All‑Covalent Organic Framework Nanofilms Assembled Lithium‑Ion Capacitor to Solve the Imbalanced Charge Storage Kinetics

Free-standing covalent organic framework(COFs)nanofilms exhibit a remarkable ability to rapidly intercalate/de-intercalate Li^(+) in lithium-ion batteries,while simultaneously exposing affluent active sites in supercapacitors.The development of these nanofilms offers a promising solution to address the persistent challenge of imbalanced charge storage kinetics between battery-type anode and capacitor-type cathode in lithium-ion capacitors(LICs).Herein,for the first time,custom-made COFBTMB-TP and COFTAPB-BPY nanofilms are synthesized as the anode and cathode,respectively,for an all-COF nanofilm-structured LIC.The COFBTMB-TP nanofilm with strong electronegative–CF3 groups enables tuning the partial electron cloud density for Li^(+) migration to ensure the rapid anode kinetic process.The thickness-regulated cathodic COFTAPB-BPY nanofilm can fit the anodic COF nanofilm in the capacity.Due to the aligned 1D channel,2D aromatic skeleton and accessible active sites of COF nanofilms,the whole COFTAPB-BPY//COFBTMB-TP LIC demonstrates a high energy density of 318 mWh cm^(−3) at a high-power density of 6 W cm^(−3),excellent rate capability,good cycle stability with the capacity retention rate of 77%after 5000-cycle.The COFTAPB-BPY//COFBTMB-TP LIC represents a new benchmark for currently reported film-type LICs and even film-type supercapacitors.After being comprehensively explored via ex situ XPS,7Li solid-state NMR analyses,and DFT calculation,it is found that the COFBTMB-TP nanofilm facilitates the reversible conversion of semi-ionic to ionic C–F bonds during lithium storage.COFBTMB-TP exhibits a strong interaction with Li^(+) due to the C–F,C=O,and C–N bonds,facilitating Li^(+) desolation and absorption from the electrolyte.This work addresses the challenge of imbalanced charge storage kinetics and capacity between the anode and cathode and also pave the way for future miniaturized and wearable LIC devices.

Accelerating Oxygen Electrocatalysis Kinetics on Metal-Organic Frameworks via Bond Length Optimization

Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hampered their practical use in water splitting.Herein,we develop a bond length adjustment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs(donated as AE-CoNDA)to serve as efficient catalyst for water splitting.AE-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm^(−2)and a small Tafel slope of 62 mV dec^(−1)with excellent stability over 100 h.After integrated AE-CoNDA onto BiVO_(4),photocurrent density of 4.3 mA cm^(−2)is achieved at 1.23 V.Experimental investigations demonstrate that the stretched Co-O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p,which accounts for the fast kinetics and high activity.Theoretical calculations reveal that the stretched Co-O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting.

基于.NET Framework技术的测试用例系统设计

软件测试环节直接影响着产品的成败,本文所介绍的测试用例系统设计是使用基于.NET的面向对象的可视化编程工具与SQL Server数据库相结合,采用应用服务器技术的C/S架构,按项目测试流程进行设计,把测试用例融入项目设计中,贯穿整个开发过程,大大减少重复工作量以及充分发挥每个人的效率,提高测试效率和速度。所设计的系统包括用户管理,项目管理,测试用例库管理,缺陷管理等功能模块,集成安全性与可维护性,实现集中管理,使整个软件系统开发的业务周期缩短、开发成本降低,也同步提高项目的核心竞争力。

Hollow Metal-Organic Framework/MXene/Nanocellulose Composite Films for Giga/Terahertz Electromagnetic Shielding and Photothermal Conversion

With the continuous advancement of communication technology,the escalating demand for electromagnetic shielding interference(EMI)materials with multifunctional and wideband EMI performance has become urgent.Controlling the electrical and magnetic components and designing the EMI material structure have attracted extensive interest,but remain a huge challenge.Herein,we reported the alternating electromagnetic structure composite films composed of hollow metal-organic frameworks/layered MXene/nanocellulose(HMN)by alternating vacuum-assisted filtration process.The HMN composite films exhibit excellent EMI shielding effectiveness performance in the GHz frequency(66.8 dB at Kaband)and THz frequency(114.6 dB at 0.1-4.0 THz).Besides,the HMN composite films also exhibit a high reflection loss of 39.7 dB at 0.7 THz with an effective absorption bandwidth up to 2.1 THz.Moreover,HMN composite films show remarkable photothermal conversion performance,which can reach 104.6℃under 2.0 Sun and 235.4℃under 0.8 W cm^(−2),respectively.The unique micro-and macrostructural design structures will absorb more incident electromagnetic waves via interfacial polarization/multiple scattering and produce more heat energy via the local surface plasmon resonance effect.These features make the HMN composite film a promising candidate for advanced EMI devices for future 6G communication and the protection of electronic equipment in cold environments.

