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Rainfall-triggered waste dump instability analysis based on surface 3D deformation in physical model test
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作者 LI Hanlin JIN Xiaoguang +2 位作者 HE Jie XUE Yunchuan YANG Zhongping 《Journal of Mountain Science》 SCIE CSCD 2024年第5期1549-1563,共15页
Landslide is the second largest natural disaster after earthquake. It is of significance to study the evolution laws and failure mechanism of landslides based on its surface 3D deformation information. Based on the ra... Landslide is the second largest natural disaster after earthquake. It is of significance to study the evolution laws and failure mechanism of landslides based on its surface 3D deformation information. Based on the rainfall-triggered waste dump instability model test, we studied the failure mechanisms of the waste dump by integrating surface deformation and internal slope stress and proposed novel parameters for identifying landslide stability. We developed a noncontact measurement device, which can obtain millimeter-level 3D deformation data for surface scene in physical model test;Then we developed the similar materials and established a test model for a waste dump. Based on the failure characteristics of slope surface, internal stress of slope body and displacement contours during the whole process, we divided the slope instability process in model test into four stages: rainfall infiltration and surface erosion, shallow sliding, deep sliding, and overall instability. Based on the obtained surface deformation data, we calculated the volume change during slope instability process and compared it with the point displacement on slope surface. The results showed that the volume change can not only reflect the slow-ultra acceleration process of slope failure, but also fully reflect the above four stages and reduce the fluctuations caused by random factors. Finally, this paper proposed two stability identification parameters: the volume change rate above the slip surface and the relative velocity of volume change rate. According to the calculation of these two parameters in model test, they can be used for study the deformation and failure mechanism of slope stability. 展开更多
关键词 Waste dump stability Physical model test Surface 3D deformation stability identification
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矢车菊-3-葡萄糖苷提取纯化、生物活性及稳态化技术的研究进展
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作者 高琦 孙铭阳 +3 位作者 袁兴铃 彭雪 王宁 薛友林 《现代食品科技》 CAS 北大核心 2024年第6期318-326,共9页
矢车菊-3-葡萄糖苷(Cyanidin-3-glucoside,C3G)是自然界中分布最为广泛的一种花青素,富含于水果、蔬菜和谷物中,具有抗氧化、抗癌、抗炎以及维持视觉健康等生理功能,在食品、医药等行业备受关注。提取纯化是利用C3G的重要步骤,但C3G在... 矢车菊-3-葡萄糖苷(Cyanidin-3-glucoside,C3G)是自然界中分布最为广泛的一种花青素,富含于水果、蔬菜和谷物中,具有抗氧化、抗癌、抗炎以及维持视觉健康等生理功能,在食品、医药等行业备受关注。提取纯化是利用C3G的重要步骤,但C3G在储存、加工过程中易受外界环境的影响而失去原有的颜色和生理价值。为促进C3G在食品领域的应用,该文汇总了C3G在不同食物中的含量及常见的提取纯化方法,概述了C3G抗氧化、抗癌、抗炎以及维持视觉健康等生物活性,并从生物大分子复合和分子修饰两个方面介绍了C3G的稳态化方法,为未来研究和综合开发利用C3G提供理论依据。 展开更多
关键词 矢车菊-3-葡萄糖苷 提取 纯化 生理功能 稳定性保持
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高温高压下UH_(3)结构稳定性及其冲击分解
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作者 王玉锋 郝龙 +2 位作者 吴凤超 耿华运 李俊 《高压物理学报》 CAS CSCD 北大核心 2024年第3期80-89,共10页
