The novel complex of Mn(V): Mn·3/2(μ -DHBQ)·4H2O·2Cl (where, H2DHBQ =2,5-dihydroxyl- 1,4-benzoquinone) was synthesized and its crystal structure has been determined by X-ray diffraction. The complex be...The novel complex of Mn(V): Mn·3/2(μ -DHBQ)·4H2O·2Cl (where, H2DHBQ =2,5-dihydroxyl- 1,4-benzoquinone) was synthesized and its crystal structure has been determined by X-ray diffraction. The complex belongs to trigonal system with space group P3(# 147), a= 1 .415(2)nm, c=0.6552(4) nm, V=1 .1371(7) nm-3, Z=2, Dx=1.183 g/cm3, μ=7.37 cm-1, F(000)=408.00,R=0.041, Rw=0.046.展开更多
文摘The novel complex of Mn(V): Mn·3/2(μ -DHBQ)·4H2O·2Cl (where, H2DHBQ =2,5-dihydroxyl- 1,4-benzoquinone) was synthesized and its crystal structure has been determined by X-ray diffraction. The complex belongs to trigonal system with space group P3(# 147), a= 1 .415(2)nm, c=0.6552(4) nm, V=1 .1371(7) nm-3, Z=2, Dx=1.183 g/cm3, μ=7.37 cm-1, F(000)=408.00,R=0.041, Rw=0.046.
