Europium（Ⅲ） compound with 2-oxopropionic acid salicyloyl hydrazone （C10H10N2O4, H3L） and 1,10-phenanthroline （C12H8N2, phen） has been prepared. A yellow prismatic crystal of the compound was obtained, and the m...Europium（Ⅲ） compound with 2-oxopropionic acid salicyloyl hydrazone （C10H10N2O4, H3L） and 1,10-phenanthroline （C12H8N2, phen） has been prepared. A yellow prismatic crystal of the compound was obtained, and the molecule crystallized in the triclinic space group P-1. There are two 9-coordinated complex molecules in every structure unit, where every Eu atom is coordinated by three water molecules and two tridentate C10H10N2O4 ligands, forming two stable pentacycles. The coordination polyhedron around Eu^3＋ was described as a single cap square antiprism. In the crystal cell, there are one free 1,10-phenanthroline and four water molecules. The thermal decomposition of the compound and its kinetics were studied by non-isothermal thermogravimetry. The Kissinger＇s method and Ozawa＇s method were used to calculate the activation energy value of the first-step decomposition. The stages of the decompositions were identified by TG-DTG-DSC curve. The non-isothermal kinetic data were analyzed by means of integral and differential methods. The possible reaction mechanism and the kinetic equations were investigated by comparing the kinetic parameters.展开更多
A novel gadolinium（Ⅲ） complex with N-（2-propionic acid）-salicyloyl hydrazone （C10H10N2O4, H3L） and 1,10-phenanthroline （C12H8N2, phen） was prepared and characterized. The crystal structure of [Gd（H2L）（HL...A novel gadolinium（Ⅲ） complex with N-（2-propionic acid）-salicyloyl hydrazone （C10H10N2O4, H3L） and 1,10-phenanthroline （C12H8N2, phen） was prepared and characterized. The crystal structure of [Gd（H2L）（HL）- （H2O）3]2·phen·4H2O was determined by X-ray single crystal diffractometry. The crystal complex crystallizes in the triclinic system with space group P-1. There are two 9-coordinated structure units in every complex molecule, in which Gd（Ⅲ） is coordinated by two tridentate ligands （H2L and HL forms） and three water molecules and both the structural units take a distorted monocapped square antiprism. There is a free 1,10-phenanthroline connecting with coordinated water by hydrogen bonds in the crystal. The bioactivity tests indicate that the complex is an inhibitor against three bacteria.展开更多
基金Project supported by the Natural Science Foundation of Shaanxi Province （No. 2004B02）, the Breeding Industrialized Fund of the Education Com mittee of Shaanxi Province （No. 06JC02） and Xi＇an Science Technology Bureau （No. GG06113）.
文摘Europium（Ⅲ） compound with 2-oxopropionic acid salicyloyl hydrazone （C10H10N2O4, H3L） and 1,10-phenanthroline （C12H8N2, phen） has been prepared. A yellow prismatic crystal of the compound was obtained, and the molecule crystallized in the triclinic space group P-1. There are two 9-coordinated complex molecules in every structure unit, where every Eu atom is coordinated by three water molecules and two tridentate C10H10N2O4 ligands, forming two stable pentacycles. The coordination polyhedron around Eu^3＋ was described as a single cap square antiprism. In the crystal cell, there are one free 1,10-phenanthroline and four water molecules. The thermal decomposition of the compound and its kinetics were studied by non-isothermal thermogravimetry. The Kissinger＇s method and Ozawa＇s method were used to calculate the activation energy value of the first-step decomposition. The stages of the decompositions were identified by TG-DTG-DSC curve. The non-isothermal kinetic data were analyzed by means of integral and differential methods. The possible reaction mechanism and the kinetic equations were investigated by comparing the kinetic parameters.
基金Project supported by the Natural Science Foundation 0f Shaanxi Province （No. 2004B02） and the Education Commission of Shaanxi Province （No. 03JK085）.
文摘A novel gadolinium（Ⅲ） complex with N-（2-propionic acid）-salicyloyl hydrazone （C10H10N2O4, H3L） and 1,10-phenanthroline （C12H8N2, phen） was prepared and characterized. The crystal structure of [Gd（H2L）（HL）- （H2O）3]2·phen·4H2O was determined by X-ray single crystal diffractometry. The crystal complex crystallizes in the triclinic system with space group P-1. There are two 9-coordinated structure units in every complex molecule, in which Gd（Ⅲ） is coordinated by two tridentate ligands （H2L and HL forms） and three water molecules and both the structural units take a distorted monocapped square antiprism. There is a free 1,10-phenanthroline connecting with coordinated water by hydrogen bonds in the crystal. The bioactivity tests indicate that the complex is an inhibitor against three bacteria.
