Integrated computational materials engineering(ICME)is to integrate multi-scale computational simulations and key experimental methods such as macroscopic,mesoscopic,and microscopic into the whole process of Al alloys...Integrated computational materials engineering(ICME)is to integrate multi-scale computational simulations and key experimental methods such as macroscopic,mesoscopic,and microscopic into the whole process of Al alloys design and development,which enables the design and development of Al alloys to upgrade from traditional empirical to the integration of compositionprocess-structure-mechanical property,thus greatly accelerating its development speed and reducing its development cost.This study combines calculation of phase diagram(CALPHAD),Finite element calculations,first principle calculations,and microstructure characterization methods to predict and regulate the formation and structure of composite precipitates from the design of highmodulus Al alloy compositions and optimize the casting process parameters to inhibit the formation of micropore defects in the casting process,and the final tensile strength of Al alloys reaches420 MPa and Young's modulus reaches more than 88 GPa,which achieves the design goal of the high strength and modulus Al alloys,and establishes a new mode of the design and development of the strength/modulus Al alloys.展开更多
The microstructure stability of Al 3Ti/Al alloy prepared by mechanical alloying (MA) was investigated in the simulating environment in which they may be used. The results show that the MA alloy possesses fine microstr...The microstructure stability of Al 3Ti/Al alloy prepared by mechanical alloying (MA) was investigated in the simulating environment in which they may be used. The results show that the MA alloy possesses fine microstructure (the grain size is about 0.5 μm). After cycling loaded followed by heat exposure at 350 ℃ for 24 h, no microstructure coarsening of the alloy occurred, which means that the Al 3Ti/Al alloy behaves good microstructure stability at high temperature. The compression yield strength of the alloy reaches up to 247 MPa at 350 ℃. [展开更多
A novel and effective method to co-extrude metallic alloys is described which named Direct Extrusion and Bending-Shear Deformation.The compound extrusion plates have cracked at 290℃ and 3 mm/s.According to this pheno...A novel and effective method to co-extrude metallic alloys is described which named Direct Extrusion and Bending-Shear Deformation.The compound extrusion plates have cracked at 290℃ and 3 mm/s.According to this phenomenon,a model was built to investigate the crack generation and development between the 6061 Al and AZ31 Mg alloy during the compound extrusion process by DEFORM-3D.The cracking behavior of the Mg/Al composite rod with a soft Mg AZ31 core and a hard Al 6061 sleeve were systematically studied to disclose the influence of microstructure on crack in the different regions.The simulation results show that the distribution of strain and velocity has significant differences due to the influence of dies structure and material properties at different locations in the same region.The experimental results show that in the same conditions,there are differences in recrystallization and texture weakening of AZ31 Mg alloys and 6061 Al alloy,which are important factors for the formation of crack.Both the Mg layer and the Al layer have a homogeneous microstructure in the region d.展开更多
The machine-learning approach was investigated to predict the mechanical properties of Cu–Al alloys manufactured using the powder metallurgy technique to increase the rate of fabrication and characterization of new m...The machine-learning approach was investigated to predict the mechanical properties of Cu–Al alloys manufactured using the powder metallurgy technique to increase the rate of fabrication and characterization of new materials and provide physical insights into their properties.Six algorithms were used to construct the prediction models, with chemical composition and porosity of the compacts chosen as the descriptors.The results show that the sequential minimal optimization algorithm for support vector regression with a puk kernel(SMOreg/puk) model demonstrated the best prediction ability. Specifically, its predictions exhibited the highest correlation coefficient and lowest error among the predictions of the six models. The SMOreg/puk model was subsequently applied to predict the tensile strength and hardness of Cu–Al alloys and provide guidance for composition design to achieve the expected values. With the guidance of the SMOreg/puk model, Cu–12Al–6Ni alloy with a tensile strength(390 MPa) and hardness(HB 139) that reached the expected values was developed.展开更多
The as-cast and as-extruded Mg–9Li–1Al–xCa alloys(x=0,0.2;wt%)were prepared by a simple alloying process followed by hot extrusion with an extrusion ratio of 28.2.The microstructures of the as-cast and as-extruded...The as-cast and as-extruded Mg–9Li–1Al–xCa alloys(x=0,0.2;wt%)were prepared by a simple alloying process followed by hot extrusion with an extrusion ratio of 28.2.The microstructures of the as-cast and as-extruded Mg–9Li–1Al–xCa alloys were observed to investigate the effect of calcium(Ca)element on the Mg–9Li–1Al(LA91)alloy,and the crystallographic calculations between Al_(2)Ca and the matrix(α-Mg andβ-Li phases)were examined on the basis of the edge-to-edge matching model.The experimental results indicate that the addition of 0.2 wt%Ca into LA91 alloy reduce the size of theα-Mg phases in the as-cast alloy and that ofβ-Li phases in the as-extruded alloy due to the Al_(2)Ca particles distributed inside the matrix.Crystallographic calculation results suggested that there is a good crystallographic matching between the matrix and Al_(2)Ca,which confirmed that Al_(2)Ca particles can act as a heterogeneous nucleation site for bothα-Mg andβ-Li phases and were effective grain refiners for LA91 alloy.展开更多
