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A 3D shell-like approach using element-free Galerkin method for analysis of thin and thick plate structures 被引量:6
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作者 Yu Yin Lin-Quan Yao Yang Cao 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2013年第1期85-98,共14页
A new efficient meshless method based on the element-free Galerkin method is proposed to analyze the static deformation of thin and thick plate structures in this paper. Using the new 3D shell-like kinematics in analo... A new efficient meshless method based on the element-free Galerkin method is proposed to analyze the static deformation of thin and thick plate structures in this paper. Using the new 3D shell-like kinematics in analogy to the solid-shell concept of the finite element method, discretization is carried out by the nodes located on the upper and lower surfaces of the structures. The approximation of all unknown field variables is carried out by using the moving least squares (MLS) approximation scheme in the in-plane directions, while the linear interpolation is applied through the thickness direction. Thus, different boundary conditions are defined only using displacements and penalty method is used to enforce the essential boundary conditions. The constrained Galerkin weak form, which incorporates only dis- placement degrees of freedom (d.o.f.s), is derived. A modified 3D constitutive relationship is adopted in order to avoid or eliminate some self-locking effects. The numeric efficiency of the proposed meshless formulation is illustrated by the numeric examples. 展开更多
关键词 Meshless methods 3D shell-like Moving least squares approximation SELF-LOCKING Thin plate
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An adaptive finite-difference method for seismic traveltime modeling based on 3D eikonal equation
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作者 Bao-Ping Qiao Qing-Qing Li +2 位作者 Wei-Guang He Dan Zhao Qu-Bo Wu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期195-205,共11页
3D eikonal equation is a partial differential equation for the calculation of first-arrival traveltimes and has been widely applied in many scopes such as ray tracing,source localization,reflection migration,seismic m... 3D eikonal equation is a partial differential equation for the calculation of first-arrival traveltimes and has been widely applied in many scopes such as ray tracing,source localization,reflection migration,seismic monitoring and tomographic imaging.In recent years,many advanced methods have been developed to solve the 3D eikonal equation in heterogeneous media.However,there are still challenges for the stable and accurate calculation of first-arrival traveltimes in 3D strongly inhomogeneous media.In this paper,we propose an adaptive finite-difference(AFD)method to numerically solve the 3D eikonal equation.The novel method makes full use of the advantages of different local operators characterizing different seismic wave types to calculate factors and traveltimes,and then the most accurate factor and traveltime are adaptively selected for the convergent updating based on the Fermat principle.Combined with global fast sweeping describing seismic waves propagating along eight directions in 3D media,our novel method can achieve the robust calculation of first-arrival traveltimes with high precision at grid points either near source point or far away from source point even in a velocity model with large and sharp contrasts.Several numerical examples show the good performance of the AFD method,which will be beneficial to many scientific applications. 展开更多
