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一种基于三角数分解的可配置2-D卷积器优化方法
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作者 黄继业 肖强 +4 位作者 田大海 高明裕 王俊帆 董哲康 黄汐威 《电子与信息学报》 EI CAS CSCD 北大核心 2024年第7期3054-3062,共9页
多尺寸2-D卷积通过特征提取在检测、分类等计算机视觉任务中发挥着重要作用。然而,目前缺少一种高效的可配置2-D卷积器设计方法,这限制了卷积神经网络(CNN)模型在边缘端的部署和应用。该文基于乘法管理以及奇平方数的三角数分解方法,提... 多尺寸2-D卷积通过特征提取在检测、分类等计算机视觉任务中发挥着重要作用。然而,目前缺少一种高效的可配置2-D卷积器设计方法,这限制了卷积神经网络(CNN)模型在边缘端的部署和应用。该文基于乘法管理以及奇平方数的三角数分解方法,提出一种高性能、高适应性的卷积核尺寸可配置的2-D卷积器。所提2-D卷积器包含一定数量的处理单元(PE)以及相应的控制单元,前者负责运算任务,后者负责管理乘法运算的组合,二者结合以实现不同尺寸的卷积。具体地,首先根据应用场景确定一个奇数列表,列表中为2-D卷积器所支持的尺寸,并利用三角数分解得到对应的三角数列表;其次,根据三角数列表和计算需求,确定PE的总数量;最后,基于以小凑大的方法,确定PE的互连方式,完成电路设计。该可配置2-D卷积器通过Verilog硬件描述语言(HDL)设计实现,由Vivado 2 022.2在XCZU7EG板卡上进行仿真和分析。实验结果表明,相比同类方法,该文所提可配置2-D卷积器,乘法资源利用率得到显著提升,由20%~50%提升至89%,并以514个逻辑单元实现1 500 MB/s的吞吐率,具有广泛的适用性。 展开更多
关键词 2-d卷积器 可配置架构 乘法管理 三角数分解
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High-efficiency sodium storage of Co_(0.85)Se/WSe_(2) encapsulated in N-doped carbon polyhedron via vacancy and heterojunction engineering 被引量:1
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作者 Ya Ru Pei Hong Yu Zhou +5 位作者 Ming Zhao Jian Chen Li Xin Ge Wei Zhang Chun Cheng Yang Qing Jiang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第1期94-107,共14页
With the advantage of fast charge transfer,heterojunction engineering is identified as a viable method to reinforce the anodes'sodium storage performance.Also,vacancies can effectively strengthen the Na+adsorption... With the advantage of fast charge transfer,heterojunction engineering is identified as a viable method to reinforce the anodes'sodium storage performance.Also,vacancies can effectively strengthen the Na+adsorption ability and provide extra active sites for Na+adsorption.However,their synchronous engineering is rarely reported.Herein,a hybrid of Co_(0.85)Se/WSe_(2) heterostructure with Se vacancies and N-doped carbon polyhedron(CoWSe/NCP)has been fabricated for the first time via a hydrothermal and subsequent selenization strategy.Spherical aberration-corrected transmission electron microscopy confirms the phase interface of the Co_(0.85)Se/WSe_(2) heterostructure and the existence of Se vacancies.Density functional theory simulations reveal the accelerated charge transfer and enhanced Na+adsorption ability,which are contributed by the Co_(0.85)Se/WSe_(2) heterostructure and Se vacancies,respectively.As expected,the CoWSe/NCP anode in sodium-ion battery achieves outstanding rate capability(339.6 mAh g^(−1) at 20 A g^(−1)),outperforming almost all Co/W-based selenides. 展开更多
关键词 Co_(0.85)Se/WSe_(2)heterostructure density functional theory simulations N-doped carbon polyhedron Se vacancies sodium-ion batteries
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ARCADE 2 Spatial Roar, What Theory of Relation Reveals
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作者 Russell Bagdoo 《Journal of Modern Physics》 2024年第5期690-719,共30页
The theory of Relation provides an explanation for the Arcade 2 excess. It assumes that the isotropic radio emission measured by the Arcade 2 Collaboration, which is 5 - 6 times brighter than the expected contribution... The theory of Relation provides an explanation for the Arcade 2 excess. It assumes that the isotropic radio emission measured by the Arcade 2 Collaboration, which is 5 - 6 times brighter than the expected contributions from known extra-galactic sources, is the residue of an immense primitive energy of ordinary matter released by a relativistic bang almost 100 million years after the big bang, which gave the mass-energy the missing gravity to activate contraction. This