Expediting^(*)OH accumulation kinetics on metal-organic frameworks-derived CoOOH with CeO_(2) “accelerator” for electrocatalytic 5-hydroxymethylfurfural oxidation valorization

In this work,nickel foam supported CeO_(2)-modified CoBDC(BDC stands for terephthalic acid linker)metal-organic frameworks(NF/CoBDC@CeO_(2)) are prepared by hydrothermal and subsequent impregnation methods,which can be further transformed to NF/CoOOH@CeO_(2) by reconstruction during the electrocatalytic test.The obtained NF/CoOOH@CeO_(2) exhibits excellent performance in electrocatalytic oxidation of 5-hydroxymethylfurfural(HMF) because the introduction of CeO_(2) can optimize the electronic structure of the heterointerface and accelerate the accumulation of ^(*)OH.It requires only a potential of 1.290 V_(RHE) to provide a current density of 50 mA cm^(-2) in 1.0 M KOH+50 mM HMF,which is 222 mV lower than that required in 1,0 M KOH(1.512 V_(RHE)).In addition,density-functional theory calculation results demonstrate that CeO_(2) biases the electrons to the CoOOH side at the heterointerface and promotes the adsorption of ^(*)OH and ^(*)HMF on the catalyst surface,which lower the reaction energy barrier and facilitate the electrocata lytic oxidation process.

Tectonic framework of Qilian orogen: reveal from an aeromagnetic anomaly feature

The Qilian Orogenic belt is one of the typical orogenic belts globally and a natural laboratory for studying plate tectonics.Many researchers have studied the ophiolite and high pressure and ultra-high pressure metamorphic rocks in the Qilian orogen and obtained valuable achievements.However,a hot debate exists on the basement property,the distribution of ophiolite,and the boundaries of tectonic units.Large-scale high-precision aeromagnetic surveys have recently been conducted in the Qilian Orogenic belt and adjacent areas.In this study,we are trying to analysis the tectonic framework of the Qilian Orogen using 1:500,000 aeromagnetic data.The results provide geophysical perspectives for studying the structural framework and deformation of this area.According to the aeromagnetic∆T anomaly map,the central and Southern Qilian have the same magnetic anomaly feature that noticeably differs from the North Qilian Orogenic belt and the Qaidam Block.This result indicates that the central and Southern Qilian have a unified magnetic basement and differ from the North Qilian orogenic belt and Qaidam Block.The map shows the distribution of ophiolite in the North Qilian orogenic belt.Linear magnetic anomalies represent the ophiolites because the mafic–ultramafic rocks usually have high magnetic susceptibility.The ophiolite belts are continuously distributed in the western part of North Qilian orogenic belt and have a large scale.However,the scale of the ophiolite belt and the outcropping of mafic–ultramafic rocks reduces when they pass through Qilian County to the east.The results indicate differences in the evolution process between the eastern and western parts of North Qilian,with Qilian County as the transition zone.This study also systematically defines the geophysical boundaries of the Qaidam Block,Qilian Block,North Qilian Orogenic belt,and Alxa block.It is proposed that the sinistral displacement of the Altun Fault is adjusted and absorbed by the series of NE-trending faults in the Qilian orogen and merge into the Longshoushan–Gushi Fault.The extension of the North Qilian Orogenic belt is strengthened by the neotectonics movement along the shearing direction,which separated the North Qilian Orogenic belt into several segments and formed a series of northeast-trending faults.