The oxidation behavior of sputtered Ni-3Cr-20Al coating at 900℃ in air was investigated. A dense Al2O3 layer was formed on the sputtered Ni-3Cr-20Al coating after 200 h oxidation. However, owing to the segregation of...The oxidation behavior of sputtered Ni-3Cr-20Al coating at 900℃ in air was investigated. A dense Al2O3 layer was formed on the sputtered Ni-3Cr-20Al coating after 200 h oxidation. However, owing to the segregation of Ni3Al during oxidation process at high temperature, the spinel NiAl2O4 was also formed in the Al2O3 layer. It was found that the formation of NiAl2O4 had no detrimental effect on the oxidation resistance of the sputtered Ni-3Cr-20Al coating due to the excellent adhesion shown by the Al2O3 and NiAl2O4 complex oxide scale.展开更多
The microplasma oxidation process of LY 12 Al alloy in Na2SiO3-KOH-NaAL2 system has been studied. The voltage-time curve of oxidation process is changed with the variation of current densities. The voltage breakdown a...The microplasma oxidation process of LY 12 Al alloy in Na2SiO3-KOH-NaAL2 system has been studied. The voltage-time curve of oxidation process is changed with the variation of current densities. The voltage breakdown and hardness of coating increase with increasing current density. The phase composition, morphologies, element and the distribution of ceramic coating are investigated by XRD, EPMA.展开更多
The aim of present study is to analyze the influence of volume percentage(vol.%) of nano-sized particles(TiB_2: average size is 35 nm) on microstructure, mechanical and tribological behavior of 6061-T6 Al alloy surfac...The aim of present study is to analyze the influence of volume percentage(vol.%) of nano-sized particles(TiB_2: average size is 35 nm) on microstructure, mechanical and tribological behavior of 6061-T6 Al alloy surface nano composite prepared via Friction stir process(FSP). The microstructure of the fabricated surface nanocomposites is examined using optical microscopy(OM) and scanning electron microscope(SEM) for distribution of TiB_2 nano reinforcement particles, thickness of nano composite layer formed on the Aluminum alloy substrate and fracture features. The depth of surface nano composite layer is measured as 3683.82 m m along the cross section of stir zone of nano composite perpendicular to FSP. It was observed that increase in volume percentage of TiB_2 particles, the microhardness is increased up to132 Hv and it is greater than as-received Al alloy's microhardness(104 Hv). It is also observed that at 4volume percentage higher tensile properties exhibited as compared with the 2 and 8 vol. %. It is found that high wear resistance exhibited at 4 volume percentage as-compared with the 2 and 8 vol. %. The observed wear and mechanical properties are interrelated with microstructure, fractography and worn morphology.展开更多
This study investigates the effects of billet homogenization temperature on the dynamic recrystallization behavior during high-speed extrusion and resultant microstructure and tensile properties of the Mg–5Bi–3Al(BA...This study investigates the effects of billet homogenization temperature on the dynamic recrystallization behavior during high-speed extrusion and resultant microstructure and tensile properties of the Mg–5Bi–3Al(BA53,wt%)alloy.Two billets homogenized at 350 and450℃(350H and 450H billets)are extruded at a high speed of 69 m/min.The 350H billet has a relatively smaller grain size and a higher abundance of fine Mg3Bi2particles compared to the 450H billet.During extrusion of the 350H billet,enhanced dynamic recrystallization occurs as a result of its finer grains and abundance of particles,while the growth of recrystallized grains is suppressed by the grain-boundary pinning effect of particles.Ultimately,the extruded 350H material is characterized by smaller grains,relatively greater number of Mg3Bi2particles,and a higher internal strain energy than the extruded 450H material.The tensile strength of the extruded 350H material is higher than that of the extruded 450H material owing to stronger grain-boundary hardening,particle hardening,and strain hardening effects.The extruded 350H material also exhibits a higher tensile elongation as its smaller grains inhibit the formation of crack-inducing undesirable twins during tension.The results from this study demonstrate that a decrease in the homogenization temperature from 450 to 350℃leads to improved strength and ductility in the high-speed-extruded BA53 material.展开更多
Relationship between the processing parameters and the properties of semi-solid processed Al alloys were studied and microstructure and mechanical properties of semi-solid processed Al parts for automobile application...Relationship between the processing parameters and the properties of semi-solid processed Al alloys were studied and microstructure and mechanical properties of semi-solid processed Al parts for automobile application as a function of processing parameters were compared with those of die-cast parts and forged parts. In addition, the locations for the gate during the semi-solid processing were varied to elucidate the distribution of micro-porosities and resulting mechanical properties and the T6 heat tre...展开更多
