Air-sea Interaction of Typhoon Sinlaku (2002) Simulated by the Canadian MC2 Model

Three experiments for the simulation of typhoon Sinlaku （2002） over the western North Pacific are performed in this study by using the Canadian Mesoscale Compressible Community （MC2） atmospheric model. The objective of these simulations is to investigate the air-sea interaction during extreme weather conditions, and to determine the sensitivity of the typhoon evolution to the sea surface temperature （SST） cooling induced by the typhoon. It is shown from the three experiments that the surface heat fluxes have a substantial influence on the slow-moving cyclone over its lifetime. When the SST in the East China coastal ocean becomes 1℃ cooler in the simulation, less latent heat and sensible heat fluxes from the underlying ocean to the cyclone tend to reduce the typhoon intensity. The cyclone is weakened by 7 hPa at the time of its peak intensity. The SST cooling also has impacts on the vertical structure of the typhoon by weakening the warm core and drying the eye wall. With a finer horizontal resolution of （1/6）° × （1/6）°, the model produces higher surface wind, and therefore more surface heat fluxes are emitted from the ocean surface to the cyclone, in the finer-resolution MC2 grid compared with the relatively lower resolution of 0.25° × 0.25° MC2 grid.

Unstable Tropical Air-Sea Interaction Waves and Their Physical Mechanisms

In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the atmosphere and the ocean. There exist two kinds of air-sea interaction waves in the coupled model, that is, the high-frequency fast waves and the low-frequency slow waves. The phase speed of the fast waves is westward and the frequencies are close to those of the equatorial Rossby waves in the atmosphere. The slow waves propagate westward in the part of short wavelengths and eastward in that of long wavelengths. There exist instabilities for both the westward and eastward propagating slow waves. If the fast waves are filtered off, there is little effect on the slow waves which have great influence on the long range process in the tropical air-sea coupled system. According to the tropical air-sea interaction waves we obtain here, a possible explanation to the propagating process of ENSO events is given.

CISK Kelvin Wave with Evaporation-Wind Feedbackand Air-Sea Interaction-A Further Study ofTropical Intraseasonal Oscillation Mechanism

The wave-CISK (cumulus convection heating feedback), the air-sea interaction and the evaporation-wind feedback are together introduced into a simple theoretical model, in order to understand their effect on driving tropical atmospheric intraseasonal oscillation (ISO). The results showed that among the introduced dynamical processes the wave-CISK plays a major role in reducing phase speed of the wave to be closer to the observed tropical ISO. While the evaporation-wind feedback plays a major role in unstabilizing the wave. The air-sea interaction has certain effect on slowing down the phase speed of the wave. Therefore, the wave-CISK and evaporation-wind feedback can be regarded as fundamental dynamical mechanism of the tropical ISO. This study also shows that since the effects of the evaporation-wind feedback and the air-sea interaction were introduced, the excited wave is zonally dispersive, which can dynamically explain the activity feature of the observed ISO in the tropical atmosphere very well.

Effect of Decadal Changes in Air-Sea Interaction on the Climate Mean State over the Tropical Pacific

Collaboration of interannual variabilities and the climate mean state determines the type of E1 Nifio. Recent studies highlight the impact of a La Nifia-like mean state change, which acts to suppress the convection and low-level convergence over the central Pacific, on the predominance of central Pacific （CP） E1 Nifio in the most recent decade. However, how interannual variabilities affect the climate mean state has been less thoroughly investigated. Using a linear shallow-water model, the ef- fect of decadal changes of air-sea interaction on the two types of El Nifio and the climate mean state over the tropical Pacific is examined. It is demonstrated that the predominance of the eastem Pacific （EP） and CP E1 Nino is dominated mainly by relationships between anomalous wind stresses and sea surface temperature （SST）. Furthermore, changes between air-sea interactions from 1980-98 to 1999-2011 prompted the generation of the La Ninalike pattern, which is similar to the background change in the most recent decade.

