The corrosion behaviors of ultra-high strength steel 30CrMnSiNi2A in sodium chloride solution were studied by weight loss and electrochemical methods. The morphology of corrosion products was observed using scanning e...The corrosion behaviors of ultra-high strength steel 30CrMnSiNi2A in sodium chloride solution were studied by weight loss and electrochemical methods. The morphology of corrosion products was observed using scanning electron microscopy（SEM） and the composition was analyzed using an energy dispersive spectroscopy（EDS） and X-Ray diffraction （XRD）. The experimental results showed that the corrosion came from pitting corrosion and the rust layer was composed of outer rust layer γ-FeOOH and inner rust layer Fe_2O_3 with a little β-FeOOH. The correlation between corrosion rate and test time accorded with exponential rule. The corrosion current measured by polarization methods was higher than that calculated by weight loss method after a long-time immersion, the main reason was that,β-FeOOH and γ-Fe_2O_3 transformed by γ-FeOOH led to overestimating corrosion rate. The processes of corrosion prophase were obtained from XRD and EIS results. The corrosion product, Fe（OH）_2 formed at the initial stage stayed at a non-steady state and then consequently transferred to γ-FeOOH, γ-Fe_2O_3 or β-FeOOH.展开更多
Spall fracture is a damage that occurs in a body when two rarefaction waves interact and produce enough dynamic tension breakage,and then the spall zone is founded in the interior of the target.Behavior of materials i...Spall fracture is a damage that occurs in a body when two rarefaction waves interact and produce enough dynamic tension breakage,and then the spall zone is founded in the interior of the target.Behavior of materials in the spall phenomenon is strongly affected by the stress level,time of loading and so on.The spall properties of 30CrMnSiNi2A steel loaded by a gas gun were investigated using the planar impact experiment and the two-wave structural profiles of free surface velocities of specimens were recorded by velocity interferometer system for any reflector （VISAR） techniques.The Hugoniot elastic limit （HEL）,spall strength,spall thickness and strain rate were obtained in the plate impact experiments of 30CrMnSiNi2A steel specimens with different thickness.The result indicates that the values of HEL and spall strength increase with the increasing strain rate.The dynamic spall fracture and corresponding microscopic mechanism of 30CrMnSiNi2A at different strain rates were evaluated through the fracture analysis and fractography using a scanning electron microscope （SEM）.展开更多
Two post weld heat treatments (PWHT), 900 ℃ oil quenched and low temperature tempered (PWHTA) and high temperature tempered and then 900 ℃ oil quenched and low temperature tempered (PWHTB), are employed to t...Two post weld heat treatments (PWHT), 900 ℃ oil quenched and low temperature tempered (PWHTA) and high temperature tempered and then 900 ℃ oil quenched and low temperature tempered (PWHTB), are employed to treat the weldment. Then the effect of two post weld heat treatment processes on the microstructure,mechanical properties and fracture toughness of electron beam welded joints of 30CrMnSiNi2A steel have been discussed. The results show that, after two kinds of PWHT the microstructure and hardness at every zones of EBW joints are nearly same. Although the welds have good mechanical properties, fracture toughness of both weld and heat affected zone (HAZ) is low, the CTOD values of welds are comparatively higher than that of HAZ. Microstructure and fracture toughness of two EBW joints have no evident differences.展开更多