relativistic bang, via a Lorentz energy transformation, would have released enormous energy held to be the source of the powerful radio noise detected by the NASA researchers. This transformation would have simultaneously triggered the formation of the first stars from dense gas and the reionization of less dense neutral gas. This departs from the idea that continuous reionization began after the formation of the first stars. We emphasize the importance of primordial magnetic fields, which would have generated significant density fluctuations during recombination and acted as a direct seed for cosmic structures. The first stars and galaxies were bathed in strong magnetic fields that gave rise to the radio microwave din (boom) discovered by Arcade 2. These intense magnetic fields alter the trajectory of charged particles zooming near the speed of light, triggering the space roar and emitting radiation that forms a synchrotron radio background. The theory of Relation offers an alternative to the Lambda-CDM cosmological model, which has become the standard model of the big bang, which leads straight to the vacuum catastrophe. 展开更多
关键词 Arcade 2 Excess Relativistic Bang theory of Relation Lorentz Energy Transformation Cosmic Statics Cosmic Boom Synchrotron Radio Background Primordial Magnetic Fields
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2-D Modeling and Calculations of Stratospheric Ozone and Influences of Convection, Diffusion, and Time
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作者 Ibraheem Alelmi Laurie Wei Sen Nieh 《Atmospheric and Climate Sciences》 2024年第2期250-276,共27页
An engineering system approach of 2-D cylindrical model of transient mass balance calculations of ozone and other concerned chemicals along with fourteen photolysis, ozone-generating and ozone-depleting chemical react... An engineering system approach of 2-D cylindrical model of transient mass balance calculations of ozone and other concerned chemicals along with fourteen photolysis, ozone-generating and ozone-depleting chemical reaction equations was developed, validated, and used for studying the ozone concentrations, distribution and peak of the layer, ozone depletion and total ozone abundance in the stratosphere. The calculated ozone concentrations and profile at both the Equator and a 60˚N location were found to follow closely with the measured data. The calculated average ozone concentration was within 1% of the measured average, and the deviation of ozone profiles was within 14%. The monthly evolution of stratospheric ozone concentrations and distribution above the Equator was studied with results discussed in details. The influences of slow air movement in both altitudinal and radial directions on ozone concentrations and profile in the stratosphere were explored and discussed. Parametric studies of the influences of gas diffusivities of ozone D<sub>O3</sub> and active atomic oxygen D<sub>O</sub> on ozone concentrations and distributions were also studied and delineated. Having both influences through physical diffusion and chemical reactions, the diffusivity (and diffusion) of atomic oxygen D<sub>O</sub> was found to be more sensitive and important than that of ozone D<sub>O3</sub> on ozone concentrations and distribution. The 2-D ozone model present in this paper for stratospheric ozone and its layer and depletion is shown to be robust, convenient, efficient, and executable for analyzing the complex ozone phenomena in the stratosphere. . 展开更多
关键词 Stratospheric Ozone 2-d Model Ozone Layer Ozone Depletion CONVECTION DIFFUSION
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Er掺杂PbF_(2)晶体的局域团簇结构与光谱性能研究
