The reaction mechanism of 3 chlorophenol with OH, H in aqueous solution was studied by transient technology. The 3 chlorophenol aqueous solutions have been saturated with air or N 2 previously. Under alkaline condi...The reaction mechanism of 3 chlorophenol with OH, H in aqueous solution was studied by transient technology. The 3 chlorophenol aqueous solutions have been saturated with air or N 2 previously. Under alkaline condition, the reaction of OH radical with 3 chlorophenol produces 3 chlorinated phenoxyl radical, with the absorption peaks at 400 nm and 417 nm. Under neutral condition, the reaction of OH radical with 3 chlorophenol produces OH adduct with the maximal absorption at about 340 nm. And in acid solution, the reaction of H with 3 chlorophenol produces H adduct with the maximal absorption at about 320 nm. 3 chlorophenol is compared with 4 and 2 chlorophenols from the free radical pathways. The results show that the positions of chlorine on the aromatic ring strongly influence the dehalogenation and degradation process.展开更多
文摘The reaction mechanism of 3 chlorophenol with OH, H in aqueous solution was studied by transient technology. The 3 chlorophenol aqueous solutions have been saturated with air or N 2 previously. Under alkaline condition, the reaction of OH radical with 3 chlorophenol produces 3 chlorinated phenoxyl radical, with the absorption peaks at 400 nm and 417 nm. Under neutral condition, the reaction of OH radical with 3 chlorophenol produces OH adduct with the maximal absorption at about 340 nm. And in acid solution, the reaction of H with 3 chlorophenol produces H adduct with the maximal absorption at about 320 nm. 3 chlorophenol is compared with 4 and 2 chlorophenols from the free radical pathways. The results show that the positions of chlorine on the aromatic ring strongly influence the dehalogenation and degradation process.