Two quinary high-entropy alloys(HEAs) with equiatomic concentrations formed by doping either Cu or Al elements into the quaternary NiFeCoCr alloy are produced by arc melting and spray casting techniques.Their entropy ...Two quinary high-entropy alloys(HEAs) with equiatomic concentrations formed by doping either Cu or Al elements into the quaternary NiFeCoCr alloy are produced by arc melting and spray casting techniques.Their entropy of fusion,thermal expansion coefficient and thermal diffusivity are experimentally investigated with differential scanning calorimetry,dilatometry and laser flash methods.The NiFeCoCrCu HEAs contain a facecentered cubic high-entropy phase plus a minor interdendritic(Cu) phase and display a lower entropy of fusion and the Vickers hardness.The NiFeCoCrAl HEAs consist of two body-centered cubic high-entropy phases with coarse dendritic structures and show higher entropy of fusion and the Vickers hardness.Both the thermal expansion coefficient and the thermal diffusivity of the former Cu-doped alloy are significantly larger than those of the latter Al-doped alloy.Although the temperature dependence of thermal diffusivity is similar for both HEAs,it is peculiar that the thermal expansion curve of the NiFeCoCrAl alloy exhibits an inflexion at temperatures of860-912 K.展开更多
The current investigation of refill friction stir spot welding(refill FSSW)Al alloy to copper primarily involved plunging the tool into bottom copper sheet to achieve both metallurgical and mechanical interfacial bond...The current investigation of refill friction stir spot welding(refill FSSW)Al alloy to copper primarily involved plunging the tool into bottom copper sheet to achieve both metallurgical and mechanical interfacial bonding.Compared to conventional FSSW and pinless FSSW,weld strength can be significantly improved by using this method.Nevertheless,tool wear is a critical issue during refill FSSW.In this study,defect-free Al/copper dissimilar welds were successfully fabricated using refill FSSW by only plunging the tool into top Al alloy sheet.Overall,two types of continuous and ultra-thin intermetallic compounds(IMCs)layers were identified at the whole Al/copper interface.Also,strong evidence of melting and resolidification was observed in the localized region.The peak temperature obtained at the center of Al/copper interface was 591℃,and the heating rate reached up to 916℃/s during the sleeve penetration phase.A softened weld region was produced via refill FSSW process,the hardness profile exhibited a W-shaped appearance along middle thickness of top Al alloy.The weld lap shear load was insensitive to the welding condition,whose scatter was rather small.The fracture path exclusively propagated along the IMCs layer of Cu_(9)Al_(4) under the external lap shear loadings,both CuAl_(2) and Cu_(9)Al_(4) were detected on the fractured surface on the copper side.This research indicated that acceptable weld strength can be achieved via pure metallurgical joining mechanism,which has significant potential for the industrial applications.展开更多
The dynamic oxidation of molten Mg–Al alloy was investigated via the oxide/metal/oxide(OMO)sandwich method.The characteristics of sandwiches were explored using optical microscopy,scanning electron microscopy,X-ray e...The dynamic oxidation of molten Mg–Al alloy was investigated via the oxide/metal/oxide(OMO)sandwich method.The characteristics of sandwiches were explored using optical microscopy,scanning electron microscopy,X-ray energy dispersive spectroscopy,and X-ray diffraction analyses.The results showed the formation of porous oxide films with varying thicknesses from 0.43 to 16.7 mm.Both the measurements and calculations confirmed the literature findings that the oxidation product consists mainly of MgO and Mg Al_(2)O_(4)compounds.The increase in thickness and amount of folds formed on the oxide films implies the significant effect of aluminum in reducing the oxidation resistance of magnesium.展开更多
In this work, two kinds of binders, Ammonium Zirconium Carbonate(AZC) and Ammonium Metatungstate(AMT) hydrate, and three kinds of powders(ZrO 2, Al2O3 and Y2O3) were mixed to fabricate six kinds of face coating system...In this work, two kinds of binders, Ammonium Zirconium Carbonate(AZC) and Ammonium Metatungstate(AMT) hydrate, and three kinds of powders(ZrO 2, Al2O3 and Y2O3) were mixed to fabricate six kinds of face coating systems. The thermal behaviors of the AZC and AMT dried binders were investigated by TG-DTA, and the phase transformation of the two binders was determined by XRD. Monoclinic ZrO 2 phase was formed from AZC at 620 °C and WO3 at 700 °C, and the phase transformation was completed at lower than 1000 °C in both binders, and therefore, the sintering temperature for the molds was selected at 950 °C. The interaction between the ceramic molds with different face coatings and the Ti-48Al-2Cr-2Nb alloy during investment casting was studied. Results showed no α-case reaction in the TiA l-mold reaction, and the AMT + Y2O3 face coating appeared to be the best choice for investment casting of TiA l alloys under the experimental conditions.展开更多
The short-range repulsive interactions of any force field must be modified to be applicable for high energy atomic collisions because of extremely far from equilibrium state when used in molecular dynamics(MD)simulati...The short-range repulsive interactions of any force field must be modified to be applicable for high energy atomic collisions because of extremely far from equilibrium state when used in molecular dynamics(MD)simulations.In this work,the short-range repulsive interaction of a reactive force field(ReaxFF),describing Fe-Ni-Al alloy system,is well modified by adding a tabulated function form based on Ziegler-Biersack-Littmark(ZBL)potential.The modified interaction covers three ranges,including short range,smooth range,and primordial range.The short range is totally predominated by ZBL potential.The primordial range means the interactions in this range is the as-is ReaxFF with no changes.The smooth range links the short-range ZBL and primordial-range ReaxFF potentials with a taper function.Both energies and forces are guaranteed to be continuous,and qualified to the consistent requirement in LAMMPS.This modified force field is applicable for simulations of energetic particle bombardments and reproducing point defects'booming and recombination effectively.展开更多