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作者 李琳 张沛雄 +4 位作者 谭俊成 朱思祁 尹浩 李真 陈振强 《人工晶体学报》 CAS 北大核心 2024年第7期1112-1120,共9页
本文采用Bridgman法成功生长了一系列Er∶PbF_(2)晶体。利用基于密度泛函理论的第一性原理计算详细研究了Er^(3+)在PbF_(2)晶体中的团簇效应。首次获得了Er∶PbF_(2)晶体的上转换发光特性(发光强度、颜色变化)与团簇结构之间的关系。研... 本文采用Bridgman法成功生长了一系列Er∶PbF_(2)晶体。利用基于密度泛函理论的第一性原理计算详细研究了Er^(3+)在PbF_(2)晶体中的团簇效应。首次获得了Er∶PbF_(2)晶体的上转换发光特性(发光强度、颜色变化)与团簇结构之间的关系。研究发现,随着Er^(3+)浓度增加,团簇从单聚体向高阶构型演化,Er^(3+)离子之间的距离先减小后增大,这使得上转换发光中的红色发射强度先增大后减小,红绿发光比也在Er^(3+)浓度高于6.5%(摩尔分数)后逐渐减小,即发光颜色可以从红色调整为黄绿色。该研究证明了稀土离子团簇的结构演化可以调控Er∶PbF_(2)的光谱特性,为多色发光材料的设计提供一种新方法。 展开更多
关键词 Er∶PbF_(2)晶体 上转换发光 密度泛函理论 铒离子团簇 光谱性能
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表面基团对Ti_(3)C_(2)T_(x)吸附NO性能影响的第一性原理研究
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作者 邱毅 邹江峰 +4 位作者 马智炜 罗强 刘忠华 陈洋 代逸飞 《材料导报》 EI CAS CSCD 北大核心 2024年第5期138-142,共5页
本工作基于密度泛函理论的第一性原理方法,构建了Ti_(3)C_(2)O_(2)、Ti_(3)C_(2)O1.5(OH)0.5、Ti_(3)C_(2)O(OH)、Ti_(3)C_(2)O1.5F0.5和Ti_(3)C_(2)OF五种模型,从几何结构、电荷转移以及电子性质等方面研究了基团种类和比例对Ti_(3)C_(... 本工作基于密度泛函理论的第一性原理方法,构建了Ti_(3)C_(2)O_(2)、Ti_(3)C_(2)O1.5(OH)0.5、Ti_(3)C_(2)O(OH)、Ti_(3)C_(2)O1.5F0.5和Ti_(3)C_(2)OF五种模型,从几何结构、电荷转移以及电子性质等方面研究了基团种类和比例对Ti_(3)C_(2)T_(x)吸附NO的影响。结果表明:相较于Ti_(3)C_(2)O_(2),含低比例-OH和-F基团的Ti_(3)C_(2)T_(x)对NO的吸附能更大,电荷转移更弱,不利于其探测NO,与实验结果一致;但随着-OH和-F比例的提高,吸附能分别减小和增大,电荷转移分别增强和减弱,表明高比例的-OH有利于Ti_(3)C_(2)T_(x)探测NO,而高比例的-F是不利的;同时,在吸附NO后,Ti_(3)C_(2)O_(2)在费米能级附近的能带极值曲率变小,电子有效质量增大,表明-O基团有利于Ti_(3)C_(2)T_(x)探测NO。在几何弛豫过程中NO分子总是以N原子靠近衬底,吸附距离均较小,而且最近邻原子的电子轨道出现杂化,电子的聚集和消散位于两端,表明最近邻原子间成键较弱且偏离子性。此计算结果可以为Ti_(3)C_(2)T_(x)探测和屏蔽NO提供理论指导,同时为Ti_(3)C_(2)T_(x)的表面改性提供思路。 展开更多
关键词 二维材料 Ti_(3)C_(2)T_(x) NO吸附 密度泛函理论 电子性质
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Investigation of the structural, electronic and mechanical properties of CaO–SiO_(2) compound particles in steel based on density functional theory 被引量:1
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作者 Chao Gu Ziyu Lyu +1 位作者 Qin Hu Yanping Bao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第4期744-755,共12页
CaO–SiO_(2)compounds compromise one of the most common series of oxide particles in liquid steels, which could significantly affect the service performance of the steels as crack initiation sites. However, the struct... CaO–SiO_(2)compounds compromise one of the most common series of oxide particles in liquid steels, which could significantly affect the service performance of the steels as crack initiation sites. However, the structural, electronic, and mechanical properties of the compounds in CaO–SiO_(2)system are still not fully clarified due to the difficulties in the experiments. In this study, a thorough investigation of these properties of CaO–SiO_(2)compound particles in steels was conducted based on first-principles density functional theory. Corresponding phases were determined by thermodynamic calculation, including gamma dicalcium silicate(γ-C2S), alpha-prime(L) dicalcium silicate(αL′-C2S), alpha-prime(H) dicalcium silicate(αH′-C2S), alpha dicalcium silicate(α-C2S), rankinite(C3S2), hatrurite(C3S), wollastonite(CS), and pseudowollastonite(Ps-CS). The results showed that the calculated crystal structures of the eight phases agree well with the experimental results. All the eight phases are stable according to the calculated formation energies, and γ-C2S is the most stable. O atom contributes the most to the reactivity of these phases. The Young’s modulus of the eight phases is in the range of 100.63–132.04 GPa. Poisson’s ratio is in the range of0.249–0.281. This study provided further understanding concerning the CaO–SiO_(2)compound particles in steels and fulfilled the corresponding property database, paving the way for inclusion engineering and design in terms of fracture-resistant steels. 展开更多