利用统计物理模型构建了UH_(3)晶体及其化学分解产物的状态方程,通过比较Gibbs自由能获得了UH_(3)的高温高压相图,并将其应用于疏松和密实UH_(3)冲击压缩性质研究中。结果表明:等温压缩下,UH_(3)晶体在压力约74.0 GPa时发生化学分解,提... 利用统计物理模型构建了UH_(3)晶体及其化学分解产物的状态方程,通过比较Gibbs自由能获得了UH_(3)的高温高压相图,并将其应用于疏松和密实UH_(3)冲击压缩性质研究中。结果表明:等温压缩下,UH_(3)晶体在压力约74.0 GPa时发生化学分解,提高温度有助于化学分解的发生,但压力对UH_(3)化学分解相边界的影响是非单调的;冲击加载下,密实UH_(3)在35~50 GPa压力范围内发生化学分解,并且由于冲击分解伴随着明显的体积塌缩,分解产物的雨贡纽曲线位于等温压缩线下方,曲线位置关系反常;UH_(3)的冲击分解压力随着疏松度的增大而减小,当UH_(3)材料的初始疏松度为1.5时,在化学分解转变压力范围内,UH_(3)的分解产物比UH_(3)晶体更难压缩,表现出类似大疏松度材料在冲击作用下的“反常膨胀”现象。研究结果丰富了对UH_(3)材料动态压缩特性的认识,为锕系金属氢化物的高温高压物理化学性质研究提供了理论参考。 展开更多
关键词 UH_(3) 氢化物 状态方程 高温高压 结构稳定性 化学分解
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Fe_(3)O_(4)@CuMOF催化文冠果油制备生物柴油的研究
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作者 郝一男 王任飞 +5 位作者 张国 王晶文 任志远 沈洪霞 王德刚 姚利宏 《林产工业》 北大核心 2024年第7期28-34,共7页
金属有机框架(MOFs)材料的高表面积、结构稳定性和可调功能使其成为制备生物柴油的理想催化剂。本文通过溶剂热法制备磁性Fe_(3)O_(4)@Cu MOF催化剂,利用傅里叶红外变换光谱(FTIR)、扫描电镜(SEM)、能谱分析(EDS)、X射线衍射(XRD)、N2... 金属有机框架(MOFs)材料的高表面积、结构稳定性和可调功能使其成为制备生物柴油的理想催化剂。本文通过溶剂热法制备磁性Fe_(3)O_(4)@Cu MOF催化剂,利用傅里叶红外变换光谱(FTIR)、扫描电镜(SEM)、能谱分析(EDS)、X射线衍射(XRD)、N2吸脱附(BET)、热重分析(TG)等手段对催化剂的微观结构和热稳定性进行表征,并应用于文冠果油制备生物柴油的反应中。结果表明:Fe_(3)O_(4)@Cu MOF催化剂表面粗糙多孔,比表面积为206.239 m^(2)/g,平均孔径为6.64 nm,属于介孔材料。Fe_(3)O_(4)@Cu MOF的饱和磁化强度为12.6 emu/g,易分离回收。当催化剂用量为3 wt%、醇油摩尔比为20∶1、反应温度为60℃、反应时间为2 h时,生物柴油产率最高,为75.0%。Fe_(3)O_(4)@Cu MOF循环使用5次后,其催化生物柴油的产率仍能达到69.25%。 展开更多
关键词 Fe_(3)O_(4)@Cu MOF催化剂 生物柴油 文冠果油 稳定性 产率
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基于悬浮液等离子喷涂的Ba(Mg_(1/3)Ta_(2/3))O_(3)悬浮液制备及涂层组织结构 被引量:1
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作者 曹毓鹏 赵王鑫 +6 位作者 李立 马新野 郑晓霞 刘义 李文辉 宁先进 王全胜 《太原理工大学学报》 CAS 北大核心 2024年第3期493-502,共10页
【目的】常规大气等离子喷涂制备新型热障涂层陶瓷层候选材料Ba(Mg_(1/3)Ta_(2/3))O_(3)(BMT)涂层应变容限较低。【方法】基于悬浮液等离子喷涂技术(SPS),以乙醇为分散介质,聚丙烯酸(PAA)、聚乙烯亚胺(PEI)和聚乙二醇(PEG)为分散剂,借... 【目的】常规大气等离子喷涂制备新型热障涂层陶瓷层候选材料Ba(Mg_(1/3)Ta_(2/3))O_(3)(BMT)涂层应变容限较低。【方法】基于悬浮液等离子喷涂技术(SPS),以乙醇为分散介质,聚丙烯酸(PAA)、聚乙烯亚胺(PEI)和聚乙二醇(PEG)为分散剂,借助机械球磨制备了不同成分配比的BMT悬浮液。通过重力沉降观察法、紫外-可见分光光度计、Zeta电位仪对悬浮液的分散行为进行了研究,分析了分散剂种类及添加量对BMT悬浮液稳定性的影响;并利用SPS沉积了BMT涂层,对涂层的物相结构、表面形貌和截面组织进行了表征分析。【结果】结果表明:分散剂PEI在BMT颗粒表面吸附能够提高其Zeta电位,增强颗粒间斥力,并提供空间位阻作用,相比PAA和PEG,BMT悬浮液可以获得更好的分散效果。同时,添加PEI的BMT悬浮液黏度较低(介于1.5~2mPa·s),适用于SPS.由SPS制备的BMT涂层基本维持了BMT的物相结构,涂层呈现明显的柱状晶组织,且随悬浮液固含量的提高,涂层沉积效率增加,所形成的柱状晶体积更大,符合高应变容限涂层的组织结构特征。 展开更多
关键词 Ba(Mg_(1/3)Ta_(2/3))O_(3) 悬浮液等离子喷涂 分散剂 稳定性 组织结构
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高热稳定性近红外荧光粉BaY_(2)Al_(2)Ga_(2)SiO_(12):Cr^(3+)的合成及发光性质 被引量:1
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作者 袁玮鸿 庞然 +1 位作者 张粟 张洪杰 《发光学报》 EI CAS CSCD 北大核心 2024年第2期290-298,共9页
近年来,近红外荧光粉转换发光二极管(NIR pc-LED)在夜视、生物成像和无损检测等领域引起了广泛关注。然而,获得兼具高量子效率和优异热稳定性的近红外荧光粉仍然是一个巨大挑战。本文利用高温固相法合成了一种新型近红外荧光粉BaY_(2)Al... 近年来,近红外荧光粉转换发光二极管(NIR pc-LED)在夜视、生物成像和无损检测等领域引起了广泛关注。然而,获得兼具高量子效率和优异热稳定性的近红外荧光粉仍然是一个巨大挑战。本文利用高温固相法合成了一种新型近红外荧光粉BaY_(2)Al_(2)Ga_(2)SiO_(12):Cr^(3+)(BYAGSO:Cr^(3+)),并系统研究了材料的结构和发光性质。在440 nm蓝光激发下,BYAGSO:Cr^(3+)荧光粉的发射光谱在650~850 nm范围内呈现锐线和宽带的混合发射,源于Cr^(3+):^(2)E→^(4)A_(2)自旋禁戒跃迁和^(4)T_(2)→^(4)A_(2)自旋允许跃迁发射。该近红外发光表现出可观的量子效率和良好的热稳定性,最优化样品的外量子效率可达30.3%,在200℃时样品的发光强度可保持其在室温时强度的99%。通过将BYAGSO:Cr^(3+)荧光粉与450 nm蓝光LED芯片结合,我们封装了一个NIR pc‐LED器件。该器件在300m A驱动电流下,输出功率为70.83 mW;在20m A驱动电流下,光电转换效率为11.20%。研究结果表明,BY-AGSO:Cr^(3+)在NIR pc-LED领域具有良好的应用前景。 展开更多
