The title complex, {[Cu2（4,4＇-bipyridine）2（μ-O2CMe）2（O2CMe）2],H2O}n 1, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2/c with a = 13.4474...The title complex, {[Cu2（4,4＇-bipyridine）2（μ-O2CMe）2（O2CMe）2],H2O}n 1, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2/c with a = 13.4474（5）, b = 11.7566（2）, c = 19.5380（6）A, β = 92.930（2）°, V = 3084.84（16） A^3, Z = 4, Cu2C28N409H30, Mr = 693.64, Dc = 1.494 g/cm^3, F（000） = 1424 and μ（MoKα） = 1.436 mm^-1. With the use of 2062 observed reflections （I 〉 2σ（I））, the structure was refined to R = 0.0769 and wR = 0.2154. In complex 1, the dimeric copper acetate units are linked through 4,4’-bipyridine to yield ID molecular ladders. These ladders are connected via O-H…O hydrogen bonds to generate 2D layers, which are further linked through C-H…O hydrogen bonds to give a 3D supramolecular network.展开更多
A new compound [Zn3（C7NO4H3）3Cl4]·[C6NO2H6]4·4H2O （I） has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018（14）,b=12...A new compound [Zn3（C7NO4H3）3Cl4]·[C6NO2H6]4·4H2O （I） has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018（14）,b=12.6902（10）,c=25.1170（2）,β=90.54°,V=5387.0（8）3,Z=4,Zn3C45H41Cl4N7O24,Mr=1401.76,Dc=1.728 g/cm3,F（000）=2840,μ（MoKa）=1.615 mm-1,the R= 0.0758 and wR=0.2060 for 3468 observed reflections （I 〉 2σ（I））.Analysis of single-crystal X-ray diffraction data shows that compound I displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.展开更多
Treatment of bis（2-dimethylaminoethyl） ether（BDMAE） with nickel acetate afforded a novel 3D nickel（Ⅱ） complex [Ni（BDMAE）（H2O）3·（CH3COO）2·（H2O）2] under solvothermal conditions. Its crystal stru...Treatment of bis（2-dimethylaminoethyl） ether（BDMAE） with nickel acetate afforded a novel 3D nickel（Ⅱ） complex [Ni（BDMAE）（H2O）3·（CH3COO）2·（H2O）2] under solvothermal conditions. Its crystal structure was characterized by elemental analysis, IR spectrum, PXRD and single-crystal X-ray diffraction analysis. The complex belongs to the orthorhombic system, space group C2221 with a=8.823（2）, b=13.932（3）, c=17.563（4） , V=2158.9（8） 3, Z=4, C（12）H（36）N2NiO（10）, Mr=427.14, Dc=1.314 g/cm3, F（000）=920 and μ=0.944 mm（-1）. Single-crystal X-ray diffraction reveals that the mononuclear nickel（Ⅱ） ion is six-coordinated to one oxygen, two nitrogen atoms of the BDMAE ligand and three oxygen atoms of coordinated water molecules. The complex exhibits a 3D supramolecular structure through a variety of intermolecular and intramolecular hydrogen bonding interactions. In addition, the complex has been investigated for catalytic properties towards the Henry reaction of nitromethane with p-nitrobenzaldehyde, and the results indicated that the 1-p-nitrophenyl-2-nitroethanol product was obtained in excellent yield under optimum conditions with the complex as the catalyst.展开更多
A new three-dimensional (3D) lanthanide-aromatic monocarboxylate dimer supramolecular network [La2(DNBA)4(DMF)8][W6O19] (DNBA=3,5-dinitrobenzoate, DMF=dimethylfomamide) was synthesized using hexatungstate anion (W6O19...A new three-dimensional (3D) lanthanide-aromatic monocarboxylate dimer supramolecular network [La2(DNBA)4(DMF)8][W6O19] (DNBA=3,5-dinitrobenzoate, DMF=dimethylfomamide) was synthesized using hexatungstate anion (W6O192-) as template. The crystal structure of the title compound has been determined by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a=1.334 54(18) nm, b=1.387 52(19) nm, c=1.426 06(19) nm, α=102.189(2)°, β=101.023(2)°, γ=116.349(2)°, V=2.187 2(5) nm3, Dc=2.364 g·cm-3, Z=1, F(000)=1 453.40. The single crystal structure reveals that two La髥 ions are bridged by four 3,5-dinitrobenzoate anions as asymmetrically bridging ligands, leading to dimeric cores, [La2(DNBA)4(DMF)8]2+; [La2(DNBA)4(DMF)8]2+ groups are joined together by π-π stacking interaction between the aromatic groups to form a two-dimensional grid-like network; the 2D supramolecular layers are further extended into 3D supramolecular network with a 1D box-like channels by hydrogen bonding interactions, in which hexatungstate polyanions reside. CCDC: 284694.展开更多
Macroscopic supramolecular assembly （MSA） has been a recent progress in supramolecular chemistry. MSA mainly focuses on studies of the building blocks with a size beyond ten micrometers and the non-covalent interact...Macroscopic supramolecular assembly （MSA） has been a recent progress in supramolecular chemistry. MSA mainly focuses on studies of the building blocks with a size beyond ten micrometers and the non-covalent interactions between these interactive building blocks to form ordered structures. MSA is essential to realize the concept of＂self-assembly at all scales＂ by bridging most supramolecular researches at molecular level and at macroscopic scale. This review summaries the development of MSA, the basic design principle and related strategies to achieve MSA and potential applications. Correspondingly, we try to elucidate the correlations and differences between ＂macroscopic assembly＂ and MSA based on intermolecular interactions; the design principle and the underlying assembly mechanism of MSA are proposed to understand the reported MSA behaviors; to demonstrate further applications of MSA, we introduce some methods to improve the ordered degree of the assembled structures from the point of precise assembly and thus envision some possible fields for the use of MSA.展开更多
基金This work was supported by the Science Foundation of Fujian Provincial Key Laboratory of Polymer Materials
文摘The title complex, {[Cu2（4,4＇-bipyridine）2（μ-O2CMe）2（O2CMe）2],H2O}n 1, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2/c with a = 13.4474（5）, b = 11.7566（2）, c = 19.5380（6）A, β = 92.930（2）°, V = 3084.84（16） A^3, Z = 4, Cu2C28N409H30, Mr = 693.64, Dc = 1.494 g/cm^3, F（000） = 1424 and μ（MoKα） = 1.436 mm^-1. With the use of 2062 observed reflections （I 〉 2σ（I））, the structure was refined to R = 0.0769 and wR = 0.2154. In complex 1, the dimeric copper acetate units are linked through 4,4’-bipyridine to yield ID molecular ladders. These ladders are connected via O-H…O hydrogen bonds to generate 2D layers, which are further linked through C-H…O hydrogen bonds to give a 3D supramolecular network.