关键词 CaO–SiO_(2) density functional theory structural property electronic property mechanical property
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Effects of zinc on χ-Fe_(5)C_(2) for carbon dioxide hydrogenation to olefins:Insights from experimental and density function theory calculations 被引量:1
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作者 Xianglin Liu Minjie Xu +2 位作者 Chenxi Cao Zixu Yang Jing Xu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期206-214,共9页
Production of light olefins from CO_(2), the primary greenhouse gases, is of great importance to mitigate the adverse effects of CO_(2) emission on environment and to supply the value-added products from nonpetroleum ... Production of light olefins from CO_(2), the primary greenhouse gases, is of great importance to mitigate the adverse effects of CO_(2) emission on environment and to supply the value-added products from nonpetroleum resource. However, development of robust catalyst with controllable selectivity and stability remains a challenge. Herein, we report that Zn-promoted Fe catalyst can boost the stable and selective production of light olefins from CO_(2). Specifically, the Zn-promoted Fe exhibits a highly stable activity and olefin selectivity over 200 h time-on-stream compared to the unpromoted Fe catalyst, primarily owing to the preservation of active χ-Fe_(5)C_(2) phase. Structural characterizations of the spent catalysts suggest that Zn substantially regulates the content of iron carbide on the surface and suppresses the reoxidation of bulk iron carbide during the reaction. DFT calculations confirm that adsorption of surface carbon atoms and graphene-like carbonaceous species are not thermochemically favored on Zn-promoted Fe catalyst. Carbon deposition by CAC coupling reactions of two surface carbon atoms and dehydrogenation of CH intermediate are also inhibited. Furthermore, the effects of Zn on antioxidation of iron carbide were also investigated. Zn favored the hydrogenation of surface adsorbed oxygen atoms to H_(2)O and the desorption of H_(2)O, which reduces the possibility of surface carbide being oxidized by the chemisorbed oxygen. 展开更多
关键词 Reaction engineering χ-Fe_(5)C_(2) Zn promoter Carbon dioxide HYDROGENATION Density function theory
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基于循证理论的预见性护理策略结合声门下间歇冲洗预防2型糖尿病伴心力衰竭患者呼吸机相关性肺炎的效果及对炎性介质水平的影响
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作者 李花 徐娟 朱海慧 《临床医学研究与实践》 2024年第18期126-129,共4页
目的分析基于循证理论的预见性护理策略结合声门下间歇冲洗在预防2型糖尿病(T2DM)伴心力衰竭(HF)患者呼吸机相关性肺炎(VAP)中的应用效果。方法择取2021年1月至2022年1月收治的100例T2DM伴HF患者为研究对象,随机将其分为对照组和观察组,... 目的分析基于循证理论的预见性护理策略结合声门下间歇冲洗在预防2型糖尿病(T2DM)伴心力衰竭(HF)患者呼吸机相关性肺炎(VAP)中的应用效果。方法择取2021年1月至2022年1月收治的100例T2DM伴HF患者为研究对象,随机将其分为对照组和观察组,各50例。对照组采用常规护理干预,观察组在对照组基础上加基于循证理论的预见性护理策略结合声门下间歇冲洗。比较两组的干预效果。结果观察组的VAP发生率、随机血糖水平低于对照组,机械通气时间、气管插管时间及住院时间短于对照组(P<0.05)。干预后,观察组的肿瘤坏死因子-α(TNF-α)、降钙素原(PCT)及C反应蛋白(CRP)水平低于对照组(P<0.05)。干预后,观察组的脑钠肽(BNP)水平及糖化血红蛋白(HbA1c)低于对照组(P<0.05)。结论基于循证理论的预见性护理策略结合声门下间歇冲洗能够有效预防T2DM伴HF患者VAP的发生,降低炎性介质水平,改善血糖及心功能,值得临床推广与应用。 展开更多
关键词 循证理论 预见性护理策略 声门下间歇冲洗 2型糖尿病 心力衰竭 呼吸机相关性肺炎 炎性介质 心功能
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Density functional theory study of NO_2 -sensing mechanisms of pure and Ti-doped WO_3 (002) surfaces 被引量:3
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作者 胡明 王巍丹 +1 位作者 曾晶 秦玉香 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第10期177-184,共8页
