning were significantly lower than in the light thinning(P<0.05 level).Xanthobacteraceae dominated the abundant bacterial taxa,and Saitozyma and Mortierlla the abundant fungal taxa.The most common rare bacterial taxa varied;there was no prevalent rare fungal taxa under different thinnings.In addition,soil available nitrogen,total phosphorus,and p H had significant effects on rare bacterial taxa.Nutrients,especially available phosphorus,but not nitrogen,affected abundant and rare soil fungi.The results indicate that soil properties rather than plant factors affect abundant and rare microbial communities in soils of mixed stands.Thinning,through mediating soil properties,influences both abundant and rare bacterial and fungal communities in the mixed C.lanceolata and S.tzumu stand.展开更多
The quality and aroma of strong-flavor Baijiu are mainly dependent on Daqu,pit mud(PM),and the interaction of both.However,little is known about how their combination patterns affect the microbiome and metabolome of Z...The quality and aroma of strong-flavor Baijiu are mainly dependent on Daqu,pit mud(PM),and the interaction of both.However,little is known about how their combination patterns affect the microbiome and metabolome of Zaopei,especially the metabolic function of rare taxa.Here,an experiment on industrial size was designed to assess the effects of 6 combinations(3 kinds of Daqu×2 kinds of PM)on the composition and assembly of different taxa,as well as the flavor profile.The results showed that Zaopei's microbiota was composed of a few abundant taxa and enormous rare taxa,and rare bacterial and abundant fungal subcommunities were significantly affected by combination patterns.The assembly processes of abundant/rare taxa and bacterial/fungal communities were distinct,and environmental changes mediated the balance between stochastic and deterministic processes in rare bacteria assembly.Furthermore,specific combination patterns improved the flavor quality of Zaopei by enhancing the interspecies interaction,which was closely related to rare taxa,especially rare bacteria.These findings highlighted that rare bacteria might be the keystone in involving community interaction and maintaining metabolic function,which provided a scientific foundation for better understanding and regulating the brewing microbiota from the viewpoint of microbial ecology.展开更多
In this paper, we discuss some properties about an abundant semigroup with a quasi-ideal adequate transversal. Moreover, we show that the product of two quasi-ideal adequate transversals of an abundant semigroup which...In this paper, we discuss some properties about an abundant semigroup with a quasi-ideal adequate transversal. Moreover, we show that the product of two quasi-ideal adequate transversals of an abundant semigroup which satisfies some conditions is a quasiideal adequate transversal.展开更多
Variations of picoplankton groups were investigated over a one-month period in Daya Bay and Sanya Bay,in the northern South China Sea.The two coastal regions exhibited different variation patterns in physicochemical p...Variations of picoplankton groups were investigated over a one-month period in Daya Bay and Sanya Bay,in the northern South China Sea.The two coastal regions exhibited different variation patterns in physicochemical parameters.Moreover,the diel variations of picoplankton groups were different between the two bays.The abundance of the picoplankton in Sanya Bay displayed a pronounced diel variation,while it was not significant in Daya Bay.In addition,some similar patterns of picoplankton abundance were discovered.In the two bays,virioplankton exhibited the smallest fluctuation range,whereas picocyanobacteria fluctuated most markedly.The fluctuation range of picoplankton groups was larger in spring tide than in neap tide,especially in Sanya Bay.Random forest model analysis demonstrated that the variation of picoplankton groups was attributed to physical and chemical factors in Sanya Bay and Daya Bay,respectively.Therefore,our findings suggest that virioplankton abundance can persist more stably in response to changing environmental conditions compared to bacterioplankton and picophytoplankton.展开更多
The abundance, distribution and diversity of epibenthic echinoderm were investigated at Dungonab Bay in the Red Sea coastal water of the Sudan. Four permanent line transects were chosen. Eight (30 × 2) square met...The abundance, distribution and diversity of epibenthic echinoderm were investigated at Dungonab Bay in the Red Sea coastal water of the Sudan. Four permanent line transects were chosen. Eight (30 × 2) square metre belt transects along each permanent line transect at 20 metre intervals were used to collect data. The data were subjected to univariate and multivariate analyses. Spatial variations of epibenthic echinoderm abundance were assessed with one-way analysis of variance. Hierarchical agglomerative clustering was used to identify and illustrate the similarities in echinoderm abundance between line transects and between belt transects. Indices of richness (d), diversity (H'), evenness (J') and dominance (C) were used to explain the diversity of epibenthic echinoderm species. The distribution pattern of each echinoderm species was determined in each permanent line transect. A total of 986 individuals were recorded within sixteen species of epibenthic echinoderms in the four line transects. Holothuriidae was the dominant family (5 species and 342 individuals). The most abundant echinoderms species was Pearsonothuria graeffei (77 individuals, about 7.81%). Abundances intra-transects and intra-families were insignificant (f = 1.67, p = 0.183, df = 3 and f = 3.24, p = 0.083, df = 9, respectively). The highest values of Shannon-Wiener diversity index (H'), Pielou evenness index (J'), Margalef species richness index (d), and Simpson Dominance index (C) were 2.738, 0.9875, 2.791 and 0.07159, respectively. The distribution patterns of all species in the study transects varied between clumped and uniform, with the exception of Asthenosoma varium of the Echinothuridae family, which had clumped distribution patterns in all transects. The study concluded that Dungonab Bay supports rich and diverse communities of epibenthic echinoderms.展开更多
Inland wetlands in Abu Dhabi Emirate are wintering and stopover sites for migratory birds of prey. We conducted long-term regular monitoring surveys in Al Wathba Wetland Reserve (AWWR) from January 1995 to December 20...Inland wetlands in Abu Dhabi Emirate are wintering and stopover sites for migratory birds of prey. We conducted long-term regular monitoring surveys in Al Wathba Wetland Reserve (AWWR) from January 1995 to December 2022. Both diurnal and occasionally nocturnal surveys were undertaken to record the migratory raptors and owls in the Wetland Reserve. During the study, a total of 1282 regular monitoring visits were undertaken and 27 species of diurnal raptors and owls representing five families and three orders were detected. These represent 57% of the total species of birds of prey recorded in the UAE. Overall, 63% of all the species that we observed were Accipitriformes followed by 26% Falconiformes and 11% Strigiformes. We found that changes in mean daily temperature have a positive effect on raptor species diversity and abundance in the Wetland Reserve. The species encounter rate was higher in low temperature as compared to high temperature and overall regression equation was statistically significant F (4, 1126) = 8.49), p = 0.00). However, the numbers of raptors did not vary significantly across the years (p = 0.51). Western Marsh-harrier (Circus aeruginosus) and Greater Spotted Eagle (Clanga clanga) were recorded to be the most abundant species in the wetland reserve followed by Common Kestrel (Falco tinnunculus). However, the encounter rate of globally threatened Greater Spotted Eagle was detected to have significantly decreased since 2016. Moreover, 63% of the species detected were uncommon and rarely recorded such as 1) Saker Falcon 2) Lanner Falcon 3) Long-eared Owl & Merlin, which were the rare records from the wetland reserve. Furthermore, 27 years of regular monitoring in the wetland have yielded diverse diurnal raptors and owl fauna (H) = 0.83, (E) = 1.43 (Shannon Diversity Index). The results demonstrate that long-term monitoring surveys in arid environments are essential to determine the trends in the raptor populations and to document rare and globally important species.展开更多