Progress of Large-Scale Air-Sea Interaction Studies in China

This paper summarizes the progress of large-scale air-sea interaction studies that has been achieved in China in the four-year period from July 1998 to July 2002, including seven aspects in the area of the air-sea interaction, namely air-sea interaction related to the tropical Pacific Ocean, monsoon-related air-sea interaction, air-sea interaction in the north Pacific Ocean, air-sea interaction in the Indian Ocean, air-sea interactions in the global oceans, field experiments, and oceanic cruise surveys. However more attention has been paid to the first and the second aspects because a large number of papers in the reference literature for preparing and organizing this paper are concentrated in the tropical Pacific Ocean, such as the ENSO process with its climatic effects and dynamics, and the monsoon-related air-sea interaction. The literature also involves various phenomena with their different time and spatial scales such as intraseasonal, annual, interannual, and interdecadal variabilities in the atmosphere/ocean interaction system, reflecting the contemporary themes in the four-year period at the beginning of an ara from the post-TOGA to CLIVAR studies. Apparently, it is a difficult task to summarize the great progress in this area, as it is extracted from a large quantity of literature, although the authors tried very hard.

SEASONAL DEPENDENCE OF LOCAL AIR-SEA INTERACTION OVER THE TROPICAL WESTERN PACIFIC WARM POOL

Based on the air-sea interface heat fluxes and related meteorological variables datasets recently released by Objectively Analyzed Air-Sea Fluxes(OA Flux) Project of Woods Hole Oceanographic Institution,as well as the outgoing longwave radiation and surface wind datasets from National Oceanic and Atmospheric Administration,the seasonal dependence of local air-sea interaction over the tropical western Pacific warm pool(referred to the region(1o-6oN,144o-154oE)) is revealed and the probable impacts of remote forcing on the air-sea interaction are examined.The results indicated the dominance of oceanic forcing with the significant impact of ENSO in March and that of atmospheric feedback without notable influence of remote forcing in June.While the interannual variability of sea surface temperature anomaly(SSTA) is larger than that of SSTA tendency when oceanic forcing is dominant,the opposite is true when atmospheric feedback is dominant.The magnitude of the oceanic forcing of the atmosphere tends to decrease in March with the occurrence of ENSO,though ENSO has little influence on the atmospheric feedback to the ocean in June.The local air-sea interaction is substantially the same before and after the removal of the effect of Indian Oceanic Dipole.The reduction of shortwave radiation fluxes into the western Pacific warm pool,due to the enhanced overlaying convection in March associated with ENSO,leads to the decline of SST tendency that will weaken the oceanic forcing of the atmosphere.

COUPLING PATTERNS OF AIR-SEA INTERACTION AT MIDDLE & LOWER LATITUDES AND THEIR INTERDECADAL OSCILLATION

Diagnostic studies have been done of the seasonal and interdecadal variations of the coupling patterns for the air-sea interactions in the northern Pacific region, by using 500-hPa geopotential height field of the Northern Hemisphere and monthly mean SST field of northern Pacific Ocean (1951 ~ 1995) and with the aid of the Singular Value Decomposition (SVD) technique. The results show that: (1) The distribution patterns of SVD, which link with the El Ni駉 (or La Ni馻) events, are important in the interaction between the atmosphere and ocean while the atmosphere, coupling with it, varies like the PNA teleconnection does. The coupling of air-sea interactions is the highest in the winter (January), specifically linking the El Ni駉 event with the PNA pattern in the geopotential height field. Of the four seasons, summer has the poorest coupling when the 500-hPa geopotential height field corresponding to the La Ni馻 event displays patterns similar to the East Asian-Pacific one (PJ). The spring and autumn are both transitional and the coupling is less tight in the autumn than in the spring. (2) Significant changes have taken place around 1976 in the pattern of air-sea coupling, with the year抯 winter having intensified PNA pattern of 500-hPa winter geopotential height field, deepened Aleutian low that moves southeast and the summer following it having outstanding PJ pattern of 500-hPa geopotential height field, which is not so before 1976.

THE IMPACT OF AIR-SEA INTERACTIONS ON TYPHOON STRUCTURE

In this work,the results of a coupled experiment and an uncoupled experiment conducted in one of our former works are used to analyze the impact of air-sea interactions on the structure of typhoons.Results reveal that typhoon-induced SST decreases to reduce the latent heat fluxes transporting from the ocean to the atmosphere and cause the flux of sensible heat to transfer downward from the atmosphere to the ocean.Such SST reduction also has remarkable impacts on the typhoon structure by making the typhoon more axisymmetric,especially in the middle and high levels.This study also analyzes the basic characteristics of symmetric typhoon structure.

