The acid gas absorption in four potassium based amino acid salt solutions was predicted using artificial neural network(ANN). Two hundred fifty-five experimental data points for CO_2 absorption in the four potassium b...The acid gas absorption in four potassium based amino acid salt solutions was predicted using artificial neural network(ANN). Two hundred fifty-five experimental data points for CO_2 absorption in the four potassium based amino acid salt solutions containing potassium lysinate, potassium prolinate, potassium glycinate, and potassium taurate were used in this modeling. Amine salt solution's type, temperature, equilibrium partial pressure of acid gas, the molar concentration of the solution, molecular weight, and the boiling point were considered as inputs to ANN to prognosticate the capacity of amino acid salt solution to absorb acid gas. Regression analysis was employed to assess the performance of the network. Levenberg–Marquardt back-propagation algorithm was used to train the optimal ANN with 5:12:1 architecture. The model findings indicated that the proposed ANN has the capability to predict precisely the absorption of acid gases in various amino acid salt solutions with Mean Square Error(MSE) value of 0.0011, the Average Absolute Relative Deviation(AARD) percent of 5.54%,and the correlation coefficient(R^2) of 0.9828.展开更多
Lithium production in China mainly depends on hard rock lithium ores,which has a defect in resources,environment,and economy compared with extracting lithium from brine.This paper focuses on the research progress of e...Lithium production in China mainly depends on hard rock lithium ores,which has a defect in resources,environment,and economy compared with extracting lithium from brine.This paper focuses on the research progress of extracting lithium from spodumene,lepidolite,petalite,and zinnwaldite by acid,alkali,salt roasting,and chlorination methods,and analyzes the resource intensity,environmental impact,and production cost of industrial lithium extraction from spodumene and lepidolite.It is found that the sulfuric acid method has a high lithium recovery rate,but with a complicated process and high energy consumption;alkali and chlorination methods can directly react with lithium ores,reducing energy consumption,but need to optimize reaction conditions and safety of equipment and operation;the salt roasting method has large material flux and high energy consumption,so require adjustment of sulfate ratio to increase the lithium yield and reduce production cost.Compared with extracting lithium from brine,extracting lithium from ores,calcination,roasting,purity,and other processes consume more resources and energy;and its environmental impact mainly comes from the pollutants discharged by fossil energy,9.3-60.4 times that of lithium extracted from brine.The processing cost of lithium extraction from lepidolite by sulfate roasting method is higher than that from spodumene by sulfuric acid due to the consumption of high-value sulfate.However,the production costs of both are mainly affected by the price of lithium ores,which is less competitive than that of extracting lithium from brine.Thus,the process of extracting lithium from ores should develop appropriate technology,shorten the process flow,save resources and energy,and increase the recovery rate of related elements to reduce environmental impact and improve the added value of by-products and the economy of the process.展开更多