In the present study, Ti-45Al-(6, 7, 8)Nb(at%) and Ti-45Al-8Nb-0.5(Mn, Si, Y, B) alloys were prepared by arc melting and casting into Zr O2(Y2O3 stabilized) ceramic moulds to study the effect of alloying elements Nb a...In the present study, Ti-45Al-(6, 7, 8)Nb(at%) and Ti-45Al-8Nb-0.5(Mn, Si, Y, B) alloys were prepared by arc melting and casting into Zr O2(Y2O3 stabilized) ceramic moulds to study the effect of alloying elements Nb and Mn, Si, Y, B on the interfacial reaction between casting Ti Al alloys and ceramic moulds by SEM, and the elements' distribution in the interface reaction layer by line scanning. The results showed that with an increase in Nb content, the interfacial reaction weakened and the thickness of the reaction layer decreased gradually. The interface reaction thickness of the alloys with Nb content of 6, 7, 8at% were 60, 34 and 26 μm, respectively. Clearly, the addition of 8at% Nb to Ti-45 Al is the best for the thickness of the reaction layer. The addition of Nb would form a Nb-rich film in the reaction layer, which could reduce the solubility of oxygen in the interface, and suppress further diffusion of oxygen to the matrix. If the same content of Mn, Si, Y, or B alloying elements were added respectively to Ti-45Al-8Nb, the thickness of the interface reaction layer from large to small was as follows: Mn>Si>Y>B. The interface reaction thickness increased after 0.5at% Mn added, had no obvious change after 0.5at% Si addition, and decreased after adding 0.5at% Y or B. The introduced elements, which formed a protective film or/and promoted the formation of a dense aluminum oxide layer, would be of benefit to the resistance of interfacial reaction.展开更多
In order to refine microstructure grains and improve mechanical properties of TiAl alloys,Ti44Al(at.%)alloy was rapidly solidified by melt spinning under different cooling rates.Microstructure and microhardness of the...In order to refine microstructure grains and improve mechanical properties of TiAl alloys,Ti44Al(at.%)alloy was rapidly solidified by melt spinning under different cooling rates.Microstructure and microhardness of the alloy before and after rapid solidification were investigated.XRD results show that the ratio ofα2 phase in binary alloy increased with the cooling rates,which is caused by moreαphases directly transforming toα2 phases.Grain morphology changed from long dendrite to the mixture of equiaxed and dendrite to equiaxed with the increase of cooling rates.The grain size was refined from 200-600μm of as⁃cast to 18μm of the alloy cooled at 4.9×10^5 K/s,which is caused by the undercooling induced from rapid solidification.Lamellar spacing was decreased from 4.5μm of as⁃cast to 1.1μm by rapid solidification.With the increase of cooling rate,the content ofα2 phase increased andγphase decreased gradually.Rapid solidification can reduce the segregation of elements.The microhardness was improved from 247 HV to 556 HV,which results from grain refinement strengthening,reduction of lamellar spacing,and more content ofα2 phase.展开更多
The microstructure evolution of the fine-grained 5083 Al alloy was investigated in annealing temperature range of 150−300℃.Then the effects of the different annealed microstructures on high-temperature deformation be...The microstructure evolution of the fine-grained 5083 Al alloy was investigated in annealing temperature range of 150−300℃.Then the effects of the different annealed microstructures on high-temperature deformation behavior were further studied.The results indicate that the initial recrystallization temperature is about 200℃.By tensile tests at 380−570℃and in strain rate range of 4.17×10^(−4)−1.0×10^(−2) s^(−1),the optimum superplastic parameters are obtained as follows:the annealed temperature 250℃,the tensile temperature 550℃and the strain rate 4.17×10^(−4) s^(−1).With the aid of scanning electronic microscopy(SEM),the fractography of the alloy after the superplastic deformation was analyzed.The results reveal that intergranular cavities with fine size and homogeneous distribution are beneficial to superplastic deformation.展开更多
The diffusivity of hydrogen in two Ni3Al alloys (No.1 and No.2) has been measured in the temperature range of 100’C to 420’C using an ultrahigh vacuum gaseous permeation technique. The diffusivity data fall into two...The diffusivity of hydrogen in two Ni3Al alloys (No.1 and No.2) has been measured in the temperature range of 100’C to 420’C using an ultrahigh vacuum gaseous permeation technique. The diffusivity data fall into two segments, in which the hydrogen diffusivity adheres to the Arrhenius form, respectively. From the hydrogen diffusivity, it is conjectured that the hydrogen diffusivity reflects the hydrogen transportation along the grain boundaries at lower temperature and the hydrogen transportation in the lattice at higher temperature. The intergranular fracture of L12-type intermetallics induced by hydrogen at relative low temperature results from hydrogen transportation along the grain boundaries and not in the lattice.展开更多