Density functional theory (DFT) calculations are employed to explore the NO2-sensing mechanisms of pure and Ti-doped WO3 (002) surfaces. When Ti is doped into the WO3 surface, two substitution models are considere... Density functional theory (DFT) calculations are employed to explore the NO2-sensing mechanisms of pure and Ti-doped WO3 (002) surfaces. When Ti is doped into the WO3 surface, two substitution models are considered: substitution of Ti for W6c and substitution of Ti for Wsc. The results reveal that substitution of Ti for 5-fold W forms a stable doping structure, and doping induces some new electronic states in the band gap, which may lead to changes in the surface properties. Four top adsorption models of NO2 on pure and Ti-doped WO3 (002) surfaces are investigated: adsorptions on 5-fold W (Ti), on 6-fold W, on bridging oxygen, and on plane oxygen. The most stable and likely NO2 adsorption structures are both N-end oriented to the surface bridge oxygen Olc site. By comparing the adsorption energy and the electronic population, it is found that Ti doping can enhance the adsorption of NO2, which theoretically proves the experimental observation that Ti doping can greatly increase the WO3 gas sensor sensitivity to NO2 gas. 展开更多
关键词 ADSORPTION Ti doping NO2-sensing density functional theory
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Experimental and theoretical studies on two-dimensional vanadium carbide hybrid nanomaterials derived from V_(4)AlC_(3) as excellent catalyst for MgH_(2)
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作者 Zhiqiang Lan Huiren Liang +7 位作者 Xiaobin Wen Jiayang Hu Hua Ning Liang Zeng Haizhen Liu Jun Tan Jürgen Eckert Jin Guo 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第10期3790-3799,共10页
Hydrogen is considered one of the most ideal future energy carriers.The safe storage and convenient transportation of hydrogen are key factors for the utilization of hydrogen energy.In the current investigation,two-di... Hydrogen is considered one of the most ideal future energy carriers.The safe storage and convenient transportation of hydrogen are key factors for the utilization of hydrogen energy.In the current investigation,two-dimensional vanadium carbide(VC) was prepared by an etching method using V_(4)AlC_(3) as a precursor and then employed to enhance the hydrogen storage properties of MgH_(2).The studied results indicate that VC-doped MgH_(2) can absorb hydrogen at room temperature and release hydrogen at 170℃. Moreover,it absorbs 5.0 wt.%of H_(2) within 9.8 min at 100℃ and desorbs 5.0 wt.% of H_(2) within 3.2 min at 300℃.The dehydrogenation apparent activation energy of VC-doped MgH_(2) is 89.3 ± 2.8 kJ/mol,which is far lower than that of additive-free MgH_(2)(138.5 ± 2.4 kJ/mol),respectively.Ab-initio simulations showed that VC can stretch Mg-H bonds and make the Mg-H bonds easier to break,which is responsible for the decrease of dehydrogenation temperature and conducive to accelerating the diffusion rate of hydrogen atoms,thus,the hydrogen storage properties of MgH_(2) are remarkable improved through addition of VC. 展开更多
关键词 MgH_2 TWO-dIMENSIONAL Hydrogen storage material Density functional theory
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Platinum quantum dots-decorated MXene-derived titanium dioxide nanowire/Ti_(3)C_(2) heterostructure for use in solar-driven gas-phase carbon dioxide reduction to yield value-added fuels
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作者 Kamakshaiah Charyulu Devarayapalli S.V.Prabhakar Vattikuti +4 位作者 Dong Jin Kim Youngsu Lim Bolam Kim Gyuhyeon Kim Dae Sung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第7期627-637,I0013,共12页
