通过液相法制得了球形Ni(OH)2,再与Mn(NO3)2、CH3COOLi通过固相法制备了富锂正极材料Li[Li0.2Ni0.2Mn0.6]O2。通过X射线衍射光谱法(XRD)、扫描电子显微镜法(SEM)、粒度分析仪、循环伏安、交流阻抗以及充放电测试对样品的结构、形貌和电...通过液相法制得了球形Ni(OH)2,再与Mn(NO3)2、CH3COOLi通过固相法制备了富锂正极材料Li[Li0.2Ni0.2Mn0.6]O2。通过X射线衍射光谱法(XRD)、扫描电子显微镜法(SEM)、粒度分析仪、循环伏安、交流阻抗以及充放电测试对样品的结构、形貌和电化学性能进行了表征。结果表明,合成温度为900℃时,材料结晶度高,阳离子混排程度低,颗粒表面光滑均一;在20 m A/g时,首次放电比容量为174.02 m Ah/g,在60 m A/g的高倍率放电条件下比容量仍可达到80.56m Ah/g。展开更多
In order to investigate the global distributions of temporal variations of OH and O2 nightglow emissions,we statistically analyzed their variations with altitude,local time,and season,using the OH and O2 airglow emiss...In order to investigate the global distributions of temporal variations of OH and O2 nightglow emissions,we statistically analyzed their variations with altitude,local time,and season,using the OH and O2 airglow emission rate data observed by the TIMED satellite between 2002 and 2009.The results indicated that the OH nightglow emission was stronger than dayglow emission and the O2 nightglow emission was weaker than dayglow emission.In the tropics,the OH nightglow intensity reached its maximum near midnight;at higher latitudes,the OH nightglow intensities after sunset and before sunrise were much strong.At the equinoxes,the O2 nightglow intensity in the tropics decreased with local time;at the solstices,the local time-latitude distribution of the O2 nightglow intensity had a valley(with weak emission).As for the altitude-latitude distributions of nightglow emission rates,the distribution for OH nightglow at the equinoxes had one peak(with strong emission)at the equator,with a peak height around 85 km;the peak for the March equinox was stronger than that for the September equinox.The distribution for O2 nightglow at the equinoxes had three peaks,lying at 30°in the spring and autumn hemispheres and at the equator,and the peak height at the equator was the lowest.The distributions for both OH and O2 nightglow emissions at the solstices had three peaks.Both nightglow intensities in the tropics had obvious annual and semi-annual variations,the peaks and valleys for semi-annual variations appeared near the equinoxes and solstices,respectively,and the peak at the March equinox was larger than that at the September equinox.The distributions of both OH and O2 nightglow intensities showed a hemispheric asymmetry.展开更多
文摘通过液相法制得了球形Ni(OH)2,再与Mn(NO3)2、CH3COOLi通过固相法制备了富锂正极材料Li[Li0.2Ni0.2Mn0.6]O2。通过X射线衍射光谱法(XRD)、扫描电子显微镜法(SEM)、粒度分析仪、循环伏安、交流阻抗以及充放电测试对样品的结构、形貌和电化学性能进行了表征。结果表明,合成温度为900℃时,材料结晶度高,阳离子混排程度低,颗粒表面光滑均一;在20 m A/g时,首次放电比容量为174.02 m Ah/g,在60 m A/g的高倍率放电条件下比容量仍可达到80.56m Ah/g。
基金supported by the National Natural Science Foundation of China(Grant Nos.40874080,40890165,40911120063,41004062)the National Basic Research Program of China("973"Project)(Grant No.2006CB806306)+1 种基金China Postdoctoral Science Foundation Funded Project(Grnat No.20100481450)the Specialized Research Fund for State Key Laboratories
文摘In order to investigate the global distributions of temporal variations of OH and O2 nightglow emissions,we statistically analyzed their variations with altitude,local time,and season,using the OH and O2 airglow emission rate data observed by the TIMED satellite between 2002 and 2009.The results indicated that the OH nightglow emission was stronger than dayglow emission and the O2 nightglow emission was weaker than dayglow emission.In the tropics,the OH nightglow intensity reached its maximum near midnight;at higher latitudes,the OH nightglow intensities after sunset and before sunrise were much strong.At the equinoxes,the O2 nightglow intensity in the tropics decreased with local time;at the solstices,the local time-latitude distribution of the O2 nightglow intensity had a valley(with weak emission).As for the altitude-latitude distributions of nightglow emission rates,the distribution for OH nightglow at the equinoxes had one peak(with strong emission)at the equator,with a peak height around 85 km;the peak for the March equinox was stronger than that for the September equinox.The distribution for O2 nightglow at the equinoxes had three peaks,lying at 30°in the spring and autumn hemispheres and at the equator,and the peak height at the equator was the lowest.The distributions for both OH and O2 nightglow emissions at the solstices had three peaks.Both nightglow intensities in the tropics had obvious annual and semi-annual variations,the peaks and valleys for semi-annual variations appeared near the equinoxes and solstices,respectively,and the peak at the March equinox was larger than that at the September equinox.The distributions of both OH and O2 nightglow intensities showed a hemispheric asymmetry.