The aging characteristics, stress corrosion behaviour and chemical composition of grain boundary in 7175 high-strength Al alloy during long term aging process have been investigated by hardness measurement, constant e...The aging characteristics, stress corrosion behaviour and chemical composition of grain boundary in 7175 high-strength Al alloy during long term aging process have been investigated by hardness measurement, constant elongation rate testing (CERT) and energy spectroscopy analysis. The results indicate that double peaks in aged state feature the hardness and strength of 7175 Al alloy Although the intensity of double peaks is almost equal, the stress corrosion resistance in the second peak-aged state is better than that of the first peak-aged state. The effects of Mg segregation on the binding energy of grain boundary have been calculated by using free electron theory developed by the authors. The results show that Mg segregation plays a significant role in controlling stress corrosion susceptibility which is consistent with the experimental results.展开更多
基金supported by the National Natural Science Foundation of China(No.52073030)。
文摘Integrated computational materials engineering(ICME)is to integrate multi-scale computational simulations and key experimental methods such as macroscopic,mesoscopic,and microscopic into the whole process of Al alloys design and development,which enables the design and development of Al alloys to upgrade from traditional empirical to the integration of compositionprocess-structure-mechanical property,thus greatly accelerating its development speed and reducing its development cost.This study combines calculation of phase diagram(CALPHAD),Finite element calculations,first principle calculations,and microstructure characterization methods to predict and regulate the formation and structure of composite precipitates from the design of highmodulus Al alloy compositions and optimize the casting process parameters to inhibit the formation of micropore defects in the casting process,and the final tensile strength of Al alloys reaches420 MPa and Young's modulus reaches more than 88 GPa,which achieves the design goal of the high strength and modulus Al alloys,and establishes a new mode of the design and development of the strength/modulus Al alloys.
文摘The microstructure stability of Al 3Ti/Al alloy prepared by mechanical alloying (MA) was investigated in the simulating environment in which they may be used. The results show that the MA alloy possesses fine microstructure (the grain size is about 0.5 μm). After cycling loaded followed by heat exposure at 350 ℃ for 24 h, no microstructure coarsening of the alloy occurred, which means that the Al 3Ti/Al alloy behaves good microstructure stability at high temperature. The compression yield strength of the alloy reaches up to 247 MPa at 350 ℃. [
基金This work was partly supported by National Natural Science Foundation of China(Grant nos.51975207&51728202)Hunan Provincial Natural Science Foundation for Excellent Young Scholars of China(Grant no.2019JJ30010)+1 种基金the Scientific Research Fund of Hunan Provincial Education Department(Grant No.17B089)the Hunan Provincial Research and Innovation Project for postgraduate(Grant No.CX2018B696).
文摘A novel and effective method to co-extrude metallic alloys is described which named Direct Extrusion and Bending-Shear Deformation.The compound extrusion plates have cracked at 290℃ and 3 mm/s.According to this phenomenon,a model was built to investigate the crack generation and development between the 6061 Al and AZ31 Mg alloy during the compound extrusion process by DEFORM-3D.The cracking behavior of the Mg/Al composite rod with a soft Mg AZ31 core and a hard Al 6061 sleeve were systematically studied to disclose the influence of microstructure on crack in the different regions.The simulation results show that the distribution of strain and velocity has significant differences due to the influence of dies structure and material properties at different locations in the same region.The experimental results show that in the same conditions,there are differences in recrystallization and texture weakening of AZ31 Mg alloys and 6061 Al alloy,which are important factors for the formation of crack.Both the Mg layer and the Al layer have a homogeneous microstructure in the region d.
基金financial support from the National Key Research and Development Program of China(No.2016YFB0700503)the National High Technology Research and Development Program of China(No.2015AA03420)+2 种基金Beijing Science and Technology Plan(No.D16110300240000)National Natural Science Foundation of China(No.51172018)the Science and Technology Research Program of Chongqing Municipal Education Commission(No.KJQN201801202)
文摘The machine-learning approach was investigated to predict the mechanical properties of Cu–Al alloys manufactured using the powder metallurgy technique to increase the rate of fabrication and characterization of new materials and provide physical insights into their properties.Six algorithms were used to construct the prediction models, with chemical composition and porosity of the compacts chosen as the descriptors.The results show that the sequential minimal optimization algorithm for support vector regression with a puk kernel(SMOreg/puk) model demonstrated the best prediction ability. Specifically, its predictions exhibited the highest correlation coefficient and lowest error among the predictions of the six models. The SMOreg/puk model was subsequently applied to predict the tensile strength and hardness of Cu–Al alloys and provide guidance for composition design to achieve the expected values. With the guidance of the SMOreg/puk model, Cu–12Al–6Ni alloy with a tensile strength(390 MPa) and hardness(HB 139) that reached the expected values was developed.
基金The authors are grateful for the financial supports from National Natural Science Foundation of China(51171212)Chongqing Science and Technology Commission(CSTC2012JJJQ50001,CSTC2013jcyjC60001,cstc2012ggB 50003)+1 种基金The National Science and Technology Program of China(2013DFA71070)the Fundamental Research Funds for the Central Universities(CDJZR13138801).