Globally, human activities have a significant impact on the diversity, abundance, and distribution of large mammals in Protected Areas (PAs). These disturbances increase human pressure on biodiversity and species habi...Globally, human activities have a significant impact on the diversity, abundance, and distribution of large mammals in Protected Areas (PAs). These disturbances increase human pressure on biodiversity and species habitats, highlighting the need for conservation. This study aimed to assess the abundance and distribution of large mammals in different habitat types within Nimule National Park (NNP) and understand the impacts of human activities on them. Data on the abundance and distribution of large mammals and their respective habitat types were collected through line transect surveys. Human activity signs were observed and recorded along the transect lines. To estimate the impacts of human activities on the diversity, abundance, and distribution of large mammal species, as well as to identify any significant differences between them and their habitat types, the study utilized the Kruskal Wallis test, Polynomial multiple regressions, and diversity indices. The findings from the Shannon-Weiner and Simpson indices indicated that large mammal species were more diverse inside the park (H’ = 1.136;D = 0.570) compared to the buffer zone (H’ = 0.413;D = 0.171), with 85% (443 out of 510 samples) recorded within Nimule National Park. The species abundance showed a semi-balanced status (0.58). The diversity results among different habitat types revealed that large mammals were more diverse and highly distributed in both open woodlands (244) and dense woodlands (192), while riverine vegetation had the lowest diversity (8). Statistical tests demonstrated a highly significant difference at a 99% confidence interval (p-value = 0.01) between habitat types and identified species of large mammals. Additionally, the results highlighted the high abundance of Uganda kob (274), baboons (141), and warthog (57) across most habitat types, accounting for at least 75% of their distribution. The most prevalent human activities observed were cattle footprints (27%) and cattle dung (14%). Human footprints and tree cutting combined accounted for 9%, indicating the practice of livestock grazing, poaching, encroachment, and fuelwood collection by local communities. However, these activities did not appear to significantly impact the diversity, abundance, and distribution of large mammals in Nimule National Park. Therefore, it is crucial to foster shared responsibilities and engage relevant stakeholders in the management and conservation of large wildlife species. Regular community awareness programs should be implemented to cultivate a sense of ownership. Moreover, it is recommended that a comprehensive survey be conducted on the population status of all mammal species in Nimule National Park, including its surrounding Buffer Zone. Monitoring the impact of human activities on their behavior and habitats using satellite images should also be carried out at least every five to ten years.展开更多
Big Bang nucleosynthesis(BBN)theory predicts the primordial abundances of the light elements^(2) H(referred to as deuterium,or D for short),^(3)He,^(4)He,and^(7) Li produced in the early universe.Among these,deuterium...Big Bang nucleosynthesis(BBN)theory predicts the primordial abundances of the light elements^(2) H(referred to as deuterium,or D for short),^(3)He,^(4)He,and^(7) Li produced in the early universe.Among these,deuterium,the first nuclide produced by BBN,is a key primordial material for subsequent reactions.To date,the uncertainty in predicted deuterium abundance(D/H)remains larger than the observational precision.In this study,the Monte Carlo simulation code PRIMAT was used to investigate the sensitivity of 11 important BBN reactions to deuterium abundance.We found that the reaction rate uncertainties of the four reactions d(d,n)^(3)He,d(d,p)t,d(p,γ)^(3)He,and p(n,γ)d had the largest influence on the calculated D/H uncertainty.Currently,the calculated D/H uncertainty cannot reach observational precision even with the recent LUNA precise d(p,γ)^(3) He rate.From the nuclear physics aspect,there is still room to largely reduce the reaction-rate uncertainties;hence,further measurements of the important reactions involved in BBN are still necessary.A photodisintegration experiment will be conducted at the Shanghai Laser Electron Gamma Source Facility to precisely study the deuterium production reaction of p(n,γ)d.展开更多
The present study conducted in the town of Ombessa aims to assess the influence of abiotic factors on the abundance dynamics and antibiotic susceptibility of Escherichia coli and Enterococcus faecalis isolated from so...The present study conducted in the town of Ombessa aims to assess the influence of abiotic factors on the abundance dynamics and antibiotic susceptibility of Escherichia coli and Enterococcus faecalis isolated from some aquatic systems from February to July 2022, monthly samples were taken at 10 water points used by the population (8 groundwater points and 2 surface water points). Samples were analyzed for physico-chemical parameters such as temperature, pH, electrical conductivity. Bacteriological variables such as BHAM, E. coli and E. faecalis abundances were also assessed. Antibiotic susceptibility of E. coli and E. faecalis was assessed using 06 antibiotics using the Kirby-Bauer diffusion disk method. The results show that bacterial abundances were the highest in surface waters. Bacterial densities were the highest in May and the lowest in February. The average densities recorded were 3845 CFU/100mL for BHAM, 380 CFU/100mL for E. coli and 14 CFU/100mL for E. faecalis in groundwater;and 8583 CFU/100mL for BHAM, 6878 CFU/100mL for E. coli and 812 CFU/100mL for E. faecalis in surface water. Antibiotic susceptibility tests showed that these bacterial species are sensitive to Gentamicin, Chloramphenicol, Azithromycin and Ciprofloxacin. They are all resistant to Trimethoprim/Sulfamethoxazole, E. coli is resistant to Doxycycline and E. faecalis has an intermediate sensitivity to Gentamicin. Overall, the Multiresistance to Antibiotics (MRA) indices obtained were above 0.2, indicating the presence of multidrug resistance in bacterial communities. The physico-chemical properties of the water varied over time and space, but on the whole remained below the threshold values of WHO guidelines. The degree of linkage between abiotic water variables and bacteriological parameters has shown that bacterial densities are more abundant in rainy seasons and increased O2 levels favor bacterial growth, while TSS, CO2 and dissolved nitrate levels affect the sensitivity of these bacterial species to antibiotics.展开更多
