A two-dimensional（2D） 44 topological ZnⅡ coordination polymer {[Zn2Cl2（L）（4bpy）2]}∞（H2L = anthracene-9,10-dicarboxylic acid, 4bpy = 4,4ˊ-bipyridine） based on binuclear [Zn2Cl2] nodes has been synthesized an...A two-dimensional（2D） 44 topological ZnⅡ coordination polymer {[Zn2Cl2（L）（4bpy）2]}∞（H2L = anthracene-9,10-dicarboxylic acid, 4bpy = 4,4ˊ-bipyridine） based on binuclear [Zn2Cl2] nodes has been synthesized and characterized by IR, elemental analysis, X-ray powder diffraction and single-crystal X-ray diffraction analysis. Moreover, the luminescent properties of the correspon- ding compound have been briefly investigated.展开更多
A metal-organic framework （MOF） formulated as [Cd2（μ3-L）2（DMF）4]·H2O （CdL） [H2L=9-（pyridin-4-yl）- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condi...A metal-organic framework （MOF） formulated as [Cd2（μ3-L）2（DMF）4]·H2O （CdL） [H2L=9-（pyridin-4-yl）- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condition. Crystal structural analysis reveals that CalL features the layered 2D framework with L2- ligands as 3-connected nodes. The compound CdL emits blue-violet light with the narrow emission peak and the emission maximum at 414 nm upon excitation at the maximum excitation wavelength of 340 nm. The compound CalL has a similar emission spectrum curve to the free H2L ligand that indicates the emission of compound CdL should be originated from the coordinated L2 ligands.展开更多
基金Supported by the key project of Science,the Technology Department of Henan province(No.112102210371)the science and technology research projects of Education Department of Henan province(No.12B150003)
文摘A two-dimensional（2D） 44 topological ZnⅡ coordination polymer {[Zn2Cl2（L）（4bpy）2]}∞（H2L = anthracene-9,10-dicarboxylic acid, 4bpy = 4,4ˊ-bipyridine） based on binuclear [Zn2Cl2] nodes has been synthesized and characterized by IR, elemental analysis, X-ray powder diffraction and single-crystal X-ray diffraction analysis. Moreover, the luminescent properties of the correspon- ding compound have been briefly investigated.
文摘A metal-organic framework （MOF） formulated as [Cd2（μ3-L）2（DMF）4]·H2O （CdL） [H2L=9-（pyridin-4-yl）- 9H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide] was synthesized under solvothermal condition. Crystal structural analysis reveals that CalL features the layered 2D framework with L2- ligands as 3-connected nodes. The compound CdL emits blue-violet light with the narrow emission peak and the emission maximum at 414 nm upon excitation at the maximum excitation wavelength of 340 nm. The compound CalL has a similar emission spectrum curve to the free H2L ligand that indicates the emission of compound CdL should be originated from the coordinated L2 ligands.