文摘The as-cast and as-extruded Mg–9Li–1Al–xCa alloys(x=0,0.2;wt%)were prepared by a simple alloying process followed by hot extrusion with an extrusion ratio of 28.2.The microstructures of the as-cast and as-extruded Mg–9Li–1Al–xCa alloys were observed to investigate the effect of calcium(Ca)element on the Mg–9Li–1Al(LA91)alloy,and the crystallographic calculations between Al_(2)Ca and the matrix(α-Mg andβ-Li phases)were examined on the basis of the edge-to-edge matching model.The experimental results indicate that the addition of 0.2 wt%Ca into LA91 alloy reduce the size of theα-Mg phases in the as-cast alloy and that ofβ-Li phases in the as-extruded alloy due to the Al_(2)Ca particles distributed inside the matrix.Crystallographic calculation results suggested that there is a good crystallographic matching between the matrix and Al_(2)Ca,which confirmed that Al_(2)Ca particles can act as a heterogeneous nucleation site for bothα-Mg andβ-Li phases and were effective grain refiners for LA91 alloy.
基金National Natural Science Foundation of China !under grant 59671060
文摘The oxidation behavior of sputtered Ni-3Cr-20Al coating at 900℃ in air was investigated. A dense Al2O3 layer was formed on the sputtered Ni-3Cr-20Al coating after 200 h oxidation. However, owing to the segregation of Ni3Al during oxidation process at high temperature, the spinel NiAl2O4 was also formed in the Al2O3 layer. It was found that the formation of NiAl2O4 had no detrimental effect on the oxidation resistance of the sputtered Ni-3Cr-20Al coating due to the excellent adhesion shown by the Al2O3 and NiAl2O4 complex oxide scale.
文摘The microplasma oxidation process of LY 12 Al alloy in Na2SiO3-KOH-NaAL2 system has been studied. The voltage-time curve of oxidation process is changed with the variation of current densities. The voltage breakdown and hardness of coating increase with increasing current density. The phase composition, morphologies, element and the distribution of ceramic coating are investigated by XRD, EPMA.
文摘The aim of present study is to analyze the influence of volume percentage(vol.%) of nano-sized particles(TiB_2: average size is 35 nm) on microstructure, mechanical and tribological behavior of 6061-T6 Al alloy surface nano composite prepared via Friction stir process(FSP). The microstructure of the fabricated surface nanocomposites is examined using optical microscopy(OM) and scanning electron microscope(SEM) for distribution of TiB_2 nano reinforcement particles, thickness of nano composite layer formed on the Aluminum alloy substrate and fracture features. The depth of surface nano composite layer is measured as 3683.82 m m along the cross section of stir zone of nano composite perpendicular to FSP. It was observed that increase in volume percentage of TiB_2 particles, the microhardness is increased up to132 Hv and it is greater than as-received Al alloy's microhardness(104 Hv). It is also observed that at 4volume percentage higher tensile properties exhibited as compared with the 2 and 8 vol. %. It is found that high wear resistance exhibited at 4 volume percentage as-compared with the 2 and 8 vol. %. The observed wear and mechanical properties are interrelated with microstructure, fractography and worn morphology.
基金supported by a National Research Foundation of Korea(NRF)grant funded by the Ministry of Science,ICT and Future Planning(MSIP,South Korea)(No.2019R1A2C1085272)the Materials and Components Technology Development Program of the Ministry of Trade,Industry and Energy(MOTIE,South Korea)(No.20011091)。
文摘This study investigates the effects of billet homogenization temperature on the dynamic recrystallization behavior during high-speed extrusion and resultant microstructure and tensile properties of the Mg–5Bi–3Al(BA53,wt%)alloy.Two billets homogenized at 350 and450℃(350H and 450H billets)are extruded at a high speed of 69 m/min.The 350H billet has a relatively smaller grain size and a higher abundance of fine Mg3Bi2particles compared to the 450H billet.During extrusion of the 350H billet,enhanced dynamic recrystallization occurs as a result of its finer grains and abundance of particles,while the growth of recrystallized grains is suppressed by the grain-boundary pinning effect of particles.Ultimately,the extruded 350H material is characterized by smaller grains,relatively greater number of Mg3Bi2particles,and a higher internal strain energy than the extruded 450H material.The tensile strength of the extruded 350H material is higher than that of the extruded 450H material owing to stronger grain-boundary hardening,particle hardening,and strain hardening effects.The extruded 350H material also exhibits a higher tensile elongation as its smaller grains inhibit the formation of crack-inducing undesirable twins during tension.The results from this study demonstrate that a decrease in the homogenization temperature from 450 to 350℃leads to improved strength and ductility in the high-speed-extruded BA53 material.
文摘Relationship between the processing parameters and the properties of semi-solid processed Al alloys were studied and microstructure and mechanical properties of semi-solid processed Al parts for automobile application as a function of processing parameters were compared with those of die-cast parts and forged parts. In addition, the locations for the gate during the semi-solid processing were varied to elucidate the distribution of micro-porosities and resulting mechanical properties and the T6 heat tre...
