Platinum nanowire （PtNW） can be grown by electrodeposition in polycarbonate membrane, with the average diameter of the nanowires about 250 nm. The PtNW and multiwalled carbon nanotubes （CNT） are then dispersed int...Platinum nanowire （PtNW） can be grown by electrodeposition in polycarbonate membrane, with the average diameter of the nanowires about 250 nm. The PtNW and multiwalled carbon nanotubes （CNT） are then dispersed into chitosan （CHIT） solution. The resulting PtNW-CNT-CHIT material brings new capabilities for electrochemical devices by using the synergistic action of the electrocatalytic activity of PtNW and CNT. By dropping the PtNW-CNT-CHIT film onto the glassy carbon （GO） electrode surface, and after evaporation an amperometric sensor for the determination of indole-3-acetic acid （IAA） was developed. The oxidation current of IAA increased significantly at the PtNW-CNT-CHIT film coated GC electrode, in contrast to that at the CNT-CHIT modified GC. The linear response of the sensor is from 50 ng/ml to 50 μg/ml with a detection limit of 25 ng/mL.展开更多
Developing high-performance non-precious metal electrocatalysts for oxygen reduction reaction(ORR)is crucial for the commercialization of fuel cells and metal-air batteries.However,doped carbon-based materials only sh...Developing high-performance non-precious metal electrocatalysts for oxygen reduction reaction(ORR)is crucial for the commercialization of fuel cells and metal-air batteries.However,doped carbon-based materials only show good ORR activity in alkaline medium,and become less effective in acidic environment.We believe that an appropriate combination of both ionic and electronic transport path,and well dopant distribution of doped carbon-based materials would help to realize high ORR performance un-der both acidic and alkaline cond让ions.Accordingly,a nitrogen and sulfur co-doped carbon framework with hierarchical through-hole structure is fabricated by morphology-controlled solid-state pyrolysis of poly(aniline-co-2-ami no thiophenol)foam.The uniform high concentrations of nitrogen and sulfur,high intrinsic conductivity,and integrated three dimensional ionic and electronic transfer passageways of the 3D porous structure lead to synergistic effects in catalyzing ORR.As a result,the limiting current density of the carbonized poly(aniline-co-2-aminothiophenol)foam is equivalent to commercial Pt/C in acidic environment,and twice the latter in alkaline medium.展开更多
Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D printing.It is biodegradable and environmentally friendly biopolymer which made out of corn.However,it exhibits weak mechan...Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D printing.It is biodegradable and environmentally friendly biopolymer which made out of corn.However,it exhibits weak mechanical properties which reduced its usability as a functional prototype in a real-world application.In the present study,two PLA composites are created through coextruded with 3K carbon fibres and twisted Kevlar string(as core fibre)to form a fibre reinforced parts(FRP).The mechanical strength of printed parts was examined using ASTM D638 standard with a strain rate of 1 mm/min.It has been demonstrated that the FRPs coextruded with 3K carbon fibres had achieved significant improvement in Young’s modulus(+180.6%,9.205 GPa),ultimate tensile strength(+175.3%,103 MPa)and maximum tensile strain(+21.6%,1.833%).Although the Young’s modulus of Kevlar FRP was found to be similar to as compared to unreinforced PLA(~3.29 GPa),it has gained significant increment in terms of maximum tensile strain(+179.7%,104.64 MPa),and maximum tensile strain(+257%,5.384%).Thus,this study revealed two unique composite materials,in which the 3K carbon FRP can offer stiff and high strength structure while Kevlar FRP offers similar strength but at a higher elasticity.展开更多
To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limes...To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limestone samples at different temperatures and constant pH, HCl concentration. The relationship between Ca^(2+) concentration and time was revealed through the experiments; pore size distribution before and after dissolution indicate that there is no correlation between the temperature and pore size variation, but pore size variation in grain limestone is more significant, indicating that the variation is mainly controlled by the heterogeneity of the rock itself(initial porosity and permeability) and the abundance of unstable minerals(related to crystal shape, size and mineral type). At different temperatures, the two kinds of carbonate rocks had very small variation in pore throat radius from 0.003 mm to 0.040 mm, which is 1.3 to 3.5 times more, 1.7 on average of the original pore throat radius. Their pore throat length varied from 0.05 mm to 0.35 mm. The minor changes in the pore throat radius, length and connectivity brought big changes to permeability of up to 1 000×10^(-3) μm^2.展开更多
In this work,conductive polymer nanocomposites were developed based on a biodegradable and biobased polymer(poly(lactic acid)),with the incorporation of only 0.3 wt%of carbon nanotubes(CNTs)to be used as volatile solv...In this work,conductive polymer nanocomposites were developed based on a biodegradable and biobased polymer(poly(lactic acid)),with the incorporation of only 0.3 wt%of carbon nanotubes(CNTs)to be used as volatile solvent sensors.The correct dispersion of the nanofiller was achieved thanks to a CNT non-covalent modification with an azo-dye(disperse orange 3)which allowed to reach the percolation for electric conduction in values as low as 0.3 wt%.The chemo-resistive properties of the developed sensors were investigated by exposure to organic vapors(ethanol,tetrahydrofuran and toluene)and water vapor,showing good selectivity.In addition,considering the manipulation to which the sensor will be exposed,wear resistance was characterized,finding that the incorporation of CNTs produced an increase in more than a 50%.展开更多
To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut sh...To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.展开更多
基金supported by the NNSF of China(No.20435010,30540019,30670190 and 3060049)the Natural Science Foundation of Hunan Province(No.0JJY1003 and 05C306).
