3D printing techniques offer an effective method in fabricating complex radially multi-material structures.However,it is challenging for complex and delicate radially multi-material model geometries without supporting...3D printing techniques offer an effective method in fabricating complex radially multi-material structures.However,it is challenging for complex and delicate radially multi-material model geometries without supporting structures,such as tissue vessels and tubular graft,among others.In this work,we tackle these challenges by developing a polar digital light processing technique which uses a rod as the printing platform.The 3D model fabrication is accomplished through line projection.The rotation and translation of the rod are synchronized to project and illuminate the photosensitive material volume.By controlling the distance between the rod and the printing window,we achieved the printing of tubular structures with a minimum wall thickness as thin as 50 micrometers.By controlling the width of fine slits at the printing window,we achieved the printing of structures with a minimum feature size of 10 micrometers.Our process accomplished the fabrication of thin-walled tubular graft structure with a thickness of only 100 micrometers and lengths of several centimeters within a timeframe of just 100 s.Additionally,it enables the printing of axial multi-material structures,thereby achieving adjustable mechanical strength.This method is conducive to rapid customization of tubular grafts and the manufacturing of tubular components in fields such as dentistry,aerospace,and more.展开更多
To achieve full-surface strain measurement of variable curvature objects,a 360°3D digital image correlation(DIC)system is proposed.The measurement system consists of four double-camera systems,which capture the o...To achieve full-surface strain measurement of variable curvature objects,a 360°3D digital image correlation(DIC)system is proposed.The measurement system consists of four double-camera systems,which capture the object’s entire surface from multiple angles,enabling comprehensive full-surface measurement.To increase the stitching quality,a hierarchical coordinate matching method is proposed.Initially,a 3D rigid body calibration auxiliary block is employed to track motion trajectory,which enables preliminary matching of four 3D-DIC sub-systems.Subsequently,secondary precise matching is performed based on feature points on the test specimen’s surface.Through the hierarchical coordinate matching method,the local 3D coordinate systems of each double-camera system are unified into a global coordinate system,achieving 3D surface reconstruction of the variable curvature cylindrical shell,and error analysis is conducted on the results.Furthermore,axial compression buckling experiment is conducted to measure the displacement and strain fields on the cylindrical shell’s surface.The experimental results are compared with the finite element analysis,validating the accuracy and effectiveness of the proposed multi-camera 3D-DIC measuring system.展开更多
It is a research subject in computer vision to 3D reconstruction of an object represented by a single 2D line drawing. Previous works on 3D reconstruction from 2D line drawings focus on objects with lines, plane, view...It is a research subject in computer vision to 3D reconstruction of an object represented by a single 2D line drawing. Previous works on 3D reconstruction from 2D line drawings focus on objects with lines, plane, view, and so on. This paper mainly studies the 3D reconstruction from 2D line drawings. Besides, a new approach is proposed: it is that for the research of the point coordinates of 2D line drawings, so as to achieve the object reconstruction by the reconstruction of point coordinates. The reconstruction process includes: (1) the collection of point coordinates (X,Y) of 2D line drawings; (2) the derivation of mathematical formula about the reconstruction of the point of 2D line drawings, and calculating the corresponding point of the 3D coordinates; (3) the regeneration of 3D graphics with 3D points; (4) analyze error by the proportional of parallel of axonometric projection, in order to prove the accuracy of the method.展开更多
The system mathematical model of flexible 3D measuring system is built by theoretical analysis, and the theoretical formula for measuring space point coordinate is also derived. Frog-jumping based coordinate transform...The system mathematical model of flexible 3D measuring system is built by theoretical analysis, and the theoretical formula for measuring space point coordinate is also derived. Frog-jumping based coordinate transform method is put forward in order to solve measuring problem for large size parts. The frog-jumping method is discussed, and the coordinate transform mathematical model is method of the space point coordinate compared to original value, and an advanced method is provided, Form the space point coordinate transform formula can derive the calculation measuring method for measuring large size parts.展开更多
