Impact of climate change and human activities on the spatiotemporal dynamics of surface water area in Gansu Province, China

Understanding the dynamics of surface water area and their drivers is crucial for human survival and ecosystem stability in inland arid and semi-arid areas.This study took Gansu Province,China,a typical area with complex terrain and variable climate,as the research subject.Based on Google Earth Engine,we used Landsat data and the Open-surface Water Detection Method with Enhanced Impurity Control method to monitor the spatiotemporal dynamics of surface water area in Gansu Province from 1985 to 2022,and quantitatively analyzed the main causes of regional differences in surface water area.The findings revealed that surface water area in Gansu Province expanded by 406.88 km2 from 1985 to 2022.Seasonal surface water area exhibited significant fluctuations,while permanent surface water area showed a steady increase.Notably,terrestrial water storage exhibited a trend of first decreasing and then increasing,correlated with the dynamics of surface water area.Climate change and human activities jointly affected surface hydrological processes,with the impact of climate change being slightly higher than that of human activities.Spatially,climate change affected the'source'of surface water to a greater extent,while human activities tended to affect the'destination'of surface water.Challenges of surface water resources faced by inland arid and semi-arid areas like Gansu Province are multifaceted.Therefore,we summarized the surface hydrology patterns typical in inland arid and semi-arid areas and tailored surface water'supply-demand'balance strategies.The study not only sheds light on the dynamics of surface water area in Gansu Province,but also offers valuable insights for ecological protection and surface water resource management in inland arid and semi-arid areas facing water scarcity.

Correlation of periodontal inflamed surface area with glycated hemoglobin,interleukin-6 and lipoprotein(a)in type 2 diabetes with retinopathy

BACKGROUND The two-way relationship between periodontitis and type 2 diabetes mellitus(T2DM)is well established.Prolonged hyperglycemia contributes to increased periodontal destruction and severe periodontitis,accentuating diabetic complications.An inflammatory link exists between diabetic retinopathy(DR)and periodontitis,but the studies regarding this association and the role of lipoprotein(a)[Lp(a)]and interleukin-6(IL-6)in these conditions are scarce in the literature.AIM To determine the correlation of periodontal inflamed surface area(PISA)with glycated Hb(HbA1c),serum IL-6 and Lp(a)in T2DM subjects with retinopathy.METHODS This cross-sectional study comprised 40 T2DM subjects with DR and 40 T2DM subjects without DR.All subjects were assessed for periodontal parameters[bleeding on probing(BOP),probing pocket depth,clinical attachment loss(CAL),oral hygiene index-simplified,plaque index(PI)and PISA],and systemic parameters[HbA1c,fasting plasma glucose and postprandial plasma glucose,fasting lipid profile,serum IL-6 and serum Lp(a)].RESULTS The proportion of periodontitis in T2DM with and without DR was 47.5%and 27.5%respectively.Severity of periodontitis,CAL,PISA,IL-6 and Lp(a)were higher in T2DM with DR group compared to T2DM without DR group.Significant difference was observed in the mean percentage of sites with BOP between T2DM with DR(69%)and T2DM without DR(41%),but there was no significant difference in PI(P>0.05).HbA1c was positively correlated with CAL(r=0.351,P=0.001),and PISA(r=0.393,P≤0.001)in study subjects.A positive correlation was found between PISA and IL-6(r=0.651,P<0.0001);PISA and Lp(a)(r=0.59,P<0.001);CAL and IL-6(r=0.527,P<0.0001)and CAL and Lp(a)(r=0.631,P<0.001)among study subjects.CONCLUSION Despite both groups having poor glycemic control and comparable plaque scores,the periodontal parameters were higher in DR as compared to T2DM without DR.Since a bidirectional link exists between periodontitis and DM,the presence of DR may have contributed to the severity of periodontal destruction and periodontitis may have influenced the progression of DR.

High surface area biocarbon monoliths for methane storage

New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.