The fishing survey station located in the warm waters of the East China Sea is one of the abundant fishery resources of waters;with a large number of economic fish breeding grounds and economic juvenile feeding ground...The fishing survey station located in the warm waters of the East China Sea is one of the abundant fishery resources of waters;with a large number of economic fish breeding grounds and economic juvenile feeding grounds. Several fish species according to this bottom trawl survey results which appear in the annual survey from winter to autumn give us a total of 58 species, which have appeared throughout the year. But the vast majority of species appears only in certain seasons, according to the sea fish survey and based on seasonal migratory species or species mainly small endemic species. The survey of fish is tropical and subtropical warm water species and warm temperate species, and the history of the area has several types of 397 different species. There are many reasons, in addition to recent years, human disturbance and adverse consequences of environmental changes brought about, but also with the relevant sampling methods and sampler time, the survey sampled only trawl based, from Ping yang Ocean and Fisheries Bureau, the waters are still other jobs method net, gill nets, fishing industry, etc. Survey results show that the type of fish in the summer (58 species) > spring (55 species) > winter (51 species) > autumn (42 species). The type of season was among spring to summer rose, summer to autumn decline. The survey found that in the reef area of the Nanji Islands, no one species of fish is the dominant species throughout the year (according to the dominant species, each species is dominant only in one season). From the dominant species turnover accounting for the four seasons, in winter it has 53.72% of the total biomass or annual biomass, spring it has 41.53% of the overall biomass, summer it has 31.85% and autumn it has 38.56% of total biomass. Visible, seasonal succession of dominant species of fish phenomenon is very obvious, especially in the spring and winter, summer transfers dominate species at this stage show the greatest change, but winter, the transfer of this dominant species changes in minimal. Seasonal changes from biomass and the average annual marine fish survey biomass were 4832.25 g/h. From different seasons, the average biomass in winter (10779.88 g/h) > of the average biomass in spring (3624.1 g/hour) > of the mean biomass in autumn (3158 g/h) > the average Biomass in summer (1767 g/h). All of them show significant seasonal variation of the biomass, in winter and spring, the biomass is generally not high, but significantly higher than in the summer and autumn seasons. Each season, around the coast of southern Zhejiang, is less than the biomass and other catches off, which involves investigating sea location, size range, and the survey ship different network related tools. Another change from the area of biomass, some studies found that the survey of four-season fish of waters above the biological capacity of several kilograms only in some stations, namely stations and the highest biomass in summer appeared in stations 3, 7 and 11. In autumn the highest biomass appeared in stations 3, 6, 20 and 23.展开更多
Developing earth-abundant-electrocatalysts for hydrogen evolution reaction is one of the promising ways to achieve efficient water-splitting for hydrogen production(a clean chemical fuel).This paper reviews the activi...Developing earth-abundant-electrocatalysts for hydrogen evolution reaction is one of the promising ways to achieve efficient water-splitting for hydrogen production(a clean chemical fuel).This paper reviews the activity,stability and durability for hydrogen evolution reaction in alkaline medium of different types of recently reported potential electrocatalysts such as Ni,Co,NiCo,Fe,Cu,W,Mo,Se,Mn.Zn,V,and metal free based earth-abundant-electrocatalysts.Further,this paper reviews the strategies used to achieve the remarkably low overpotential(including r/i0:<35mV),high long term stability(including^:100 h)and high durability(including>5000 cycles)of potential earth-abundant-electrocatalysts for hydrogen evolution reaction in alkaline medium and those are better or well comparable with the state-of-the-art,noble,Pt/C electrocatalyst.Finally,this paper summarizes the efficient strategies such as preparing porous structured materials,preparing nanostructured materials with superaerophobic surface,preparing nanostructured materials,preparing carbon composites/integrating electrocatalysts with carbon,preparing amorphous materials,preparing materials w让h oxygen vacancies/defects,preparing metal chalcogenides,preparing bimetallic/multi-metallic materials,doping metals or heteroatoms,preparing electrocatalysts with core-shell structure,decorating electrocatalysts with amines,preparing homojunction/heterojunction structured materials,preparing hollow structured materials,and preparing boronrich surface to enhance the activity,stability,and durability for HER.展开更多
Taking Chongzuo City of Guangxi Zhuang Autonomous Region as an example, the employment effect of the resource-abundant industrial cluster in southwestern Guangxi Province is analyzed according to the data from the Cho...Taking Chongzuo City of Guangxi Zhuang Autonomous Region as an example, the employment effect of the resource-abundant industrial cluster in southwestern Guangxi Province is analyzed according to the data from the Chongzuo Statistical Yearbook , Guangxi Statistical Yearbook from 2003 to 2008 and the data from the relevant sections of Chongzuo City, and the four employment effects of industrial cluster--the spatial expansion effect of employment chain, optimizing effect of employment structure, the multiplier effect of employment absorption and the effect of improving the quality of labors and the degree of the intensity of employment and location quotient of employment. Results show that the employment absorption of sugar industry in Chongzuo City is stable and upward slightly, and it shows strong employment effect; the sugar industry in Chongzuo is not only competitive, but also has a great share of market in employment, so it owns strong absorption of employment. The countermeasures for improving the employment level of resource-abundant and industrial cluster in southwest of Guangxi Province are put forward, including elongating industrial chain and widening employment space; strengthening various kinds of formal and informal training to improve the employment capability of laborers; laying stress on industrial structure and optimizing the employment structure; strengthening the construction of the industrial economic zone towards ASEAN(Association of Southeast Asian Nations), and fully displaying the regional advantages of the offshore border.展开更多
The meteorological conditions in the abundant or the lean years of crops in Mudanjiang City of Heilongjiang Province were analyzed. The study shows that heat,water and light coordinated closely in the abundant years;o...The meteorological conditions in the abundant or the lean years of crops in Mudanjiang City of Heilongjiang Province were analyzed. The study shows that heat,water and light coordinated closely in the abundant years;on the contrary,the comprehensive meteorological conditions were unfavorable for agricultural production in the lean years. A good yield showed up when there were a higher temperature and a larger amount of accumulated temperature above 10 ℃ with no sign of cold damage,an exactly favorable precipitation distribution with little drought or water-logging and a comparatively abundant light during the growing season(from May to September) . However,the crop yield was low when there were a lower temperature and a smaller amount of accumulated temperature,an abnormal precipitation distribution with drought or water logging and scant sunlight during the growing season(from May to September).展开更多