关键词 3D eikonal equation Accurate traveltimes Global fast sweeping 3D inhomogeneous media Adaptive finite-difference method
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AHermitian C^(2) Differential Reproducing Kernel Interpolation Meshless Method for the 3D Microstructure-Dependent Static Flexural Analysis of Simply Supported and Functionally Graded Microplates
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作者 Chih-Ping Wu Ruei-Syuan Chang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第10期917-949,共33页
This work develops a Hermitian C^(2) differential reproducing kernel interpolation meshless(DRKIM)method within the consistent couple stress theory(CCST)framework to study the three-dimensional(3D)microstructuredepend... This work develops a Hermitian C^(2) differential reproducing kernel interpolation meshless(DRKIM)method within the consistent couple stress theory(CCST)framework to study the three-dimensional(3D)microstructuredependent static flexural behavior of a functionally graded(FG)microplate subjected to mechanical loads and placed under full simple supports.In the formulation,we select the transverse stress and displacement components and their first-and second-order derivatives as primary variables.Then,we set up the differential reproducing conditions(DRCs)to obtain the shape functions of the Hermitian C^(2) differential reproducing kernel(DRK)interpolant’s derivatives without using direct differentiation.The interpolant’s shape function is combined with a primitive function that possesses Kronecker delta properties and an enrichment function that constituents DRCs.As a result,the primary variables and their first-and second-order derivatives satisfy the nodal interpolation properties.Subsequently,incorporating ourHermitianC^(2)DRKinterpolant intothe strong formof the3DCCST,we develop a DRKIM method to analyze the FG microplate’s 3D microstructure-dependent static flexural behavior.The Hermitian C^(2) DRKIM method is confirmed to be accurate and fast in its convergence rate by comparing the solutions it produces with the relevant 3D solutions available in the literature.Finally,the impact of essential factors on the transverse stresses,in-plane stresses,displacements,and couple stresses that are induced in the loaded microplate is examined.These factors include the length-to-thickness ratio,the material length-scale parameter,and the inhomogeneity index,which appear to be significant. 展开更多
关键词 Consistent/modified couple stress theory differential reproducing kernel methods microplates point collocation methods static flexural 3D microstructure-dependent analysis
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无水草酸辅助硝酸铁热分解制备高饱和磁化强度γ-Fe_(2)O_(3)纳米粒子
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作者 高波 赵斯琴 长山 《应用化工》 CAS CSCD 北大核心 2024年第7期1578-1582,共5页
采用硝酸铁和无水草酸为原料,通过简便的一步固相法焙烧制备γ-Fe_(2)O_(3)纳米粒子。采用XRD、SEM-EDS、N_(2)-吸附/脱附和VSM等表征手段分析了样品的结构、形态和磁性能。研究表明,在Fe(NO_(3))_(3)·9H_(2)O中添加C_(2)H_(2)O_(... 采用硝酸铁和无水草酸为原料,通过简便的一步固相法焙烧制备γ-Fe_(2)O_(3)纳米粒子。采用XRD、SEM-EDS、N_(2)-吸附/脱附和VSM等表征手段分析了样品的结构、形态和磁性能。研究表明,在Fe(NO_(3))_(3)·9H_(2)O中添加C_(2)H_(2)O_(4),可以制备出饱和磁化强度为76.3 emu/g的棒状γ-Fe_(2)O_(3)。 展开更多
关键词 九水硝酸铁 高饱和磁化强度 棒状γ-fe_(2)O_(3) 一步固相法
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Characterization of La-doped xBiInO_3(1-x)PbTiO_3 Piezoelectric Films Deposited by the Radio-Frequency Magnetron Sputtering Method 被引量:1
