Four novel mononuclear ruthenium(II) complexes [Ru-(dmb) 2L] 2+ [dmb=4,4′-dimethyl-2,2′-bipyridine, L=imid-azo-[4,5-f]phenanthroline (IP), 2-phenylimidazo-phenanthroline (PIP), 2-(4′-hydroxyphenyl)imidazo-phe...Four novel mononuclear ruthenium(II) complexes [Ru-(dmb) 2L] 2+ [dmb=4,4′-dimethyl-2,2′-bipyridine, L=imid-azo-[4,5-f]phenanthroline (IP), 2-phenylimidazo-phenanthroline (PIP), 2-(4′-hydroxyphenyl)imidazo-phenanthroline (HOP), 2-(4′-dimethylami- nophenyl)imidazo-phenanthroline (DMNP)] were synthesized and characterized by ES-MS, 1H NMR, UV-vis and electrochemistry. The nonlinear optical properties of the ruthenium(II) complexes were investigated by Z-scan techniques with 12 ns laser pulse at 540 nm, and all of them exhibit both nonlinear optical (NLO) absorption and self-defocusing effect. The corresponding effective NLO susceptibility |χ 3| of the complexes is in the range of 2.68×10 -12-4.57×10 -12 esu.展开更多
文摘Four novel mononuclear ruthenium(II) complexes [Ru-(dmb) 2L] 2+ [dmb=4,4′-dimethyl-2,2′-bipyridine, L=imid-azo-[4,5-f]phenanthroline (IP), 2-phenylimidazo-phenanthroline (PIP), 2-(4′-hydroxyphenyl)imidazo-phenanthroline (HOP), 2-(4′-dimethylami- nophenyl)imidazo-phenanthroline (DMNP)] were synthesized and characterized by ES-MS, 1H NMR, UV-vis and electrochemistry. The nonlinear optical properties of the ruthenium(II) complexes were investigated by Z-scan techniques with 12 ns laser pulse at 540 nm, and all of them exhibit both nonlinear optical (NLO) absorption and self-defocusing effect. The corresponding effective NLO susceptibility |χ 3| of the complexes is in the range of 2.68×10 -12-4.57×10 -12 esu.