Tuning the electronic structure of the electrocatalysts for oxygen evolution reaction(OER)is a promising way to achieve efficient alkaline water splitting for clean energy production(H2).At first,this paper introduces...Tuning the electronic structure of the electrocatalysts for oxygen evolution reaction(OER)is a promising way to achieve efficient alkaline water splitting for clean energy production(H2).At first,this paper introduces the significance of the tuning of electronic structure,where modifying the electronic structure of the electrocatalysts could generate active sites having optimal adsorption energy with OER intermediates,and that could diminish the energy barrier for OER,and that could improve the activity for OER.Later,this paper reviews the tuning of electronic structure along with catalytic performances,synthetic methodologies,chemical properties,and DFT calculations on various nanostructured earth-abundant electrocatalysts for OER in alkaline environment.Further,this review discusses the tuning of the electronic structure of the several nanostructured earth-abundant electrocatalysts including oxide,(oxy)hydroxide,layered double hydroxide,alloy,metal phosphide/phosphate,nitride,sulfide,selenide,carbon containing materials,MOF,core-shell/hetero/hollow structured materials,and materials with vacancies/defects for OER in alkaline environment(including activity:overpotential(η)of ≤200 mV at10 m A cm^(-2);stability:≥100 h;durability:≥5000 cycles).Then,this review discusses the robust stability of the electrocatalysts for OER towards practical application.Moreover,this review discusses the in situ formation of thin layer on the catalyst surface during OER.In addition,this review discusses the influence of the adsorption energy of the OER intermediates on OER performance of the catalysts.Finally,this review summarizes the various promising strategies for tuning the electronic structure of the electrocatalysts to achieve enhanced performance for OER in alkaline environment.展开更多
Transition metal chalcogenides have nowadays garnered burgeoning interest owing to their fascinating electronic and catalytic properties,thus possessing great implications for energy conversion and storage application...Transition metal chalcogenides have nowadays garnered burgeoning interest owing to their fascinating electronic and catalytic properties,thus possessing great implications for energy conversion and storage applications.In this regard,their controllable synthesis in a large scale at low cost has readily become a focus of research.Herein we report diatomite-template generic and scalable production of VS2 and other transition metal sulfides targeting emerging energy conversion and storage applications.The conformal growth of VS2over diatomite template would endow them with defect-abundant features.Throughout detailed experimental investigation in combination with theoretical simulation,we reveal that the enriched active sites/sulfur vacancies of thus-derived VS2 architectures would pose positive impacts on the catalytic performance such in electrocatalytic hydrogen evolution reactions.We further show that the favorable electrical conductivity and highly exposed sites of VS2 hold promise for serving as sulfur host in the realm of Li-S batteries.Our work offers new insights into the templated and customized synthesis of defect-rich sulfides in a scalable fashion to benefit multifunctional energy applications.展开更多
Objective The Tarim Basin is China's largest ore-bearing interior basin, and contains mainly marine oils. The Kuqa depression, a secondary structural unit within the northem Tarim Basin, is composed of Mesozoic and ...Objective The Tarim Basin is China's largest ore-bearing interior basin, and contains mainly marine oils. The Kuqa depression, a secondary structural unit within the northem Tarim Basin, is composed of Mesozoic and Cenozoic clastic sedimentary rocks dominated by continental oil. Previous research suggests that the crude oils especially condensates in the Kuqa depression are rich in abnormally high abundant rearranged hopanes. On the basis of 41 condensate samples and five oil samples from the Kuqa depression, this work systematically discussed the relationship between biomarker parameters and rearranged hopanes and deeply investigated the influence of depositional environment, original source,展开更多
On the base of the construction of abundant semigroups with a normal medial idempotent [14], in this paper we consider a class of naturally ordered abundant semigroups which satisfies the regularity condition and cont...On the base of the construction of abundant semigroups with a normal medial idempotent [14], in this paper we consider a class of naturally ordered abundant semigroups which satisfies the regularity condition and contains a greatest idempotent. Furthermore, we give a completely description of the overall structure of such ordered semigroups via the algebraic structure of them, which generalizes known result obtained by Blyth and McFadden[3].展开更多
Soil microorganisms play important roles in nitrogen transformation. The aim of this study was to characterize changes in the activity of nitrogen transformation enzymes and the abundance of nitrogen function genes in...Soil microorganisms play important roles in nitrogen transformation. The aim of this study was to characterize changes in the activity of nitrogen transformation enzymes and the abundance of nitrogen function genes in rhizosphere soil aerated using three different methods(continuous flooding(CF), continuous flooding and aeration(CFA), and alternate wetting and drying(AWD)). The abundances of amoA ammonia-oxidizing archaea(AOA) and ammonia-oxidizing bacteria(AOB), nirS, nirK, and nifH genes, and the activities of urease, protease, ammonia oxidase, nitrate reductase, and nitrite reductase were measured at the tillering(S1), heading(S2), and ripening(S3) stages. We analyzed the relationships of the aforementioned microbial activity indices, in addition to soil microbial biomass carbon(MBC) and soil microbial biomass nitrogen(MBN), with the concentration of soil nitrate and ammonium nitrogen. The abundance of nitrogen function genes and the activities of nitrogen invertase in rice rhizosphere soil were higher at S2 compared with S1 and S3 in all treatments. AWD and CFA increased the abundance of amoA and nifH genes, and the activities of urease, protease, and ammonia oxidase, and decreased the abundance of nirS and nirK genes and the activities of nitrate reductase and nitrite reductase, with the effect of AWD being particularly strong. During the entire growth period, the mean abundances of the AOA amoA, AOB amoA, and nifH genes were 2.9, 5.8, and 3.0 higher in the AWD treatment than in the CF treatment, respectively, and the activities of urease, protease, and ammonia oxidase were 1.1, 0.5, and 0.7 higher in the AWD treatment than in the CF treatment, respectively. The abundances of the nirS and nirK genes, and the activities of nitrate reductase and nitrite reductase were 73.6, 84.8, 10.3 and 36.5% lower in the AWD treatment than in the CF treatment, respectively. The abundances of the AOA amoA, AOB amoA, and nifH genes were significantly and positively correlated with the activities of urease, protease, and ammonia oxidase, and the abundances of the nirS and nirK genes were significantly positively correlated with the activities of nitrate reductase. All the above indicators were positively correlated with soil MBC and MBN. In sum, microbial activity related to nitrogen transformation in rice rhizosphere soil was highest at S2. Aeration can effectively increase the activity of most nitrogen-converting microorganisms and MBN, and thus promote soil nitrogen transformation.展开更多
基金Supported by 2020 Guangxi Zhuang Autonomous Region Health Care Commission Self-Financing Research Projects,No.Z202000962023 Guangxi University Young and Middle-Aged Teachers’Basic Research Ability Improvement Project,No.2023KY0091+1 种基金National Natural Science Foundation of China,No.82260241the Natural Science Foundation of Guangxi Province,No.2015GXNSFAA139171 and No.2020GXNSFAA259053.