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作者 孙科学 张淑仪 +1 位作者 Kiyotaka Wasa 水修基 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第6期49-52,共4页
La-doped and undoped xBiIn03-(1 - x)PbTi03 (BI-PT) thin films are deposited on (101)SrRuO3/(lOO)Pt/(lO0) MgO substrates by the rf-magnetron sputtering method. The structures of the films are characterized by... La-doped and undoped xBiIn03-(1 - x)PbTi03 (BI-PT) thin films are deposited on (101)SrRuO3/(lOO)Pt/(lO0) MgO substrates by the rf-magnetron sputtering method. The structures of the films are characterized by XRD and SEM, and the results indicate that the thin films are grown with mainly (100) oriented and columnar structures. The ferroelectricity and piezoelectricity of the BI-PT films are also measured, and the measured results illustrate that both performances are effectively improved by the La-doping with suitable concentrations. These results will open up wide potential applications of the films in electronic devices. 展开更多
关键词 of BI Characterization of La-doped xBiInO3 x)PbTiO3 Piezoelectric Films Deposited by the Radio-frequency Magnetron Sputtering method in by La PT
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Prediction of the Photofading of Selected Derivatives of 5-(4-X-Phenylazo)-3-Cyano-1-(H or Ethyl)-6-Hydroxy-4-Methyl-2-Pyridone: Theoretical Studies, Comparison of AM1 and PM3 Methods
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作者 Krzysztof Wojciechowski Lucjan Szuster 《Computational Chemistry》 CAS 2024年第2期25-56,共32页
We analysed the photooxidation reaction in the electro-(1O2) and nucleophilic (O2•−) reaction of 2-pyridone azo derivatives. First, we calculated the energy (enthalpies) of tautomers formation, which is a measure of d... We analysed the photooxidation reaction in the electro-(1O2) and nucleophilic (O2•−) reaction of 2-pyridone azo derivatives. First, we calculated the energy (enthalpies) of tautomers formation, which is a measure of durability and the probability of their formation. We performed the light fastness calculations of the monoazopyridone dyes. Using the semi-empirical methods of quantum chemistry AM1 and PM3, the reactivity indicators of superdelocalisability (SrE(N)) and the electron density distribution in ground state on the highest occupied HOMO orbital and the lowest unoccupied excited state LUMO in 2-pyridone phenylazo derivatives were calculated. Superdelocalisability coefficients enable the stability to oxidising agents of various chemical molecules depending on the tautomeric forms in which they may occur. The results of the electron density calculations at the HOMO and LUMO boundary orbitals allow to determine the tendency to electrophilic attack with singlet oxygen 1O2 or nucleophilic attack of the superoxide anion O2•−on a specific atom in the molecule. The structure of the dyes was optimised with MM+, MD and AM1 or PM3 until a constant energy value was achieved with a convergence criterion of 0.01 kcal/mol. 展开更多
关键词 Photochemical Degradation AM1 and PM3 methods Boundary Orbitals Electron Densities Electrophilic and Nucleophilic Reaction HOMO and LUMO Orbitals
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GSK3/Nrf2调控的生物节律在机体衰老中的规律
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作者 陈伊琳 蒋晓波 +1 位作者 屈红林 刘瑞莲 《中国组织工程研究》 CAS 北大核心 2025年第6期1257-1264,共8页