基金Supported by the National Natural Science Foundation of China under Grant Nos 51571163,51371150,51271150 and 51327901
文摘Two quinary high-entropy alloys(HEAs) with equiatomic concentrations formed by doping either Cu or Al elements into the quaternary NiFeCoCr alloy are produced by arc melting and spray casting techniques.Their entropy of fusion,thermal expansion coefficient and thermal diffusivity are experimentally investigated with differential scanning calorimetry,dilatometry and laser flash methods.The NiFeCoCrCu HEAs contain a facecentered cubic high-entropy phase plus a minor interdendritic(Cu) phase and display a lower entropy of fusion and the Vickers hardness.The NiFeCoCrAl HEAs consist of two body-centered cubic high-entropy phases with coarse dendritic structures and show higher entropy of fusion and the Vickers hardness.Both the thermal expansion coefficient and the thermal diffusivity of the former Cu-doped alloy are significantly larger than those of the latter Al-doped alloy.Although the temperature dependence of thermal diffusivity is similar for both HEAs,it is peculiar that the thermal expansion curve of the NiFeCoCrAl alloy exhibits an inflexion at temperatures of860-912 K.
基金Supported by National Natural Science Foundation of China(Grant Nos.51975479,51905437)Fundamental Research Funds for the Central Universities(Grant No.3102019QD0404)+1 种基金Science and Technology Bureau of Yulin(Grant No.2019-86-1)High-Level Talent Project of Yulin University,China(Grant No.20GK06).
文摘The current investigation of refill friction stir spot welding(refill FSSW)Al alloy to copper primarily involved plunging the tool into bottom copper sheet to achieve both metallurgical and mechanical interfacial bonding.Compared to conventional FSSW and pinless FSSW,weld strength can be significantly improved by using this method.Nevertheless,tool wear is a critical issue during refill FSSW.In this study,defect-free Al/copper dissimilar welds were successfully fabricated using refill FSSW by only plunging the tool into top Al alloy sheet.Overall,two types of continuous and ultra-thin intermetallic compounds(IMCs)layers were identified at the whole Al/copper interface.Also,strong evidence of melting and resolidification was observed in the localized region.The peak temperature obtained at the center of Al/copper interface was 591℃,and the heating rate reached up to 916℃/s during the sleeve penetration phase.A softened weld region was produced via refill FSSW process,the hardness profile exhibited a W-shaped appearance along middle thickness of top Al alloy.The weld lap shear load was insensitive to the welding condition,whose scatter was rather small.The fracture path exclusively propagated along the IMCs layer of Cu_(9)Al_(4) under the external lap shear loadings,both CuAl_(2) and Cu_(9)Al_(4) were detected on the fractured surface on the copper side.This research indicated that acceptable weld strength can be achieved via pure metallurgical joining mechanism,which has significant potential for the industrial applications.
文摘The dynamic oxidation of molten Mg–Al alloy was investigated via the oxide/metal/oxide(OMO)sandwich method.The characteristics of sandwiches were explored using optical microscopy,scanning electron microscopy,X-ray energy dispersive spectroscopy,and X-ray diffraction analyses.The results showed the formation of porous oxide films with varying thicknesses from 0.43 to 16.7 mm.Both the measurements and calculations confirmed the literature findings that the oxidation product consists mainly of MgO and Mg Al_(2)O_(4)compounds.The increase in thickness and amount of folds formed on the oxide films implies the significant effect of aluminum in reducing the oxidation resistance of magnesium.
基金financially supported by the National Natural Science Foundation of China(Nos.51001040 and 51371064)
文摘In this work, two kinds of binders, Ammonium Zirconium Carbonate(AZC) and Ammonium Metatungstate(AMT) hydrate, and three kinds of powders(ZrO 2, Al2O3 and Y2O3) were mixed to fabricate six kinds of face coating systems. The thermal behaviors of the AZC and AMT dried binders were investigated by TG-DTA, and the phase transformation of the two binders was determined by XRD. Monoclinic ZrO 2 phase was formed from AZC at 620 °C and WO3 at 700 °C, and the phase transformation was completed at lower than 1000 °C in both binders, and therefore, the sintering temperature for the molds was selected at 950 °C. The interaction between the ceramic molds with different face coatings and the Ti-48Al-2Cr-2Nb alloy during investment casting was studied. Results showed no α-case reaction in the TiA l-mold reaction, and the AMT + Y2O3 face coating appeared to be the best choice for investment casting of TiA l alloys under the experimental conditions.
基金Project supported by the National Magnetic Confinement Fusion Energy Research Project(Grant Nos.2019YFE03120003,2018YFE0307100,and 2017YFE0302500)the National Natural Science Foundation of China(Grant Nos.11975034,11921006,12004010,and U20B2025).
文摘The short-range repulsive interactions of any force field must be modified to be applicable for high energy atomic collisions because of extremely far from equilibrium state when used in molecular dynamics(MD)simulations.In this work,the short-range repulsive interaction of a reactive force field(ReaxFF),describing Fe-Ni-Al alloy system,is well modified by adding a tabulated function form based on Ziegler-Biersack-Littmark(ZBL)potential.The modified interaction covers three ranges,including short range,smooth range,and primordial range.The short range is totally predominated by ZBL potential.The primordial range means the interactions in this range is the as-is ReaxFF with no changes.The smooth range links the short-range ZBL and primordial-range ReaxFF potentials with a taper function.Both energies and forces are guaranteed to be continuous,and qualified to the consistent requirement in LAMMPS.This modified force field is applicable for simulations of energetic particle bombardments and reproducing point defects'booming and recombination effectively.