The studies of the enthalpic interaction parameters, hxy, hxyy and hxxy, of alkali metal halides with glycine, α-alanine and α-aminobutyric acid were published. Synthetic considering of the results of the studies, ...The studies of the enthalpic interaction parameters, hxy, hxyy and hxxy, of alkali metal halides with glycine, α-alanine and α-aminobutyric acid were published. Synthetic considering of the results of the studies, some inter- esting behaviors of the interaction between alkali metal halides and the α-amino acids have been found. The values of hxywill increase with the increase of the number of carbon atoms in alkyl side chain of amino acid molecules and decrease with the increase of the radius of the ions. The increasing of the salt’s effect on the hydrophobic hydration structure as the radii of anion is more obvious than as that of cation. The value of hxxy will regularly decrease with the increase of the number of carbon atoms in the alkyl chain of amino acids and linear increase with the increase of the radius. But the relation of hxxywith the radius of cations is not evident. The value of hxyywill increase with the increase of the radii of the ions. As the increase of the number of carbon atoms of amino acids, hxyyis decreas for the ions which have lager size and there is a maximum value at α-alanine for the ions which have small size. The behaviors of the interaction mentioned above were further discussed in view of electrostatic and structural interac- tions.展开更多
采用碱溶酸沉的方法提取南极磷虾分离蛋白(krill protein isolate,KPI),通过喷雾干燥和冷冻干燥的方式制备南极磷虾分离蛋白粉,并对这两种分离蛋白粉的结构及功能特性进行比较分析。结果表明:与冷冻干燥南极磷虾分离蛋白(freeze-dried k...采用碱溶酸沉的方法提取南极磷虾分离蛋白(krill protein isolate,KPI),通过喷雾干燥和冷冻干燥的方式制备南极磷虾分离蛋白粉,并对这两种分离蛋白粉的结构及功能特性进行比较分析。结果表明:与冷冻干燥南极磷虾分离蛋白(freeze-dried krill protein isolate,FKPI)相比,喷雾干燥南极磷虾分离蛋白(spray-dried krill protein isolate,SKPI)明度大,色泽较好;扫描电子显微镜结果显示,SKPI呈现出向内凹陷的不规则球状结构,而FKPI为薄层片状结构,SKPI的堆积密度高于FKPI;圆二色谱进一步表明,与KPI相比,SKPI和FKPI均呈现α-螺旋含量下降、β-转角含量增加的趋势,其中,SKPI的α-螺旋含量下降27.9%,β-转角含量增加12.2%,表明喷雾干燥后蛋白质的二级结构均从有规则的结构向无规则的结构转化;SKPI持水力、持油力、乳化稳定性和起泡性等均高于FKPI,而SKPI的溶解性、乳化性却比FKPI的差。可见,不同的干燥方式会改变南极磷虾分离蛋白的结构特性,并进一步影响其功能特性。展开更多
为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO_(4)·2H_(2)O)含量的新方法。实验采用4.5m M Na_(2)CO_(3)/1.4m M Na HCO_(3)淋洗液,在1.0m L·min^(-1)流速下对...为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO_(4)·2H_(2)O)含量的新方法。实验采用4.5m M Na_(2)CO_(3)/1.4m M Na HCO_(3)淋洗液,在1.0m L·min^(-1)流速下对硫酸盐进行测定,测定方法的相对标准偏差(RSD)为2.3%,加标回收率为91.0%~102%,检出限为0.003g·kg^(-1)。该方法操作简单、高效、准确度高,适用于工程勘察中大批量样品的测定。展开更多
文摘The acid gas absorption in four potassium based amino acid salt solutions was predicted using artificial neural network(ANN). Two hundred fifty-five experimental data points for CO_2 absorption in the four potassium based amino acid salt solutions containing potassium lysinate, potassium prolinate, potassium glycinate, and potassium taurate were used in this modeling. Amine salt solution's type, temperature, equilibrium partial pressure of acid gas, the molar concentration of the solution, molecular weight, and the boiling point were considered as inputs to ANN to prognosticate the capacity of amino acid salt solution to absorb acid gas. Regression analysis was employed to assess the performance of the network. Levenberg–Marquardt back-propagation algorithm was used to train the optimal ANN with 5:12:1 architecture. The model findings indicated that the proposed ANN has the capability to predict precisely the absorption of acid gases in various amino acid salt solutions with Mean Square Error(MSE) value of 0.0011, the Average Absolute Relative Deviation(AARD) percent of 5.54%,and the correlation coefficient(R^2) of 0.9828.