背景:生物节律(昼夜节律)紊乱是一个典型的与衰老有关的问题,维持生物节律的正常运作可能是一种很有前景的抗衰老策略。核转录因子NF-E2相关因子2的表达具有生物节律;糖原合成酶激酶3系统代表了一个“调节阀”,它控制核转录因子NF-E2相... 背景:生物节律(昼夜节律)紊乱是一个典型的与衰老有关的问题,维持生物节律的正常运作可能是一种很有前景的抗衰老策略。核转录因子NF-E2相关因子2的表达具有生物节律;糖原合成酶激酶3系统代表了一个“调节阀”,它控制核转录因子NF-E2相关因子2水平的细微振荡。抗氧化基因转录水平的昼夜变化可以影响生物体对氧化应激的反应,但是糖原合成酶激酶3/NF-E2相关因子2在调节机体衰老中的具体分子机制仍令人困惑。目的:拟通过对该领域文献的回顾,寻找糖原合成酶激酶3/核转录因子NF-E2相关因子2调控的生物节律在机体衰老中的一般规律。方法:文献资料法通过对有关“糖原合成酶激酶3、核转录因子NF-E2相关因子2、生物节律以及衰老”等相关文献进行检索、查阅和筛选,为全文的分析奠定理论基础。对比分析法通过对所得到文献进行阅读分析,比较文献之间的异同点,为论点提供合理的理论支撑。通过对文献的进一步对比分析,理清相关指标间的关系,为全文的分析明确思路。结果与结论:①糖原合成酶激酶3可通过对节律基因的调节间接调控核转录因子NF-E2相关因子2的表达;②糖原合成酶激酶3和核转录因子NF-E2相关因子2是抗衰老程序的组成部分,且与生物节律相关;③并且糖原合成酶激酶3/核转录因子NF-E2相关因子2参与多种代谢途径,包括与衰老相关疾病(2型糖尿病和癌症)和神经退行性疾病相关的代谢途径。 展开更多
关键词 糖原合成酶激酶3 核转录因子NF-E2相关因子2 生物节律 衰老 神经退行性疾病
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Optimization of geometric parameters of reinforced sheets based on a cell-based smoothed discrete shear gap(CS-FEM-DSG3) method
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作者 Mehrdad Sarafrazi Armen Adamian 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第8期2024-2035,共12页
Optimization of design features of reinforced sheet is investigated. Initially, equations governing composite structures are extracted based on Kirchhoff sheet model under bending using Hamilton's principal. Then,... Optimization of design features of reinforced sheet is investigated. Initially, equations governing composite structures are extracted based on Kirchhoff sheet model under bending using Hamilton's principal. Then, design parameters for the composite structure are extracted with simple supportive boundary conditions from proposed solution. Next, optimization is achieved by determining dimensions of a reinforced sheet specimen. Weight optimization of reinforced sheet structure has been obtained based on variations in thickness and number of longitudinal and transverse reinforcements. Buckling static characteristic is utilized in optimization process. To solve the extracted equations, semi-analytical method of CS-DSG3 has been applied. Results are presented in graphs that show variation of design parameters by changing the geometric parameters. ABAQUS software has been used for design verification. The results show that an increase in thickness of 3 mm skip value tends to be zero. Also, there is a change in the amount of deflection for sheets with a minimum thickness of 3 mm by increasing the number of longitudinal and transverse reinforcement. There is a good agreement between the numerical method of finite elements and the method X-FEM-DSG3. 展开更多
关键词 OPTIMIZATION reinforced sheet design CS-fEM-DSG3 method
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Determination of the full-field stress and displacement using photoelasticity and sampling moirémethod in a 3D-printed model
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作者 Zhangyu Ren Qi Zhang +1 位作者 Yang Ju Huimin Xie 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2022年第6期409-418,共10页
The quantitative characterization of the full-field stress and displacement is significant for analyzing the failure and instability of engineering materials.Various optical measurement techniques such as photoelastic... The quantitative characterization of the full-field stress and displacement is significant for analyzing the failure and instability of engineering materials.Various optical measurement techniques such as photoelasticity,moiréand digital image correlation methods have been developed to achieve this goal.However,these methods are difficult to incorporate to determine the stress and displacement