THE ROLE OF MERIDIONAL WIND STRESS IN THE TROPICAL UNSTABLE AIR-SEA INTERACTION

With a simple tropical coupled ocean-atmosphere model, this paper presents an analysis aiming to understand the relative role of the meridional and zonal wind stresses in the tropical unstable air-sea interaction. The roles of the zonal wind stress, the meridional wind stress and the both are considered respectively into the coupled system. It is demonstrated that the meridional component of the wind stress does not lead to any instability under the local thermal balance assumption, but it does lead to a weak instability under the sea surface temperature advection assumption. Unstable air-sea interaction is dominated by the zonal component of the wind stress, suggesting that ignoring the meridional wind stress is approximately feasible in studying the tropical unstable air-sea interaction.

SPATIAL PATTERN OF THE AIR-SEA INTERACTION NEAR THE SOUTH CHINA SEA DURING WINTER

This paper delineates the coupled and principal pattrns of sea surface temperture (SST) and surface wind near the South China Sea (SCS), and discusses the mechanisms of air-sea coupling near the SCS and their asspcoiation with the Asian monsoon. Singular value decomposition (SVD) and single field principal component analysis (PCA) are applied to the so and wind anomalies from the 1979 - 1995 NCEP/NCAR reanalysis data.The leading SVD mode explains a predominant amount of squared covariance between the SST and zonal or meridional wind. During winte, the meridional wind’s relation to the SST is betterr than the relation of zonal wind to ase. Despite the large magnitude of the squared covariance between SST and zonalor meridional wind, the spatial patterns of the first mode of SVD between the SST and meridional wind are similar. They both exhibit ellipe-shaped variance with the center near the SCS and a northeast-southwest oriented main axis. The spatial patterne of the leading mode of SVD between the SST and zonal wind are also similar to a certain degree. The zonal wind is not as closely correlated to the SST as the meridional wind is. These results suggest that the meridional wind and SST are stronly coupled during the winter season, and that there is a certain coupled action system in the SCS.

KEY AREAS OF AIR-SEA INTERACTION IN GLOBAL OCEANS AND STUDY OF THE CLIMATOLOGICAL FEATURES

Seven key areas of air-sea interaction in the global oceans are determined by comprehensive analysis of the global data of monthly mean sea surface temperature (SST), surface wind, temperature, humidity, sea surface sensible heat and latent heat fluxes. The time-lag correlation between SST and each atmospheric element in each key area are focally analyzed to expose the same and the different features of air-sea interaction in different key areas. The results show that the air-sea thermal interaction is strong in each area, SST, tem-perature and humidity can be fairly replaced with one another, particularly in the central eastern Pacific and the south India Ocean. The dynamic effect on SST is different in different areas and in the central western Pacific such effect is more important. The correlation between sensible heat, latent heat and SST is more significant in the eastern Pacific, the western Pacific and the two major monsoon areas — the northwestern Pacific and the south India Ocean. By analyzing the sustainable correlation probability of SST and every atmospheric element in each key area, we further know that the anomalies of which element, in which area and in which period are well sustained or easily destroyed. This is beneficial not only to prediction, but also to discussion of the physical mechanism of air-sea interaction.

IMPACT OF AIR-SEA INTERACTION ON THE GENESIS OF TROPICAL INCIPIENT VORTEX OVER SOUTH CHINA SEA： A CASE STUDY

Based on 6-hourly sensible heat flux and latent heat flux from the NCEP Climate Forecast System Reanalysis(CFSR) and circulation data from the Japanese 25-year Reanalysis(JRA-25),the initial developing process of tropical cyclone Mindulle(1005) in 2010 has been diagnosed to reveal the impact of air-sea interaction over the South China Sea(SCS) on the genesis of its incipient vortex.The results show that the incipient vortex first occurred east of the Luzon Island on 0000 UTC 20 August,suggesting that the topographic forcing of the Luzon Island for easterly winds over the western Pacific might be one of the factors responsible for the formation of the incipient vortex.During the formation stage of the incipient vortex,strong southeasterlies over the SCS caused warm water of the middle and eastern SCS to flow toward the Luzon Island due to Ekman transport resulting from wind stress,leading to an increase of the sea surface temperature and sensible heat flux into the atmosphere.Although the anomalous sensible heating favored surface pressure to reduce,it was not conducive to the increase of local vorticity associated with the vortex above the heating area because,according to the atmospheric thermal adaptation theory,the anticyclonic vorticity would be created in the lower troposphere due to the decreased vertical gradient of the sensible heating.However,the ascending motions occurred over the eastern area of the anomalous sensible heating due to the augmentation of the vorticity advection with increasing height,causing water vapor to condense in the middle and upper troposphere.In turn,cyclonic vorticity was generated in the lower troposphere due to the increased vertical gradient of the condensation latent heating,resulting in the formation and further growth of the incipient vortex.Therefore,the vorticity creation due to the condensation heating played a dominant role during the subsequent enhancing stage of the incipient vortex.