文摘BACKGROUND Alzheimer’s disease(AD)is a neurodegenerative condition characterized by oxidative stress and neuroinflammation.Tanshinone ⅡA(Tan-ⅡA),a bioactive compound isolated from Salvia miltiorrhiza plants,has shown potential neuroprotective effects;however,the mechanisms underlying such a function remain unclear.AIM To investigate potential Tan-ⅡA neuroprotective effects in AD and to elucidate their underlying mechanisms.METHODS Hematoxylin and eosin staining was utilized to analyze structural brain tissue morphology.To assess changes in oxidative stress and neuroinflammation,we performed enzyme-linked immunosorbent assay and western blotting.Additionally,the effect of Tan-ⅡA on AD cell models was evaluated in vitro using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay.Genetic changes related to the long non-coding RNA(lncRNA)nuclear-enriched abundant transcript 1(NEAT1)/microRNA(miRNA,miR)-291a-3p/member RAS oncogene family Rab22a axis were assessed through reverse transcription quantitative polymerase chain reaction.RESULTS In vivo,Tan-ⅡA treatment improved neuronal morphology and attenuated oxidative stress and neuroinflammation in the brain tissue of AD mice.In vitro experiments showed that Tan-ⅡA dose-dependently ameliorated the amyloid-beta 1-42-induced reduction of neural stem cell viability,apoptosis,oxidative stress,and neuroinflammation.In this process,the lncRNA NEAT1-a potential therapeutic target-is highly expressed in AD mice and downregulated via Tan-ⅡA treatment.Mechanistically,NEAT1 promotes the transcription and translation of Rab22a via miR-291a-3p,which activates nuclear factor kappa-B(NF-κB)signaling,leading to activation of the pro-apoptotic B-cell lymphoma 2-associated X protein and inhibition of the anti-apoptotic B-cell lymphoma 2 protein,which exacerbates AD.Tan-ⅡA intervention effectively blocked this process by inhibiting the NEAT1/miR-291a-3p/Rab22a axis and NF-κB signaling.CONCLUSION This study demonstrates that Tan-ⅡA exerts neuroprotective effects in AD by modulating the NEAT1/miR-291a-3p/Rab22a/NF-κB signaling pathway,serving as a foundation for the development of innovative approaches for AD therapy.
基金The National Natural Science Foundation of China under contract Nos 41920104006the Scientific Research Fund of Second Institute of Oceanography+3 种基金Ministry of Natural Resources under contract Nos JZ2001,XRJH2410,and QNYC2102the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University under contract No.SL2021MS021the Global Climate Changes and Air-sea Interaction Program under contract No.GASI-02-PAC-ST-Wwinthe Taishan Scholars Program under contract No.tsqn202306282。
文摘The South China Sea(SCS)is a marginal sea connecting the Pacific and Indian oceans and has gained much attention in recent decades.The dynamics in the northeast SCS are considerably influenced by topography,monsoons,tropical cyclones,the Kuroshio intrusion,and water exchange through the Luzon Strait(LS).
基金the Sino-German Cooperation Forestry Major Scientific Research Project(zdczhz2021ky09)the National Natural Science Foundation of China(31971487 and 42277245).
文摘Thinning is an effective management step for sustainable forest development,yet less attention is paid to the restoration of soil microbiota after thinning.In this study,both abundant and rare soil microbial communities(i.e.,bacterial,fungal),were evaluated under various thinning treatments in a mixed stand of Cunninghamia lanceolata and Sassafras tzumu using Mi Seq sequencing.Thinning did not significantly change either abundant or rare bacterial and fungal community composition,but affected their alpha diversity.The Shannon–Wiener indexes of rare fungal taxa under medium thinning were significantly lower than in the light thinning(P<0.05 level).Xanthobacteraceae dominated the abundant bacterial taxa,and Saitozyma and Mortierlla the abundant fungal taxa.The most common rare bacterial taxa varied;there was no prevalent rare fungal taxa under different thinnings.In addition,soil available nitrogen,total phosphorus,and p H had significant effects on rare bacterial taxa.Nutrients,especially available phosphorus,but not nitrogen,affected abundant and rare soil fungi.The results indicate that soil properties rather than plant factors affect abundant and rare microbial communities in soils of mixed stands.Thinning,through mediating soil properties,influences both abundant and rare bacterial and fungal communities in the mixed C.lanceolata and S.tzumu stand.
基金supported by the Cooperation Project of Luzhou Laojiao Co.,Ltd.Sichuan University (21H0997)。
文摘The quality and aroma of strong-flavor Baijiu are mainly dependent on Daqu,pit mud(PM),and the interaction of both.However,little is known about how their combination patterns affect the microbiome and metabolome of Zaopei,especially the metabolic function of rare taxa.Here,an experiment on industrial size was designed to assess the effects of 6 combinations(3 kinds of Daqu×2 kinds of PM)on the composition and assembly of different taxa,as well as the flavor profile.The results showed that Zaopei's microbiota was composed of a few abundant taxa and enormous rare taxa,and rare bacterial and abundant fungal subcommunities were significantly affected by combination patterns.The assembly processes of abundant/rare taxa and bacterial/fungal communities were distinct,and environmental changes mediated the balance between stochastic and deterministic processes in rare bacteria assembly.Furthermore,specific combination patterns improved the flavor quality of Zaopei by enhancing the interspecies interaction,which was closely related to rare taxa,especially rare bacteria.These findings highlighted that rare bacteria might be the keystone in involving community interaction and maintaining metabolic function,which provided a scientific foundation for better understanding and regulating the brewing microbiota from the viewpoint of microbial ecology.
基金Supported by National Natural Science Foundation of China(90818020) Supported by Scientific Research Foundation of China Jiliang University(20060810)
文摘In this paper, we discuss some properties about an abundant semigroup with a quasi-ideal adequate transversal. Moreover, we show that the product of two quasi-ideal adequate transversals of an abundant semigroup which satisfies some conditions is a quasiideal adequate transversal.
基金Supported by the National Natural Science Foundation of China(Nos.42176116,41576126,41890851,U21A6001)the Natural Science Foundation of Guangdong Province(No.2017A030306020)+4 种基金the Guangdong Major Project of Basic and Applied Basic Research(No.2019B030302004)the Rising Star Foundation of the South China Sea Institute of Oceanology(No.NHXX2019ST0101)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2018377)the Science and Technology Planning Project of Guangdong Province of China(No.2021B1212050023)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA19060503)。
文摘Variations of picoplankton groups were investigated over a one-month period in Daya Bay and Sanya Bay,in the northern South China Sea.The two coastal regions exhibited different variation patterns in physicochemical parameters.Moreover,the diel variations of picoplankton groups were different between the two bays.The abundance of the picoplankton in Sanya Bay displayed a pronounced diel variation,while it was not significant in Daya Bay.In addition,some similar patterns of picoplankton abundance were discovered.In the two bays,virioplankton exhibited the smallest fluctuation range,whereas picocyanobacteria fluctuated most markedly.The fluctuation range of picoplankton groups was larger in spring tide than in neap tide,especially in Sanya Bay.Random forest model analysis demonstrated that the variation of picoplankton groups was attributed to physical and chemical factors in Sanya Bay and Daya Bay,respectively.Therefore,our findings suggest that virioplankton abundance can persist more stably in response to changing environmental conditions compared to bacterioplankton and picophytoplankton.