Influence of the Moho surface distribution on the oil and gas basins in China seas and adjacent areas

Owing to the strategic significance of national oil and gas resources,their exploration and production must be prioritized in China.Oil and gas resources are closely related to deep crustal structures,and Moho characteristics influence oil and gas distribution.Therefore,it is important to study the relationship between the variation of the Moho surface depth undulation and hydrocarbon basins for the future prediction of their locations.The Moho depth in the study area can be inverted using the Moho depth control information,the Moho gravity anomaly,and the variable density distribution calculated by the infinite plate.Based on these results,the influences of Moho characteristics on petroleum basins were studied.We found that the Moho surface depth undulation deviation and crustal thickness undulation deviation in the hydrocarbon-rich basins are large,and the horizontal gradient deviation of the Moho surface shows a positive linear relationship with oil and gas resources in the basin.The oil-bearing mechanism of the Moho basin is further discussed herein.The Moho uplift area and the slope zone correspond to the distribution of oil and gas fields.The tensile stress produced by the Moho uplift can form tensile fractures or cause tensile fractures on the surface,further developing into a fault or depression basin that receives deposits.The organic matter can become oil and natural gas under suitable chemical and structural conditions.Under the action of groundwater or other dynamic forces,oil and natural gas are gradually transported to the uplift or the buried hill in the depression zone,and oil and gas fields are formed under the condition of good caprock.The research results can provide new insights into the relationship between deep structures and oil and gas basins as well as assist in the strategic planning of oil and gas exploration activities.

Using satellite-derived land surface temperatures to clarify the spatiotemporal warming trends of the Alborz Mountains in northern Iran

The Alborz Mountains are some of the highest in Iran,and they play an important role in controlling the climate of the country’s northern regions.The land surface temperature(LST)is an important variable that affects the ecosystem of this area.This study investigated the spatiotemporal changes and trends of the nighttime LST in the western region of the Central Alborz Mountains at elevations of 1500-4000 m above sea level.MODIS data were extracted for the period of 2000-2021,and the Mann-Kendall nonparametric test was applied to evaluating the changes in the LST.The results indicated a significant increasing trend for the monthly average LST in May-August along the southern aspect.Both the northern and southern aspects showed decreasing trends for the monthly average LST in October,November,and March and an increasing trend in other months.At all elevations,the average decadal change in the monthly average LST was more severe along the southern aspect(0.60°C)than along the northern aspect(0.37°C).The LST difference between the northern and southern aspects decreased in the cold months but increased in the hot months.At the same elevation,the difference in the lapse rate between the northern and southern aspects was greater in the hot months than in the cold months.With increasing elevation,the lapse rate between the northern and southern aspects disappeared.Climate change was concluded to greatly decrease the difference in LST at different elevations for April-July.

Spatio-temporal Evolution Characteristics and Driving Forces of Winter Urban Heat Island:A Case Study of Rapid Urbanization Area of Fuzhou City,China

Under the influence of anthropogenic and climate change,the problems caused by urban heat island(UHI)has become increasingly prominent.In order to promote urban sustainable development and improve the quality of human settlements,it is significant for exploring the evolution characteristics of urban thermal environment and analyzing its driving forces.Taking the Landsat series images as the basic data sources,the winter land surface temperature(LST)of the rapid urbanization area of Fuzhou City in China was quantitatively retrieved from 2001 to 2021.Combing comprehensively the standard deviation ellipse model,profile analysis and GeoDetector model,the spatio-temporal evolution characteristics and influencing factors of the winter urban thermal environment were systematically analyzed.The results showed that the winter LST presented an increasing trend in the study area during 2001–2021,and the winter LST of the central urban regions was significantly higher than the suburbs.There was a strong UHI effect from 2001 to 2021with an expansion trend from the central urban regions to the suburbs and coastal areas in space scale.The LST of green lands and wetlands are significantly lower than croplands,artificial surface and unvegetated lands.Vegetation and water bodies had a significant mitigation effect on UHI,especially in the micro-scale.The winter UHI had been jointly driven by the underlying surface and socio-economic factors in a nonlinear or two-factor interactive enhancement mode,and socio-economic factors had played a leading role.This research could provide data support and decision-making references for rationally planning urban layout and promoting sustainable urban development.

