The effect of ultraviolet(UV)radiation and biocide benzalkonium chloride(BKC)on fungal-induced corrosion of AA7075 induced by Aspergillus terreus(A.terreus)was deeply studied using analysis of biological activity,surf...The effect of ultraviolet(UV)radiation and biocide benzalkonium chloride(BKC)on fungal-induced corrosion of AA7075 induced by Aspergillus terreus(A.terreus)was deeply studied using analysis of biological activity,surface analysis,and electrochemical measurements.Results demonstrated that the planktonic and sessile spore concentrations decline by more than two orders of magnitude when UV radiation and BKC are combinedly used compared with the control.UV radiation can inhibit the biological activity of A.terreus and influence the stability of passive film of AA7075.Except for direct disinfection,the physical adsorption of BKC on the specimen can effectively inhibit the attachment of A.terreus.The combination of UV radiation and BKC can much more effectively inhibit the corrosion of AA,especially pitting corrosion,due to their synergistic effect.The combined application of UV radiation and BKC can be a good method to effectively inhibit fungal-induced corrosion.展开更多
The evolution of microstructure during hot deformation is key to achieving good mechanical properties in aluminum alloys.We have developed a cellular automaton(CA) based model to simulate the microstructural evolution...The evolution of microstructure during hot deformation is key to achieving good mechanical properties in aluminum alloys.We have developed a cellular automaton(CA) based model to simulate the microstructural evolution in 7075 aluminum alloy during hot deformation.Isothermal compression tests were conducted to obtain material parameters for 7075 aluminum alloy,leading to the establishment of models for dislocation density,nucleation of recrystallized grains,and grain growth.Integrating these aspects with grain topological deformation,our CA model effectively predicts flow stress,dynamic recrystallization(DRX) volume fraction,and average grain size under diverse deformation conditions.A systematic comparison was made between electron back scattered diffraction(EBSD) maps and CA model simulated under different deformation temperatures(573 to 723 K),strain rates(0.001 to 1 s^(-1)),and strain amounts(30% to 70%).These analyses indicate that large strain,high temperature,and low strain rate facilitate dynamic recrystallization and grain refinement.The results from the CA model show good accuracy and predictive capability,with experimental error within 10%.展开更多
The anodizing parameters of voltage, current density, temperature, and electrolyte choice were assessed to find an appropriate combination for the superheated slurry cast 7075 Al alloy substrate.The alloy was anodized...The anodizing parameters of voltage, current density, temperature, and electrolyte choice were assessed to find an appropriate combination for the superheated slurry cast 7075 Al alloy substrate.The alloy was anodized in sulfuric acid electrolyte or alternatively in sulfuric acid mixed with boric acid or citric acid. The voltages applied were in the range of 15-30 V. Anodizing current densities tested were 2 and 3 A/dm^2,while temperatures tested were 5 and 15 ℃. Thickness, surface morphology, hardness,and corrosion resistance of the oxide film were then evaluated.It was found that 25 V,2 A/dm^2 and 5 ℃ were suitable for this alloy when anodized in sulfuric acid. The oxide film was smooth with uniform thickness, low porosity, high hardness,and had the highest corrosion resistance at these parameters. However, discontinuous oxide films were observed from samples anodized at higher temperature of 15 ℃.Alternative electrolytes considered were sulfuric acid mixed with boric acid or citric acid. The results showed that electrolytes with boric acid or citric acid increased thickness, hardness, corrosion resistance and quality of the oxide films.However, these oxide films were inferior to those obtained with sulfuric acid electrolyte at lower temperature(25 V, 2 A/dm^2 and5 ℃).展开更多
研究了平均应力效应对7075-T651铝合金疲劳性能的影响,选取了R=0.5、0.3、0.1和-0.1四组应力比进行疲劳试验。结果表明,同一应力比下,随着峰值应力水平的增加,疲劳寿命逐渐降低;而同一峰值应力水平下,随着应力比的提高,疲劳寿命则呈现...研究了平均应力效应对7075-T651铝合金疲劳性能的影响,选取了R=0.5、0.3、0.1和-0.1四组应力比进行疲劳试验。结果表明,同一应力比下,随着峰值应力水平的增加,疲劳寿命逐渐降低;而同一峰值应力水平下,随着应力比的提高,疲劳寿命则呈现出逐渐升高的趋势。同时,使用扫描电子显微镜(Scanning Electron Microscopy,SEM)观察疲劳断口形貌发现,在峰值应力相同的情况下,裂纹萌生及扩展区的扇形面积随平均应力的增大而增大。最后,基于7075-T651铝合金疲劳实验结果,提出了一种考虑S-N-R的改进型预测模型,结果对比显示相较于其他模型,此模型在一定程度上对7075-T651铝合金具有更好的疲劳寿命预测效果。展开更多
基金supported by the Guangdong Basic and Applied Basic Research Foundation,China(No.2023A1515012146)the National Natural Science Foundation of China(No.52271083)+1 种基金the Fundamental Research Funds for the Central Universities,China(No.22qntd0801)the Shanghai Engineering Technology Research Centre of Deep Offshore Material,China(No.19DZ2253100)。
文摘The effect of ultraviolet(UV)radiation and biocide benzalkonium chloride(BKC)on fungal-induced corrosion of AA7075 induced by Aspergillus terreus(A.terreus)was deeply studied using analysis of biological activity,surface analysis,and electrochemical measurements.Results demonstrated that the planktonic and sessile spore concentrations decline by more than two orders of magnitude when UV radiation and BKC are combinedly used compared with the control.UV radiation can inhibit the biological activity of A.terreus and influence the stability of passive film of AA7075.Except for direct disinfection,the physical adsorption of BKC on the specimen can effectively inhibit the attachment of A.terreus.The combination of UV radiation and BKC can much more effectively inhibit the corrosion of AA,especially pitting corrosion,due to their synergistic effect.The combined application of UV radiation and BKC can be a good method to effectively inhibit fungal-induced corrosion.