基金financially supported by the National Natural Science Foundation of China(71991484,41971265,72088101,and 71991480)the National Key R&D program of China(2021YFC2901801)。
文摘Lithium production in China mainly depends on hard rock lithium ores,which has a defect in resources,environment,and economy compared with extracting lithium from brine.This paper focuses on the research progress of extracting lithium from spodumene,lepidolite,petalite,and zinnwaldite by acid,alkali,salt roasting,and chlorination methods,and analyzes the resource intensity,environmental impact,and production cost of industrial lithium extraction from spodumene and lepidolite.It is found that the sulfuric acid method has a high lithium recovery rate,but with a complicated process and high energy consumption;alkali and chlorination methods can directly react with lithium ores,reducing energy consumption,but need to optimize reaction conditions and safety of equipment and operation;the salt roasting method has large material flux and high energy consumption,so require adjustment of sulfate ratio to increase the lithium yield and reduce production cost.Compared with extracting lithium from brine,extracting lithium from ores,calcination,roasting,purity,and other processes consume more resources and energy;and its environmental impact mainly comes from the pollutants discharged by fossil energy,9.3-60.4 times that of lithium extracted from brine.The processing cost of lithium extraction from lepidolite by sulfate roasting method is higher than that from spodumene by sulfuric acid due to the consumption of high-value sulfate.However,the production costs of both are mainly affected by the price of lithium ores,which is less competitive than that of extracting lithium from brine.Thus,the process of extracting lithium from ores should develop appropriate technology,shorten the process flow,save resources and energy,and increase the recovery rate of related elements to reduce environmental impact and improve the added value of by-products and the economy of the process.
基金Project supported by the National Natural Science Foundation of China (No. 29773011) and the Education Department of Henan Province (No.20011500012).
文摘The studies of the enthalpic interaction parameters, hxy, hxyy and hxxy, of alkali metal halides with glycine, α-alanine and α-aminobutyric acid were published. Synthetic considering of the results of the studies, some inter- esting behaviors of the interaction between alkali metal halides and the α-amino acids have been found. The values of hxywill increase with the increase of the number of carbon atoms in alkyl side chain of amino acid molecules and decrease with the increase of the radius of the ions. The increasing of the salt’s effect on the hydrophobic hydration structure as the radii of anion is more obvious than as that of cation. The value of hxxy will regularly decrease with the increase of the number of carbon atoms in the alkyl chain of amino acids and linear increase with the increase of the radius. But the relation of hxxywith the radius of cations is not evident. The value of hxyywill increase with the increase of the radii of the ions. As the increase of the number of carbon atoms of amino acids, hxyyis decreas for the ions which have lager size and there is a maximum value at α-alanine for the ions which have small size. The behaviors of the interaction mentioned above were further discussed in view of electrostatic and structural interac- tions.
文摘采用碱溶酸沉的方法提取南极磷虾分离蛋白(krill protein isolate,KPI),通过喷雾干燥和冷冻干燥的方式制备南极磷虾分离蛋白粉,并对这两种分离蛋白粉的结构及功能特性进行比较分析。结果表明:与冷冻干燥南极磷虾分离蛋白(freeze-dried krill protein isolate,FKPI)相比,喷雾干燥南极磷虾分离蛋白(spray-dried krill protein isolate,SKPI)明度大,色泽较好;扫描电子显微镜结果显示,SKPI呈现出向内凹陷的不规则球状结构,而FKPI为薄层片状结构,SKPI的堆积密度高于FKPI;圆二色谱进一步表明,与KPI相比,SKPI和FKPI均呈现α-螺旋含量下降、β-转角含量增加的趋势,其中,SKPI的α-螺旋含量下降27.9%,β-转角含量增加12.2%,表明喷雾干燥后蛋白质的二级结构均从有规则的结构向无规则的结构转化;SKPI持水力、持油力、乳化稳定性和起泡性等均高于FKPI,而SKPI的溶解性、乳化性却比FKPI的差。可见,不同的干燥方式会改变南极磷虾分离蛋白的结构特性,并进一步影响其功能特性。
文摘为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO_(4)·2H_(2)O)含量的新方法。实验采用4.5m M Na_(2)CO_(3)/1.4m M Na HCO_(3)淋洗液,在1.0m L·min^(-1)流速下对硫酸盐进行测定,测定方法的相对标准偏差(RSD)为2.3%,加标回收率为91.0%~102%,检出限为0.003g·kg^(-1)。该方法操作简单、高效、准确度高,适用于工程勘察中大批量样品的测定。