Solar-driven photocatalytic CO_(2) reduction to produce valuable chemicals and fuels offers an attractive strategy in alleviating the energy crisis.Pt quantum dots(PtQDs)with TiO_(2) nanowire(TiO_(2)NW)/Ti_(3)C_(2) MX... Solar-driven photocatalytic CO_(2) reduction to produce valuable chemicals and fuels offers an attractive strategy in alleviating the energy crisis.Pt quantum dots(PtQDs)with TiO_(2) nanowire(TiO_(2)NW)/Ti_(3)C_(2) MXene heterostructures(Pt-TiO_(2)NW/Ti_(3)C_(2)) with tight interfacial contacts between the various components were prepared at room temperature via oxidation reactions.The incorporated PtQDs played crucial roles as electron conduction bridges supported by the cocatalyst effect,effectively enhancing the separation efficiencies of photoinduced electron/hole pairs and improving CO_(2) reduction under simulated solar light irradiation.The Pt-TiO_(2)NW/Ti_(3)C_(2) heterostructures exhibited remarkable carbon monoxide(CO)and methane(CH_(4)) production at respective rates of 38.14 and 36.15μmol g^(-1)after 10 h of simulated solar light irradiation,an apparent quantum yield of 1.68%,and 79.2%selectivity for CH4.The photocatalytic activities of the Pt-TiO_(2) NW/Ti_(3)C_(2) heterostructures for CO_(2) reduction were significantly enhanced compared to those of TiO_(2)NW/Ti_(3)C_(2) and the single-component photocatalysts,and they exhibited remarkable stabilities even after five cycles.In addition,the densities of states and electronic characteristics of Ti_(3)C_(2) MXene and Pt-TiO_(2)NW/Ti_(3)C_(2) were studied using density functional theory,and a synergistic mechanism of the improvement in CO_(2) photoreduction is proposed. 展开更多
关键词 MXene CO_(2)reduction Density functional theory Quantum dot PHOTOCATALYST
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一种高速2-D滑动FFT的设计实现
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作者 许丁鸿 张多利 +2 位作者 陶相颖 韩帅鹏 宋宇鲲 《合肥工业大学学报(自然科学版)》 CAS 北大核心 2023年第7期912-918,共7页
文章介绍了采用2-D快速傅里叶变换(fast Fourier transform,FFT)算法的滑动窗FFT的基本特性原理和硬件实现过程,完成了窗长256点、步长16点的2-D滑动窗FFT的专用集成电路(application specific integrated circuit,ASIC)设计。传统FFT... 文章介绍了采用2-D快速傅里叶变换(fast Fourier transform,FFT)算法的滑动窗FFT的基本特性原理和硬件实现过程,完成了窗长256点、步长16点的2-D滑动窗FFT的专用集成电路(application specific integrated circuit,ASIC)设计。传统FFT算法受序列完整性的制约,时滞较大,无法满足某些高实时性信号分析领域的处理速度要求。该文采用滑动FFT算法,克服了传统FFT对序列完整性的依赖,设计的滑动FFT处理器使用2-D FFT压缩新序列计算时间,以基16蝶形运算器为核心,采用系数复用和高基Booth方法优化系数编码技术压缩乘法器的数量,减少电路面积。所设计的2-D滑动FFT完成单次滑动窗长的计算时间比传统算法节约了16.1%,变换结果与MATLAB的运算结果相比,信噪比(signal-to-noise ratio,SNR)大于130 dB。在TSMC 28 nm的工艺下,工作主频为600 MHz,面积为1980μm×2060μm。 展开更多
关键词 快速傅里叶变换(FFT) 滑动FFT 2-d FFT算法 高基Booth编码
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Analysis on D2D Heterogeneous Networks with State-Dependent Priority Traffic
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作者 Guangjun Liang Jianfang Xin +2 位作者 Linging Xia Xueli Ni Yi Cao 《Computers, Materials & Continua》 SCIE EI 2023年第2期2981-2998,共18页
In this work,we consider the performance analysis of state dependent priority traffic and scheduling in device to device(D2D)heterogeneous networks.There are two priority transmission types of data in wireless communi... In this work,we consider the performance analysis of state dependent priority traffic and scheduling in device to device(D2D)heterogeneous networks.There are two priority transmission types of data in wireless communication,such as video or telephone,which always meet the requirements of high priority(HP)data transmission first.If there is a large amount of low priority(LP)data,there will be a large amount of LP data that cannot be sent.This situation will cause excessive delay of LP data and packet dropping probability.In order to solve this problem,the