fields simultaneously because the tested models must contain particles and grating for displacement measurement;however,these elements will disturb the light passing through the tested models using photoelasticity.In this study,by combining photoelasticity and the sampling moirémethod,we developed a method to determine the stress and displacement fields simultaneously in a three-dimensional(3D)-printed photoelastic model with orthogonal grating.Then,the full-field stress was determined by analyzing 10 photoelastic patterns,and the displacement fields were calculated using the sampling moirémethod.The results indicate that the developed method can simultaneously determine the stress and displacement fields. 展开更多
关键词 Stress fields Displacement fields PHOTOELASTICITY Sampling moirémethod 3D printing technique
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An Eco-friendly Method for Novel Scaffolds: Novel N2-Substituted Fused Pyrazolo (4',3':5,6) Pyrano (2,3-d) Pyrimidine Terminated by Hydroxy Group
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作者 Omar K. AI-Duaij 《Journal of Chemistry and Chemical Engineering》 2013年第9期821-828,共8页
Four components have been reacted in water and in the presence of N-morpholine yielded pyrnopyrazole as a simple substrate for novel N2-acyclonucleoside derivatives of fused pyranopyrazole. The sodium salt of fused py... Four components have been reacted in water and in the presence of N-morpholine yielded pyrnopyrazole as a simple substrate for novel N2-acyclonucleoside derivatives of fused pyranopyrazole. The sodium salt of fused pyranopyrazole reacted with halo alcohols led to the formation of new scaffolds from fused pyranopyrazole derivatives. All newly prepared compounds are characterized spectroscopically. 展开更多
关键词 Multi-component reactions eco-friendly method pyrazolo [2 3-c] pyran halo-alcohols acyclonucleosidation.
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Thermal stability and electrical transport properties of Ge/Sn-codoped single crystalline β-Zn4Sb3 prepared by the Sn-flux method
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作者 Hong-xia Liu Shu-ping Deng +2 位作者 De-cong Li Lan-xian Shen Shu-kang Deng 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第2期441-445,共5页
This study prepares a group of single crystalline β-Zn_4Sb_3 with Ge and Sn codoped by the Sn-flux method according to the nominal stoichiometric ratios of Zn_(4.4)Sb_3 Ge_xSn_3(x = 0–0.15). The prepared samples... This study prepares a group of single crystalline β-Zn_4Sb_3 with Ge and Sn codoped by the Sn-flux method according to the nominal stoichiometric ratios of Zn_(4.4)Sb_3 Ge_xSn_3(x = 0–0.15). The prepared samples possess a metallic luster surface with perfect appearance and large crystal sizes. The microscopic cracks or defects are invisible in the samples from the back-scattered electron image. Except for the heavily Ge-doped sample of x = 0.15, all the samples are single phase with space group R3c. The thermal analysis results show that the samples doped with Ge exhibit an excellent thermal stability.Compared with the polycrystalline Ge-substituted β-Zn_4Sb_3, the present single crystals have higher carrier mobility, and hence the electrical conductivity is improved, which reaches 7.48×10~4S·m^(-1) at room temperature for the x = 0.1 sample.The change of Ge and Sn contents does not improve the Seebeck coefficient significantly. Benefiting from the increased electrical conductivity, the sample with x = 0.075 gets the highest power factor of 1.45×10^(-3)W·m^(-1)·K^(-2) at 543 K. 展开更多