Research on the Legal Framework of Content Regulations for Network Platforms

In the era of the Internet,various network platforms have evolved into new hubs for information dissemination.Currently,China has established a platform-centered content regulation framework,wherein platforms proactively enforce content regulations in accordance with legal censorship obligations.Additionally,platform policies and user agreements augment their authority in content regulation.The platforms can achieve cost-effective and highly efficient content regulation by leveraging their strategic advantages enabled by their own technical capabilities and extensive coverage.The platform self-regulation model,however,still faces challenges.First,accurately evaluating content remains a formidable task;second,ensuring effective platform publicity through self-regulation poses difficulties;third,users may potentially face disadvantages due to the platform’s right of self-regulation;and fourth,digital copyright owners face challenges when defending digital copyright disputes under the safe harbor rule.Therefore,it is imperative to establish,review,and revise the legal framework for content regulation of network platforms in order to enhance the efficiency of their governance systems.The formulation of the legal framework for content regulation of network platforms may encompass the following aspects:rationalizing obligations pertaining to platform content regulations,enhancing supervision over platform self-regulation,and establishing a dual-track responsibility system for digital copyright content regulation.This will ensure a harmonious balance among public interests,users’personal rights and interests,and commercial benefits through regulating the content on network platforms.

An End-To-End Hyperbolic Deep Graph Convolutional Neural Network Framework

Graph Convolutional Neural Networks(GCNs)have been widely used in various fields due to their powerful capabilities in processing graph-structured data.However,GCNs encounter significant challenges when applied to scale-free graphs with power-law distributions,resulting in substantial distortions.Moreover,most of the existing GCN models are shallow structures,which restricts their ability to capture dependencies among distant nodes and more refined high-order node features in scale-free graphs with hierarchical structures.To more broadly and precisely apply GCNs to real-world graphs exhibiting scale-free or hierarchical structures and utilize multi-level aggregation of GCNs for capturing high-level information in local representations,we propose the Hyperbolic Deep Graph Convolutional Neural Network(HDGCNN),an end-to-end deep graph representation learning framework that can map scale-free graphs from Euclidean space to hyperbolic space.In HDGCNN,we define the fundamental operations of deep graph convolutional neural networks in hyperbolic space.Additionally,we introduce a hyperbolic feature transformation method based on identity mapping and a dense connection scheme based on a novel non-local message passing framework.In addition,we present a neighborhood aggregation method that combines initial structural featureswith hyperbolic attention coefficients.Through the above methods,HDGCNN effectively leverages both the structural features and node features of graph data,enabling enhanced exploration of non-local structural features and more refined node features in scale-free or hierarchical graphs.Experimental results demonstrate that HDGCNN achieves remarkable performance improvements over state-ofthe-art GCNs in node classification and link prediction tasks,even when utilizing low-dimensional embedding representations.Furthermore,when compared to shallow hyperbolic graph convolutional neural network models,HDGCNN exhibits notable advantages and performance enhancements.

Construction of 3D porous Cu_(1.81)S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage

Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific capacities.However,the inferior intrinsic conductivity and large volume variation during sodiation-desodiation processes seriously affect its high-rate and long-cyde performance,unbeneficial for the application as fast-charging and long-cycling SIBs anode.Herein,the three-dimensional porous Cu_(1.81)S/nitrogen-doped carbon frameworks(Cu_(1.81)S/NC)are synthesized by the simple and facile sol-gel and annealing processes,which can accommodate the volumetric expansion of Cu_(1.81)S nanoparticles and accelerate the transmission of ions and electrons during Na^(+)insertion/extraction processes,exhibiting the excellent rate capability(250.6 mA·g^(-1)at 20.0 A·g^(-1))and outstanding cycling stability(70% capacity retention for 6000 cycles at 10.0 A·g^(-1))for SIBs.Moreover,the Na-ion full cells coupled with Na_(3)V_(2)(PO_(4))_(3)/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g^(-1)at 5.0 A·g^(-1)and long-cycle performance with the 86.9% capacity retention at 2.0 A·g^(-1)after 750 cycles.This work proposes a promising way for the conversionbased metal sulfides for the applications as fast-charging sodium-ion battery anode.