The ablation tests on coated and uncoated Q235 B steel sheets were conducted under 30/80 μs impulse current simulating the lightning first return stroke current, aimed at further understanding the ablation characteri...The ablation tests on coated and uncoated Q235 B steel sheets were conducted under 30/80 μs impulse current simulating the lightning first return stroke current, aimed at further understanding the ablation characteristics of steel and investigating the impact of anti-corrosion coating on these characteristics. Ablation characteristics were investigated through the macroscopic morphology and x-ray diffraction patterns on the surface of damaged zones, the microstructure and micro Vickers hardness on the cross-section of damaged zones, and the maximum rear-face temperature of sample sheets. It can be concluded that the ablation areas of uncoated sheet consist of the melted layer and the heat-affect layer. These ablation areas include not only the area ablated directly by the arc root, of which the depth is deeper, but also the area forming due to the splashing of molten steel, of which the depth is shallower and decreases when the area’s distance from the arc attachment point increases. For coated sheet, coating materials have decomposed and evaporated forming an ablation pit on the sheet surface, in which the steel surface is exposed, and zinc filler of coating primer has infused into the exposed surface. The ablation diameter of uncoated sheet relates to the amplitude of the 30/80 μs impulse current in quadratic function, while for coated sheet, the relation is linear. In general, under the 30/80 μs impulse current, the coating can decrease the energy injected from the arc to the steel sheet and reduce the melting and splashing of steel. As a result, the ablation severity of uncoated sheet is severer than that of coated sheet.展开更多
The conditions of heating and cooling of piercing mandrels made of 4X5MFS steel of a three-roll screw mill 30-80 in the production of a closed cavity of steel vessels of small volume are determined.It is established t...The conditions of heating and cooling of piercing mandrels made of 4X5MFS steel of a three-roll screw mill 30-80 in the production of a closed cavity of steel vessels of small volume are determined.It is established that multiple cycles of heating up to 600℃ and cooling with water up to 80℃ for about 7 seconds/1 cycle lead to the formation of ridges,shells and cracks on the surface and in the volume of the tool.The loss of structural strength of the material leads to the breakdown of the mandrel during the stitching process.The technique and equipment of magnetic powder control have been developed to establish the dynamics of the growth of internal and external defects of mandrels.An equation is obtained that allows determining the increase in the number of defects in the sewing tool of a screw rolling mill.The technology of non-destructive testing made it possible to develop a rational plan for replacing the sewing mandrels,which allows for predicting the appearance of defects leading to a complex breakdown of the deforming tool at the NPO Pribor machine-building enterprise.展开更多
通过采用电弧炉出钢前在钢包中加入40%的锰铁,LF精炼前期调整成分,精炼中期和末期控制精炼渣碱度≥2.5,软吹氩搅拌,控制中间包钢水过热度≤35℃,连铸全程进行保护浇铸等工艺措施,贵阳特钢—炼钢厂成功进行了80Mn14钢(%:0.75～0.96C、13...通过采用电弧炉出钢前在钢包中加入40%的锰铁,LF精炼前期调整成分,精炼中期和末期控制精炼渣碱度≥2.5,软吹氩搅拌,控制中间包钢水过热度≤35℃,连铸全程进行保护浇铸等工艺措施,贵阳特钢—炼钢厂成功进行了80Mn14钢(%:0.75～0.96C、13.00～15.50Mn、≤0.80Si、≤0.070P、≤0.030S)的30 t EBT AF-35 t LF-260mm×300mm连铸机流程生产,产品各项性能均满足标准要求。展开更多
EA4T车轴钢(/%:0.22～0.29C、0.15～0.40Si、0.50～0.80Mn、≤0.020P、≤0.015S、0.90～1.20Cr、0.15～0.30Mo、≤0.06V)采用30 t EBT电弧炉40 t LF/VD-5 t铸锭工艺生产,并经8 MN油压机锻成300 mm x300mm钢坯,锻造比≥9。结果表明,EA4T...EA4T车轴钢(/%:0.22～0.29C、0.15～0.40Si、0.50～0.80Mn、≤0.020P、≤0.015S、0.90～1.20Cr、0.15～0.30Mo、≤0.06V)采用30 t EBT电弧炉40 t LF/VD-5 t铸锭工艺生产,并经8 MN油压机锻成300 mm x300mm钢坯,锻造比≥9。结果表明,EA4T钢[O]为(12-15)×10^(-6),[H]为(1.2～1.6)×10^(-6),经900～920℃淬火,600～650℃回火后,抗拉强度R_m721~745 N/mm^2,屈服强度R_eh463～470 N/mm^2,伸长率A_5 19.0%～19.5%,纵向冲击功53～73 J,横向冲击功36～41 J,组织为贝氏体一回火马氏体,10~7循环疲劳极限为350 N/mm^2。展开更多
Dynamic mechanical performances of 30CrMnSiNi2A alloy steel under high pressure of 1-15 GPa are studied with a one stage light gas gun. With the particle velocity ranging from 150 m/s to 300 m/s, the Hugoniot curve ...Dynamic mechanical performances of 30CrMnSiNi2A alloy steel under high pressure of 1-15 GPa are studied with a one stage light gas gun. With the particle velocity ranging from 150 m/s to 300 m/s, the Hugoniot curve of 30CrMnSiNi2A alloy steel is analyzed and obtained based on the experimental data and the parameters of equation of state are obtained by calculating. The Grüneisen equation of state can be determined through these parameters.展开更多
