A new 3D Ag（I） coordination polymer {[Ag（AZDB）（0.5）（bpe）（0.5）]·H2O}n（1） has been papared by azobenzene-3,3？-dicarboxylicate（H2AZDB）, 1,2-bis（4-pyridyl）ethylene（bpe） and silver salts via hydroth...A new 3D Ag（I） coordination polymer {[Ag（AZDB）（0.5）（bpe）（0.5）]·H2O}n（1） has been papared by azobenzene-3,3？-dicarboxylicate（H2AZDB）, 1,2-bis（4-pyridyl）ethylene（bpe） and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum（IR）, powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）. The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal（4, 6）-connected fsc net with a（4^4·6^10·8）（4^4·6^2） topology.Moreover, the photoluminescent properties have also been discussed.展开更多
基金supported by the NSF of Hubei Province(No.2014CFB277)the Open Foundation of Ministry of Education Key Laboratory of Synthetic and Natural Functional Molecular Chemistry(No.338080057)
文摘A new 3D Ag（I） coordination polymer {[Ag（AZDB）（0.5）（bpe）（0.5）]·H2O}n（1） has been papared by azobenzene-3,3？-dicarboxylicate（H2AZDB）, 1,2-bis（4-pyridyl）ethylene（bpe） and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum（IR）, powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）. The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal（4, 6）-connected fsc net with a（4^4·6^10·8）（4^4·6^2） topology.Moreover, the photoluminescent properties have also been discussed.