文摘The abundance, distribution and diversity of epibenthic echinoderm were investigated at Dungonab Bay in the Red Sea coastal water of the Sudan. Four permanent line transects were chosen. Eight (30 × 2) square metre belt transects along each permanent line transect at 20 metre intervals were used to collect data. The data were subjected to univariate and multivariate analyses. Spatial variations of epibenthic echinoderm abundance were assessed with one-way analysis of variance. Hierarchical agglomerative clustering was used to identify and illustrate the similarities in echinoderm abundance between line transects and between belt transects. Indices of richness (d), diversity (H'), evenness (J') and dominance (C) were used to explain the diversity of epibenthic echinoderm species. The distribution pattern of each echinoderm species was determined in each permanent line transect. A total of 986 individuals were recorded within sixteen species of epibenthic echinoderms in the four line transects. Holothuriidae was the dominant family (5 species and 342 individuals). The most abundant echinoderms species was Pearsonothuria graeffei (77 individuals, about 7.81%). Abundances intra-transects and intra-families were insignificant (f = 1.67, p = 0.183, df = 3 and f = 3.24, p = 0.083, df = 9, respectively). The highest values of Shannon-Wiener diversity index (H'), Pielou evenness index (J'), Margalef species richness index (d), and Simpson Dominance index (C) were 2.738, 0.9875, 2.791 and 0.07159, respectively. The distribution patterns of all species in the study transects varied between clumped and uniform, with the exception of Asthenosoma varium of the Echinothuridae family, which had clumped distribution patterns in all transects. The study concluded that Dungonab Bay supports rich and diverse communities of epibenthic echinoderms.
文摘Inland wetlands in Abu Dhabi Emirate are wintering and stopover sites for migratory birds of prey. We conducted long-term regular monitoring surveys in Al Wathba Wetland Reserve (AWWR) from January 1995 to December 2022. Both diurnal and occasionally nocturnal surveys were undertaken to record the migratory raptors and owls in the Wetland Reserve. During the study, a total of 1282 regular monitoring visits were undertaken and 27 species of diurnal raptors and owls representing five families and three orders were detected. These represent 57% of the total species of birds of prey recorded in the UAE. Overall, 63% of all the species that we observed were Accipitriformes followed by 26% Falconiformes and 11% Strigiformes. We found that changes in mean daily temperature have a positive effect on raptor species diversity and abundance in the Wetland Reserve. The species encounter rate was higher in low temperature as compared to high temperature and overall regression equation was statistically significant F (4, 1126) = 8.49), p = 0.00). However, the numbers of raptors did not vary significantly across the years (p = 0.51). Western Marsh-harrier (Circus aeruginosus) and Greater Spotted Eagle (Clanga clanga) were recorded to be the most abundant species in the wetland reserve followed by Common Kestrel (Falco tinnunculus). However, the encounter rate of globally threatened Greater Spotted Eagle was detected to have significantly decreased since 2016. Moreover, 63% of the species detected were uncommon and rarely recorded such as 1) Saker Falcon 2) Lanner Falcon 3) Long-eared Owl & Merlin, which were the rare records from the wetland reserve. Furthermore, 27 years of regular monitoring in the wetland have yielded diverse diurnal raptors and owl fauna (H) = 0.83, (E) = 1.43 (Shannon Diversity Index). The results demonstrate that long-term monitoring surveys in arid environments are essential to determine the trends in the raptor populations and to document rare and globally important species.
文摘Globally, human activities have a significant impact on the diversity, abundance, and distribution of large mammals in Protected Areas (PAs). These disturbances increase human pressure on biodiversity and species habitats, highlighting the need for conservation. This study aimed to assess the abundance and distribution of large mammals in different habitat types within Nimule National Park (NNP) and understand the impacts of human activities on them. Data on the abundance and distribution of large mammals and their respective habitat types were collected through line transect surveys. Human activity signs were observed and recorded along the transect lines. To estimate the impacts of human activities on the diversity, abundance, and distribution of large mammal species, as well as to identify any significant differences between them and their habitat types, the study utilized the Kruskal Wallis test, Polynomial multiple regressions, and diversity indices. The findings from the Shannon-Weiner and Simpson indices indicated that large mammal species were more diverse inside the park (H’ = 1.136;D = 0.570) compared to the buffer zone (H’ = 0.413;D = 0.171), with 85% (443 out of 510 samples) recorded within Nimule National Park. The species abundance showed a semi-balanced status (0.58). The diversity results among different habitat types revealed that large mammals were more diverse and highly distributed in both open woodlands (244) and dense woodlands (192), while riverine vegetation had the lowest diversity (8). Statistical tests demonstrated a highly significant difference at a 99% confidence interval (p-value = 0.01) between habitat types and identified species of large mammals. Additionally, the results highlighted the high abundance of Uganda kob (274), baboons (141), and warthog (57) across most habitat types, accounting for at least 75% of their distribution. The most prevalent human activities observed were cattle footprints (27%) and cattle dung (14%). Human footprints and tree cutting combined accounted for 9%, indicating the practice of livestock grazing, poaching, encroachment, and fuelwood collection by local communities. However, these activities did not appear to significantly impact the diversity, abundance, and distribution of large mammals in Nimule National Park. Therefore, it is crucial to foster shared responsibilities and engage relevant stakeholders in the management and conservation of large wildlife species. Regular community awareness programs should be implemented to cultivate a sense of ownership. Moreover, it is recommended that a comprehensive survey be conducted on the population status of all mammal species in Nimule National Park, including its surrounding Buffer Zone. Monitoring the impact of human activities on their behavior and habitats using satellite images should also be carried out at least every five to ten years.
基金supported by the National Key R&D Program of China(No.2022YFA1602401)by the National Natural Science Foundation of China(No.11825504)。
文摘Big Bang nucleosynthesis(BBN)theory predicts the primordial abundances of the light elements^(2) H(referred to as deuterium,or D for short),^(3)He,^(4)He,and^(7) Li produced in the early universe.Among these,deuterium,the first nuclide produced by BBN,is a key primordial material for subsequent reactions.To date,the uncertainty in predicted deuterium abundance(D/H)remains larger than the observational precision.In this study,the Monte Carlo simulation code PRIMAT was used to investigate the sensitivity of 11 important BBN reactions to deuterium abundance.We found that the reaction rate uncertainties of the four reactions d(d,n)^(3)He,d(d,p)t,d(p,γ)^(3)He,and p(n,γ)d had the largest influence on the calculated D/H uncertainty.Currently,the calculated D/H uncertainty cannot reach observational precision even with the recent LUNA precise d(p,γ)^(3) He rate.From the nuclear physics aspect,there is still room to largely reduce the reaction-rate uncertainties;hence,further measurements of the important reactions involved in BBN are still necessary.A photodisintegration experiment will be conducted at the Shanghai Laser Electron Gamma Source Facility to precisely study the deuterium production reaction of p(n,γ)d.
