Effect of bioflocculants on the coagulation activity of alum for removal of trihalomethane precursors from low turbid water

Reactivity of chlorine towards hydrophobic groups present in natural organic matter（NOM）provokes the formation of carcinogenic disinfection byproducts such as trihalomethanes in chlorinated water. The present study aimed to investigate the variations in coagulant activity of alum using two different bioflocculants（coagulant aid） namely, Moringa oleifera and Cyamopsis tetragonoloba for the removal of hydrophobic fractions of NOM and subsequent chlorine consumption by treated water. Effect of dual coagulants on trihalomethane surrogate parameters such as total organic carbon, dissolved organic carbon, UV absorbing materials and prominent hydrophobic species such as phenolic groups along with aromatic chromophores, polyhydroxy aromatic moiety have also been studied. The concept of differential spectroscopy and absorbance slope index has been employed to understand the combined effects of alum-bioflocculants on the reactivity of NOM with chlorine. Our result shows that the combination of alum and C. tetragonoloba is more efficient for reducing trihalomethane surrogates from chlorinated water as compared to M. oleifera. C. tetragonoloba elicited synchronized effects of sweep coagulation and particle bridging-adsorption which eventually facilitated efficient removal of hydrophobic fractions of NOM. The variation in the mechanistic approach of bioflocculants was due to the presence of cationic charge on M. oleifera and adhesive property of C. tetragonoloba.

Monitoring of Carbon Monoxide (CO) changes in the atmosphere and urban environmental indices extracted from remote sensing images for 932 Iran cities from 2019 to 2021

Carbon Monoxide(CO)is an important urban pollutant with a relation to 5,transition economies based on emission intensities.In this study,Sentinel-MODerate resolution Imaging Spectroradiometer(MODIS),and Landsat-8 images were used to investigate the variations of CO and urban environmental indices and the correlations between them.From the assessed correlations for 932 Iranian cities,it occurred that the assessed indices were all correlated.The highest CO levels were 0.031 in the spring of 2019 and 2020,whereas in 2021 it was equal to 0.030 in both the spring and winter,respectively.In 2019 and 2020 the maximum values of the Enhanced Vegetation Index(EVI)in the spring were 0.181 and 0.183.Exceptionally high Absorbing Aerosol Index(AAI)values of–0.834 and–1.0,along with Urban Index(UI)of 0.102 and 0.092,were correlated with recorded spikes in CO level,despite that these seasons’EVI values were not so abnormal.It was forecasted that in 2030 rises in the CO level by 13.2%in the winter and by 17.5%in the fall are expected,with the simultaneous increase of AAI by 204.5%and 980.2%,and Aerosol Optical Depth(AOD)by 27%and 5%in the winter and spring,respectively.

Thermo-oxidative degradation of Nylon 1010 films:Colorimetric evaluation and its correlation with material properties

The thermo-oxidative aging behaviors of Nylon 1010 films were studied by various analytical methods,such as measuring the chromaticity,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break of the aged films.The thermo-oxidative aging plots of the results obtained via these various methods at different temperatures are subjected to the time-temperature superposition analysis,which are found to be well superposed.The b＊ values are used as X axis and the other results,i.e.,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break,are used as V axis,respectively.The relationship between the b values and the other results is obtained,from which we can derive the changes of physical and chemical properties at different b＊ values.Since the b＊ values can be quickly determined by using a portable spectrophotometer,the on-line evaluation of the thermo-oxidative aging of Nylon 1010 can be realized.