文摘Platinum nanowire （PtNW） can be grown by electrodeposition in polycarbonate membrane, with the average diameter of the nanowires about 250 nm. The PtNW and multiwalled carbon nanotubes （CNT） are then dispersed into chitosan （CHIT） solution. The resulting PtNW-CNT-CHIT material brings new capabilities for electrochemical devices by using the synergistic action of the electrocatalytic activity of PtNW and CNT. By dropping the PtNW-CNT-CHIT film onto the glassy carbon （GO） electrode surface, and after evaporation an amperometric sensor for the determination of indole-3-acetic acid （IAA） was developed. The oxidation current of IAA increased significantly at the PtNW-CNT-CHIT film coated GC electrode, in contrast to that at the CNT-CHIT modified GC. The linear response of the sensor is from 50 ng/ml to 50 μg/ml with a detection limit of 25 ng/mL.
基金financial support by the National Natural Science Foundation of China (Grant: 51333008)Young Teacher Training Program of Sun Yat-sen University (Grant: 17lgpy86)
文摘Developing high-performance non-precious metal electrocatalysts for oxygen reduction reaction(ORR)is crucial for the commercialization of fuel cells and metal-air batteries.However,doped carbon-based materials only show good ORR activity in alkaline medium,and become less effective in acidic environment.We believe that an appropriate combination of both ionic and electronic transport path,and well dopant distribution of doped carbon-based materials would help to realize high ORR performance un-der both acidic and alkaline cond让ions.Accordingly,a nitrogen and sulfur co-doped carbon framework with hierarchical through-hole structure is fabricated by morphology-controlled solid-state pyrolysis of poly(aniline-co-2-ami no thiophenol)foam.The uniform high concentrations of nitrogen and sulfur,high intrinsic conductivity,and integrated three dimensional ionic and electronic transfer passageways of the 3D porous structure lead to synergistic effects in catalyzing ORR.As a result,the limiting current density of the carbonized poly(aniline-co-2-aminothiophenol)foam is equivalent to commercial Pt/C in acidic environment,and twice the latter in alkaline medium.
基金This project is funded by Universiti Tunku Abdul Rahman through the grant number IPSR/RMC/UTARRF/2018-C2/T02.
文摘Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D printing.It is biodegradable and environmentally friendly biopolymer which made out of corn.However,it exhibits weak mechanical properties which reduced its usability as a functional prototype in a real-world application.In the present study,two PLA composites are created through coextruded with 3K carbon fibres and twisted Kevlar string(as core fibre)to form a fibre reinforced parts(FRP).The mechanical strength of printed parts was examined using ASTM D638 standard with a strain rate of 1 mm/min.It has been demonstrated that the FRPs coextruded with 3K carbon fibres had achieved significant improvement in Young’s modulus(+180.6%,9.205 GPa),ultimate tensile strength(+175.3%,103 MPa)and maximum tensile strain(+21.6%,1.833%).Although the Young’s modulus of Kevlar FRP was found to be similar to as compared to unreinforced PLA(~3.29 GPa),it has gained significant increment in terms of maximum tensile strain(+179.7%,104.64 MPa),and maximum tensile strain(+257%,5.384%).Thus,this study revealed two unique composite materials,in which the 3K carbon FRP can offer stiff and high strength structure while Kevlar FRP offers similar strength but at a higher elasticity.
基金sponsored by PETRONAS and YUTP (Yayasan Universiti Teknologi PETRONAS)
文摘To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limestone samples at different temperatures and constant pH, HCl concentration. The relationship between Ca^(2+) concentration and time was revealed through the experiments; pore size distribution before and after dissolution indicate that there is no correlation between the temperature and pore size variation, but pore size variation in grain limestone is more significant, indicating that the variation is mainly controlled by the heterogeneity of the rock itself(initial porosity and permeability) and the abundance of unstable minerals(related to crystal shape, size and mineral type). At different temperatures, the two kinds of carbonate rocks had very small variation in pore throat radius from 0.003 mm to 0.040 mm, which is 1.3 to 3.5 times more, 1.7 on average of the original pore throat radius. Their pore throat length varied from 0.05 mm to 0.35 mm. The minor changes in the pore throat radius, length and connectivity brought big changes to permeability of up to 1 000×10^(-3) μm^2.
文摘In this work,conductive polymer nanocomposites were developed based on a biodegradable and biobased polymer(poly(lactic acid)),with the incorporation of only 0.3 wt%of carbon nanotubes(CNTs)to be used as volatile solvent sensors.The correct dispersion of the nanofiller was achieved thanks to a CNT non-covalent modification with an azo-dye(disperse orange 3)which allowed to reach the percolation for electric conduction in values as low as 0.3 wt%.The chemo-resistive properties of the developed sensors were investigated by exposure to organic vapors(ethanol,tetrahydrofuran and toluene)and water vapor,showing good selectivity.In addition,considering the manipulation to which the sensor will be exposed,wear resistance was characterized,finding that the incorporation of CNTs produced an increase in more than a 50%.
基金Funded by the General Project of Science and Technology Plan of Yunnan Science and Technology Department(Nos.202001AT070029,2019FB077)Open Fund of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab-20-4)。
文摘To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.