关键词 近红外发射 Cr^(3+) 热稳定性 量子效率 荧光粉转换发光二极管
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Nominal Model-Based Sliding Mode Control with Backstepping for 3-Axis Flight Table 被引量:11
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作者 刘金琨 孙富春 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2006年第1期65-71,共7页
Based on nominal model, a novel global sliding mode controller (GSMC) with a new control scheme is proposed for a practical uncertain servo system. This control scheme consists of two combined controllers, One is th... Based on nominal model, a novel global sliding mode controller (GSMC) with a new control scheme is proposed for a practical uncertain servo system. This control scheme consists of two combined controllers, One is the global sliding mode controller for practical plant, the other is the integral backstepping controller for nominal model. Modeling error between practical plant and nominal model is used to design GSMC. The steady-state control accuracy can be guaranteed by the integral backstepping control law, and the global robustness can be obtained by GSMC. The stability of the proposed controller is proved according to the Lyapunov approach. The simulation results both of sine signal and step signal tracking for 3-axis flight table are investigated to show good position tracking performance and high robustness with respect to large and parameter changes over all the response time. 展开更多
关键词 nominal model sliding mode control backstepping control robust control 3-axis flight table
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Stiffness of Postural Alignment System Based on 3-Axis Actuators for Large Aircraft Components 被引量:4
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作者 GUO Zhimin JIANG Junxia KE Yinglin 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2010年第4期524-531,共8页
Aircraft digital flexible assembly fixture and technologies are widely used in developed countries, while the traditional jig-based assembly mode is still used in China. The application study of aircraft digital flexi... Aircraft digital flexible assembly fixture and technologies are widely used in developed countries, while the traditional jig-based assembly mode is still used in China. The application study of aircraft digital flexible assembly system is just beginning in our country recently. To meet the requirements of automated posture alignment and join in digital assembly system for large aircraft components, a novel fitting fixture called 3-axis actuator is developed. On the basis of the actuators, three kinds of posture alignment system for large aircraft components are proposed, including the non-redundant system, the redundant actuating system, and the redundant leg system, and their constitutions and properties are introduced. Through deriving the feeding transmission stiffness model of single actuator and analyzing the inverse kinematics of these systems, the relationship between the external force and the changes of position and orientation of large aircraft component is obtained, and then the postural alignment stiffness models are established. With the method mentioned above, the postural alignment stiffness of three