The formation of precipitated austenite in 9% Ni steel exposed at the temperature of α+γ re- gion and its influence on impact tonghness at cryogenic temperature have been studied. Austenite-rich and ferrite-rich ban...The formation of precipitated austenite in 9% Ni steel exposed at the temperature of α+γ re- gion and its influence on impact tonghness at cryogenic temperature have been studied. Austenite-rich and ferrite-rich bands are formed during soaking because of the re-distribu- tion of elements of C,N and Ni.The former phase is enriched of Ni,Mn,C and N,while the latter one is relatively pure.Part of the austenite formed at intermediate temperatures trans- forms into martensite when the steel is cooled down to room temperature.The complex struc- ture which consists of fine martensite and austenite exhibits a moderate strength and high enough cryogenic toughness.The austenite enriched of C,N and Ni is still stable at the cryogenic temperature.The tearing ridges on the impact fracture surface is densely occupied by the precipitated austenite,elongated along the tearing direction.One of the important cause of the excellent eryogenic properties is that the precipitated austenite absorbs the impurities and thus purifies the matrix of the steel.展开更多
The intergranular cracking of 9% Ni cast steel seems mainly to relate to the segregation of contaminates H,S and P along boundaries.An addition of rare earth may eliminate the seg- regation of these contaminates along...The intergranular cracking of 9% Ni cast steel seems mainly to relate to the segregation of contaminates H,S and P along boundaries.An addition of rare earth may eliminate the seg- regation of these contaminates along grain boundaries and improve the binding force among boundaries,so as to reduce remarkably the intergranular cracking.展开更多
A kind of ceramic slurry was prepared and sprayed onto the surface of 9Ni steel at room temperature. The coating layer will not only reduce the depth of the formed Ni-enriched entanglement at high temperature but also...A kind of ceramic slurry was prepared and sprayed onto the surface of 9Ni steel at room temperature. The coating layer will not only reduce the depth of the formed Ni-enriched entanglement at high temperature but also have an excellent ability to resist oxidation of the 9Ni steel. Compared to bare specimen, the depths of the entanglement of the coated 9Ni specimen could be successfully reduced by 74.1% and the oxidation loss be decreased by 62.3% by heating at 1 250 ℃ for 60 min. In addition, the coated specimen indicates no trace of oxide pegs. It proves that the coating has outstanding improvement to internal oxidation resistance. Some characterization methods such as metalloscopy, XRD, XPS, SEM and EDX have been used to reveal a possible protective mechanism. The result shows that the coating layer reacts with the iron oxide to form Mg Fe2O4 on the surface of the coated specimen, which could provide a smaller diffusion coefficient rate of Fe ion. The coating with a low cost and easy implementation is promisingly applicable in the slab-reheating process of the 9Ni steel.展开更多
文摘The formation of precipitated austenite in 9% Ni steel exposed at the temperature of α+γ re- gion and its influence on impact tonghness at cryogenic temperature have been studied. Austenite-rich and ferrite-rich bands are formed during soaking because of the re-distribu- tion of elements of C,N and Ni.The former phase is enriched of Ni,Mn,C and N,while the latter one is relatively pure.Part of the austenite formed at intermediate temperatures trans- forms into martensite when the steel is cooled down to room temperature.The complex struc- ture which consists of fine martensite and austenite exhibits a moderate strength and high enough cryogenic toughness.The austenite enriched of C,N and Ni is still stable at the cryogenic temperature.The tearing ridges on the impact fracture surface is densely occupied by the precipitated austenite,elongated along the tearing direction.One of the important cause of the excellent eryogenic properties is that the precipitated austenite absorbs the impurities and thus purifies the matrix of the steel.
文摘The intergranular cracking of 9% Ni cast steel seems mainly to relate to the segregation of contaminates H,S and P along boundaries.An addition of rare earth may eliminate the seg- regation of these contaminates along grain boundaries and improve the binding force among boundaries,so as to reduce remarkably the intergranular cracking.
基金Funded by the Key Projects in the National Science &Technology Pillar Program in the Twelfth Five-year Plan Period(No.2012BAB08B04)the National Natural Science Foundation of China(No.51202249)
文摘A kind of ceramic slurry was prepared and sprayed onto the surface of 9Ni steel at room temperature. The coating layer will not only reduce the depth of the formed Ni-enriched entanglement at high temperature but also have an excellent ability to resist oxidation of the 9Ni steel. Compared to bare specimen, the depths of the entanglement of the coated 9Ni specimen could be successfully reduced by 74.1% and the oxidation loss be decreased by 62.3% by heating at 1 250 ℃ for 60 min. In addition, the coated specimen indicates no trace of oxide pegs. It proves that the coating has outstanding improvement to internal oxidation resistance. Some characterization methods such as metalloscopy, XRD, XPS, SEM and EDX have been used to reveal a possible protective mechanism. The result shows that the coating layer reacts with the iron oxide to form Mg Fe2O4 on the surface of the coated specimen, which could provide a smaller diffusion coefficient rate of Fe ion. The coating with a low cost and easy implementation is promisingly applicable in the slab-reheating process of the 9Ni steel.
