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铀-2-(3,5-二溴-2-吡啶偶氮)-5-二乙氨基苯酚-Triton X-100析相体系的研究及应用 被引量:4
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作者 曾锋 崔昆燕 《分析化学》 SCIE EI CAS CSCD 北大核心 1995年第11期1323-1325,共3页
本文研究了铀-2-(3,5-二溴-2-吡啶偶氨)-5-二乙氨基苯酚(3,5-diBr-PADAP)-Triton X-100析相光度体系,建立了矿石中微量铀的测定方法,在pH 7.5三乙醇胺-盐酸介质中,将胶束溶液在 95±1℃加热 1h.络合物即被Triton X-100相完全富集.... 本文研究了铀-2-(3,5-二溴-2-吡啶偶氨)-5-二乙氨基苯酚(3,5-diBr-PADAP)-Triton X-100析相光度体系,建立了矿石中微量铀的测定方法,在pH 7.5三乙醇胺-盐酸介质中,将胶束溶液在 95±1℃加热 1h.络合物即被Triton X-100相完全富集.络合物最大吸收峰位于565nm.摩尔吸光系数为1.02×10~5L·mol~(-1)·cm~(-1),铀含量在0~12μg/5mL服从比耳定律.采用TBP萃淋树脂分离干扰离子,测定矿石中微量铀,结果满意. 展开更多
关键词 光度法 矿石 析相当 PADAP
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Determination of Cationic Surfactant by Laser Thermal Lens Spectrometry 被引量:1
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作者 Hong Tao YAN Ying ZHANG Yang YAN 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第11期1107-1110,共4页
A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfoni... A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples. 展开更多
关键词 Determination of cationic surfactant cetylpyridinium bromide (CPB) cetyltri- methyl-ammonium bromide (CTMAB) 1-hydroxy-2-(5-nitro-2-pyridylazo)-8-aminonaphthalene- 3 6-disulfonic acid (5-NO2-PAHA) laser thermal lens spectrometry.
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