systems is computed by using the algebraic formulate, and the results show that redundant properties can increase system's postural alignment stiffness. As an example, a optimized layout of the assembly system for a given model of aircraft is developed, the results of application show that the layout has many advantages, such as high accuracy, stiffness, stability, reliability, efficiency and flexible, which can satisfy the requirement of aircraft digital assembly system well. The proposed study of postural alignment stiffness for different systems can supply the theoretic support for the optimization layout design of aircraft digital assembly system, and contribute to evaluate the system working performance of systems. 展开更多
关键词 3-axis actuator large aircraft component redundant postural alignment stiffness posture-holding
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高稳定液态D-阿洛酮糖3-差向异构酶制剂研究 被引量:1
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作者 韩亚宏 郭元亨 +4 位作者 王小艳 丁长河 周浩 冉小力 田芳 《当代化工》 CAS 2024年第3期712-716,721,共6页
为解决D-阿洛酮糖3-差向异构酶(DAE)衰减过快、贮运成本高的问题,拟开发一款具有良好存贮稳定性的DEA液态酶制剂。以半衰期为评价依据,通过单因素试验筛选出对半衰期影响显著的4个因素,并进一步利用响应曲面法对酶制剂的配方进行优化。... 为解决D-阿洛酮糖3-差向异构酶(DAE)衰减过快、贮运成本高的问题,拟开发一款具有良好存贮稳定性的DEA液态酶制剂。以半衰期为评价依据,通过单因素试验筛选出对半衰期影响显著的4个因素,并进一步利用响应曲面法对酶制剂的配方进行优化。结果表明:稳定DAE酶制剂的最佳配比为0.1mol·L^(-1)CaCl_(2)、3.96%海藻糖、41.68%葡萄糖、29.32%PEG-400。在此条件下,半衰期为292天,与模拟理论值的相对误差仅为0.17%。通过工艺优化,将DAE的储存时间大幅延长,提高了酶制剂的贮运性能。 展开更多
关键词 D-阿洛酮糖3-差向异构酶 高稳定性 液态酶制剂
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QFT Robust Control Design for 3-Axis Flight Table Servo System with Large Friction 被引量:3
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作者 刘金琨 尔联洁 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2004年第1期34-38,共5页
The 3-axis flight table is an important device and a typical high performanceposition and speed servo system used in the hardware-in-the-loop simulation of flight controlsystem. Friction force and uncertainty are the ... The 3-axis flight table is an important device and a typical high performanceposition and speed servo system used in the hardware-in-the-loop simulation of flight controlsystem. Friction force and uncertainty are the main characteristics in the 3-axis flight table servosystem. Based on the description of dynamic and static model of a nonlinear Stribeck frictionmodel, and taking account of the practical uncertainties of 3-axis flight table servo system, theQFT controller is designed. Simulation and realtime results are presented. 展开更多
关键词 quantitative feedback theory 3-axis flight table friction model ROBUSTCONTROL
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Al_(2)O_(3)-SiO_(2)复合纳米气凝胶材料耐高温性能研究 被引量:1
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作者 吴佳臻 徐长伟 +1 位作者 张忠伦 王明铭 《复合材料科学与工程》 CAS 北大核心 2024年第2期67-74,共8页
以正硅酸四乙酯(TEOS)和六水合氯化铝(AlCl_(3)·6H_(2)O)作为混合前驱体,环氧丙烷作为网络诱捕剂,在不添加螯合剂情况下,采用溶胶-凝胶工艺与CO_(2)超临界干燥法制备出了不同摩尔比的Al_(2)O_(3)-SiO_(2)复合气凝胶。对样品分别进... 以正硅酸四乙酯(TEOS)和六水合氯化铝(AlCl_(3)·6H_(2)O)作为混合前驱体,环氧丙烷作为网络诱捕剂,在不添加螯合剂情况下,采用溶胶-凝胶工艺与CO_(2)超临界干燥法制备出了不同摩尔比的Al_(2)O_(3)-SiO_(2)复合气凝胶。对样品分别进行600℃、800℃、1000℃和1200℃热处理,并利用傅里叶红外光谱分析仪、扫描电镜、X射线衍射仪、比表面积分析仪、热重差热分析仪等仪器对Al_(2)O_(3)-SiO_(2)复合气凝胶的微观形貌、结构及热稳定性能进行表征。结果表明:当AlCl_(3)·6H_(2)O∶TEOS=8∶1时,Al_(2)O_(3)-SiO_(2)气凝胶样品在1000℃和1200℃热处理后的导热系数分别为0.0621 W/m·K和0.0803 W/m·K,在1000℃以上热处理后,孔径更加均匀,保留了较好的介孔结构;并且不同的热处理温度延缓了晶型转变,在常温和1200℃条件下,样品比表面积分别为617.14 m^(2)/g和102.9 m^(2)/g,为均匀的介孔结构(孔直径为8~32 nm),孔径低于常温下空气的平均自由程,在1200℃热处理后,样品总失重率为16.3%,具有较好的高温热稳定性。 展开更多
