Coupling reaction of 4-chloro-7-H-pyrrolo[2,3-d]pyrimidine with 2,3,5-tri-O-acetyl -β-D-ribofuranosyl chloride under the basic condition was investigated. An abnormal coupling reaction, in which the heterocyclic base...Coupling reaction of 4-chloro-7-H-pyrrolo[2,3-d]pyrimidine with 2,3,5-tri-O-acetyl -β-D-ribofuranosyl chloride under the basic condition was investigated. An abnormal coupling reaction, in which the heterocyclic base attacked at the carbon of 1,2-O-methylidene moiety instead of anomeric carbon of ribose was observed and the structure of products 5a, 5b were identified by NMR and X-Ray diffraction.展开更多
The time-domain BEM was developed to analyze the dynamic stress intensity factor ( DSIF) of 3-D elastodynamic crack problems. To simulate the stress singularity along the front of a crack, eight-node isoparametric sin...The time-domain BEM was developed to analyze the dynamic stress intensity factor ( DSIF) of 3-D elastodynamic crack problems. To simulate the stress singularity along the front of a crack, eight-node isoparametric singular elements were used, and the DSIF for a semi-circular surface crack was firstly calculated based on displacement equation using the time-domain BEM formulation. The new scheme to determine the time step was brought forward. By the dynamic analysis program of time-domain BEM compiled by its, several numerical examples are presented, which demonstrate the unconditional stability and high accuracy of time-domain BEM applied to 3-D elastodynamic crack problems.展开更多
Examines a nonoverlapping domain decomposition method based on the natural boundary reduction. Development of the D-N alternating algorithm; Studies the convergence of the D-N method for exterior spherical domain; Dis...Examines a nonoverlapping domain decomposition method based on the natural boundary reduction. Development of the D-N alternating algorithm; Studies the convergence of the D-N method for exterior spherical domain; Discussion of the discrete form of the D-N alternating algorithm.展开更多
The development of two boundary element algorithms for solving 3-D, frictional, and linear elastostatic contact problems is reported in this paper. The algorithms employ nonconforming discreti- zations for solving 3...The development of two boundary element algorithms for solving 3-D, frictional, and linear elastostatic contact problems is reported in this paper. The algorithms employ nonconforming discreti- zations for solving 3-D boundary element models, which provide much needed flexibility in the bound- ary element modeling for 3-D contact problems. These algorithms are implemented in a new 3-D boundary element code and verified using several examples. For the numerical examples studied, the results using the new boundary element algorithms match very well with the results using a commercial finite element code, and clearly demonstrate the feasibility of the new boundary element approach for 3-D contact analysis.展开更多
A new approach for three dimensional (3-D) shape measurement was proposed based on colorcoded fringe and neural networks. By applying the phase-shift technique to fringe projection, point clouds were generated with hi...A new approach for three dimensional (3-D) shape measurement was proposed based on colorcoded fringe and neural networks. By applying the phase-shift technique to fringe projection, point clouds were generated with high spatial resolution and limited accuracy. The picture element correspondence problem was solved by using projected color-coded fringes with different orientations. Once the high accurate corresponding points were decided, high precision dense 3-D points cloud was calculated by the well trained net. High spatial resolution can be obtained by the phase-shift technique and high accuracy 3-D object point coordinates are achieved by the well trained net, which is not dependent on the camera model and will work for any type of camera. Some experiments verify the performance of this method.展开更多
基金This work was supported by the National Natural Science Foundation of China.
文摘Coupling reaction of 4-chloro-7-H-pyrrolo[2,3-d]pyrimidine with 2,3,5-tri-O-acetyl -β-D-ribofuranosyl chloride under the basic condition was investigated. An abnormal coupling reaction, in which the heterocyclic base attacked at the carbon of 1,2-O-methylidene moiety instead of anomeric carbon of ribose was observed and the structure of products 5a, 5b were identified by NMR and X-Ray diffraction.
文摘The time-domain BEM was developed to analyze the dynamic stress intensity factor ( DSIF) of 3-D elastodynamic crack problems. To simulate the stress singularity along the front of a crack, eight-node isoparametric singular elements were used, and the DSIF for a semi-circular surface crack was firstly calculated based on displacement equation using the time-domain BEM formulation. The new scheme to determine the time step was brought forward. By the dynamic analysis program of time-domain BEM compiled by its, several numerical examples are presented, which demonstrate the unconditional stability and high accuracy of time-domain BEM applied to 3-D elastodynamic crack problems.
基金The. Project supported by the Special Funds for State Major Basic Research Projects, the Chinese NationalKey Project for Basic
文摘Examines a nonoverlapping domain decomposition method based on the natural boundary reduction. Development of the D-N alternating algorithm; Studies the convergence of the D-N method for exterior spherical domain; Discussion of the discrete form of the D-N alternating algorithm.
文摘The development of two boundary element algorithms for solving 3-D, frictional, and linear elastostatic contact problems is reported in this paper. The algorithms employ nonconforming discreti- zations for solving 3-D boundary element models, which provide much needed flexibility in the bound- ary element modeling for 3-D contact problems. These algorithms are implemented in a new 3-D boundary element code and verified using several examples. For the numerical examples studied, the results using the new boundary element algorithms match very well with the results using a commercial finite element code, and clearly demonstrate the feasibility of the new boundary element approach for 3-D contact analysis.
基金Supported by the Eleventh Five-Year Pre-Research Project of China
文摘A new approach for three dimensional (3-D) shape measurement was proposed based on colorcoded fringe and neural networks. By applying the phase-shift technique to fringe projection, point clouds were generated with high spatial resolution and limited accuracy. The picture element correspondence problem was solved by using projected color-coded fringes with different orientations. Once the high accurate corresponding points were decided, high precision dense 3-D points cloud was calculated by the well trained net. High spatial resolution can be obtained by the phase-shift technique and high accuracy 3-D object point coordinates are achieved by the well trained net, which is not dependent on the camera model and will work for any type of camera. Some experiments verify the performance of this method.