SINGULAR CROSS SPECTRUM APPLIED ON DIAGNOSTIC ANALYSIS OF AIR-SEA INTERACTION

The Singular Cross Spectrum Analysis (SCSA) method was employed to investigate the coupledperiods of air-sea/mid-low circulation interaction using 1951-1993 500-hpa geopotential heights and the seasurface temperature (SST) in the Northern Hemisphere. Results show that air-sea correlation is noticeable on the3-7 year scale which is similar to ENSO circle. In this sense, ENSO is a Strong signal. Quasi-ten/quasi-four yearperiods are prominent in the mid-low interaction, and quasi-if our year oscillation is uniform with the ENSO circle.Studies indicate that the mid-low interaction possess quasi-ten year oscillation beside being affected by ENSO.

Machine learning with active pharmaceutical ingredient/polymer interaction mechanism:Prediction for complex phase behaviors of pharmaceuticals and formulations

The high throughput prediction of the thermodynamic phase behavior of active pharmaceutical ingredients(APIs)with pharmaceutically relevant excipients remains a major scientific challenge in the screening of pharmaceutical formulations.In this work,a developed machine-learning model efficiently predicts the solubility of APIs in polymers by learning the phase equilibrium principle and using a few molecular descriptors.Under the few-shot learning framework,thermodynamic theory(perturbed-chain statistical associating fluid theory)was used for data augmentation,and computational chemistry was applied for molecular descriptors'screening.The results showed that the developed machine-learning model can predict the API-polymer phase diagram accurately,broaden the solubility data of APIs in polymers,and reproduce the relationship between API solubility and the interaction mechanisms between API and polymer successfully,which provided efficient guidance for the development of pharmaceutical formulations.

Strong metal–support interaction boosts the electrocatalytic hydrogen evolution capability of Ru nanoparticles supported on titanium nitride

Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group metal.Herein,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic water.Characterizations reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree increased.Further study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption capacity.Thus,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 h.This study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering.

Electrostatic Interaction-directed Construction of Hierarchical Nanostructured Carbon Composite with Dual Electrical Conductive Networks for Zinc-ion Hybrid Capacitors with Ultrastability

Metal-organic framework(MOF)-derived carbon composites have been considered as the promising materials for energy storage.However,the construction of MOF-based composites with highly controllable mode via the liquid-liquid synthesis method has a great challenge because of the simultaneous heterogeneous nucleation on substrates and the self-nucleation of individual MOF nanocrystals in the liquid phase.Herein,we report a bidirectional electrostatic generated self-assembly strategy to achieve the precisely controlled coatings of single-layer nanoscale MOFs on a range of substrates,including carbon nanotubes(CNTs),graphene oxide(GO),MXene,layered double hydroxides(LDHs),MOFs,and SiO_(2).The obtained MOF-based nanostructured carbon composite exhibits the hierarchical porosity(V_(meso)/V_(micro)∶2.4),ultrahigh N content of 12.4 at.%and"dual electrical conductive networks."The assembled aqueous zinc-ion hybrid capacitor(ZIC)with the prepared nanocarbon composite as a cathode shows a high specific capacitance of 236 F g^(-1)at 0.5 A g^(-1),great rate performance of 98 F g^(-1)at 100 A g^(-1),and especially,an ultralong cycling stability up to 230000 cycles with the capacitance retention of 90.1%.This work develops a repeatable and general method for the controlled construction of MOF coatings on various functional substrates and further fabricates carbon composites for ZICs with ultrastability.