关键词 硅铝复合气凝胶 热处理 微观结构 热稳定性 复合材料
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基于有机胺盐表面修饰的CsPbI_(3)全无机钙钛矿太阳能电池性能的提升 被引量:1
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作者 柳宇 徐凌波 崔灿 《浙江理工大学学报(自然科学版)》 2024年第2期145-152,共8页
有机胺盐表面修饰是钙钛矿太阳能电池中钝化钙钛矿表面缺陷和提升电池稳定性的有效方法。旋涂苯乙基碘化铵(phenylethylammonium iodide,PEAI)和四丁基碘化铵(tetrabutylammonium iodide,TBAI)溶液在CsPbI_(3)钙钛矿薄膜表面并进行热处... 有机胺盐表面修饰是钙钛矿太阳能电池中钝化钙钛矿表面缺陷和提升电池稳定性的有效方法。旋涂苯乙基碘化铵(phenylethylammonium iodide,PEAI)和四丁基碘化铵(tetrabutylammonium iodide,TBAI)溶液在CsPbI_(3)钙钛矿薄膜表面并进行热处理,修饰钙钛矿表面,采用X射线衍射仪、扫描电镜、稳态-瞬态荧光寿命光谱仪对薄膜的结构形貌和光电性能进行表征分析,通过电流密度-电压测试、电化学阻抗测试和暗态电流密度-电压测试对比两种表面修饰剂对CsPbI_(3)钙钛矿薄膜和器件性能的影响。结果表明:PEAI不能与CsPbI_(3)发生离子交换生成低维钙钛矿,仅通过吸附在表面钝化缺陷并阻碍水汽侵入,提升薄膜的稳定性;而TBAI可有效进入无机CsPbI_(3)钙钛矿晶格,形成低维钙钛矿相,进而改善薄膜形貌、钝化缺陷并提升薄膜的稳定性;TBAI修饰的电池器件光电转换效率相较于PEAI修饰的器件提升了8.5%,同时器件的稳定性也得到了增强。该研究为开发适用于全无机CsPbI_(3)钙钛矿的新型表面修饰剂提供了指导和方向。 展开更多
关键词 表面修饰 四丁基碘化铵 苯乙基碘化铵 稳定性 CsPbI_(3) 光电性能
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Al_(2)O_(3)前驱体对Cu/ZnO/Al_(2)O_(3)催化甲醇重整制氢性能的影响
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作者 黄敏 薄其飞 +5 位作者 李娟 乔靖萱 袁善良 张彪 陈洪林 蒋毅 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第10期1443-1452,共10页
采用共沉淀法制备了一系列Cu/ZnO/Al_(2)O_(3)催化剂,通过XRD、BET、H_(2)-TPR、N_(2)O化学吸附、XPS表征技术,研究了Al_(2)O_(3)前驱体对催化剂结构的影响,同时对其在甲醇重整制氢中的性能进行了考察。结果表明,当Al^(3+)与Cu^(2+)、Zn... 采用共沉淀法制备了一系列Cu/ZnO/Al_(2)O_(3)催化剂,通过XRD、BET、H_(2)-TPR、N_(2)O化学吸附、XPS表征技术,研究了Al_(2)O_(3)前驱体对催化剂结构的影响,同时对其在甲醇重整制氢中的性能进行了考察。结果表明,当Al^(3+)与Cu^(2+)、Zn^(2+)同时共沉淀时,Al^(3+)对碱式碳酸盐中Cu^(2+)-Zn^(2+)部分取代生成类水滑石结构,增强了Zn-Al之间的相互作用。相反,在Cu^(2+)、Zn^(2+)完成共沉淀后,引入Al_(2)O_(3)前驱体对消除Al^(3+)对碱式碳酸盐中Cu-Zn取代的不良影响具有积极作用,有利于促进Cu-ZnO间的相互作用、CuO物种的分散和催化剂的还原,进一步促进表面Cu的分散,有利于其活性的提升。其中,以拟薄水铝石为铝源制备的催化剂呈现出优异的活性。在水醇物质的量比为1.2,反应温度为493 K的条件下,甲醇转化率可达94.8%,H_(2)时空收率可达97.5 mol/(kg·h),并且连续运行25 h其活性仍保持相对稳定。在反应条件下,经过723 K的10 h热处理后,该催化剂的活性损失率仅为5.37%。 展开更多
关键词 Al_(2)O_(3)前驱体 Cu/ZnO/Al_(2)O_(3)催化剂 甲醇水蒸气重整 热稳定性
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THEORETICAL RESULTS ON THE EXISTENCE,REGULARITY AND ASYMPTOTIC STABILITY OF ENHANCED PULLBACK ATTRACTORS:APPLICATIONS TO 3D PRIMITIVE EQUATIONS
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作者 王仁海 郭柏灵 黄代文 《Acta Mathematica Scientia》 SCIE CSCD 2023年第6期2493-2518,共26页
Several new concepts of enhanced pullback attractors for nonautonomous dynamical systems are introduced here by uniformly enhancing the compactness and attraction of the usual pullback attractors over an infinite forw... Several new concepts of enhanced pullback attractors for nonautonomous dynamical systems are introduced here by uniformly enhancing the compactness and attraction of the usual pullback attractors over an infinite forward time-interval under strong and weak topologies.Then we provide some theoretical results for the existence,regularity and asymptotic stability of these enhanced pullback attractors under general theoretical frameworks which can be applied to a large class of PDEs.The existence of these enhanced attractors is