The phosphors that are able to convert vacuum ultraviolet(VUV) light into visible light are demanded for the development of novel displaying and lighting devices.NaYF4:Pr3+,Dy3+,NaGdF4:Pr3+,NaGdF4:Dy3+and NaG...The phosphors that are able to convert vacuum ultraviolet(VUV) light into visible light are demanded for the development of novel displaying and lighting devices.NaYF4:Pr3+,Dy3+,NaGdF4:Pr3+,NaGdF4:Dy3+and NaGdF4:Pr3+,Dy3+were prepared by hydrothermal synthesis method and their luminescent properties in VUV-vis spectral region were investigated at room temperature.For NaYF4:Pr3+,Dy3+,no energy transfer process from Pr3+to Dy3+was observed.However,the introduction of Gd3+into the fluoride lattice led to intense Dy3+emissions upon Pr3+4f5d state excitation.Gd3+acted as an intermediate,resulting in efficient energy transfer from Pr3+to Dy3+in NaGdF4.Pr3+transferred most of its energy to Gd3+,and then the energy was transferred from Gd3+to Dy3+.So NaGdF4:Pr3+,Dy3+not only took full advantage of the intense Pr3+4f5d absorption,but converted the VUV excitation light into the near-white emission of Dy3+.展开更多
基金supported by National Natural Science Foundation of China(11274038,10979009,61078069)Fundamental Research Funds for the Central Universities(2011JBM296)
文摘The phosphors that are able to convert vacuum ultraviolet(VUV) light into visible light are demanded for the development of novel displaying and lighting devices.NaYF4:Pr3+,Dy3+,NaGdF4:Pr3+,NaGdF4:Dy3+and NaGdF4:Pr3+,Dy3+were prepared by hydrothermal synthesis method and their luminescent properties in VUV-vis spectral region were investigated at room temperature.For NaYF4:Pr3+,Dy3+,no energy transfer process from Pr3+to Dy3+was observed.However,the introduction of Gd3+into the fluoride lattice led to intense Dy3+emissions upon Pr3+4f5d state excitation.Gd3+acted as an intermediate,resulting in efficient energy transfer from Pr3+to Dy3+in NaGdF4.Pr3+transferred most of its energy to Gd3+,and then the energy was transferred from Gd3+to Dy3+.So NaGdF4:Pr3+,Dy3+not only took full advantage of the intense Pr3+4f5d absorption,but converted the VUV excitation light into the near-white emission of Dy3+.