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Improved Neural Network Prediction on Electrochemistry Properties of AB_5-Based Alloy
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作者 刘杨 吴锋 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第S1期134-138,共5页
A traditional neural network was improved in two ways. An improved algorithm is associated into the network in order to enhance the optimization rate and predictability of the network. Two different methods were suppl... A traditional neural network was improved in two ways. An improved algorithm is associated into the network in order to enhance the optimization rate and predictability of the network. Two different methods were supplied to improve the generalization of the network. With this improved neural network, the properties of the AB_5-based hydrogen-storage alloys, the initial discharge capacity and capacity retention ratios after charge-discharge cycles, were predicted. A better prediction result was obtained by using the network. 展开更多
关键词 back propagation network LEVENBERG-MARQUARDT GENERALIZATION ab_5-based alloy property prediction
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Electrode Characteristics of MmNi_5-based Alloys for Nickel-Metal Hydride Batteries
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作者 Mingming GENG (Dept. of Precision Alloy, Central Iron & Steel Research Institute, Beijing, 100081. China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1994年第4期310-312,共3页
Negative electrodes of the Ni-metal hydride battery were made from hydrogen storage alloy Mm0.9Ti0. 1Ni3. 9Mn0.4Co0.4Al0.3 mod fied by coating with Ni or mixing with Co powder. The cell volume expansion of hexagonal s... Negative electrodes of the Ni-metal hydride battery were made from hydrogen storage alloy Mm0.9Ti0. 1Ni3. 9Mn0.4Co0.4Al0.3 mod fied by coating with Ni or mixing with Co powder. The cell volume expansion of hexagonal structure was about 12 % after coating with 11 % Ni on the alloy Surface,When this alloy was mixed with Co powder. the discharge capacity and the utilization efficiency of the hydrogen storage alloy increased. When the alloy was coated with 11 wt-% Ni and also mixed with 10 wt-% Co powder. the capacity decay for a small sealed cylindrical cell (AA size. 1 Ah) was only about 4 % after 200 cycles 展开更多
关键词 Ni Met Electrode Characteristics of MmNi5-based alloys for Nickel-Metal Hydride Batteries PVA
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Research of heat treatment of low-Co AB_5 type hydrogen storage alloys for MH-Ni batteries 被引量:6
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作者 GUOJinghong CHENDemin +2 位作者 LIUGuozhong YANGKe MAJun 《Rare Metals》 SCIE EI CAS CSCD 2003年第3期175-178,共4页