harder to obtain than the backward case[33],since it is difficult to uniformly control the long-time pullback behavior of the systems over the forward time-interval.As applications of our theoretical results,we consider the famous 3D primitive equations modelling the large-scale ocean and atmosphere dynamics,and prove the existence,regularity and asymptotic stability of the enhanced pullback attractors in V×V and H^(2)×H^(2) for the time-dependent forces which satisfy some weak conditions. 展开更多
关键词 3D primitive equations pullback attractors REGULARITY FATTENING stability
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STABILITY CONDITIONS AND THE MIRROR SYMMETRY OF K3 SURFACES IN ATTRACTOR BACKGROUNDS
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作者 卢文轩 《Acta Mathematica Scientia》 SCIE CSCD 2023年第3期1007-1030,共24页
We study the space of stability conditions on K3 surfaces from the perspective of mirror symmetry. This is done in the attractor backgrounds(moduli). We find certain highly non-generic behaviors of marginal stability ... We study the space of stability conditions on K3 surfaces from the perspective of mirror symmetry. This is done in the attractor backgrounds(moduli). We find certain highly non-generic behaviors of marginal stability walls(a key notion in the study of wall crossings)in the space of stability conditions. These correspond via mirror symmetry to some nongeneric behaviors of special Lagrangians in an attractor background. The main results can be understood as a mirror correspondence in a synthesis of the homological mirror conjecture and SYZ mirror conjecture. 展开更多
关键词 mirror symmetry stability conditions K3 surfaces attractor mechanism
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Long-term and short-term stability characteristics of receiver inter system bias for BDS3/BDS2
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作者 Jingxuan Guo Weiping Jiang +2 位作者 Yan Chen Xincheng Ma Hua Chen 《Geodesy and Geodynamics》 CSCD 2023年第2期143-149,共7页
The study of inter-system bias(ISB)is important for multi-system fusion and the performance of different signal compatibility.In this paper,the stability of ISB at the BDS3/BDS2 receiver end is calculated and analyzed... The study of inter-system bias(ISB)is important for multi-system fusion and the performance of different signal compatibility.In this paper,the stability of ISB at the BDS3/BDS2 receiver end is calculated and analyzed for different time spans(DOY 060~090 in 2021)from a total of 31 MGEX and iGMAS stations.We adopted two estimation strategies,random walk and constant approach,using the precision products of orbit and clock bias provided by WUM,the influence of which on ISB was also analyzed.Our results showed that the ISB value varied little within a day,and the mean of daily ISB standard deviation was only 0.037 m when the observation condition was good.The signal reception was continuous,indicating a high ISB stability for one day.If extending the time series to one month,however,the ISB standard deviation calculated by constant approach,in which a constant ISB is estimated on a daily basis was about 0.1 m,and the results of adjacent days were not continuous,with