This paper presents a direct method to find the internal faces. It uses four sets of information: get the coordinates of each point on the 3D composite objects; (~)based on the 3D coordinates to calculate all the p...This paper presents a direct method to find the internal faces. It uses four sets of information: get the coordinates of each point on the 3D composite objects; (~)based on the 3D coordinates to calculate all the plane equation of two objects; (~)calculate all the intersecting lines of the two objects and exclude the intersecting lines which are not within the scope of the plane;finding the internal face, the remaining intersecting lines formed the plane is the internal face of the two objects. We proposed a new algorithm for finding internal faces. This algorithm could be adapted to any regular composite objects .The algorithm works well for finding internal faces.展开更多
When linearizing three-dimensional(3 D)coordinate similarity transformation model with large rotations,we usually encounter the ill-posed normal matrix which may aggravate the instability of solutions.To alleviate the...When linearizing three-dimensional(3 D)coordinate similarity transformation model with large rotations,we usually encounter the ill-posed normal matrix which may aggravate the instability of solutions.To alleviate the problem,a series of conversions are contributed to the 3 D coordinate similarity transformation model in this paper.We deduced a complete solution for the 3 D coordinate similarity transformation at any rotation with the nonlinear adjustment methodology,which involves the errors of the common and the non-common points.Furthermore,as the large condition number of the normal matrix resulted in an intractable form,we introduced the bary-centralization technique and a surrogate process for deterministic element of the normal matrix,and proved its benefit for alleviating the condition number.The experimental results show that our approach can obtain the smaller condition number to stabilize the convergence of the interested parameters.Especially,our approach can be implemented for considering the errors of the common and the non-common points,thus the accuracy of the transformed coordinates improves.展开更多
A new three-dimensional coordination polymer {[Co(BPTC)0.5(bix)]′(H2O)}n (1, H4BPTC = 1,1′-biphenyl-2,2′,6,6′-tetracarboxylic acid, bix = 1,3-bis(imidazol-l-ylmethyl)-benzene) has been synthesized by the...A new three-dimensional coordination polymer {[Co(BPTC)0.5(bix)]′(H2O)}n (1, H4BPTC = 1,1′-biphenyl-2,2′,6,6′-tetracarboxylic acid, bix = 1,3-bis(imidazol-l-ylmethyl)-benzene) has been synthesized by the hydrothermal method and characterized by IR, elemental analysis, and single-crystal X-ray analysis. The crystal is of orthorhombic, space group Pbcn with a = 13.2975(10), b = 13.8424(12), c = 22.6367(17) A, CoC22H19N4Os, Mr = 478.34, V = 4166.7(6) A3, Dc = 1.525 g/cm^3, F(000) = 1968,μ = 0.867 mm^-1, S = 1.023 and Z = 8. The final R = 0.0683 and wR = 0.1529 for 3655 observed reflections with I 〉 20(I). In the title complex, the 2D Co-BPTC layer is formed through self-assembly of Co(II) ions and bridging BPTC4-ligands in a molar ratio of 2:1. The metal-organic lattice layers are further united together through the second bridging ligand bix to form a 3D metal-organic framework. The thermal stability of the title complex was studied by thermal gravimetric (TG) and differential thermal analysis (DTA).展开更多
A three-dimensional coordination polymer {[Cd2(HCAM)2(H2O)4].3.SH2O}n was synthesized by the hydrothermal reaction of H3CAM (H3CAM = 4-hydroxypyridine-2,6-dicerboxylic acid) and Cd(NO3)2·4H2O. The structu...A three-dimensional coordination polymer {[Cd2(HCAM)2(H2O)4].3.SH2O}n was synthesized by the hydrothermal reaction of H3CAM (H3CAM = 4-hydroxypyridine-2,6-dicerboxylic acid) and Cd(NO3)2·4H2O. The structure was characterized by elemental analysis, thermal gravimetric analysis, infrared spectroscopy and single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 9.4389(19), b = 11.009(2), c = 11.192(2) A, α = 87.87(3), β= 74.63(3), γ = 81.22(3)°, V= 1108.2(4) A3, Z = 2, Dc= 2.164 g/cm3,μ = 2.011 mm^-1, F(000) = 710, R = 0.0419 and wR = 0.1170. X-ray analysis reveals that the title compound adopts a one-dimensional staircase structure by carboxyl of H3CAM and water molecules, and it is further linked by hydrogen bonds to form a 3-D metal-organic open framework. The thermal gravimetric analysis displays that the framework exists stably below 300 ℃.展开更多