data transmission process of high priority queue and low priority queue is studied.Considering the priority jump strategy to the priority queuing model,the queuing process with two priority data is modeled as a two-dimensionalMarkov chain.A state dependent priority jump queuing strategy is proposed,which can improve the discarding performance of low priority data.The quasi birth and death process method(QBD)and fixed point iterationmethod are used to solve the causality,and the steady-state probability distribution is further obtained.Then,performance parameters such as average queue length,average throughput,average delay and packet dropping probability for both high and low priority data can be expressed.The simulation results verify the correctness of the theoretical derivation.Meanwhile,the proposed priority jump queuing strategy can significantly improve the drop performance of low-priority data. 展开更多
关键词 Stochastic geometry queuing theory D2D heterogeneous networks quasi-birth and death process
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SO_(2)对K2CO_(3)吸附CO_(2)性能影响的实验及DFT机理研究
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作者 郭百合 李艳红 +3 位作者 张靖超 王彦霖 乔晓磊 金燕 《中国电机工程学报》 EI CSCD 北大核心 2024年第2期659-669,I0019,共12页
电站锅炉的尾气在脱硫后含有微量的SO_(2),导致CO_(2)吸附剂性能变差。根据电厂烟气的组分,采用模拟烟气在实验室条件下对K2CO_(3)吸附剂的CO_(2)吸附性能及SO_(2)对CO_(2)吸附的影响进行实验研究。结合XRD分析,利用密度泛函理论(densit... 电站锅炉的尾气在脱硫后含有微量的SO_(2),导致CO_(2)吸附剂性能变差。根据电厂烟气的组分,采用模拟烟气在实验室条件下对K2CO_(3)吸附剂的CO_(2)吸附性能及SO_(2)对CO_(2)吸附的影响进行实验研究。结合XRD分析,利用密度泛函理论(density functional theory,DFT)对SO_(2)在K2CO_(3)吸附剂上的影响及CO_(2)吸附机理进行理论研究。结果表明,受SO_(2)分子S原子活跃的s轨道影响,S的p轨道及O原子活性均增强,与K2CO_(3)表面O原子价带顶能带简并,SO_(2)被优先吸附在K2CO_(3)表面的O顶位,并将CO_(2)推离吸附剂表面,导致吸附剂活性位点虽有空余却无法吸附CO_(2)。在实验中表现为:模拟烟气中CO_(2)体积浓度为10%时,气氛中体积浓度为0.007%的SO_(2)会使吸附剂的吸附量由1.65 mmol/g降低至1.01 mmol/g。提出CO_(2)与H2O在K2CO_(3)(001)表面的吸附机理,理论计算的反应活化能为40.7 kJ/mol,反应热为-54.9 kJ/mol。 展开更多
关键词 K2CO_(3)吸附剂 CO_(2)捕集 SO_(2)影响 密度泛函理论 机理研究
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Fe、La掺杂和氧缺陷对CeO_(2)表面吸附As_(2)O_(3)的密度泛函理论研究
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作者 卢鲲鹏 张凯华 张锴 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第8期1149-1161,共13页
采用密度泛函理论研究了As_(2)O_(3)(g)在Fe、La掺杂CeO_(2)(110)表面及氧缺陷LaCeO(110)表面的吸附行为,探索了LaCeO表面砷吸附能力显著高于FeCeO表面的主要原因。结果表明,As_(2)O_(3)(g)的吸附效果与吸附位点数量、吸附能、键长和电... 采用密度泛函理论研究了As_(2)O_(3)(g)在Fe、La掺杂CeO_(2)(110)表面及氧缺陷LaCeO(110)表面的吸附行为,探索了LaCeO表面砷吸附能力显著高于FeCeO表面的主要原因。结果表明,As_(2)O_(3)(g)的吸附效果与吸附位点数量、吸附能、键长和电荷转移密切相关。纯CeO_(2)表面的吸附主要为化学吸附,吸附能绝对值大于−4.22 eV,电荷转移量为(−0.19)−(−0.31)e,As_(2)O_(3)得到电荷带负电,起表面受主作用,因此吸附量较小。FeCeO(110)表面新增Fe顶位和Bridge-2桥位两个吸附位,其中,Fe顶位为化学吸附,Fe掺杂改变了FeCeO表面电子分布和晶格结构,但并未改变As_(2)O_(3)与FeCeO之间的电荷转移方向,因此,As_(2)O_(3)仍呈负离子形式吸附。LaCeO(110)表面新增了三个吸附位:La顶位、Bridge-3桥位和Hollow-2空位,La掺杂改变了As_(2)O_(3)与LaCeO之间的电荷转移方向,使得As_(2)O_(3)失电子呈正离子吸附,起表面施主作用,因此,吸附能力增强。无O_(2)环境下,单一O缺陷LaCeO(110)表面吸附能力低于完整LaCeO表面;有O_(2)环境下,O缺陷有利于As_(2)O_(3)的吸附。 展开更多
关键词 密度泛函理论 二氧化铈 Fe、La掺杂 As_(2)O_(3)吸附 O缺陷
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以CeO_(2)为载体的Fe基载氧体与CO反应机理模拟
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作者 穆林 孙萌 +4 位作者 张彬 尚妍 东明 陈建标 霍兆义 《洁净煤技术》 CAS CSCD 北大核心 2024年第2期114-122,共9页
化学链燃烧技术是一种新型的近“零碳”排放燃烧技术,载氧体在化学链燃烧反应过程中发挥着载氧和传热的双重作用。以活性催化组分为载体,通过调谐微观结构提高Fe基载氧体的反应性能是目前化学链领域的研究热点之一。基于密度泛函理论,以... 化学链燃烧技术是一种新型的近“零碳”排放燃烧技术,载氧体在化学链燃烧反应过程中发挥着载氧和传热的双重作用。以活性催化组分为载体,通过调谐微观结构提高Fe基载氧体的反应性能是目前化学链领域的研究热点之一。基于密度泛函理论,以CeO_(2)为活性催化载体,对Fe基载氧体进行催化调谐。通过优化构建组合物模型,系统分析了组合物模型中Fe_(2)O_(3)团簇不同点位吸附CO的态密度、吸附能、差分电荷密度和活化能等电子结构特性参数。研究结果表明,Fe_(2)O_(3)团簇的电子向CeO_(2)(111)表面转移,Fe_(2)O_(3)团簇的吸附能为-3.92 eV,Fe2O3团簇与CeO_(2)(111)表面稳定结合;态密度(DOS)分析发现负载后的Fe_(2)O_(3)团簇p和d轨道在-8~0 eV电子向费米能级方向迁移,表明吸附作用增强。Fe_(2)O_(3)团簇p和d轨道中电子减少,现存电子向高能级跃迁,Fe_(2)O_(3)团簇电子活性增强,CO分子在Fe_(2)O_(3)/CeO2复合载氧体的Fe_(2)O_(3)团簇3个吸附位反应的活化能均降低。此外,CeO_(2)(111)增强了CO在Fe_(2)O_(3)团簇Fe顶位的吸附作用,吸附能由-0.33 eV增至-1.78 eV;同时,削弱了在O顶位的过强吸附作用,吸附能由-2.69 eV降至-2.32 eV,有利于后期CO_(2)分子脱离Fe_(2)O_(3)团簇表面,从而有效调谐Fe2O3团簇整体对CO的吸附效果,为Fe基载氧体的设计制备和优化调谐提供理论指导。 展开更多