Pollutant loads of surface runoff in Wuhan City Zoo, an urban tourist area

The pollutant loads of surface runoff in an urban tourist area have been investigated for two years in the Wuhan City Zoo, China. Eight sampling sites, including two woodlands, three animal yards, two roofs and one road, were selected for sampling and study. The results indicate that pollutants ranked in a predictable order of decreasing load （e.g. animal yard〉roof〉woodland〉road）, with animal yards acting as the key pollution source in the zoo. Pollutants were transported mainly by particulate form in runoff. Particulate nitrogen and particulate phosphorous accounted on average for 61%, 78% of total pollutant, respectively, over 13 monitored rainfall events. These results indicate the treatment practices should be implemented to improve particulate nutrient removal. Analysis of the M（V） curve indicate that no first flush effect existed in the surface runoff from pervious areas （e.g. woodland, animal ground yard）, whereas a first flush effect was evident in runoff from impervious surfaces （e.g. animal cement yard, roof, road）.

Preparation of High-Surface Area Nano-CeO_2 by Template-Assisted Precipitation Method

The high-surface area nano-CeO2 was prepared by Ce（NO3）3 by precipitation method, with surfactant cetyhrimethyl ammonium bromide （CTAB） as templating agent. The effects of the precipitating agents, reaction temperature, ageing time, and calcination temperature on the surface area, as well as the pore structure and the mean crystallite size of nano-CeO2 were studied. It was found that the reaction of Ce（NO3）3 with NaOH in the presence of CTAB at 90℃ for 12 h yieldsed a cerium oxide/surfaetant mixture, which after calcination at 400℃ resulted in high-surface area nano-CeO2. The mean crystallite size of CeO2 was approximately 6 nm, surface area was in excess of 200 m^2· g ^- 1, pore size was approximately 9 nm, and the pore distribution was concentrative. Moreover, the surface area can still reach 147 m^2·g^- 1 after calcination at 700 ℃, which showed the good thermal stability of the CeO2. The number of oxygen vacancies in the structure of CeO2 corresponded with the surface area of CeO2, and the high surface area was propitious to the formalion of oxygen vacancies.

CFD model simulation of bubble surface area flux in flotation column reactor in presence of minerals

Bubble surface area flux(S_b) is one of the main design parameter in flotation column that typically employed to describe the gas dispersion properties, and it has a strong correlation with the flotation rate constant. There is a limited information available in the literature regarding the effect of particle type,density, wettability and concentration on Sb. In this paper, computational fluid dynamics(CFD) simulations are performed to study the gas–liquid–solid three-phase flow dynamics in flotation column by employing the Eulerian–Eulerian formulation with k-e turbulence model. The model is developed by writing Fortran subroutine and incorporating then into the commercial CFD code AVL FIRE, v.2014.This paper studies the effects of superficial gas velocities and particle type, density, wettability and concentration on Sband bubble concentration in the flotation column. The model has been validated against published experimental data. It was found that the CFD model was able to predict, where the response variable as indicated by R-Square value of 0.98. These results suggest that the developed CFD model is reasonable to describe the flotation column reactor. From the CFD results, it is also found that Sb decreased with increasing solid concentration and hydrophobicity, but increased with increasing superficial gas velocity. For example, approximately 28% reduction in the surface area flux is observed when coal concentration is increased from 0 to 10%, by volume. While for the same solid concentration and gas flow rate, the bubble surface area flux is approximately increased by 7% in the presences of sphalerite.A possible explanation for this might be that increasing solid concentration and hydrophobicity promotes the bubble coalescence rate leading to the increase in bubble size. Also, it was found that the bubble concentration would decrease with addition of hydrophobic particle(i.e., coal). For instance, under the same operating conditions, approximately 23% reduction in the bubble concentration is predicted when the system was working with hydrophobic particles. The results presented are useful for understanding flow dynamics of three-phase system and provide a basis for further development of CFD model for flotation column.