A new Gd coordination polymer based on 2-(pyridin-3-yl)-lH-imidazole-4,5-dicar- boxylate, formulated as {[Gd2(HPyIDC)2(H2O)5]·(bpy)·(NO3)2·3H2O}n (1, bpy = 4,4'-bipyridine) has been synthes...A new Gd coordination polymer based on 2-(pyridin-3-yl)-lH-imidazole-4,5-dicar- boxylate, formulated as {[Gd2(HPyIDC)2(H2O)5]·(bpy)·(NO3)2·3H2O}n (1, bpy = 4,4'-bipyridine) has been synthesized under hydrothermal conditions. The compound crystallizes in triclinic, space group Pi with a = 11.451(2), b = 11.596(2), c = 15.7333(3) A, β = 79.47(3)°, Z = 2, V= 1948.6(7) A^3, C30H34Gd2N10O22, Dc = 2.047 g/cm^3, Mr= 1201.17, 2(MoKa) = 0.71073 A,μ = 3.477 mml, F(000) = 1176, the final R = 0.0554 and wR = 0.1181. Polymer 1 is a 2D network built up from 4-connected HPylDC2- anion and 4-connected Gd ions. Dielectric constant of complex 1 was measured at different frequencies with temperature variation.展开更多
The title Mn(Ⅱ) coordination polymer,poly{[heptaaqua-(μ4-bi-phenyl-3,3?,5,5?-tetracarboxylate)-bimanganese(Ⅱ)] pentahydrate},[Mn_2(bpta)(H_2O)_7]_n·5n H_2O(I),is crystallized from a mixture of bi...The title Mn(Ⅱ) coordination polymer,poly{[heptaaqua-(μ4-bi-phenyl-3,3?,5,5?-tetracarboxylate)-bimanganese(Ⅱ)] pentahydrate},[Mn_2(bpta)(H_2O)_7]_n·5n H_2O(I),is crystallized from a mixture of biphenyl-3,3?,5,5?-tetracarboxylic acid(H_4bpta) and MnCl_2·4H_2O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn(Ⅱ) cations,one fully deprotonated H4 bpta ligand,seven coordinated water molecules and five solvent water as guest molecules. In I,each Mn(Ⅱ) atom is octahedrally coordinated by six oxygen atoms from bpta^(4-) anions and coordinated water molecules. In the Mn(Ⅱ) cations,one half Mn(Ⅱ) ion of them located at a 2-fold axis generating a trinuclear [Mn_3(H_2O)_2(RCOO)_2] linker by μ1,1-O(water) and μ1,3-O,O?(carboxylate) bridges and another half Mn(Ⅱ) ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn(Ⅱ) cations are linked together by biphenyl-3,3?,5,5?-tetracarboxylates to form a three-dimensional framework with a(42.84) topology of a(4,4)-connected net,in which the positions of the trinuclear [Mn_3(H_2O)_2(R-COO)_2] linker as a 4-connector linking four bpta^(4-) ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1 ?~3,amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.展开更多
The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of signi...The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.展开更多
If a geocentric 3D coordinate system is adopted in China to replace 2D non-geocentric coordinate system, the coordinates of the surface points will be changed accordingly. The influences on the current maps of China, ...If a geocentric 3D coordinate system is adopted in China to replace 2D non-geocentric coordinate system, the coordinates of the surface points will be changed accordingly. The influences on the current maps of China, especially the topographic maps, are discussed due to the replacement of the coordinate systems. Taking the replacement of Xi’an 80 coordinate system by GRS80 for a numerical example, this paper analyzes the changes of latitude, longitude, Gauss plane coordinates of the surface points, as well as the orientation and the length changes between the points on the map, including the changes of map border lines and sheet corner points.展开更多
A new compound, {[Sm^2L3(H2O)4]·(4,4'-bpy)·3H2O}n(1, H2 L = 5-(3-pyridyl methoxy) isophthalic acid, 4,4'-bpy = 4,4A-dipyridyl), has been hydrothermally synthesized and characterized by single-cryst...A new compound, {[Sm^2L3(H2O)4]·(4,4'-bpy)·3H2O}n(1, H2 L = 5-(3-pyridyl methoxy) isophthalic acid, 4,4'-bpy = 4,4A-dipyridyl), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 11.266(2), b = 15.530(3), c = 16.711(3) A, α = 112.803(3), β = 90.526(1), γ = 94.006(3)°, V = 2686.6(9) A3, Z = 2, Dc = 1.727 g/cm^3, μ = 2.251 mm-1, F(000) = 1392, S = 0.999, the final R = 0.0296 and wR = 0.1058. In the title compound, two crystallographically independent Sm^3+ cations are bridged by the carboxyl group of L2- ligands to form two different {Sm^2} binuclear subunits which are further connected by two distinct L2- ligands to shape a 1D chain, and such 1D chains are linked up to generate a 2D coordination polymer by another crystallographically unique L2- ligand. The thermogravimetric analysis and luminescent property of the title compound were also investigated.展开更多