关键词 Fe基载氧体 CeO_(2)载体 密度泛函理论 一氧化碳 催化
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2型糖尿病患者自我管理认知量表的编制及信效度检验
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作者 顾淑燕 王孝勇 +2 位作者 张宁 顾海 王小玲 《护理学杂志》 CSCD 北大核心 2024年第8期29-32,38,共5页
目的编制2型糖尿病患者自我管理认知量表并检验其信效度,为科学动态测量患者自我管理认知水平提供有效工具。方法基于保护动机理论,结合专家咨询及预调查形成2型糖尿病患者自我管理认知初始量表,在南京、济南和上海分2批次调查739例患者... 目的编制2型糖尿病患者自我管理认知量表并检验其信效度,为科学动态测量患者自我管理认知水平提供有效工具。方法基于保护动机理论,结合专家咨询及预调查形成2型糖尿病患者自我管理认知初始量表,在南京、济南和上海分2批次调查739例患者,评价量表的信效度。结果形成的正式量表包括严重性、易感性、反应效能、自我效能和反应代价5个维度共29个条目。探索性因子分析提取5个公因子,累计方差贡献率为70.017%;验证性因子分析显示χ^(2)/df=2.763,RMSEA=0.070,NFI=0.905,IFI=0.938,TLI=0.930,CFI=0.937;量表AVE=0.557~0.924,Cronbach′sα系数为0.826。结论量表信效度良好,可用于测量2型糖尿病自我管理认知水平。 展开更多
关键词 2型糖尿病 自我管理 认知 保护动机理论 信度 效度 评估量表
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2-D distributed pose estimation of multi-agent systems using bearing measurements
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作者 Xu Fang Jitao Li +1 位作者 Xiaolei Li Lihua Xie 《Journal of Automation and Intelligence》 2023年第2期70-78,共9页
This article studies distributed pose(orientation and position)estimation of leader–follower multi-agent systems over𝜅-layer graphs in 2-D plane.Only the leaders have access to their orientations and position... This article studies distributed pose(orientation and position)estimation of leader–follower multi-agent systems over𝜅-layer graphs in 2-D plane.Only the leaders have access to their orientations and positions,while the followers can measure the relative bearings or(angular and linear)velocities in their unknown local coordinate frames.For the orientation estimation,the local relative bearings are used to obtain the relative orientations among the agents,based on which a distributed orientation estimation algorithm is proposed for each follower to estimate its orientation.For the position estimation,the local relative bearings are used to obtain the position constraints among the agents,and a distributed position estimation algorithm is proposed for each follower to estimate its position by solving its position constraints.Both the orientation and position estimation errors converge to zero asymptotically.A simulation example is given to verify the theoretical results. 展开更多
关键词 Pose estimation Distributed algorithm Bearing measurements Multi-agent system Local coordinate frame 2-d plane
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O_(2)在金团簇阳离子上的吸附:键合强度和活化程度的分析
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作者 胡瑾 黄璐璐 +3 位作者 刘文 金正千 王雪峰 邢小鹏 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2024年第2期351-360,I0040-I0052,I0104,共24页
本文结合团簇反应动力学实验和量子化学计算,研究了O_(2)在金团簇阳离子上的吸附与活化.实验发现,在温和条件下,Au_(10)^(+)能快速吸附单个O_(2)分子形成Au_(10)O_(2)^(+);Au_(2)^(+)和Au_(4)^(+)的反应性则较低,但相应的氩络合物Au_(2)... 本文结合团簇反应动力学实验和量子化学计算,研究了O_(2)在金团簇阳离子上的吸附与活化.实验发现,在温和条件下,Au_(10)^(+)能快速吸附单个O_(2)分子形成Au_(10)O_(2)^(+);Au_(2)^(+)和Au_(4)^(+)的反应性则较低,但相应的氩络合物Au_(2)ArO_(2)^(+)和Au_(4)Ar_(1,2)O_(2)^(+)很容易形成;除此之外,其他尺寸的团簇都表现出反应惰性.理论计算表明,O_(2)倾向于以端接的方式吸附在具有线型或平面型结构的Au_(n)^(+)(n=2~7)簇和Au_(8)^(+)的平面异构体上,并表现出极低的活化程度吸附在具有三维结构的Au_(n)^(+)(n=9,11,13)簇上的O_(2)也呈现出类似的特征。与此形成鲜明对比的是,在Au_(8)^(+)的三维异构体和n=10,12,14的偶数大尺寸Au_(n)^(+)上,O_(2)倾向于以侧向桥接的方式吸附并被高度活化.理论预测的O_(2)在团簇上的键合强度结合动力学因素影响,合理地解释了实验中观察到的反应产物Au_(2,4,10)O_(2)^(+),Au_(2)ArO_(2)^(+)和Au_(4)ArO_(2)^(+). 展开更多
关键词 金簇阳离子 飞行时间质谱仪 密度泛函理论 O_(2)活化
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