Mesoporous molecular sieve MCM-41 has been synthesized in the extremely dense system (with H2O/Si<10) and characterized by XRD, N-2 adsorption isotherm as well as probe reactions of cracking of cumene and isomeriza...Mesoporous molecular sieve MCM-41 has been synthesized in the extremely dense system (with H2O/Si<10) and characterized by XRD, N-2 adsorption isotherm as well as probe reactions of cracking of cumene and isomerization of o-xylene.展开更多
ZSM-5/MCM-41 composite molecular sieve was prepared by the nano-assembling method.The ZSM-5 molecular sieve,the MCM-41 molecular sieve,the ZSM-5/MCM-41 mechanical mixture and the ZSM-5/MCM-41 composite molecular sieve...ZSM-5/MCM-41 composite molecular sieve was prepared by the nano-assembling method.The ZSM-5 molecular sieve,the MCM-41 molecular sieve,the ZSM-5/MCM-41 mechanical mixture and the ZSM-5/MCM-41 composite molecular sieve were characterized by X-ray powder diffractometry,N_2 adsorption isotherms,temperature programmed desorption of ammonia and scanning electron microscopy and their properties were analyzed.Using FCC gasoline as the feed,activities of different molecular sieves for reducing olefin content were investigated in a continuous high-pressure micro-reactor unit under the following conditions:a reaction temperature of 400℃,a reaction time of 2 h,a weight hourly space velocity of 3h^(-1),and a reaction pressure of 2.0 MPa.The results showed that the HMCM-41 molecular sieve had low reaction performance,and the HZSM-5 molecular sieve demonstrated high aromatization activity,while the ZSM-5/MCM- 41 composite molecular sieve exhibited a best olefin-reducing performance because of its high isomerization activity and moderate aromatization activity.With a largest olefin-reducmg capability and a reasonable distribution of products,the composite molecular sieve was more suitable for FCC gasoline upgrading compared to other three catalysts.展开更多
Following hydrothermal synthesis process, MCM-41 was synthesized by using cetyltriethylammonium bromide as templating agent. The experimental results showed that MCM-41 with pore diameter in the range of 4-7 nm can be...Following hydrothermal synthesis process, MCM-41 was synthesized by using cetyltriethylammonium bromide as templating agent. The experimental results showed that MCM-41 with pore diameter in the range of 4-7 nm can be obtained by adjusting nsurf/nsi. It was proved that cetyltriethylammonium bromide is an effective templating agent for increasing pore diameter of molecular sieve MCM-41.展开更多
The new crystalline V-Ti-silicalite with mesoporous MCM-41 type molecular sieve structure is synthesized hydrothermally; The framework IR spectra associated with ESR, Si-29 MAS NMR, DRS and XPS data shows that V and T...The new crystalline V-Ti-silicalite with mesoporous MCM-41 type molecular sieve structure is synthesized hydrothermally; The framework IR spectra associated with ESR, Si-29 MAS NMR, DRS and XPS data shows that V and Ti are simultaneously incorporated into V-TiMCM-41 framework.展开更多
Mesoporous molecular sieves Al-MCM-41 with n（SiO2）/n（Al2O3） ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction（XRD） patterns and the N2 physical sorption,the as-synthesized Al-MCM-41 exhibite...Mesoporous molecular sieves Al-MCM-41 with n（SiO2）/n（Al2O3） ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction（XRD） patterns and the N2 physical sorption,the as-synthesized Al-MCM-41 exhibited typical hexagonal structure,large surface areas and narrow pore distribution.The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with methyl tert-butyl-ether（MTBE） was then investigated.The effects of temperature,weight hourly space velocity（WHSV） and the feed ratio n（MTBE）/n（p-cresol） on p-cresol conversion and product selectivity were examined.The results showed that mesoporous HAl-MCM-41 molecular sieves（n（SiO2）/n（Al2O3） = 20） is an efficient catalyst with high activity,selectivity and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.展开更多
文摘Mesoporous molecular sieve MCM-41 has been synthesized in the extremely dense system (with H2O/Si<10) and characterized by XRD, N-2 adsorption isotherm as well as probe reactions of cracking of cumene and isomerization of o-xylene.
文摘ZSM-5/MCM-41 composite molecular sieve was prepared by the nano-assembling method.The ZSM-5 molecular sieve,the MCM-41 molecular sieve,the ZSM-5/MCM-41 mechanical mixture and the ZSM-5/MCM-41 composite molecular sieve were characterized by X-ray powder diffractometry,N_2 adsorption isotherms,temperature programmed desorption of ammonia and scanning electron microscopy and their properties were analyzed.Using FCC gasoline as the feed,activities of different molecular sieves for reducing olefin content were investigated in a continuous high-pressure micro-reactor unit under the following conditions:a reaction temperature of 400℃,a reaction time of 2 h,a weight hourly space velocity of 3h^(-1),and a reaction pressure of 2.0 MPa.The results showed that the HMCM-41 molecular sieve had low reaction performance,and the HZSM-5 molecular sieve demonstrated high aromatization activity,while the ZSM-5/MCM- 41 composite molecular sieve exhibited a best olefin-reducing performance because of its high isomerization activity and moderate aromatization activity.With a largest olefin-reducmg capability and a reasonable distribution of products,the composite molecular sieve was more suitable for FCC gasoline upgrading compared to other three catalysts.
文摘Following hydrothermal synthesis process, MCM-41 was synthesized by using cetyltriethylammonium bromide as templating agent. The experimental results showed that MCM-41 with pore diameter in the range of 4-7 nm can be obtained by adjusting nsurf/nsi. It was proved that cetyltriethylammonium bromide is an effective templating agent for increasing pore diameter of molecular sieve MCM-41.
文摘The new crystalline V-Ti-silicalite with mesoporous MCM-41 type molecular sieve structure is synthesized hydrothermally; The framework IR spectra associated with ESR, Si-29 MAS NMR, DRS and XPS data shows that V and Ti are simultaneously incorporated into V-TiMCM-41 framework.
文摘Mesoporous molecular sieves Al-MCM-41 with n（SiO2）/n（Al2O3） ratio being 20,50 and 100 were prepared.As proved by X-ray diffraction（XRD） patterns and the N2 physical sorption,the as-synthesized Al-MCM-41 exhibited typical hexagonal structure,large surface areas and narrow pore distribution.The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with methyl tert-butyl-ether（MTBE） was then investigated.The effects of temperature,weight hourly space velocity（WHSV） and the feed ratio n（MTBE）/n（p-cresol） on p-cresol conversion and product selectivity were examined.The results showed that mesoporous HAl-MCM-41 molecular sieves（n（SiO2）/n（Al2O3） = 20） is an efficient catalyst with high activity,selectivity and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.