Rehabilitation devices help to recover the physical abilities of patients. This study aims to develop a portable rehabilitation device that is safe to use when?patients are holding it by hands. In a previous study, to...Rehabilitation devices help to recover the physical abilities of patients. This study aims to develop a portable rehabilitation device that is safe to use when?patients are holding it by hands. In a previous study, to realize a home rehabilitation device, a flexible spherical actuator that can provide motion to patients was developed. In this study, to measure the relative position between both handling stages, a 3D coordinate measuring device using three wire-type linear potentiometers and an embedded controller was proposed and tested. In this paper, the spherical actuator with built-in 3D coordinate measuring device is described. The measuring method and experimental results obtained are also presented. The tracking position control of the actuator using the measuring device was carried out. As a result, the position of the handling stages can be successfully controlled using the feedback signal from the tested?measuring device.展开更多
Comprehensive radiation characteristics of polarized antenna are crucial in creating practical channel coefficients for next generation wireless communication system designs.Being currently supported within3 D geometr...Comprehensive radiation characteristics of polarized antenna are crucial in creating practical channel coefficients for next generation wireless communication system designs.Being currently supported within3 D geometry-based stochastic channel models(GSCM),field patterns are technically obtained by chamber measurement(or by its best fitting).However,in some channel related performance analysis scenarios,design insight can be crystallized better by starting the derivations with theoretical co-polarization and cross-polarization components.Specifically,these two components are mathematically linked with field patterns through the proposed polarization projection algorithm.In this manuscript,we focus on revealing the transformation criterion of polarization states between the antenna plane and the propagation plane.In practice,it makes retrieving the field patterns by electromagnetic computation possible.Meanwhile,the impact imposed by distinct antenna orientations is geometrically illustrated and consequently incorporated into the proposed algorithm.This will further facilitate flexible performance evaluation of related radio transmission technologies.Our conclusions are verified by the closed-form expression of the dipole field pattern(via an analytical approach) and by chamber measurement results.Moreover,we find that its 2D degenerative case is aligned with the definitions in 3^(rd) generation partnership project(3GPP)technical report 25.996.The most obvious benefit of the proposed algorithm is to significantly reduce the cost on generating channel coefficients in GSCM simulation.展开更多
A new 3D Ag(I) coordination polymer {[Ag(AZDB)(0.5)(bpe)(0.5)]·H2O}n(1) has been papared by azobenzene-3,3?-dicarboxylicate(H2AZDB), 1,2-bis(4-pyridyl)ethylene(bpe) and silver salts via hydroth...A new 3D Ag(I) coordination polymer {[Ag(AZDB)(0.5)(bpe)(0.5)]·H2O}n(1) has been papared by azobenzene-3,3?-dicarboxylicate(H2AZDB), 1,2-bis(4-pyridyl)ethylene(bpe) and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum(IR), powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal(4, 6)-connected fsc net with a(4^4·6^10·8)(4^4·6^2) topology.Moreover, the photoluminescent properties have also been discussed.展开更多
The construction of one-dimensional(1D)sulfides has attracted extensive attention for improving mi-crowave absorption(MA)performance owing to the anisotropic conductive networks.However,the syn-thesis of conductive 1D...The construction of one-dimensional(1D)sulfides has attracted extensive attention for improving mi-crowave absorption(MA)performance owing to the anisotropic conductive networks.However,the syn-thesis of conductive 1D hierarchical materials with unique interfacial polarization and excellent MA prop-erties remains challenging.In this study,cable-like MoS_(2)/Ni_(3)S_(2) was synthesized by a one-step hydrother-mal strategy.The complex permittivity of the binary composites could be improved by tuning the thick-ness of the MoS_(2) coating.Importantly,the construction of heterogeneous contacts by MoS_(2) and Ni_(3)S_(2) contributed to enhanced polarization loss,and the charge distribution was validated by electron holog-raphy.The wide efficient absorption bandwidth can reach above 4.8 GHz at a thin thickness.These new discoveries shed light on novel structures for 1D sulfide materials and the design of functional core-shell composites for microwave absorption.展开更多
基金supported financially by the Fundamental Research Funds for the Central Universities (YWF-22-K-101,YWF-23-L-805 and YWF-23-YG-QB-006)the support from the National Natural Science Foundation of China (12372106)Fundamental Research Funds for the Central Universities