Biological Interaction and Imaging of Ultrasmall Gold Nanoparticles

Ultrasmall gold nanoparticles(AuNPs)typically includes atomically precise gold nanoclusters(AuNCs)and AuNPs with a core size below 3 nm.Serving as a bridge between small molecules and traditional inorganic nanoparticles,the ultrasmall AuNPs show the unique advantages of both small molecules(e.g.,rapid distribution,renal clearance,low non-specific organ accumulation)and nanoparticles(e.g.,long blood circulation and enhanced permeability and retention effect).The emergence of ultrasmall AuNPs creates significant opportunities to address many challenges in the health field including disease diagnosis,monitoring and treatment.Since the nano–bio interaction dictates the overall biological applications of the ultrasmall AuNPs,this review elucidates the recent advances in the biological interactions and imaging of ultrasmall AuNPs.We begin with the introduction of the factors that influence the cellular interactions of ultrasmall AuNPs.We then discuss the organ interactions,especially focus on the interactions of the liver and kidneys.We further present the recent advances in the tumor interactions of ultrasmall AuNPs.In addition,the imaging performance of the ultrasmall AuNPs is summarized and discussed.Finally,we summarize this review and provide some perspective on the future research direction of the ultrasmall AuNPs,aiming to accelerate their clinical translation.

Ecological network analysis reveals complex responses of tree species life stage interactions to stand variables

Tree interactions are essential for the structure,dynamics,and function of forest ecosystems,but variations in the architecture of life-stage interaction networks(LSINs)across forests is unclear.Here,we constructed 16 LSINs in the mountainous forests of northwest Hebei,China based on crown overlap from four mixed forests with two dominant tree species.Our results show that LSINs decrease the complexity of stand densities and basal areas due to the interaction cluster differentiation.In addition,we found that mature trees and saplings play different roles,the first acting as“hub”life stages with high connectivity and the second,as“bridges”controlling information flow with high centrality.Across the forests,life stages with higher importance showed better parameter stability within LSINs.These results reveal that the structure of tree interactions among life stages is highly related to stand variables.Our efforts contribute to the understanding of LSIN complexity and provide a basis for further research on tree interactions in complex forest communities.

Study of the Relationship Between New Ionic Interaction Parameters and Salt Solubility in Electrolyte Solutions Based on Molecular Dynamics Simulation

Studying the relationship between ionic interactions and salt solubility in seawater has implications for seawater desalination and mineral extraction.In this paper,a new method of expressing ion-to-ion interaction is proposed by using molecular dynamics simulation,and the relationship between ion-to-ion interaction and salt solubility in a simulated seawater water-salt system is investigated.By analyzing the variation of distance and contact time between ions in an electrolyte solution,from both spatial and temporal perspectives,new parameters were proposed to describe the interaction between ions:interaction distance(ID),and interaction time ratio(ITR).The best correlation between characteristic time ratio and solubility was found for a molar ratio of salt-to-water of 10:100 with a correlation coefficient of 0.96.For the same salt,a positive correlation was found between CTR and the molar ratio of salt and water.For type 1-1,type 2-1,type 1-2,and type 2-2 salts,the correlation coefficients between CTR and solubility were 0.93,0.96,0.92,and 0.98 for a salt-to-water molar ratio of 10:100,respectively.The solubility of multiple salts was predicted by simulations and compared with experimental values,yielding an average relative deviation of 12.4%.The new ion-interaction parameters offer significant advantages in describing strongly correlated and strongly hydrated electrolyte solutions.

Interatomic Interaction Models for Magnetic Materials:Recent Advances

Atomistic modeling is a widely employed theoretical method of computational materials science.It has found particular utility in the study of magnetic materials.Initially,magnetic empirical interatomic potentials or spinpolarized density functional theory(DFT)served as the primary models for describing interatomic interactions in atomistic simulations of magnetic systems.Furthermore,in recent years,a new class of interatomic potentials known as magnetic machine-learning interatomic potentials(magnetic MLIPs)has emerged.These MLIPs combine the computational efficiency,in terms of CPU time,of empirical potentials with the accuracy of DFT calculations.In this review,our focus lies on providing a comprehensive summary of the interatomic interaction models developed specifically for investigating magnetic materials.We also delve into the various problem classes to which these models can be applied.Finally,we offer insights into the future prospects of interatomic interaction model development for the exploration of magnetic materials.