Five catalytic processes and their catalysts will be introduced in my talk. Firstly,the demonstration test(3000 ton/a)results using a novel catalyst Co/SiO2 with egg-shell structure and the strategies for this catalys...Five catalytic processes and their catalysts will be introduced in my talk. Firstly,the demonstration test(3000 ton/a)results using a novel catalyst Co/SiO2 with egg-shell structure and the strategies for this catalyst preparation based on the issues from the mass transfer of produced wax from F-T synthesis will be discussed. Recent progresses on C2-oxygenate synthesis from syngas over a Rh/SiO2 catalyst and a 10 thousands ton/a demonstration test facility in China will be built in 2010 will be reported in the second section. A naphtha and diesel distillate which cut off the heavier end of S-F-A distribution direct synthesis with low methane selectivity from syngas over a Co/AC1 catalyst and a 10000 ton/a demonstration test with a bubble column slurry reactor will be talked about in this speech. A high α-alcohols of C2-C18 direct synthesis with more than 50 wt% selectivity and low methane and methanol selectivities from syngas over a Co2C/AC2 catalyst,a 3000 ton/a demonstration test with a bubble column slurry reactor and the primary fundamental understandings will be detailedly discussed in the forth section. In situ formation of homogeneous active sites on the surface of supported Rh heterogeneous catalysts and their application in hydroformylation of olefins will be introduced in fifth section.展开更多
It is already well known that availability of petroleum oil, as a world energy source, is running low. Much work has been done by experts to produce renewable energy, especially using vegetable oil as a raw material. ...It is already well known that availability of petroleum oil, as a world energy source, is running low. Much work has been done by experts to produce renewable energy, especially using vegetable oil as a raw material. Accordingly, this paper presents preparation and activity test of Cu catalyst using coconut shell activated carbon （AC） as a support, for conversion of n-pentanol and n-butanol to their alkenes as the first step of conversion of ethanol to biogasoline. This conversion is interesting due to any agriculture product containing sugar or starch can be converted to ethanol. Activated carbon was used as a catalyst support because this material is inert; hence, it would not yield unexpected side product, and pollution of environment with the used catalyst can be prevented because the used catalytic metal can easily be recovered. Results of the work showed that coconut shell carbon contained some metals, which disturbed in preparation catalyst by cation exchange process. Washing the carbon with ammonium acetate or HCI solution could reduce the metals content more compared to using water, with optimum concentration for ammonium acetate solution was 1.25 M. Application of Cu/AC in converting n-pentanol and n-butanol, based on qualitative analysis to the products using GLC, GC-MS, and FTIR, when n-pentanol and nitrogen gas were flowed into a reactor filled with Cu/AC catalyst, it could be converted to n-pentene with 200 ℃ as the optimal temperature. While when n-butanol and nitrogen gas were flowed into a reactor filled with more Cu/AC catalyst, the product was supposed to contain its aldehyde and butyl vinyl ether.展开更多
针对电动汽车充电电源额外热量产生影响电池使用寿命的问题,提出一种无电解电容隔离式单级双向AC/DC变换器。该变换器能有效阻止低频功率纹波注入电池单元,减少了额外热量的产生;同时电解电容的消除也大大提高了系统的可靠性。控制策略...针对电动汽车充电电源额外热量产生影响电池使用寿命的问题,提出一种无电解电容隔离式单级双向AC/DC变换器。该变换器能有效阻止低频功率纹波注入电池单元,减少了额外热量的产生;同时电解电容的消除也大大提高了系统的可靠性。控制策略方面,提出的一种四相控制器,不仅能使所有开关管实现零电压开关(Zero Voltage Switch,ZVS),并在导通损耗进行了性能优化。最后,通过PSIM仿真软件和实验样机,验证了理论分析的正确性和可行性。展开更多