The effect of different microstructures of steel 30CrMnSiNi2A on the susceptibility of cadmium embrittlement has been studied and compared under the unique yield strength level. The results show that the tempered mart...The effect of different microstructures of steel 30CrMnSiNi2A on the susceptibility of cadmium embrittlement has been studied and compared under the unique yield strength level. The results show that the tempered martensite exhibits the maximum susceptibility to cadmium embrittlement,while the lower bainite shows the minimum susceptibility.The mixed microstructure of the above two has a susceptibility in between.展开更多
基金Funded by the National Natural Science Foundation of China(No.51171011)
文摘The corrosion behaviors of ultra-high strength steel 30CrMnSiNi2A in sodium chloride solution were studied by weight loss and electrochemical methods. The morphology of corrosion products was observed using scanning electron microscopy（SEM） and the composition was analyzed using an energy dispersive spectroscopy（EDS） and X-Ray diffraction （XRD）. The experimental results showed that the corrosion came from pitting corrosion and the rust layer was composed of outer rust layer γ-FeOOH and inner rust layer Fe_2O_3 with a little β-FeOOH. The correlation between corrosion rate and test time accorded with exponential rule. The corrosion current measured by polarization methods was higher than that calculated by weight loss method after a long-time immersion, the main reason was that,β-FeOOH and γ-Fe_2O_3 transformed by γ-FeOOH led to overestimating corrosion rate. The processes of corrosion prophase were obtained from XRD and EIS results. The corrosion product, Fe（OH）_2 formed at the initial stage stayed at a non-steady state and then consequently transferred to γ-FeOOH, γ-Fe_2O_3 or β-FeOOH.
基金Sponsored by State Key Laboratory of Explosion Science and Technology Foundation (ZDKT08-04)
文摘Spall fracture is a damage that occurs in a body when two rarefaction waves interact and produce enough dynamic tension breakage,and then the spall zone is founded in the interior of the target.Behavior of materials in the spall phenomenon is strongly affected by the stress level,time of loading and so on.The spall properties of 30CrMnSiNi2A steel loaded by a gas gun were investigated using the planar impact experiment and the two-wave structural profiles of free surface velocities of specimens were recorded by velocity interferometer system for any reflector （VISAR） techniques.The Hugoniot elastic limit （HEL）,spall strength,spall thickness and strain rate were obtained in the plate impact experiments of 30CrMnSiNi2A steel specimens with different thickness.The result indicates that the values of HEL and spall strength increase with the increasing strain rate.The dynamic spall fracture and corresponding microscopic mechanism of 30CrMnSiNi2A at different strain rates were evaluated through the fracture analysis and fractography using a scanning electron microscope （SEM）.
文摘Two post weld heat treatments (PWHT), 900 ℃ oil quenched and low temperature tempered (PWHTA) and high temperature tempered and then 900 ℃ oil quenched and low temperature tempered (PWHTB), are employed to treat the weldment. Then the effect of two post weld heat treatment processes on the microstructure,mechanical properties and fracture toughness of electron beam welded joints of 30CrMnSiNi2A steel have been discussed. The results show that, after two kinds of PWHT the microstructure and hardness at every zones of EBW joints are nearly same. Although the welds have good mechanical properties, fracture toughness of both weld and heat affected zone (HAZ) is low, the CTOD values of welds are comparatively higher than that of HAZ. Microstructure and fracture toughness of two EBW joints have no evident differences.