文摘3D printing techniques offer an effective method in fabricating complex radially multi-material structures.However,it is challenging for complex and delicate radially multi-material model geometries without supporting structures,such as tissue vessels and tubular graft,among others.In this work,we tackle these challenges by developing a polar digital light processing technique which uses a rod as the printing platform.The 3D model fabrication is accomplished through line projection.The rotation and translation of the rod are synchronized to project and illuminate the photosensitive material volume.By controlling the distance between the rod and the printing window,we achieved the printing of tubular structures with a minimum wall thickness as thin as 50 micrometers.By controlling the width of fine slits at the printing window,we achieved the printing of structures with a minimum feature size of 10 micrometers.Our process accomplished the fabrication of thin-walled tubular graft structure with a thickness of only 100 micrometers and lengths of several centimeters within a timeframe of just 100 s.Additionally,it enables the printing of axial multi-material structures,thereby achieving adjustable mechanical strength.This method is conducive to rapid customization of tubular grafts and the manufacturing of tubular components in fields such as dentistry,aerospace,and more.
基金funded by the National Natural Science Foundations of China(Nos.12272176,U2037603).
文摘To achieve full-surface strain measurement of variable curvature objects,a 360°3D digital image correlation(DIC)system is proposed.The measurement system consists of four double-camera systems,which capture the object’s entire surface from multiple angles,enabling comprehensive full-surface measurement.To increase the stitching quality,a hierarchical coordinate matching method is proposed.Initially,a 3D rigid body calibration auxiliary block is employed to track motion trajectory,which enables preliminary matching of four 3D-DIC sub-systems.Subsequently,secondary precise matching is performed based on feature points on the test specimen’s surface.Through the hierarchical coordinate matching method,the local 3D coordinate systems of each double-camera system are unified into a global coordinate system,achieving 3D surface reconstruction of the variable curvature cylindrical shell,and error analysis is conducted on the results.Furthermore,axial compression buckling experiment is conducted to measure the displacement and strain fields on the cylindrical shell’s surface.The experimental results are compared with the finite element analysis,validating the accuracy and effectiveness of the proposed multi-camera 3D-DIC measuring system.
文摘It is a research subject in computer vision to 3D reconstruction of an object represented by a single 2D line drawing. Previous works on 3D reconstruction from 2D line drawings focus on objects with lines, plane, view, and so on. This paper mainly studies the 3D reconstruction from 2D line drawings. Besides, a new approach is proposed: it is that for the research of the point coordinates of 2D line drawings, so as to achieve the object reconstruction by the reconstruction of point coordinates. The reconstruction process includes: (1) the collection of point coordinates (X,Y) of 2D line drawings; (2) the derivation of mathematical formula about the reconstruction of the point of 2D line drawings, and calculating the corresponding point of the 3D coordinates; (3) the regeneration of 3D graphics with 3D points; (4) analyze error by the proportional of parallel of axonometric projection, in order to prove the accuracy of the method.
文摘The system mathematical model of flexible 3D measuring system is built by theoretical analysis, and the theoretical formula for measuring space point coordinate is also derived. Frog-jumping based coordinate transform method is put forward in order to solve measuring problem for large size parts. The frog-jumping method is discussed, and the coordinate transform mathematical model is method of the space point coordinate compared to original value, and an advanced method is provided, Form the space point coordinate transform formula can derive the calculation measuring method for measuring large size parts.
文摘This paper presents a direct method to find the internal faces. It uses four sets of information: get the coordinates of each point on the 3D composite objects; (~)based on the 3D coordinates to calculate all the plane equation of two objects; (~)calculate all the intersecting lines of the two objects and exclude the intersecting lines which are not within the scope of the plane;finding the internal face, the remaining intersecting lines formed the plane is the internal face of the two objects. We proposed a new algorithm for finding internal faces. This algorithm could be adapted to any regular composite objects .The algorithm works well for finding internal faces.