基金Funded by the Central Government Guides Local Funds for Science and Technology Development(No.YDZJSX20231A045)the Fundamental Research Program of Shanxi Province(Nos.202103021223288 and 202103021224282)。
文摘The evolution of microstructure during hot deformation is key to achieving good mechanical properties in aluminum alloys.We have developed a cellular automaton(CA) based model to simulate the microstructural evolution in 7075 aluminum alloy during hot deformation.Isothermal compression tests were conducted to obtain material parameters for 7075 aluminum alloy,leading to the establishment of models for dislocation density,nucleation of recrystallized grains,and grain growth.Integrating these aspects with grain topological deformation,our CA model effectively predicts flow stress,dynamic recrystallization(DRX) volume fraction,and average grain size under diverse deformation conditions.A systematic comparison was made between electron back scattered diffraction(EBSD) maps and CA model simulated under different deformation temperatures(573 to 723 K),strain rates(0.001 to 1 s^(-1)),and strain amounts(30% to 70%).These analyses indicate that large strain,high temperature,and low strain rate facilitate dynamic recrystallization and grain refinement.The results from the CA model show good accuracy and predictive capability,with experimental error within 10%.
基金financially supported by the Higher Education Research Promotionthe National Research University Project of Thailand, Office of the Higher Education (Contract No. ENG580529S)+2 种基金Center of Excellence in Materials Engineering (CEME)the Graduate Engineer Scholarship and the Graduate School ScholarshipPrince of Songkla University, including Surat Thani Campus (2016)
文摘The anodizing parameters of voltage, current density, temperature, and electrolyte choice were assessed to find an appropriate combination for the superheated slurry cast 7075 Al alloy substrate.The alloy was anodized in sulfuric acid electrolyte or alternatively in sulfuric acid mixed with boric acid or citric acid. The voltages applied were in the range of 15-30 V. Anodizing current densities tested were 2 and 3 A/dm^2,while temperatures tested were 5 and 15 ℃. Thickness, surface morphology, hardness,and corrosion resistance of the oxide film were then evaluated.It was found that 25 V,2 A/dm^2 and 5 ℃ were suitable for this alloy when anodized in sulfuric acid. The oxide film was smooth with uniform thickness, low porosity, high hardness,and had the highest corrosion resistance at these parameters. However, discontinuous oxide films were observed from samples anodized at higher temperature of 15 ℃.Alternative electrolytes considered were sulfuric acid mixed with boric acid or citric acid. The results showed that electrolytes with boric acid or citric acid increased thickness, hardness, corrosion resistance and quality of the oxide films.However, these oxide films were inferior to those obtained with sulfuric acid electrolyte at lower temperature(25 V, 2 A/dm^2 and5 ℃).
文摘研究了平均应力效应对7075-T651铝合金疲劳性能的影响,选取了R=0.5、0.3、0.1和-0.1四组应力比进行疲劳试验。结果表明,同一应力比下,随着峰值应力水平的增加,疲劳寿命逐渐降低;而同一峰值应力水平下,随着应力比的提高,疲劳寿命则呈现出逐渐升高的趋势。同时,使用扫描电子显微镜(Scanning Electron Microscopy,SEM)观察疲劳断口形貌发现,在峰值应力相同的情况下,裂纹萌生及扩展区的扇形面积随平均应力的增大而增大。最后,基于7075-T651铝合金疲劳实验结果,提出了一种考虑S-N-R的改进型预测模型,结果对比显示相较于其他模型,此模型在一定程度上对7075-T651铝合金具有更好的疲劳寿命预测效果。