基金supported by National Natural Science Foundation of China (No. 51577117)
文摘The ablation tests on coated and uncoated Q235 B steel sheets were conducted under 30/80 μs impulse current simulating the lightning first return stroke current, aimed at further understanding the ablation characteristics of steel and investigating the impact of anti-corrosion coating on these characteristics. Ablation characteristics were investigated through the macroscopic morphology and x-ray diffraction patterns on the surface of damaged zones, the microstructure and micro Vickers hardness on the cross-section of damaged zones, and the maximum rear-face temperature of sample sheets. It can be concluded that the ablation areas of uncoated sheet consist of the melted layer and the heat-affect layer. These ablation areas include not only the area ablated directly by the arc root, of which the depth is deeper, but also the area forming due to the splashing of molten steel, of which the depth is shallower and decreases when the area’s distance from the arc attachment point increases. For coated sheet, coating materials have decomposed and evaporated forming an ablation pit on the sheet surface, in which the steel surface is exposed, and zinc filler of coating primer has infused into the exposed surface. The ablation diameter of uncoated sheet relates to the amplitude of the 30/80 μs impulse current in quadratic function, while for coated sheet, the relation is linear. In general, under the 30/80 μs impulse current, the coating can decrease the energy injected from the arc to the steel sheet and reduce the melting and splashing of steel. As a result, the ablation severity of uncoated sheet is severer than that of coated sheet.
文摘The conditions of heating and cooling of piercing mandrels made of 4X5MFS steel of a three-roll screw mill 30-80 in the production of a closed cavity of steel vessels of small volume are determined.It is established that multiple cycles of heating up to 600℃ and cooling with water up to 80℃ for about 7 seconds/1 cycle lead to the formation of ridges,shells and cracks on the surface and in the volume of the tool.The loss of structural strength of the material leads to the breakdown of the mandrel during the stitching process.The technique and equipment of magnetic powder control have been developed to establish the dynamics of the growth of internal and external defects of mandrels.An equation is obtained that allows determining the increase in the number of defects in the sewing tool of a screw rolling mill.The technology of non-destructive testing made it possible to develop a rational plan for replacing the sewing mandrels,which allows for predicting the appearance of defects leading to a complex breakdown of the deforming tool at the NPO Pribor machine-building enterprise.
文摘通过采用电弧炉出钢前在钢包中加入40%的锰铁,LF精炼前期调整成分,精炼中期和末期控制精炼渣碱度≥2.5,软吹氩搅拌,控制中间包钢水过热度≤35℃,连铸全程进行保护浇铸等工艺措施,贵阳特钢—炼钢厂成功进行了80Mn14钢(%:0.75～0.96C、13.00～15.50Mn、≤0.80Si、≤0.070P、≤0.030S)的30 t EBT AF-35 t LF-260mm×300mm连铸机流程生产,产品各项性能均满足标准要求。
文摘EA4T车轴钢(/%:0.22～0.29C、0.15～0.40Si、0.50～0.80Mn、≤0.020P、≤0.015S、0.90～1.20Cr、0.15～0.30Mo、≤0.06V)采用30 t EBT电弧炉40 t LF/VD-5 t铸锭工艺生产,并经8 MN油压机锻成300 mm x300mm钢坯,锻造比≥9。结果表明,EA4T钢[O]为(12-15)×10^(-6),[H]为(1.2～1.6)×10^(-6),经900～920℃淬火,600～650℃回火后,抗拉强度R_m721~745 N/mm^2,屈服强度R_eh463～470 N/mm^2,伸长率A_5 19.0%～19.5%,纵向冲击功53～73 J,横向冲击功36～41 J,组织为贝氏体一回火马氏体,10~7循环疲劳极限为350 N/mm^2。
文摘Dynamic mechanical performances of 30CrMnSiNi2A alloy steel under high pressure of 1-15 GPa are studied with a one stage light gas gun. With the particle velocity ranging from 150 m/s to 300 m/s, the Hugoniot curve of 30CrMnSiNi2A alloy steel is analyzed and obtained based on the experimental data and the parameters of equation of state are obtained by calculating. The Grüneisen equation of state can be determined through these parameters.
文摘The effect of different microstructures of steel 30CrMnSiNi2A on the susceptibility of cadmium embrittlement has been studied and compared under the unique yield strength level. The results show that the tempered martensite exhibits the maximum susceptibility to cadmium embrittlement,while the lower bainite shows the minimum susceptibility.The mixed microstructure of the above two has a susceptibility in between.