The effects of low-Co AB_5 type hydrogen storage alloys prepared by quenchingand annealing on the performances of MH-Ni batteries were investigated, and the characteristics ofthe low-Co AB_5 type hydrogen storage allo... The effects of low-Co AB_5 type hydrogen storage alloys prepared by quenchingand annealing on the performances of MH-Ni batteries were investigated, and the characteristics ofthe low-Co AB_5 type hydrogen storage alloys were compared with those of the high-Co AB_5 typehydrogen storage alloy as well. The results showed that the faster the cooling of the low-Cohydrogen storage alloy is, the better homogeneity of the chemical composition for the alloy and thelonger cycle life of the battery are, but the electrochemical discharge capacity and high-ratedischarge ability are reduced. The high-rate discharge ability and charge retention of MH-Nibatteries for the conventional as-cast annealed low-Co hydrogen storage alloy were superior to thosefor the rapidly quenched low-Co hydrogen storage alloy and the high-Co hydrogen storage alloy, buta little inferior in the cycle life. 展开更多
关键词 storage energy technology low-Co ab_5type hydrogen storage alloy ANNEALING MH-Ni battery
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AB_(5-x)型贮氢合金研究 被引量:4
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作者 王建军 侯岩 刘杰 《电源技术》 CAS CSCD 北大核心 2003年第2期85-86,91,共3页
研究了非化学计量比不包覆的AB5-x型贮氢合金x值的变化对合金的结构、比容量和放电温度特性的影响。结果表明,x值在0.06~0.48范围内时AB5-x型贮氢合金性能较好。非化学计量比可提高合金的比容量及其氢化物的稳定性,分解氢压平台在25℃... 研究了非化学计量比不包覆的AB5-x型贮氢合金x值的变化对合金的结构、比容量和放电温度特性的影响。结果表明,x值在0.06~0.48范围内时AB5-x型贮氢合金性能较好。非化学计量比可提高合金的比容量及其氢化物的稳定性,分解氢压平台在25℃时仅为0.01MPa;同时改善合金的低温放电效率,x=0.29时,255K下,1C放电效率达90%;合金结构主体相符合CaCu5构型。 展开更多
关键词 ab5-x型贮氢合金 放电效率 放电温度特性 负极材料 MH-NI电池
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LaNi_(5.5)Sn_(1.5)⁃C⁃Si合金优异的长期吸/放氢循环性能 被引量:1
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作者 陈健 顾晨宇 +7 位作者 杨宁 邱天 徐杰 陈翔宇 朱帅 焦齐统 潘炜 刘晶晶 《材料导报》 EI CAS CSCD 北大核心 2021年第4期4112-4117,共6页
AB_(5)型储氢合金在气固储氢、氢压缩、镍氢电池等领域具有广阔的应用前景,其循环稳定性是人们的一个关注点。本实验通过电弧熔炼的冶金方法,结合长时间退火的热处理工艺,制备了以CaCu_(5)相为主相,以富Ni/Sn相为次要相,以及少量C相和S... AB_(5)型储氢合金在气固储氢、氢压缩、镍氢电池等领域具有广阔的应用前景,其循环稳定性是人们的一个关注点。本实验通过电弧熔炼的冶金方法,结合长时间退火的热处理工艺,制备了以CaCu_(5)相为主相,以富Ni/Sn相为次要相,以及少量C相和Si相弥散分布的LaNi_(5.5)Sn_(1.5)⁃C⁃Si合金,并结合LaNi5基础合金,研究了LaNi_(5.5)Sn_(1.5)⁃C⁃Si合金在1000周吸/放氢循环过程中的储氢性能变化规律。结果表明,随着吸/放氢循环,合金的储氢容量略有降低,吸/放氢平台发生细微的倾斜,但以上变化远远小于LaNi_(5)合金循环1000周的变化。LaNi_(5.5)Sn_(1.5)⁃C⁃Si合金循环1000周的容量保持率高达98%,这可能是由于C和Si相的弥散分布对合金颗粒的粉化起到了缓冲作用。此外,LaNi_(5.5)Sn_(1.5)⁃C⁃Si合金具有良好的吸氢动力学性能,在383~423 K、2 MPa氢压下200 s内即可完全吸氢,合金良好的吸氢动力学性能可能与富Ni/Sn相的催化作用有关。 展开更多
关键词 储氢材料 ab_(5)型合金 储氢性能 循环稳定性
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制备工艺对无钴AB_(5-5.6)型合金相结构和电化学性能的影响
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作者 孙艳 罗永春 《金属功能材料》 CAS 2023年第1期85-96,共12页
用真空电弧熔炼、铜辊快甩(10 m/s)和热处理(1 273 K×15 h)制备稀土系CaCu5型过计量比合金,研究不同制备工艺下,合金La_(0.55)Ce_(0.25)Y_(0.2)(NiFeAlMn)_(5.0-5.6)相结构、微观组织、电化学性能的影响规律。结果表明,在不同的制... 用真空电弧熔炼、铜辊快甩(10 m/s)和热处理(1 273 K×15 h)制备稀土系CaCu5型过计量比合金,研究不同制备工艺下,合金La_(0.55)Ce_(0.25)Y_(0.2)(NiFeAlMn)_(5.0-5.6)相结构、微观组织、电化学性能的影响规律。结果表明,在不同的制备工艺下,计量比的增加都不会改变合金的相结构。常规熔铸合金晶粒由粗大的树枝晶和第二相组成;快淬合金都呈现出细小的等轴晶或柱状晶,且抑制了第二相的形成;退火合金使成分均匀化,第二相含量较铸态合金明显减少。合金电化学性能研究表明,不同的制备工艺下,随计量比的增加,合金的放电容量均降低,循环稳定性均提高,高倍率性能均降低。但对同计量比合金而言,循环稳定性依次为退火合金大于快淬合金大于铸态合金,而高倍率性能大小正好相反。综合电化学性能可知,过计量比有利于改善合金的循环稳定性,但会降低合金的动力学性能,所以合适的计量比结合适当的制备工艺可显著提高合金的综合性能。 展开更多
关键词 无钴ab_(5-5.6)储氢合金 制备过程 微观组织 相结构 电化学性能
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