Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation processes.However,these membranes are still restricted sign...Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation processes.However,these membranes are still restricted significantly on account of low water permeability and poor dynamic tunability of 2D nanochannels under temperature stimulation.Here,we present a biomimetic negatively thermo-responsive MXene membrane by covalently grafting poly(N-isopropylacrylamide)(PNIPAm)onto MXene nanosheets.The uniformly grafted PNIPAm polymer chains can enlarge the interlayer spacings for increasing water permeability while also allowing more tunability of 2D nanochannels for enhancing the capability of gradually separating multiple molecules of different sizes.As expected,the constructed membrane exhibits ultrahigh water permeance of 95.6 L m^(-2) h^(-1) bar^(-1) at 25℃,which is eight-fold higher than the state-of-the-art negatively thermoresponsive 2D membranes.Moreover,the highly temperature-tunable 2D nanochannels enable the constructed membrane to perform excellent graded molecular sieving for dye-and antibiotic-based ternary mixtures.This strategy provides new perspectives in engineering smart 2D membrane and expands the scope of temperature-responsive membranes,showing promising applications in micro/nanofluidics and molecular separation.展开更多
针对信道状态信息未知SWIPT-D2D(Simultaneous Wireless Information and Power Transfer Device to Device)无线通信网络环境下设备间信号干扰以及设备能量损耗问题,提出通过使用近端策略优化(Proximal Policy Optimization,PPO)算法,...针对信道状态信息未知SWIPT-D2D(Simultaneous Wireless Information and Power Transfer Device to Device)无线通信网络环境下设备间信号干扰以及设备能量损耗问题,提出通过使用近端策略优化(Proximal Policy Optimization,PPO)算法,在满足蜂窝用户通信质量要求的前提下同时对D2D用户的资源块、发射功率以及功率分割比三部分进行联合优化。仿真结果表明,所提算法相比于其他算法能够为D2D用户制定更好的资源分配方案,在保证蜂窝用户保持较高通信速率的同时使D2D用户获得更高的能效。同时,当环境中用户数量增加时,所提算法相比于Dueling Double DQN(Deep Q-Network)以及DQN算法,D2D能效分别平均提高了15.95%和23.59%,当通信网络规模变大时所提算法具有更强的鲁棒性。展开更多
基金supported by the National Nature Science Foundation of China(No.22278179,U23A20688)the National Key Research and Development Program of China(2021YFB3802600)+3 种基金the Fundamental Research Funds for the Central Universities(JUSRP622035)National First-Class Discipline Program of Light Industry Technology and Engineering(LIFE2018-19)MOE&SAFEA for the 111 Project(B13025)Natural Science Foundation of Xinjiang Uygur Autonomous Region(2022D01D030).
文摘Negatively thermo-responsive 2D membranes,which mimic the stomatal opening/closing of plants,have drawn substantial interest for tunable molecular separation processes.However,these membranes are still restricted significantly on account of low water permeability and poor dynamic tunability of 2D nanochannels under temperature stimulation.Here,we present a biomimetic negatively thermo-responsive MXene membrane by covalently grafting poly(N-isopropylacrylamide)(PNIPAm)onto MXene nanosheets.The uniformly grafted PNIPAm polymer chains can enlarge the interlayer spacings for increasing water permeability while also allowing more tunability of 2D nanochannels for enhancing the capability of gradually separating multiple molecules of different sizes.As expected,the constructed membrane exhibits ultrahigh water permeance of 95.6 L m^(-2) h^(-1) bar^(-1) at 25℃,which is eight-fold higher than the state-of-the-art negatively thermoresponsive 2D membranes.Moreover,the highly temperature-tunable 2D nanochannels enable the constructed membrane to perform excellent graded molecular sieving for dye-and antibiotic-based ternary mixtures.This strategy provides new perspectives in engineering smart 2D membrane and expands the scope of temperature-responsive membranes,showing promising applications in micro/nanofluidics and molecular separation.
文摘针对信道状态信息未知SWIPT-D2D(Simultaneous Wireless Information and Power Transfer Device to Device)无线通信网络环境下设备间信号干扰以及设备能量损耗问题,提出通过使用近端策略优化(Proximal Policy Optimization,PPO)算法,在满足蜂窝用户通信质量要求的前提下同时对D2D用户的资源块、发射功率以及功率分割比三部分进行联合优化。仿真结果表明,所提算法相比于其他算法能够为D2D用户制定更好的资源分配方案,在保证蜂窝用户保持较高通信速率的同时使D2D用户获得更高的能效。同时,当环境中用户数量增加时,所提算法相比于Dueling Double DQN(Deep Q-Network)以及DQN算法,D2D能效分别平均提高了15.95%和23.59%,当通信网络规模变大时所提算法具有更强的鲁棒性。