NET Framework模型在电力通信协议转换系统中的应用

在综合自动化变电站中,继电保护设备采用的通信协议多种多样,监控系统必须同时处理多种协议。文中在电力监控的通信协议转换系统中引入NET Framework体系模型,其基本特征是在源协议与目标协议之间建立协议实时数据库(P-RTDB),并将各种通信协议转换软件中功能相同的部分抽取出来建立统一的通用协议服务。源协议和目标协议通过调用通用协议服务来收发报文和访问P-RTDB,实现了一个协议转换系统同时处理多种源协议并将它们分别转换成相应的目标协议,而且在很大程度减小了通信协议软件开发工作的负担和成本,降低了开发难度和复杂性。

基于.NET Framework 3.5架构的高校网络考勤管理系统的设计与开发

在高校教学管理工作中,学生日常考勤管理是其主要内容,是保证高校教育教学秩序正常运行的重要手段。该文描述一个基于.NET Framework 3.5架构的网络考勤系统的设计原理、总体结构及功能实现,提高考勤管理工作效率,实现学生、教师之间的数据共享,并对校园数字化工作起到有力的促进作用。

.NET Framework中序列化与反序列化方法的分析与应用

为实现数据的持久化保存,.NET Framework提供了良好的序列化机制,三种格式的序列化方法:二进制序列化、SOAP序列化、XML序列化。在反序列化时,重新创建原始对象的相同副本。本文详细分析以上几种序列化的优缺点和实现方法,并结合应用给出一个序列化实现的实例,将它应用于WinForm窗体和控件类中取得了良好的效果。

Win32 API和.NET Framework下的定时器研究

详细介绍了Windows开发环境中Win32 API和.NETFramework提供的各种定时器,对不同定时器的特点进行了分析比较,提出了解决多线程定时器带来的代码重入问题和提高定时处理实时性的方法并给出了验证。

基于Microsoft.NET Framework 2.0技术图书馆期刊发布系统的研究与实现

本文论述了图书馆期刊发布系统的计算机软件结构,介绍了在Microsof.tNET Framework2.0技术下图书馆期刊发布系统的优点与缺点,并结合本馆自身实例介绍了如何利用Microsoft公司最新的开发工具Visual Studio 2005来实现图书馆期刊发布系统的计算机软件。

.NET Framework对COM组件的调用机制研究

以COM组件与.NETFramework对象模型的差异为基础,对“运行库可调用包装类”的工作原理,创建InteropAssembly和PrimaryInteropAssembly的几种方法进行了研究和总结,并且对互操作中如何处理COM组件的事件和线程处理机制进行了分析。最后提出了一种COM组件的继承方法。

构建基于Microsoft.Net Framework的组件化Internet应用系统

介绍了Microsoft.Net Framework的技术架构和三层应用解决方案,从系统体系结构、组件技术两个方面综合考虑,结合一个实际的应用系统的实例提出了构建Internet应用系统的方案.该方案便于开发维护,并且性能优良.

基于.NET Framework平台下Web数据库技术在数字图书馆中的应用

.NET Framework平台是微软公司推出的下一代应用软件平台。本文介绍了.NET Framework平台技术,并通过实例介绍了在数字化图书馆建设中利用,NET Framework平台实现基于Web的采访模式。

.NETFramework对称算法类分析及其通用实现

在.NET Framework平台开发软件系统时,一般采用某种特定算法实现敏感信息的加密,这影响了软件的扩展性和维护性.为此,研究了.NET Framework对称算法类的继承层次结构,分析了其加密与解密的实现流程,提出了通用对称算法加密实现类的设想,并进行了可行性分析.然后介绍了通用对称算法加密类的构成,阐明了各成员的设计思路,给出了用VB.NET实现的完整代码.最后以应用实例表明,该类使用简单方便,具有良好的扩展性和维护性,其设计思想可推广到其它加密算法类.

基于.Net FrameWork的用户服务系统的实现

基于.Net FrameWork的用户服务系统的设计与实现,解决了传统管理系统中组织结构混乱、用户使用不便、安全性差等问题;完善用户管理功能的同时,提高统一企业平台的安全性,抵御潜在的安全风险。

基于.Net Micro Framework的电动汽车充电桩控制系统的设计

针对电动汽车充电桩控制系统开发周期长、扩展能力差的问题,设计了一种基于.Net Micro Framework的电动汽车充电桩控制系统。本系统基于Cortex-M3内核的开发板,采用了模块化设计原则,详细阐述了.Net Micro Framework在电动汽车充电桩控制系统中的开发流程和功能模块设计。本系统已在山东临沂焦庄、青岛薛家岛充换电站的充电桩上运行使用,运行结果表明该系统扩展能力强、开发成本低,运行更加稳定可靠。