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从二氢-β-紫罗兰酮合成茶螺烷 被引量:4
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作者 刘金 孔宁川 +4 位作者 陈永宽 朱宏春 韩志强 王海涛 范多青 《云南化工》 CAS 2003年第4期9-10,34,共3页
 二氢 β 紫罗兰酮经KBH4还原成二氢 β 紫罗兰醇,经30%H2O2/醋酐 甲酸环氧后环化脱水,得质量比为55∶45的茶螺烷和6 亚甲基茶螺烷混和物,经叔丁醇钾异构化,6h后达平衡,平衡值为m(茶螺烷):m(6 亚甲基茶螺烷)=70∶30。
关键词 二氢-β-紫罗兰酮 合成 茶螺烷 二氢-β-紫罗兰醇 醋酐 甲酸
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The Identification of Two New Sterols from Marine Organism 被引量:3
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作者 Shi Hai XU Long Mei ZENG(Department of Chemistry, Jinan University Guanzhou 510632)(Department of Chemistry Zhongshan University Guanzhou 510275) 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第6期531-534,共4页
Two new sterol have been isolated from the South China Sea marine organism. Compound 1 was isolated from the sponge Polymastia sobustia and compound 2 was obtained from the soft coral Sinularia inexplicata. Their stru... Two new sterol have been isolated from the South China Sea marine organism. Compound 1 was isolated from the sponge Polymastia sobustia and compound 2 was obtained from the soft coral Sinularia inexplicata. Their structures were established as 3 beta-hydroxy-stigmast-5en-7-one and 24-methylene cholestan -3 beta, 6 beta, 9 alpha, 19-tetrol by variety of spectral analysis such as IR, EIMS, 1DNMR, H-1-H-1 COSY, HMQC, HMBC, NOESY. 展开更多
关键词 sterol Polymastia sobustia 3 beta-hydroxy- stigmast-5en-7-one soft coral Sinularia inexplicita 24-methylene cholestan-3 beta 6 beta 9 alpha 19-tetrol
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