no apparent pattern.Concerning the random walk approach,the obtained ISB time series also had a jump,and the conclusion was the same as that of the constant strategy.Besides,receiver types showed a strong regularity in ISB numerical situation,and the distribution of ISB values corresponding to the same receiver type was relatively close.Therefore,we conclude that the ISB parameters remain stable in the short term(one day)and less stable in the long-term period.It is recommended that the ISB term should be set as a constant estimate every day in BDS3/BDS2 solutions,regardless of receiver type consistency. 展开更多
关键词 BDS3 BDS2 Inter system bias stability analysis Receiver type
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Effect of surface retaining elements on rock stability:laboratory investigation with sand powder 3D printing
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作者 Hao Feng Lishuai Jiang +3 位作者 Qingwei Wang Peng Tang Atsushi Sainoki Hani S.Mitri 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第4期305-324,共20页
This study aims to investigate the benefcial efects of surface retaining elements (SREs) on the mechanical behaviors of bolted rock and roadway stability. 3D printing (3DP) technology is utilized to create rock analog... This study aims to investigate the benefcial efects of surface retaining elements (SREs) on the mechanical behaviors of bolted rock and roadway stability. 3D printing (3DP) technology is utilized to create rock analogue prismatic specimens for conducting this investigation. Uniaxial compression tests with acoustic emission (AE) and digital image correlation techniques have been conducted on 3DP specimens bolted with diferent SREs. The results demonstrate that the strength and modulus of elasticity of the bolted specimens show a positive correlation with the area of the SRE;the AE characteristics of the bolted specimens are higher than those of the unbolted specimen, but they decrease with an increase in SRE area, thus further improving the integrity of the bolted specimens. The reinforcement efect of SREs on the surrounding rock of roadways is further analyzed using numerical modelling and feld test. The results provide a better understanding of the role of SREs in rock bolting and the optimization of rock bolting design. Furthermore, they verify the feasibility of 3DP for rock analogues in rock mechanics tests. 展开更多
关键词 Roadway stability Surface retaining element Sand-powder 3D printing Rock bolting Numerical modelling
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用于丁二烯选择性加氢Ni_(3)ZnC_(0.7)@Ni@C催化剂的设计
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作者 陈智冰 陈鑫泰 +6 位作者 吕雅丽 牟效玲 范佳辉 李经伟 严丽 林荣和 丁云杰 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第5期304-315,共12页