Ac-Stark shift of atom levels is caused by an ac-electromagnetic field. As an electromagnetic wave, laser light does induce ac-Stark shift. It is proved experimentally that if the light is linearly polarized, the dyna...Ac-Stark shift of atom levels is caused by an ac-electromagnetic field. As an electromagnetic wave, laser light does induce ac-Stark shift. It is proved experimentally that if the light is linearly polarized, the dynamic polarizability changes with polarization direction. The polarization direction of the linearly-polarized laser is tuned by 720°, and the ac-Stark shifts of the 4S1/2,m=±1/2→3D5/2,m=±1/2 clock transitions in ^40Ca^＋ are measured in steps of 10°. The frequency shifts change with laser polarization in a periodical manner and have values opposite to each other.展开更多
This paper suggests a new model for the transmission of Transmission Control Protocol (TCP) traffic over IEEE 802.11 using the new features of IEEE 802.11ac. The paper examines the first step in this direction and as ...This paper suggests a new model for the transmission of Transmission Control Protocol (TCP) traffic over IEEE 802.11 using the new features of IEEE 802.11ac. The paper examines the first step in this direction and as such we first consider a single TCP connection, which is typical in a home environment. We show that when the IEEE 802.11ac MAC is aware of QoS TCP traffic, using Reverse Direction improves the TCP Goodput in tens of percentages compared to the traditional contention based channel access. In an error-free channel this improvement is 20% while in an error-prone channel the improvement reaches 60% also using blind retransmission of frames. In our operation modes we also assume the use in Two-Level aggregation scheme, the Automatic Repeat-Request (ARQ) protocol of the IEEE 802.11ac MAC layer, the data rates and the four Access Categories defined in this standard.展开更多
为实现配电网的柔性互联,提出一种基于多绕组变压器的直接式AC-AC型智能软开关(direct AC-AC soft open point,AC-SOP)拓扑结构,可在四象限内独立控制输出电压的幅值及相位,且无直流环节,拓扑灵活性较高。建立AC-SOP互联馈线环网的数学...为实现配电网的柔性互联,提出一种基于多绕组变压器的直接式AC-AC型智能软开关(direct AC-AC soft open point,AC-SOP)拓扑结构,可在四象限内独立控制输出电压的幅值及相位,且无直流环节,拓扑灵活性较高。建立AC-SOP互联馈线环网的数学模型,并结合所提出的AC-SOP的等效占空比算法,给出AC-SOP在潮流控制模式和恢复供电模式下的闭环解耦控制策略。最后,通过仿真验证所提AC-SOP在控制互联馈线环网潮流和恢复供电方面的有效性;通过搭建单相1kW子模块,验证了所提拓扑结构可实现电压幅值与相位的独立控制。展开更多
针对风电和光伏并网发电系统的功率波动问题,研究了一种基于双向DC/AC变换器的混合储能系统的动态控制策略。对含有超级电容器与蓄电池组的混合储能系统,通过双闭环控制器对变换器内部的电压电流进行控制,把波动变化较快的电流分量分配...针对风电和光伏并网发电系统的功率波动问题,研究了一种基于双向DC/AC变换器的混合储能系统的动态控制策略。对含有超级电容器与蓄电池组的混合储能系统,通过双闭环控制器对变换器内部的电压电流进行控制,把波动变化较快的电流分量分配给超级电容器,由蓄电池来响应波动变化较慢的电流分量。同时,控制系统将超级电容器的电压稳定在预设范围内。基于扩展卡尔曼滤波(Extended Kalman Filter,EKF)对蓄电池的荷电状态(State of Charge,SOC)进行控制,使其SOC值稳定在安全范围内并延长了蓄电池的使用寿命。通过仿真实验,验证了控制方法的有效性。展开更多
文摘Five catalytic processes and their catalysts will be introduced in my talk. Firstly,the demonstration test(3000 ton/a)results using a novel catalyst Co/SiO2 with egg-shell structure and the strategies for this catalyst preparation based on the issues from the mass transfer of produced wax from F-T synthesis will be discussed. Recent progresses on C2-oxygenate synthesis from syngas over a Rh/SiO2 catalyst and a 10 thousands ton/a demonstration test facility in China will be built in 2010 will be reported in the second section. A naphtha and diesel distillate which cut off the heavier end of S-F-A distribution direct synthesis with low methane selectivity from syngas over a Co/AC1 catalyst and a 10000 ton/a demonstration test with a bubble column slurry reactor will be talked about in this speech. A high α-alcohols of C2-C18 direct synthesis with more than 50 wt% selectivity and low methane and methanol selectivities from syngas over a Co2C/AC2 catalyst,a 3000 ton/a demonstration test with a bubble column slurry reactor and the primary fundamental understandings will be detailedly discussed in the forth section. In situ formation of homogeneous active sites on the surface of supported Rh heterogeneous catalysts and their application in hydroformylation of olefins will be introduced in fifth section.