基金supported by the National Natural Science Foundation of China,Nos.41874001 and 41664001Support Program for Outstanding Youth Talents in Jiangxi Province,No.20162BCB23050National Key Research and Development Program,No.2016YFB0501405。
文摘When linearizing three-dimensional(3 D)coordinate similarity transformation model with large rotations,we usually encounter the ill-posed normal matrix which may aggravate the instability of solutions.To alleviate the problem,a series of conversions are contributed to the 3 D coordinate similarity transformation model in this paper.We deduced a complete solution for the 3 D coordinate similarity transformation at any rotation with the nonlinear adjustment methodology,which involves the errors of the common and the non-common points.Furthermore,as the large condition number of the normal matrix resulted in an intractable form,we introduced the bary-centralization technique and a surrogate process for deterministic element of the normal matrix,and proved its benefit for alleviating the condition number.The experimental results show that our approach can obtain the smaller condition number to stabilize the convergence of the interested parameters.Especially,our approach can be implemented for considering the errors of the common and the non-common points,thus the accuracy of the transformed coordinates improves.
基金supported by the International Technology Cooperation Project of Science and Technology Department of Henan Province (No. 124300510050)
文摘A new three-dimensional coordination polymer {[Co(BPTC)0.5(bix)]′(H2O)}n (1, H4BPTC = 1,1′-biphenyl-2,2′,6,6′-tetracarboxylic acid, bix = 1,3-bis(imidazol-l-ylmethyl)-benzene) has been synthesized by the hydrothermal method and characterized by IR, elemental analysis, and single-crystal X-ray analysis. The crystal is of orthorhombic, space group Pbcn with a = 13.2975(10), b = 13.8424(12), c = 22.6367(17) A, CoC22H19N4Os, Mr = 478.34, V = 4166.7(6) A3, Dc = 1.525 g/cm^3, F(000) = 1968,μ = 0.867 mm^-1, S = 1.023 and Z = 8. The final R = 0.0683 and wR = 0.1529 for 3655 observed reflections with I 〉 20(I). In the title complex, the 2D Co-BPTC layer is formed through self-assembly of Co(II) ions and bridging BPTC4-ligands in a molar ratio of 2:1. The metal-organic lattice layers are further united together through the second bridging ligand bix to form a 3D metal-organic framework. The thermal stability of the title complex was studied by thermal gravimetric (TG) and differential thermal analysis (DTA).
基金supported by the Natural Science Foundation of Hebei Province(B2009000969)
文摘A three-dimensional coordination polymer {[Cd2(HCAM)2(H2O)4].3.SH2O}n was synthesized by the hydrothermal reaction of H3CAM (H3CAM = 4-hydroxypyridine-2,6-dicerboxylic acid) and Cd(NO3)2·4H2O. The structure was characterized by elemental analysis, thermal gravimetric analysis, infrared spectroscopy and single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 9.4389(19), b = 11.009(2), c = 11.192(2) A, α = 87.87(3), β= 74.63(3), γ = 81.22(3)°, V= 1108.2(4) A3, Z = 2, Dc= 2.164 g/cm3,μ = 2.011 mm^-1, F(000) = 710, R = 0.0419 and wR = 0.1170. X-ray analysis reveals that the title compound adopts a one-dimensional staircase structure by carboxyl of H3CAM and water molecules, and it is further linked by hydrogen bonds to form a 3-D metal-organic open framework. The thermal gravimetric analysis displays that the framework exists stably below 300 ℃.
基金Supported by the National Natural Science Foundation of China(No.21201087)Jiangsu Province NSF BK20131244+1 种基金the Foundation of Jiangsu Educational Committee(11KJB150004)Qing Lan Project of Jiangsu Province
文摘A new Gd coordination polymer based on 2-(pyridin-3-yl)-lH-imidazole-4,5-dicar- boxylate, formulated as {[Gd2(HPyIDC)2(H2O)5]·(bpy)·(NO3)2·3H2O}n (1, bpy = 4,4'-bipyridine) has been synthesized under hydrothermal conditions. The compound crystallizes in triclinic, space group Pi with a = 11.451(2), b = 11.596(2), c = 15.7333(3) A, β = 79.47(3)°, Z = 2, V= 1948.6(7) A^3, C30H34Gd2N10O22, Dc = 2.047 g/cm^3, Mr= 1201.17, 2(MoKa) = 0.71073 A,μ = 3.477 mml, F(000) = 1176, the final R = 0.0554 and wR = 0.1181. Polymer 1 is a 2D network built up from 4-connected HPylDC2- anion and 4-connected Gd ions. Dielectric constant of complex 1 was measured at different frequencies with temperature variation.