文摘The present study conducted in the town of Ombessa aims to assess the influence of abiotic factors on the abundance dynamics and antibiotic susceptibility of Escherichia coli and Enterococcus faecalis isolated from some aquatic systems from February to July 2022, monthly samples were taken at 10 water points used by the population (8 groundwater points and 2 surface water points). Samples were analyzed for physico-chemical parameters such as temperature, pH, electrical conductivity. Bacteriological variables such as BHAM, E. coli and E. faecalis abundances were also assessed. Antibiotic susceptibility of E. coli and E. faecalis was assessed using 06 antibiotics using the Kirby-Bauer diffusion disk method. The results show that bacterial abundances were the highest in surface waters. Bacterial densities were the highest in May and the lowest in February. The average densities recorded were 3845 CFU/100mL for BHAM, 380 CFU/100mL for E. coli and 14 CFU/100mL for E. faecalis in groundwater;and 8583 CFU/100mL for BHAM, 6878 CFU/100mL for E. coli and 812 CFU/100mL for E. faecalis in surface water. Antibiotic susceptibility tests showed that these bacterial species are sensitive to Gentamicin, Chloramphenicol, Azithromycin and Ciprofloxacin. They are all resistant to Trimethoprim/Sulfamethoxazole, E. coli is resistant to Doxycycline and E. faecalis has an intermediate sensitivity to Gentamicin. Overall, the Multiresistance to Antibiotics (MRA) indices obtained were above 0.2, indicating the presence of multidrug resistance in bacterial communities. The physico-chemical properties of the water varied over time and space, but on the whole remained below the threshold values of WHO guidelines. The degree of linkage between abiotic water variables and bacteriological parameters has shown that bacterial densities are more abundant in rainy seasons and increased O2 levels favor bacterial growth, while TSS, CO2 and dissolved nitrate levels affect the sensitivity of these bacterial species to antibiotics.
文摘The fishing survey station located in the warm waters of the East China Sea is one of the abundant fishery resources of waters;with a large number of economic fish breeding grounds and economic juvenile feeding grounds. Several fish species according to this bottom trawl survey results which appear in the annual survey from winter to autumn give us a total of 58 species, which have appeared throughout the year. But the vast majority of species appears only in certain seasons, according to the sea fish survey and based on seasonal migratory species or species mainly small endemic species. The survey of fish is tropical and subtropical warm water species and warm temperate species, and the history of the area has several types of 397 different species. There are many reasons, in addition to recent years, human disturbance and adverse consequences of environmental changes brought about, but also with the relevant sampling methods and sampler time, the survey sampled only trawl based, from Ping yang Ocean and Fisheries Bureau, the waters are still other jobs method net, gill nets, fishing industry, etc. Survey results show that the type of fish in the summer (58 species) > spring (55 species) > winter (51 species) > autumn (42 species). The type of season was among spring to summer rose, summer to autumn decline. The survey found that in the reef area of the Nanji Islands, no one species of fish is the dominant species throughout the year (according to the dominant species, each species is dominant only in one season). From the dominant species turnover accounting for the four seasons, in winter it has 53.72% of the total biomass or annual biomass, spring it has 41.53% of the overall biomass, summer it has 31.85% and autumn it has 38.56% of total biomass. Visible, seasonal succession of dominant species of fish phenomenon is very obvious, especially in the spring and winter, summer transfers dominate species at this stage show the greatest change, but winter, the transfer of this dominant species changes in minimal. Seasonal changes from biomass and the average annual marine fish survey biomass were 4832.25 g/h. From different seasons, the average biomass in winter (10779.88 g/h) > of the average biomass in spring (3624.1 g/hour) > of the mean biomass in autumn (3158 g/h) > the average Biomass in summer (1767 g/h). All of them show significant seasonal variation of the biomass, in winter and spring, the biomass is generally not high, but significantly higher than in the summer and autumn seasons. Each season, around the coast of southern Zhejiang, is less than the biomass and other catches off, which involves investigating sea location, size range, and the survey ship different network related tools. Another change from the area of biomass, some studies found that the survey of four-season fish of waters above the biological capacity of several kilograms only in some stations, namely stations and the highest biomass in summer appeared in stations 3, 7 and 11. In autumn the highest biomass appeared in stations 3, 6, 20 and 23.
基金supported by the National Natural Science Foundation of Chinathe Innovative Research Team in the University+4 种基金the Program for Changjiang Scholarsthe Fundamental Research Funds for the Central Universitiesthe longterm subsidy mechanism from the Ministry of Financethe Ministry of Education of People’s Republic of China (PRC)the Science and Engineering Research Board (SERB), Department of Science and Technology, Government of India (Reference No. PDF/2017/000015)
文摘Developing earth-abundant-electrocatalysts for hydrogen evolution reaction is one of the promising ways to achieve efficient water-splitting for hydrogen production(a clean chemical fuel).This paper reviews the activity,stability and durability for hydrogen evolution reaction in alkaline medium of different types of recently reported potential electrocatalysts such as Ni,Co,NiCo,Fe,Cu,W,Mo,Se,Mn.Zn,V,and metal free based earth-abundant-electrocatalysts.Further,this paper reviews the strategies used to achieve the remarkably low overpotential(including r/i0:<35mV),high long term stability(including^:100 h)and high durability(including>5000 cycles)of potential earth-abundant-electrocatalysts for hydrogen evolution reaction in alkaline medium and those are better or well comparable with the state-of-the-art,noble,Pt/C electrocatalyst.Finally,this paper summarizes the efficient strategies such as preparing porous structured materials,preparing nanostructured materials with superaerophobic surface,preparing nanostructured materials,preparing carbon composites/integrating electrocatalysts with carbon,preparing amorphous materials,preparing materials w让h oxygen vacancies/defects,preparing metal chalcogenides,preparing bimetallic/multi-metallic materials,doping metals or heteroatoms,preparing electrocatalysts with core-shell structure,decorating electrocatalysts with amines,preparing homojunction/heterojunction structured materials,preparing hollow structured materials,and preparing boronrich surface to enhance the activity,stability,and durability for HER.
基金Supported by Important Special Research Projects of Guilin University of Electronic Technology (UF09022y)Special Subjects of Guangxi Human Social Science Research Center (XWSKYB2010006)Natural Science Fund of Guangxi Normal University for Nationalities(XYYB2010006)
文摘Taking Chongzuo City of Guangxi Zhuang Autonomous Region as an example, the employment effect of the resource-abundant industrial cluster in southwestern Guangxi Province is analyzed according to the data from the Chongzuo Statistical Yearbook , Guangxi Statistical Yearbook from 2003 to 2008 and the data from the relevant sections of Chongzuo City, and the four employment effects of industrial cluster--the spatial expansion effect of employment chain, optimizing effect of employment structure, the multiplier effect of employment absorption and the effect of improving the quality of labors and the degree of the intensity of employment and location quotient of employment. Results show that the employment absorption of sugar industry in Chongzuo City is stable and upward slightly, and it shows strong employment effect; the sugar industry in Chongzuo is not only competitive, but also has a great share of market in employment, so it owns strong absorption of employment. The countermeasures for improving the employment level of resource-abundant and industrial cluster in southwest of Guangxi Province are put forward, including elongating industrial chain and widening employment space; strengthening various kinds of formal and informal training to improve the employment capability of laborers; laying stress on industrial structure and optimizing the employment structure; strengthening the construction of the industrial economic zone towards ASEAN(Association of Southeast Asian Nations), and fully displaying the regional advantages of the offshore border.