关键词 thermoelectric materials β-Zn4Sb3 flux method electrical transport properties
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KF-Al_2O_3催化下二-γ-吡喃并[2,3-a;2',3'-f]萘衍生物的合成 被引量:7
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作者 周杰兴 王香善 +3 位作者 曾兆森 张梅梅 史达清 屠树江 《有机化学》 SCIE CAS CSCD 北大核心 2007年第6期786-789,共4页
以芳醛、氰乙酸酯和1,5-萘二酚为原料,以乙醇为溶剂,在80℃以KF/Al2O3为催化剂合成了一系列的2,8-二氨基-4,10-二芳基-4H,10H-二-γ-吡喃并[2,3-a;2',3'-f]萘-3,9-二羧酸酯衍生物,该反应具有反应条件温和、产率良好、操作方便... 以芳醛、氰乙酸酯和1,5-萘二酚为原料,以乙醇为溶剂,在80℃以KF/Al2O3为催化剂合成了一系列的2,8-二氨基-4,10-二芳基-4H,10H-二-γ-吡喃并[2,3-a;2',3'-f]萘-3,9-二羧酸酯衍生物,该反应具有反应条件温和、产率良好、操作方便等优点.产物的结构通过IR,1HNMR和元素分析表征,并进一步通过X射线衍射分析确证4h的结构. 展开更多
关键词 二-γ-吡喃并[2 3-a 2’ 3-f]萘 KF-AL2O3 合成
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Joint 3D traveltime calculation based on fast marching method and wavefront construction 被引量:5
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作者 孙辉 孙建国 +5 位作者 孙章庆 韩复兴 刘明忱 刘志强 高正辉 石秀林 《Applied Geophysics》 SCIE CSCD 2017年第1期56-63,189,共9页
3D traveltime calculation is widely used in seismic exploration technologies such as seismic migration and tomography. The fast marching method (FMM) is useful for calculating 3D traveltime and has proven to be effi... 3D traveltime calculation is widely used in seismic exploration technologies such as seismic migration and tomography. The fast marching method (FMM) is useful for calculating 3D traveltime and has proven to be efficient and stable. However, it has low calculation accuracy near the source, which thus gives it low overall accuracy. This paper proposes a joint traveltime calculation method to solve this problem. The method firstly employs the wavefront construction method (WFC), which has a higher calculation accuracy than FMM in calculating traveltime in the small area near the source, and secondly adopts FMM to calculate traveltime for the remaining grid nodes. Due to the increase in calculation precision of grid nodes near the source, this new algorithm is shown to have good calculation precision while maintaining the high calculation efficiency of FMM, which is employed in most of the computational area. Results are verified using various numerical models. 展开更多
关键词 Seismic wave propagation 3D traveltime computation fast marching method wavefront construction method
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7-氨基三呋咱并[3,4-b:3′,4′-f:3″,4″-d]氮杂环庚烯的合成、晶体结构及热行为 被引量:3
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作者 张海昊 贾思媛 +3 位作者 王伯周 来蔚鹏 周诚 周彦水 《火炸药学报》 EI CAS CSCD 北大核心 2014年第4期19-24,共6页
以3,4-双(3′-氨基呋咱-4′-基)呋咱为原料,经氧化和环化2步反应合成了7-氨基三呋咱并[3,4-b:3′,4′-f:3″,4″-d]氮杂环庚烯(ATFAZ),收率66%;用红外光谱、核磁共振、元素分析和质谱对其结构进行了表征,用 DSC和 TG-DTG... 以3,4-双(3′-氨基呋咱-4′-基)呋咱为原料,经氧化和环化2步反应合成了7-氨基三呋咱并[3,4-b:3′,4′-f:3″,4″-d]氮杂环庚烯(ATFAZ),收率66%;用红外光谱、核磁共振、元素分析和质谱对其结构进行了表征,用 DSC和 TG-DTG 研究了 ATFAZ 的热分解过程;培养了 ATFAZ 单晶,用 X-射线单晶衍射对晶体结构进行分析。结果表明,ATFAZ 晶体属正交晶系,空间群为 Pbca,a =1.273 nm,b =0.876(3)nm,c =1.560(6)nm,V =1.740(11) nm3,Z =8,Dc =1.788 g&#183;cm-3,μ=0.141 mm-1,F(000)=944,R 1=0.0338,wR 2=0.0976。在10℃/min 的升温条件下,其熔点为204~207℃,在210~282℃具有明显的挥发现象。 展开更多
关键词 有机化学 7-氨基三呋咱并[3 4-b 3 4′-f 3 4″-d]氮杂环庚烯 ATFAZ 晶体结构 热行为
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双呋咱并[3,4-b:3′,4′-f]氧化呋咱并[3′′,4′′-d]氧杂环庚三烯的合成 被引量:7
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作者 周彦水 王伯周 +4 位作者 王锡杰 周诚 霍欢 张叶高 刘鹏 《含能材料》 EI CAS CSCD 北大核心 2012年第1期137-138,共2页
1 引言含有呋咱或氧化呋咱含能结构单元分子中引入醚键,可增加其柔韧性。该类化合物具有能量密度高、标准生成焓大、氮含量较高、熔点低以及塑性强等特点,可以作为熔铸炸药液相载体,