基金supported by the Natural Science Foundation of Fujian Province (2006F3042)
文摘A new compound [Zn3（C7NO4H3）3Cl4]·[C6NO2H6]4·4H2O （I） has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018（14）,b=12.6902（10）,c=25.1170（2）,β=90.54°,V=5387.0（8）3,Z=4,Zn3C45H41Cl4N7O24,Mr=1401.76,Dc=1.728 g/cm3,F（000）=2840,μ（MoKa）=1.615 mm-1,the R= 0.0758 and wR=0.2060 for 3468 observed reflections （I 〉 2σ（I））.Analysis of single-crystal X-ray diffraction data shows that compound I displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.
基金supported by the National Natural Science Foundation of China(No.21271136)the Key Science Foundation of Anhui Provincial Education Department(No.KJ2016A772)the Research Team of Anhui Provincial Education Department(Photoelectric Information Materials and New Energy Devices)
文摘Treatment of bis（2-dimethylaminoethyl） ether（BDMAE） with nickel acetate afforded a novel 3D nickel（Ⅱ） complex [Ni（BDMAE）（H2O）3·（CH3COO）2·（H2O）2] under solvothermal conditions. Its crystal structure was characterized by elemental analysis, IR spectrum, PXRD and single-crystal X-ray diffraction analysis. The complex belongs to the orthorhombic system, space group C2221 with a=8.823（2）, b=13.932（3）, c=17.563（4） , V=2158.9（8） 3, Z=4, C（12）H（36）N2NiO（10）, Mr=427.14, Dc=1.314 g/cm3, F（000）=920 and μ=0.944 mm（-1）. Single-crystal X-ray diffraction reveals that the mononuclear nickel（Ⅱ） ion is six-coordinated to one oxygen, two nitrogen atoms of the BDMAE ligand and three oxygen atoms of coordinated water molecules. The complex exhibits a 3D supramolecular structure through a variety of intermolecular and intramolecular hydrogen bonding interactions. In addition, the complex has been investigated for catalytic properties towards the Henry reaction of nitromethane with p-nitrobenzaldehyde, and the results indicated that the 1-p-nitrophenyl-2-nitroethanol product was obtained in excellent yield under optimum conditions with the complex as the catalyst.
文摘A new three-dimensional (3D) lanthanide-aromatic monocarboxylate dimer supramolecular network [La2(DNBA)4(DMF)8][W6O19] (DNBA=3,5-dinitrobenzoate, DMF=dimethylfomamide) was synthesized using hexatungstate anion (W6O192-) as template. The crystal structure of the title compound has been determined by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a=1.334 54(18) nm, b=1.387 52(19) nm, c=1.426 06(19) nm, α=102.189(2)°, β=101.023(2)°, γ=116.349(2)°, V=2.187 2(5) nm3, Dc=2.364 g·cm-3, Z=1, F(000)=1 453.40. The single crystal structure reveals that two La髥 ions are bridged by four 3,5-dinitrobenzoate anions as asymmetrically bridging ligands, leading to dimeric cores, [La2(DNBA)4(DMF)8]2+; [La2(DNBA)4(DMF)8]2+ groups are joined together by π-π stacking interaction between the aromatic groups to form a two-dimensional grid-like network; the 2D supramolecular layers are further extended into 3D supramolecular network with a 1D box-like channels by hydrogen bonding interactions, in which hexatungstate polyanions reside. CCDC: 284694.
文摘Macroscopic supramolecular assembly （MSA） has been a recent progress in supramolecular chemistry. MSA mainly focuses on studies of the building blocks with a size beyond ten micrometers and the non-covalent interactions between these interactive building blocks to form ordered structures. MSA is essential to realize the concept of＂self-assembly at all scales＂ by bridging most supramolecular researches at molecular level and at macroscopic scale. This review summaries the development of MSA, the basic design principle and related strategies to achieve MSA and potential applications. Correspondingly, we try to elucidate the correlations and differences between ＂macroscopic assembly＂ and MSA based on intermolecular interactions; the design principle and the underlying assembly mechanism of MSA are proposed to understand the reported MSA behaviors; to demonstrate further applications of MSA, we introduce some methods to improve the ordered degree of the assembled structures from the point of precise assembly and thus envision some possible fields for the use of MSA.