文摘The meteorological conditions in the abundant or the lean years of crops in Mudanjiang City of Heilongjiang Province were analyzed. The study shows that heat,water and light coordinated closely in the abundant years;on the contrary,the comprehensive meteorological conditions were unfavorable for agricultural production in the lean years. A good yield showed up when there were a higher temperature and a larger amount of accumulated temperature above 10 ℃ with no sign of cold damage,an exactly favorable precipitation distribution with little drought or water-logging and a comparatively abundant light during the growing season(from May to September) . However,the crop yield was low when there were a lower temperature and a smaller amount of accumulated temperature,an abnormal precipitation distribution with drought or water logging and scant sunlight during the growing season(from May to September).
基金supported by the King Abdullah University of Science and Technology(KAUST)。
文摘Tuning the electronic structure of the electrocatalysts for oxygen evolution reaction(OER)is a promising way to achieve efficient alkaline water splitting for clean energy production(H2).At first,this paper introduces the significance of the tuning of electronic structure,where modifying the electronic structure of the electrocatalysts could generate active sites having optimal adsorption energy with OER intermediates,and that could diminish the energy barrier for OER,and that could improve the activity for OER.Later,this paper reviews the tuning of electronic structure along with catalytic performances,synthetic methodologies,chemical properties,and DFT calculations on various nanostructured earth-abundant electrocatalysts for OER in alkaline environment.Further,this review discusses the tuning of the electronic structure of the several nanostructured earth-abundant electrocatalysts including oxide,(oxy)hydroxide,layered double hydroxide,alloy,metal phosphide/phosphate,nitride,sulfide,selenide,carbon containing materials,MOF,core-shell/hetero/hollow structured materials,and materials with vacancies/defects for OER in alkaline environment(including activity:overpotential(η)of ≤200 mV at10 m A cm^(-2);stability:≥100 h;durability:≥5000 cycles).Then,this review discusses the robust stability of the electrocatalysts for OER towards practical application.Moreover,this review discusses the in situ formation of thin layer on the catalyst surface during OER.In addition,this review discusses the influence of the adsorption energy of the OER intermediates on OER performance of the catalysts.Finally,this review summarizes the various promising strategies for tuning the electronic structure of the electrocatalysts to achieve enhanced performance for OER in alkaline environment.
基金financially supported by the National Natural Science Foundation of China(nos.51702225,21671059,51702218)Jiangsu Youth Science Foundation(no.BK20170336)Program for Changjiang Scholars and Innovative Research Team in University(IRT-17R36).
文摘Transition metal chalcogenides have nowadays garnered burgeoning interest owing to their fascinating electronic and catalytic properties,thus possessing great implications for energy conversion and storage applications.In this regard,their controllable synthesis in a large scale at low cost has readily become a focus of research.Herein we report diatomite-template generic and scalable production of VS2 and other transition metal sulfides targeting emerging energy conversion and storage applications.The conformal growth of VS2over diatomite template would endow them with defect-abundant features.Throughout detailed experimental investigation in combination with theoretical simulation,we reveal that the enriched active sites/sulfur vacancies of thus-derived VS2 architectures would pose positive impacts on the catalytic performance such in electrocatalytic hydrogen evolution reactions.We further show that the favorable electrical conductivity and highly exposed sites of VS2 hold promise for serving as sulfur host in the realm of Li-S batteries.Our work offers new insights into the templated and customized synthesis of defect-rich sulfides in a scalable fashion to benefit multifunctional energy applications.
基金financed by the National Science Foundation of China(grant No.41272170)
文摘Objective The Tarim Basin is China's largest ore-bearing interior basin, and contains mainly marine oils. The Kuqa depression, a secondary structural unit within the northem Tarim Basin, is composed of Mesozoic and Cenozoic clastic sedimentary rocks dominated by continental oil. Previous research suggests that the crude oils especially condensates in the Kuqa depression are rich in abnormally high abundant rearranged hopanes. On the basis of 41 condensate samples and five oil samples from the Kuqa depression, this work systematically discussed the relationship between biomarker parameters and rearranged hopanes and deeply investigated the influence of depositional environment, original source,
文摘On the base of the construction of abundant semigroups with a normal medial idempotent [14], in this paper we consider a class of naturally ordered abundant semigroups which satisfies the regularity condition and contains a greatest idempotent. Furthermore, we give a completely description of the overall structure of such ordered semigroups via the algebraic structure of them, which generalizes known result obtained by Blyth and McFadden[3].
基金supported by the Key Research and Development Program of Zhejiang Province,China(2022C02008)the National Natural Science Foundation of China(31401343)+1 种基金the earmarked fund for China Agriculture Research System(CARS-01)the Agricultural Science and Technology Innovation Program of Chinese Academy of Agricultural Sciences(CAASZDRW202001)。
文摘Soil microorganisms play important roles in nitrogen transformation. The aim of this study was to characterize changes in the activity of nitrogen transformation enzymes and the abundance of nitrogen function genes in rhizosphere soil aerated using three different methods(continuous flooding(CF), continuous flooding and aeration(CFA), and alternate wetting and drying(AWD)). The abundances of amoA ammonia-oxidizing archaea(AOA) and ammonia-oxidizing bacteria(AOB), nirS, nirK, and nifH genes, and the activities of urease, protease, ammonia oxidase, nitrate reductase, and nitrite reductase were measured at the tillering(S1), heading(S2), and ripening(S3) stages. We analyzed the relationships of the aforementioned microbial activity indices, in addition to soil microbial biomass carbon(MBC) and soil microbial biomass nitrogen(MBN), with the concentration of soil nitrate and ammonium nitrogen. The abundance of nitrogen function genes and the activities of nitrogen invertase in rice rhizosphere soil were higher at S2 compared with S1 and S3 in all treatments. AWD and CFA increased the abundance of amoA and nifH genes, and the activities of urease, protease, and ammonia oxidase, and decreased the abundance of nirS and nirK genes and the activities of nitrate reductase and nitrite reductase, with the effect of AWD being particularly strong. During the entire growth period, the mean abundances of the AOA amoA, AOB amoA, and nifH genes were 2.9, 5.8, and 3.0 higher in the AWD treatment than in the CF treatment, respectively, and the activities of urease, protease, and ammonia oxidase were 1.1, 0.5, and 0.7 higher in the AWD treatment than in the CF treatment, respectively. The abundances of the nirS and nirK genes, and the activities of nitrate reductase and nitrite reductase were 73.6, 84.8, 10.3 and 36.5% lower in the AWD treatment than in the CF treatment, respectively. The abundances of the AOA amoA, AOB amoA, and nifH genes were significantly and positively correlated with the activities of urease, protease, and ammonia oxidase, and the abundances of the nirS and nirK genes were significantly positively correlated with the activities of nitrate reductase. All the above indicators were positively correlated with soil MBC and MBN. In sum, microbial activity related to nitrogen transformation in rice rhizosphere soil was highest at S2. Aeration can effectively increase the activity of most nitrogen-converting microorganisms and MBN, and thus promote soil nitrogen transformation.