Modified-EISA synthesis of mesoporous high surface area CeO_2 and catalytic property for CO oxidation

Mesoporous CeO2 particles with high surface area were synthesized using a modified evaporation-induced self assembly(EISA) method which combined citric acid as complexing agent.As-prepared powder and further thermal treatment samples were characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),selected area electron diffraction(SAED),Fourier transform infrared spectrometer(FTIR),thermogravimetry and differential thermal analysis(TG-DTA),Brunauer-Emmett-Teller(BET) and Barrett-Joyner-Ha...

Production Characteristics and the Control Factors of Surface Wells for Relieved Methane Drainage in the Huainan Mining Area

Based on the production data of a large number of surface drainage wells in the Huainan mining area,the present study shows that four types of typical production characteristics for relieved methane wells are recognized,of which the stable type for production and gas concentration is the most dominate,as determined by a comprehensive study on the volume and concentration of drained gases, as well as the stress changes of rocks influenced by mining.Some influence factors for the productive differences of the drainage wells were also been discussed.The results indicate that protective coal-seam mining has a significant effect on overlying strata,which promotes the development of pores and fractures of coal reservoirs for methane desorption and migration;however,the production and the stability of drainage wells are affected by deformation and damage of the overlying strata.The second distribution of strata stress is caused by mining engineering,and if the stress load is larger than the carrying capacity of the extraction well,the gas production would be influenced by the drainage well that has been damaged by rock movement.Furthermore,the case damage occurs first in the weak, lithologic interface by its special mechanical properties.The stability of drainage wells and the production status are also influenced by the different drilling techniques,uneven distribution of gas concentration,and combination of gob gas and methane from the protected layer.

Comprehensive Study on the Influence of Evapotranspiration and Albedo on Surface Temperature Related to Changes in the Leaf Area Index

Many studies have investigated the influence of evapotranspiration and albedo and emphasize their separate effects but ignore their interactive influences by changing vegetation status in large amplitudes. This paper focuses on the comprehensive influence of evapotranspiration and albedo on surface temperature by changing the leaf area index （LAD between 30^-90~N. Two LAI datasets with seasonally different amplitudes of vegetation change between 30^-90~N were used in the simulations. Seasonal differences between the results of the simulations are compared, and the major findings are as follows. （1） The interactive effects of evapotranspiration and albedo on surface temperature were different over different regions during three seasons [March-April-May （MAM）, June-July-August （JJA）, and September-October-November （SON）], i.e., they were always the same over the southeastern United States during these three seasons but were opposite over most regions between 30°-90°N during JJA. （2） Either evapotranspiration or albedo tended to be dominant over different areas and during different seasons. For example, evapotranspiration dominated almost all regions between 30^-90~N during JJA, whereas albedo played a dominant role over northwestern Eurasia during MAM and over central Eurasia during SON. （3） The response of evapotranspiration and albedo to an increase in LAI with different ranges showed different paces and signals. With relatively small amplitudes of increased LAI, the rate of the relative increase in evapotranspiration was quick, and positive changes happened in albedo. But both relative changes in evapotranspiration and albedo tended to be gentle, and the ratio of negative changes of albedo increased with relatively large increased amplitudes of LAI.

Optimum location of surface wells for remote pressure relief coalbed methane drainage in mining areas

Based on engineering tests in the Huainan coal mining area,we studied alternative well location to improve the performance of surface wells for remote pressure relief of coalbed methane in mining areas.The key factors,affecting location and well gas production were analyzed by simulation tests for similar material.The exploitation results indicate that wells located in various positions on panels could achieve relatively better gas production in regions with thin Cenozoic layers,low mining heights and slow rate of longwall advancement,but their periods of gas production lasted less than 230 days,as opposed to wells in regions with thick Cenozoic layers,greater mining heights and fast rates of longwall advancement.Wells near panel margins achieved relatively better gas production and lasted longer than centerline wells.The rules of development of mining fractures in strata over panels control gas production of surface wells.Mining fractures located in areas determined by lines of compaction and the effect of mining are well developed and can be maintained for long periods of time.Placing the well at the end of panels and on the updip return airway side of panels,determined by lines of compaction and the effect of mining,would result in surface wells for remote pressure relief CBM obtaining their longest gas production periods and highest cumulative gas production.