基金supported by the National Basic Research Program of China(973 Program,No.2011CB605500)the"Fundamental Research Funds for the Central Universities"(FRF-MP-10-005B)the National Natural Science Foundation of China under Contract No.51171015
文摘In the present study, Ti-45Al-(6, 7, 8)Nb(at%) and Ti-45Al-8Nb-0.5(Mn, Si, Y, B) alloys were prepared by arc melting and casting into Zr O2(Y2O3 stabilized) ceramic moulds to study the effect of alloying elements Nb and Mn, Si, Y, B on the interfacial reaction between casting Ti Al alloys and ceramic moulds by SEM, and the elements' distribution in the interface reaction layer by line scanning. The results showed that with an increase in Nb content, the interfacial reaction weakened and the thickness of the reaction layer decreased gradually. The interface reaction thickness of the alloys with Nb content of 6, 7, 8at% were 60, 34 and 26 μm, respectively. Clearly, the addition of 8at% Nb to Ti-45 Al is the best for the thickness of the reaction layer. The addition of Nb would form a Nb-rich film in the reaction layer, which could reduce the solubility of oxygen in the interface, and suppress further diffusion of oxygen to the matrix. If the same content of Mn, Si, Y, or B alloying elements were added respectively to Ti-45Al-8Nb, the thickness of the interface reaction layer from large to small was as follows: Mn>Si>Y>B. The interface reaction thickness increased after 0.5at% Mn added, had no obvious change after 0.5at% Si addition, and decreased after adding 0.5at% Y or B. The introduced elements, which formed a protective film or/and promoted the formation of a dense aluminum oxide layer, would be of benefit to the resistance of interfacial reaction.
基金National Natural Science Foundation of China(Grant No.51825401)the China Postdoctoral Science Foundation(Grant No.2019TQ0077).
文摘In order to refine microstructure grains and improve mechanical properties of TiAl alloys,Ti44Al(at.%)alloy was rapidly solidified by melt spinning under different cooling rates.Microstructure and microhardness of the alloy before and after rapid solidification were investigated.XRD results show that the ratio ofα2 phase in binary alloy increased with the cooling rates,which is caused by moreαphases directly transforming toα2 phases.Grain morphology changed from long dendrite to the mixture of equiaxed and dendrite to equiaxed with the increase of cooling rates.The grain size was refined from 200-600μm of as⁃cast to 18μm of the alloy cooled at 4.9×10^5 K/s,which is caused by the undercooling induced from rapid solidification.Lamellar spacing was decreased from 4.5μm of as⁃cast to 1.1μm by rapid solidification.With the increase of cooling rate,the content ofα2 phase increased andγphase decreased gradually.Rapid solidification can reduce the segregation of elements.The microhardness was improved from 247 HV to 556 HV,which results from grain refinement strengthening,reduction of lamellar spacing,and more content ofα2 phase.
文摘The microstructure evolution of the fine-grained 5083 Al alloy was investigated in annealing temperature range of 150−300℃.Then the effects of the different annealed microstructures on high-temperature deformation behavior were further studied.The results indicate that the initial recrystallization temperature is about 200℃.By tensile tests at 380−570℃and in strain rate range of 4.17×10^(−4)−1.0×10^(−2) s^(−1),the optimum superplastic parameters are obtained as follows:the annealed temperature 250℃,the tensile temperature 550℃and the strain rate 4.17×10^(−4) s^(−1).With the aid of scanning electronic microscopy(SEM),the fractography of the alloy after the superplastic deformation was analyzed.The results reveal that intergranular cavities with fine size and homogeneous distribution are beneficial to superplastic deformation.
文摘The diffusivity of hydrogen in two Ni3Al alloys (No.1 and No.2) has been measured in the temperature range of 100’C to 420’C using an ultrahigh vacuum gaseous permeation technique. The diffusivity data fall into two segments, in which the hydrogen diffusivity adheres to the Arrhenius form, respectively. From the hydrogen diffusivity, it is conjectured that the hydrogen diffusivity reflects the hydrogen transportation along the grain boundaries at lower temperature and the hydrogen transportation in the lattice at higher temperature. The intergranular fracture of L12-type intermetallics induced by hydrogen at relative low temperature results from hydrogen transportation along the grain boundaries and not in the lattice.
文摘The aging characteristics, stress corrosion behaviour and chemical composition of grain boundary in 7175 high-strength Al alloy during long term aging process have been investigated by hardness measurement, constant elongation rate testing (CERT) and energy spectroscopy analysis. The results indicate that double peaks in aged state feature the hardness and strength of 7175 Al alloy Although the intensity of double peaks is almost equal, the stress corrosion resistance in the second peak-aged state is better than that of the first peak-aged state. The effects of Mg segregation on the binding energy of grain boundary have been calculated by using free electron theory developed by the authors. The results show that Mg segregation plays a significant role in controlling stress corrosion susceptibility which is consistent with the experimental results.