基金supported by the National Natural Science Foundation of China(No.21571118)
文摘The title Mn(Ⅱ) coordination polymer,poly{[heptaaqua-(μ4-bi-phenyl-3,3?,5,5?-tetracarboxylate)-bimanganese(Ⅱ)] pentahydrate},[Mn_2(bpta)(H_2O)_7]_n·5n H_2O(I),is crystallized from a mixture of biphenyl-3,3?,5,5?-tetracarboxylic acid(H_4bpta) and MnCl_2·4H_2O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn(Ⅱ) cations,one fully deprotonated H4 bpta ligand,seven coordinated water molecules and five solvent water as guest molecules. In I,each Mn(Ⅱ) atom is octahedrally coordinated by six oxygen atoms from bpta^(4-) anions and coordinated water molecules. In the Mn(Ⅱ) cations,one half Mn(Ⅱ) ion of them located at a 2-fold axis generating a trinuclear [Mn_3(H_2O)_2(RCOO)_2] linker by μ1,1-O(water) and μ1,3-O,O?(carboxylate) bridges and another half Mn(Ⅱ) ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn(Ⅱ) cations are linked together by biphenyl-3,3?,5,5?-tetracarboxylates to form a three-dimensional framework with a(42.84) topology of a(4,4)-connected net,in which the positions of the trinuclear [Mn_3(H_2O)_2(R-COO)_2] linker as a 4-connector linking four bpta^(4-) ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1 ?~3,amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.
基金supported by the National Natural Science Foundation of China (No.52374124)National Youth Science Foundation of China (No.52204135)+3 种基金Xing Liao Talent Plan (No.XLYC2202004)Young Elite Scientists Sponsorship Program by CAST (No.2023QNRC001)Liaoning Province International Science and Technology Cooperation Plan (No.2022JH2/1070004)Liaoning Natural Science Foundation Program (No.2022-BS-327)。
文摘The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.
文摘If a geocentric 3D coordinate system is adopted in China to replace 2D non-geocentric coordinate system, the coordinates of the surface points will be changed accordingly. The influences on the current maps of China, especially the topographic maps, are discussed due to the replacement of the coordinate systems. Taking the replacement of Xi’an 80 coordinate system by GRS80 for a numerical example, this paper analyzes the changes of latitude, longitude, Gauss plane coordinates of the surface points, as well as the orientation and the length changes between the points on the map, including the changes of map border lines and sheet corner points.
基金Supported by the National Natural Science Foundation of China(Nos.21171037&21103021)the Natural Science Foundation of Fujian Province(No.2008I0013&No.2012J0142)
文摘A new compound, {[Sm^2L3(H2O)4]·(4,4'-bpy)·3H2O}n(1, H2 L = 5-(3-pyridyl methoxy) isophthalic acid, 4,4'-bpy = 4,4A-dipyridyl), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 11.266(2), b = 15.530(3), c = 16.711(3) A, α = 112.803(3), β = 90.526(1), γ = 94.006(3)°, V = 2686.6(9) A3, Z = 2, Dc = 1.727 g/cm^3, μ = 2.251 mm-1, F(000) = 1392, S = 0.999, the final R = 0.0296 and wR = 0.1058. In the title compound, two crystallographically independent Sm^3+ cations are bridged by the carboxyl group of L2- ligands to form two different {Sm^2} binuclear subunits which are further connected by two distinct L2- ligands to shape a 1D chain, and such 1D chains are linked up to generate a 2D coordination polymer by another crystallographically unique L2- ligand. The thermogravimetric analysis and luminescent property of the title compound were also investigated.