High specific surface area porous graphene grids carbon as anode materials for sodium ion batteries

Although great accomplishments of functional material synthesis have been achieved in sodium ion batteries(SIBs)recently,there are still numerous challenges and problems in preparing carbon-based materials with porous architectures and enough lattice distance for Na^+insertion.Herein we report a templated strategy to synthesize 3D porous graphene girds(PGGs)consisting of several stacking graphene structure with ultrahigh surface area and hierarchical connected structure by employing Ag nanoparticles(NPs).The Ag NPs will regenerate for decreasing the experimental cost,also in line with principles of green chemistry and environmentally friendly strategy.The PGGs obtain advanced specific capacity of160 m A h g^(-1)at current density of 50 m A h g^(-1).Moreover,112 mA h g^(-1)capacity can be gained at 1 A h g^(-1)during 1000 cycles.Due to their porous architecture,ultrahigh surface area and low amorphous graphited structure,PGGs electrode showed the excellent electrochemical performance in high rate capability.

Nickel catalysts supported on MgO with different specific surface area for carbon dioxide reforming of methane

In this paper, three kinds of MgO with different specific surface area were prepared, and their effects on the catalytic performance of nickel catalysts for the carbon dioxide reforming of methane were investigated. The results showed that MgO support with the higher specific surface area led to the higher dispersion of the active metal, which resulted in the higher initial activity. On the other hand, the specific surface area of MgO materials might not be the dominant factor for the basicity of support to chemisorb and activate CO2, which was another important factor for the performance of catalysts. Herein, Ni/MgO(CA) catalyst with proper specific surface area and strong ability to activate CO2exhibited stable catalytic property and the carbon species deposited on the Ni/MgO(CA) catalyst after 10 h of reaction at 650 ?C were mainly activated carbon species.

Preparation and Characterization of Porous Yttrium Oxide Powders with High Specific Surface Area

The porous cubic yttrium oxides with high specific surface area were prepared yttrium nitrate and its complex formed with methyl salicylate. The specific surface area by the explosive decomposition of and properties of powders synthesized at various temperatures were characterized using BET, X-ray diffraction （XRD）, infrared spectra （IR）, and scanning electron microscopy （SEM）. The results indicate that the highest specific surface area is found to be 65.37 m^2·g^-1 at the calcination temperature of 600 ℃, and then decreases to 20.33 m2· g^- 1 with the calcination temperature rising from 600 to 900 ℃. The powders show strong surface activity for adsorping water and carbon dioxide in air, which also decreases with the rising calcination temperature. The drop both on the surface area and surface activity of samples at higher temperatures may be due to pore-narrowing（sintering） effects.

Surface area processing in GIS for different mountain regions

Surface area is a fundamental parameter derived from terrain analysis in geographical information systems （GIS） for modeling the real world. Therefore, an evaluation of the techniques implemented by GIS models is important in order to obtain reliable area measurements. The study compares two raster-based methods with a TIN-based （triangulated irregular network） method for surface area approximation using a digital elevation model （DEM） with 25 m × 25 m resolution in six mountain regions of Shandong Province, China. Raster-based method I calculates surface-area grids from DEMs directly. Eight 3-dimensional triangles connecting the center point of each cell with the center points of the eight surrounding cells are generated and then the areas of the portions of each triangle that lay within the cell boundary are calculated and summed. Raster-based method Ⅱ produces the surface area of each cell directly from the pixel size and the slope value for the pixel. The results demonstrate that the surface areas calculated by rasterbased method I are equal to those of the TIN-based method. The results of raster-based method Ⅱ are the lowest but the difference in areas between the two raster-based methods decreases with the decrease in terrain complexity. Compared to the method with TINs, raster-based method II can do better because it has some advantages, such as neighborhood analysis, more consistent output and faster processing speed. The results also demonstrate that the difference between surface and horizontal areas should be considered if more than 30% of the area of a region has slopes steeper than 18.2 degrees.