关键词 有机化学 双呋咱并[3 4-b′ 4′-f]氧化呋咱并[3′′ 4′′-d]氧杂环庚三烯 合成 性能
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CaO-Al_2O_3-SiO_2-F系统玻璃密度与结构关系研究 被引量:2
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作者 孟政 刘树江 +1 位作者 沈建兴 高彬 《陶瓷学报》 CAS 北大核心 2010年第1期82-86,共5页
采用传统熔融冷却法制备了CaO-Al2O3-SiO2-AlF3(A系列)和CaO-Al2O3-SiO2-CaF2(C系列)系统玻璃,在其组成范围SiO2>45mol%、Ca/Al>1(mol)、F/Al<1(mol)内,利用Doweidar密度模型在CaO-Al2O3-SiO2-F系统玻璃A系列和C系列中分别得到... 采用传统熔融冷却法制备了CaO-Al2O3-SiO2-AlF3(A系列)和CaO-Al2O3-SiO2-CaF2(C系列)系统玻璃,在其组成范围SiO2>45mol%、Ca/Al>1(mol)、F/Al<1(mol)内,利用Doweidar密度模型在CaO-Al2O3-SiO2-F系统玻璃A系列和C系列中分别得到AlO3F四面体的体积,其值可认为是一常数VAl-f=57.82×10-24cm-3,与引入氟的形式(CaF2或AlF3)和化学计量浓度的改变无关;AlO4四面体的体积大于AlO3F四面体体积(VAl-f>VAl-o),分析认为这与质点间的键力发生改变有关(fAl-f<fAl-0),键力越小,质点间的距离越大,使VAl-f变大。由此模型得到的CaO-Al2O3-SiO2-F玻璃理论计算密度值与实际测量密度值基本相符,误差小于0.03%。 展开更多
关键词 CaO—Al2O3-SiO2-f系统玻璃 密度 结构
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CaO-Al_2O_3-SiO_2-F玻璃的红外光谱和热膨胀行为 被引量:5
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作者 孟政 刘树江 +1 位作者 沈建兴 高彬 《玻璃与搪瓷》 CAS 2010年第1期14-18,共5页
采用传统熔融冷却法制备了CaO-Al2O3-SiO2-AlF3(A系列)和CaO-Al2O3-SiO2-CaF2(C系列)系统玻璃。利用傅立叶红外光谱(FTIR)研究了氟对玻璃结构的影响,使用最小二乘曲线拟合法对第1谱带分峰拟合,并对次强谱带的弯曲振动分类,分析了各组振... 采用传统熔融冷却法制备了CaO-Al2O3-SiO2-AlF3(A系列)和CaO-Al2O3-SiO2-CaF2(C系列)系统玻璃。利用傅立叶红外光谱(FTIR)研究了氟对玻璃结构的影响,使用最小二乘曲线拟合法对第1谱带分峰拟合,并对次强谱带的弯曲振动分类,分析了各组振动与氟的关系。另外通过玻璃的热膨胀行为分析了氟对玻璃软化温度和热膨胀系数的影响。结果表明,氟在A系列和C系列中玻璃的结构变化不大,氟主要与铝生成Al-F键作为网络形成体存在,氟含量最大的A4中生成[AlO3F]四面体和[AlO2F2]四面体;氟含量增加,A系列和C系列的软化温度(Tf)都会降低,而热膨胀系数变化不大。 展开更多
关键词 CaO—Al2O3-SiO2-f玻璃 红外光谱 热膨胀
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La^(3+)-Fe^(3+)共掺杂纳米TiO_2粉体的光催化性能 被引量:7
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作者 徐晓虹 田越 +2 位作者 吴建锋 刘妍伶 赵娜 《武汉理工大学学报》 EI CAS CSCD 北大核心 2008年第6期1-5,共5页
采用溶胶-凝胶法制备了La3+-Fe3+共掺杂的TiO2纳米粉体,并以亚甲基蓝溶液为目标降解物研究了掺杂纳米TiO2粉体在紫外光作用下的光吸收和光催化性能。通过XRD和TEM等测试技术对样品的晶型、形貌和粒径尺寸进行了表征。结果表明,La3+-Fe3... 采用溶胶-凝胶法制备了La3+-Fe3+共掺杂的TiO2纳米粉体,并以亚甲基蓝溶液为目标降解物研究了掺杂纳米TiO2粉体在紫外光作用下的光吸收和光催化性能。通过XRD和TEM等测试技术对样品的晶型、形貌和粒径尺寸进行了表征。结果表明,La3+-Fe3+共掺杂制备的TiO2粉体最佳热处理温度为550℃,结晶完整、主晶相为锐钛矿型,平均粒径约为20 nm;掺杂使TiO2吸收带发生红移,光催化性能增强;共掺杂体系的最佳量为n(La3+)∶n(TiO2)=0.05%,n(Fe3+)∶n(TiO2)=0.5%。共掺杂的TiO2粉体对亚甲基蓝有良好的降解效果,反应2 h降解率达到98.72%,优于同等条件下制备的未掺杂的纯TiO2粉体。复合掺杂光催化剂对亚甲基蓝的降解遵循一级动力学方程。 展开更多
关键词 La^3+-fe^3+共掺杂 纳米TIO2粉体 溶胶-凝胶法 光催化性
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溶胶—凝胶法制备的硅掺杂α-Fe_2O_3-K_2O多孔陶瓷的湿敏性能 被引量:1
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作者 莫茂松 敖自华 +4 位作者 阙立志 王银海 赵泳 张天舒 王弘 《无锡轻工大学学报(食品与生物技术)》 CSCD 2000年第2期160-163,共4页
采用溶胶 凝胶工艺在α Fe2 O3 K2 O复合体系中掺入SiO2 .XRD、BET比表面吸附、Archimede排水法等对α Fe2 O3 K2 O SiO2 陶瓷表征结果表明 ,适量掺杂SiO2 ,材料仍以刚玉结构的α Fe2 O3为主晶相 ,但抑制了主晶相晶粒粗化 ,增大了材料... 采用溶胶 凝胶工艺在α Fe2 O3 K2 O复合体系中掺入SiO2 .XRD、BET比表面吸附、Archimede排水法等对α Fe2 O3 K2 O SiO2 陶瓷表征结果表明 ,适量掺杂SiO2 ,材料仍以刚玉结构的α Fe2 O3为主晶相 ,但抑制了主晶相晶粒粗化 ,增大了材料比表面积及孔隙率 .湿敏性能测试发现 ,掺杂摩尔分数 6%的SiO2 ,可获得全湿区范围内阻—湿特性曲线线性关系良好、灵敏度适中、湿滞小、稳定性较高的新型湿敏材料 .其中 ,K+被吸收分散在主晶相晶界硅玻璃相中是改善材料湿滞效应及性能稳定性的主要原因 . 展开更多
关键词 溶胶凝胶 掺杂 α-f3O2 陶瓷 SIO2 湿敏材料
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均匀准方形α-Fe_2O_3颗粒的制备 被引量:3
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作者 李冬妹 李明辉 +3 位作者 王卉 曲胜春 贺强 刘旭东 《吉林大学自然科学学报》 CAS CSCD 1999年第3期57-59,共3页
用改进的凝胶溶胶法在 100 ℃时陈化高浓度的 Fe( O H)3 凝胶制备窄粒度分布的准方形 α Fe2 O3 颗粒, 并探讨成核过程及 α Fe2 O3 的形成机制. 结果表明, 以 Fe Cl3 溶液添加到 Na O H 溶液... 用改进的凝胶溶胶法在 100 ℃时陈化高浓度的 Fe( O H)3 凝胶制备窄粒度分布的准方形 α Fe2 O3 颗粒, 并探讨成核过程及 α Fe2 O3 的形成机制. 结果表明, 以 Fe Cl3 溶液添加到 Na O H 溶液中的反向添加法, 在碱性条件下制备 Fe( O H)3 凝胶, 可提高 α Fe2 O3 的成核率。 展开更多
关键词 凝胶-溶胶法 超微颗粒 三氧化二铁 制备 准方形
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