文摘It is already well known that availability of petroleum oil, as a world energy source, is running low. Much work has been done by experts to produce renewable energy, especially using vegetable oil as a raw material. Accordingly, this paper presents preparation and activity test of Cu catalyst using coconut shell activated carbon （AC） as a support, for conversion of n-pentanol and n-butanol to their alkenes as the first step of conversion of ethanol to biogasoline. This conversion is interesting due to any agriculture product containing sugar or starch can be converted to ethanol. Activated carbon was used as a catalyst support because this material is inert; hence, it would not yield unexpected side product, and pollution of environment with the used catalyst can be prevented because the used catalytic metal can easily be recovered. Results of the work showed that coconut shell carbon contained some metals, which disturbed in preparation catalyst by cation exchange process. Washing the carbon with ammonium acetate or HCI solution could reduce the metals content more compared to using water, with optimum concentration for ammonium acetate solution was 1.25 M. Application of Cu/AC in converting n-pentanol and n-butanol, based on qualitative analysis to the products using GLC, GC-MS, and FTIR, when n-pentanol and nitrogen gas were flowed into a reactor filled with Cu/AC catalyst, it could be converted to n-pentene with 200 ℃ as the optimal temperature. While when n-butanol and nitrogen gas were flowed into a reactor filled with more Cu/AC catalyst, the product was supposed to contain its aldehyde and butyl vinyl ether.
文摘针对电动汽车充电电源额外热量产生影响电池使用寿命的问题,提出一种无电解电容隔离式单级双向AC/DC变换器。该变换器能有效阻止低频功率纹波注入电池单元,减少了额外热量的产生;同时电解电容的消除也大大提高了系统的可靠性。控制策略方面,提出的一种四相控制器,不仅能使所有开关管实现零电压开关(Zero Voltage Switch,ZVS),并在导通损耗进行了性能优化。最后,通过PSIM仿真软件和实验样机,验证了理论分析的正确性和可行性。
基金Project supported by the National Natural Science Foundation of China(Grant Nos.91336211,11634013,11622434,11474318,and 11504094)the Chinese Academy of Sciences(Grant No.XDB21030000)
文摘Ac-Stark shift of atom levels is caused by an ac-electromagnetic field. As an electromagnetic wave, laser light does induce ac-Stark shift. It is proved experimentally that if the light is linearly polarized, the dynamic polarizability changes with polarization direction. The polarization direction of the linearly-polarized laser is tuned by 720°, and the ac-Stark shifts of the 4S1/2,m=±1/2→3D5/2,m=±1/2 clock transitions in ^40Ca^＋ are measured in steps of 10°. The frequency shifts change with laser polarization in a periodical manner and have values opposite to each other.
文摘This paper suggests a new model for the transmission of Transmission Control Protocol (TCP) traffic over IEEE 802.11 using the new features of IEEE 802.11ac. The paper examines the first step in this direction and as such we first consider a single TCP connection, which is typical in a home environment. We show that when the IEEE 802.11ac MAC is aware of QoS TCP traffic, using Reverse Direction improves the TCP Goodput in tens of percentages compared to the traditional contention based channel access. In an error-free channel this improvement is 20% while in an error-prone channel the improvement reaches 60% also using blind retransmission of frames. In our operation modes we also assume the use in Two-Level aggregation scheme, the Automatic Repeat-Request (ARQ) protocol of the IEEE 802.11ac MAC layer, the data rates and the four Access Categories defined in this standard.
文摘为实现配电网的柔性互联,提出一种基于多绕组变压器的直接式AC-AC型智能软开关(direct AC-AC soft open point,AC-SOP)拓扑结构,可在四象限内独立控制输出电压的幅值及相位,且无直流环节,拓扑灵活性较高。建立AC-SOP互联馈线环网的数学模型,并结合所提出的AC-SOP的等效占空比算法,给出AC-SOP在潮流控制模式和恢复供电模式下的闭环解耦控制策略。最后,通过仿真验证所提AC-SOP在控制互联馈线环网潮流和恢复供电方面的有效性;通过搭建单相1kW子模块,验证了所提拓扑结构可实现电压幅值与相位的独立控制。
文摘针对风电和光伏并网发电系统的功率波动问题,研究了一种基于双向DC/AC变换器的混合储能系统的动态控制策略。对含有超级电容器与蓄电池组的混合储能系统,通过双闭环控制器对变换器内部的电压电流进行控制,把波动变化较快的电流分量分配给超级电容器,由蓄电池来响应波动变化较慢的电流分量。同时,控制系统将超级电容器的电压稳定在预设范围内。基于扩展卡尔曼滤波(Extended Kalman Filter,EKF)对蓄电池的荷电状态(State of Charge,SOC)进行控制,使其SOC值稳定在安全范围内并延长了蓄电池的使用寿命。通过仿真实验,验证了控制方法的有效性。