Re-assessing Vegetation Carbon Storage and Emissions from Land Use Change in China Using Surface Area

Land surface area estimation can provide basic information for accurately estimating vegetation carbon storage under complex terrain. This study selected China, a country dominated by mountains, as an example, and calculated terrestrial vegetation carbon storage(VCS) for 2000 and 2015 using land surface area and traditional ellipsoid area. The land surface area is estimated by a triangular network on the high precision digital elevation model.The results showed that: 1) The VCS estimated by the surface area measurement in 2000 and 2015 were 0.676 and0.692 Pg C(1 Pg = 1015 g) higher than the VCS calculated using the ellipsoid area, respectively. 2) As the elevation increases, the differences between VCS estimated by surface area measurement and ellipsoid area measurement are expanding. Specially, a clear gap was present starting from an elevation of 500 m, with the relative error exceeds8.99%. 3) The total amount of carbon emitted due to land use change reached 0.114 Pg C. The conversions of forestland and grassland to other land use type are the main reasons of the loss of vegetation carbon storage, resulting in a total amount of biomass carbon storage decreased by 0.942 and 0.111 Pg C, respectively. This study was a preliminary exploration of incorporating land surface area as a factor in resource estimation, which can help more accurately understand the status of resources and the environment in the region.

Effect of reactive surface area of minerals on mineralization trapping of CO_2 in saline aquifers

The reactive surface area, an important parameter controlling mineral reactions, affects the amount of mineralization trapping of CO2 which affects the long-term CO2 storage. The effect of the reactive surface area on the mineralization trapping of CO2 was numerically simulated for CO2 storage in saline aquifers. Three kinds of minerals, including anorthite, calcite and kaolinite, are involved in the mineral reactions. This paper models the relationship between the specific surface area and the grain diameter of anorthite based on experimental data from literature （Brantley and Mellott, 2000）. When the reactive surface areas of anorthite and calcite decrease from 838 to 83.8 m^2/m^3, the percentage of mineralization trapping of CO： after 500 years decreases from 11.8% to 0.65%. The amount of dissolved anorthite and the amounts of precipitated kaolinite and calcite decrease significantly when the reactive surface areas ofanorthite and calcite decrease from 838 to 83.8 m2/m3. Calcite is initially dissolved in the brine and then precipitates during the geochemical reactions between CO2-H20 and the minerals. Different reactive surface areas of anorthite and calcite lead to different times from dissolution to precipitation. The pH of the brine decreases with decreasing reactive surface areas of anorthite and calcite which influences the acidity of the saline aquifer. The gas saturation between the upper and lower parts of the saline aquifer increases with decreasing reactive surface areas of anorthite and calcite. The mass density distribution of brine solution shows that the CO2^＋brine solution region increases with decreasing reactive surface areas ofanorthite and calcite.

Time function of surface subsidence based on Harris model in mined-out area

The surface subsidence is a common environmental hazard in mined-out area. Based on careful analysis of the regularity of surface subsidence in mined-out area, we proposed a new time function based on Harris curve model in consideration of the shortage of current surface subsidence time functions. By analyzing the characteristics of the new time function, we found that it could meet the dynamic process, the velocity change process and the acceleration change process during surface subsidence. Then its rationality had been verified through project cases. The results show that the proposed time function model can give a good reflection of the regularity of surface subsidence in mined-out area and can accurately predict surface subsidence. And the prediction data of the model are a little greater than measured data on condition of proper measured data quantity, which is safety in the engineering. This model provides a new method for the analysis of surface subsidence in mined-out area and reference for future prediction, and it is valuable to engineering application.