文摘Rehabilitation devices help to recover the physical abilities of patients. This study aims to develop a portable rehabilitation device that is safe to use when?patients are holding it by hands. In a previous study, to realize a home rehabilitation device, a flexible spherical actuator that can provide motion to patients was developed. In this study, to measure the relative position between both handling stages, a 3D coordinate measuring device using three wire-type linear potentiometers and an embedded controller was proposed and tested. In this paper, the spherical actuator with built-in 3D coordinate measuring device is described. The measuring method and experimental results obtained are also presented. The tracking position control of the actuator using the measuring device was carried out. As a result, the position of the handling stages can be successfully controlled using the feedback signal from the tested?measuring device.
基金supported in part by the Natural Science Basic Research Plan in Shaanxi Province(No.2015JQ6221,No. 2015JQ6259,No.2015JM6341)the Fundamental Research Funds for the Central Universities(No.JB140109)+8 种基金the National Natural Science Foundation of China(No. 61401321,No.61372067)the National Hightech R&D Program of China(No. 2014AA01A704,No.2015AA7124058)the National Basic Research Program of China(No.2014CB340206)the National Key Technology R&D Program of China(No. 2012BAH16B00)the Next Generation Internet Program of China(No.CNGI1203003)the Research Culture Funds of Xi'an University of Science and Technology(No.201357)the Open Project of State Key Laboratory of Integrated Service Networks(No.ISN1601)the Open Research Fund of National Mobile Communications Research Laboratory (No.2015D01)the Science and Technology R&D Program of Shaanxi Province(No. 2014KJXX-49)
文摘Comprehensive radiation characteristics of polarized antenna are crucial in creating practical channel coefficients for next generation wireless communication system designs.Being currently supported within3 D geometry-based stochastic channel models(GSCM),field patterns are technically obtained by chamber measurement(or by its best fitting).However,in some channel related performance analysis scenarios,design insight can be crystallized better by starting the derivations with theoretical co-polarization and cross-polarization components.Specifically,these two components are mathematically linked with field patterns through the proposed polarization projection algorithm.In this manuscript,we focus on revealing the transformation criterion of polarization states between the antenna plane and the propagation plane.In practice,it makes retrieving the field patterns by electromagnetic computation possible.Meanwhile,the impact imposed by distinct antenna orientations is geometrically illustrated and consequently incorporated into the proposed algorithm.This will further facilitate flexible performance evaluation of related radio transmission technologies.Our conclusions are verified by the closed-form expression of the dipole field pattern(via an analytical approach) and by chamber measurement results.Moreover,we find that its 2D degenerative case is aligned with the definitions in 3^(rd) generation partnership project(3GPP)technical report 25.996.The most obvious benefit of the proposed algorithm is to significantly reduce the cost on generating channel coefficients in GSCM simulation.
基金supported by the NSF of Hubei Province(No.2014CFB277)the Open Foundation of Ministry of Education Key Laboratory of Synthetic and Natural Functional Molecular Chemistry(No.338080057)
文摘A new 3D Ag(I) coordination polymer {[Ag(AZDB)(0.5)(bpe)(0.5)]·H2O}n(1) has been papared by azobenzene-3,3?-dicarboxylicate(H2AZDB), 1,2-bis(4-pyridyl)ethylene(bpe) and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum(IR), powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal(4, 6)-connected fsc net with a(4^4·6^10·8)(4^4·6^2) topology.Moreover, the photoluminescent properties have also been discussed.
基金Ministry of Science and Technology of China(973 Project Nos.2021YFA1200600 and 2018YFA0209100)National Natural Science Foundation of China(Nos.52231007,51725101,11727807)。
文摘The construction of one-dimensional(1D)sulfides has attracted extensive attention for improving mi-crowave absorption(MA)performance owing to the anisotropic conductive networks.However,the syn-thesis of conductive 1D hierarchical materials with unique interfacial polarization and excellent MA prop-erties remains challenging.In this study,cable-like MoS_(2)/Ni_(3)S_(2) was synthesized by a one-step hydrother-mal strategy.The complex permittivity of the binary composites could be improved by tuning the thick-ness of the MoS_(2) coating.Importantly,the construction of heterogeneous contacts by MoS_(2) and Ni_(3)S_(2) contributed to enhanced polarization loss,and the charge distribution was validated by electron holog-raphy.The wide efficient absorption bandwidth can reach above 4.8 GHz at a thin thickness.These new discoveries shed light on novel structures for 1D sulfide materials and the design of functional core-shell composites for microwave absorption.