丁二烯选择性加氢是提升碳四综合利用效率的关键技术,因此受到了工业界和学术界的广泛关注.然而,在实际操作过程中,原料中的单烯烃也可能发生加氢,这降低了整个工艺过程的经济性.此外,丁二烯分子内含有两个共轭的C=C双键,其化学性质活泼... 丁二烯选择性加氢是提升碳四综合利用效率的关键技术,因此受到了工业界和学术界的广泛关注.然而,在实际操作过程中,原料中的单烯烃也可能发生加氢,这降低了整个工艺过程的经济性.此外,丁二烯分子内含有两个共轭的C=C双键,其化学性质活泼,容易在金属催化剂表面发生聚合生成碳沉积物,从而导致催化剂失活.因此,如何提高烯烃的选择性和催化剂的稳定性成为一项挑战.目前,丁二烯加氢反应主要采用Pd,Pt,Au等贵金属催化剂,但贵金属的高昂价格和稀缺性限制了其大规模应用.因此,开发基于廉价金属的替代催化剂具有重要意义.镍基体系在丁二烯的选择性加氢中显示出一定潜力,然而,其实际应用受到积炭和过度加氢导致的严重失活等问题的影响.本文在前期工作固相法合成Ni_(3)ZnC_(0.7)@C(采用无溶剂的固态反应法合成,将金属硝酸盐与双氰胺机械混合,再于氢气下高温还原制得,其中Ni_(3)ZnC_(0.7)颗粒外围具有碳层覆盖,详见Dalton Trans.,2023,52,11571–11580)基础上,通过对Ni_(3)ZnC_(0.7)@C进行可控的空气氧化处理去除碳层,设计制备了一种具有双核壳结构的Ni_(3)ZnC_(0.7)@Ni@C新型催化剂.该催化剂的特点是金属镍小团簇均匀分散在中心Ni_(3)ZnC_(0.7)纳米粒子上,而Ni_(3)ZnC_(0.7)@Ni被全部包裹在多孔碳壳中.利用高角度环形暗场扫描透射电子显微镜、高分辨透射电镜、热重分析和Ar离子溅射X射线光电子能谱等技术进行了表征,并提出了氧化过程中催化剂组成与结构的变化规律.实验结果表明,Ni_(3)ZnC_(0.7)@Ni@C催化剂在丁二烯选择性加氢反应中表现出较好的活性和稳定性,其性能超过了Ni_(3)ZnC_(0.7)@C和很多文献报道的镍催化体系,如Ni_(3)InC0.5和Ni_(3)In合金等.此外,本文还发现Ni_(3)ZnC_(0.7)@Ni@C催化剂在初始反应阶段的积炭行为具有自限性.相对于碳载体本身,反应中原位沉积的少量碳质(“软”积炭)能够在更低温度下被氧化,并且碳沉积在反应初期达到平衡,该现象不仅能够抑制催化剂的进一步失活,还可以显著提高总丁烯的选择性.在温和反应条件下,Ni_(3)ZnC_(0.7)@Ni@C催化剂能够获得高于93%的总丁烯选择性和98%的转化率,并且在长达80 h测试中依然保持催化性能稳定.综上,本文通过利用镍及其间隙化合物的独特性质,开发了一种高活性、高选择性的非贵金属催化剂.通过调节电子结构、表面反应性以及潜在的协同效应,显著提高了催化性能.此外,研究发现反应中原位生成的“软”积炭不仅能够抑制催化剂的过度失活,还有助提高催化剂的选择性和稳定性.上述结果对于研究存在类似积炭问题的其他催化过程具有借鉴意义. 展开更多
关键词 丁二烯加氢 间隙化合物 Ni_(3)ZnC_(0.7)@Ni@C 稳定性 结构演变
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Improving Cyclic Stability and Rate Performance of Lithium Ion Batteries Using La^(3+)Modified LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)Cathode Materials
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作者 杜玉喆 RUAN Zhefei +1 位作者 ZHANG Ruiming 张海宁 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第4期735-742,共8页
La_(4)NiLiO_(8)-coated NCM622 samples were prepared through a sol-gel method,and the electrochemical performance as cathode materials was investigated.It is revealed that part of the introduced La^(3+)ions produce a c... La_(4)NiLiO_(8)-coated NCM622 samples were prepared through a sol-gel method,and the electrochemical performance as cathode materials was investigated.It is revealed that part of the introduced La^(3+)ions produce a coating layer on the surface of NCM622 particles,while the rest occupy the 3b position of the lattice.The optimized sample exhibits a capacity retention of 96.54%after 100 cycles under 1C rate with a discharge specific capacity of 117.54 mAh·g^(-1)under 5C rate,much higher than those of the unmodified sample.The results show that the addition of La^(3+)ion can greatly improve the cyclic stability and the rate performance of NCM622. 展开更多
关键词 lithium ion batter La^(3+)doping NCM622 cycling stability rate performance
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不同核壳结构的CsPbBr_(3)纳米晶体的稳定性、生物相容性能
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作者 陈丹阳 薛娟娟 韩丹 《微纳电子技术》 CAS 2024年第2期69-77,共9页
CsPbBr_(3)钙钛矿纳米晶体(PNC)由于出色的光学性能使其在生物领域具有广泛的应用前景,但CsPbBr_(3)PNC的低稳定性及高毒性大大限制了其实际应用。因此,通过壳层包裹,采用室温重结晶法分别将环糊精(CD)和SiO_(2)包覆在CsPbBr_(3)PNC表... CsPbBr_(3)钙钛矿纳米晶体(PNC)由于出色的光学性能使其在生物领域具有广泛的应用前景,但CsPbBr_(3)PNC的低稳定性及高毒性大大限制了其实际应用。因此,通过壳层包裹,采用室温重结晶法分别将环糊精(CD)和SiO_(2)包覆在CsPbBr_(3)PNC表面合成核壳结构的CsPbBr_(3)@CD和CsPbBr_(3)@SiO_(2)。不同的包覆材料使PNC具有不同的光学特性、稳定性及生物相容性。其中,CsPbBr_(3)@SiO_(2)的荧光量子产率(36.16%)约为CsPbBr_(3)@CD(14.39%)的2.5倍。CsPbBr_(3)@SiO_(2)的平均荧光衰减寿命(101.43 ns)约为CsPbBr_(3)@CD(68.73 ns)的1.5倍。在30℃、湿度为60%的空气中放置10天后,CsPbBr_(3)@SiO_(2)荧光强度约为CsPbBr_(3)@CD的3.9倍。将CsPbBr_(3)@CD和CsPbBr_(3)@SiO_(2)与细胞共培养,细胞存活率分别为51.27%和88.57%。结果表明,相较于CsPbBr_(3)@CD,CsPbBr_(3)@SiO_(2)具有更好的光学特性、稳定性以及生物相容性,更有利于在生物医学领域应用。 展开更多
关键词 钙钛矿纳米晶体(PNC) 重结晶法 CsPbBr_(3) 核壳结构 稳定性 生物相容性
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