Aluminum(Al)powder is widely used in solid propellants.In particular,nano-Al has attracted extensive scholarly attention in the field of energetic materials due to its higher reactivity than micro-Al.However,the exist...Aluminum(Al)powder is widely used in solid propellants.In particular,nano-Al has attracted extensive scholarly attention in the field of energetic materials due to its higher reactivity than micro-Al.However,the existence of aluminum oxide film on its surface reduces the heat release performance of the aluminum powder,which greatly limits its application.Hence,this paper used iron,a component of solid propellant,to coat micron-Al and nano-Al to improve the heat release efficiency and reactivity of Al powder.SEM,TEM,EDS,XRD,XPS,and BET were used to investigate the morphological structure and properties of pure Al and Fe/Al composite fuels of different sizes.The results show that Fe was uniformly coated on the surface of Al powder.There was no reaction between Fe and Al,and Fe/Al composite fuels had a larger specific surface area than pure Al,which could better improve the reactivity of pure Al.Besides,the catalytic effects of pure Al and Fe/Al composite fuels of different sizes on ammonium perchlorate and ammonium nitrate were explored.The results show that the catalysis of pure Al powder could be greatly improved by coating Fe on the surface of Al powder.Especially,the micron-Fe/Al composite fuel had a higher catalytic effect than the pure nano-Al powder.Hence,Fe/Al composite fuels are expected to be widely used in solid propellants.展开更多
In recent years,the addition of Ni has been widely acknowledged to be capable of enhancing the mechanical properties of Al-Si alloys.However,the effect of Ni on the wear behaviors of Al-Si alloys and Al matrix composi...In recent years,the addition of Ni has been widely acknowledged to be capable of enhancing the mechanical properties of Al-Si alloys.However,the effect of Ni on the wear behaviors of Al-Si alloys and Al matrix composites,particularly at elevated temperat-ures,remains an understudied area.In this study,Al-Si-Cu-Mg-Ni/20wt%SiC particles(SiCp)composites with varying Ni contents were prepared by using a semisolid stir casting method.The effect of Ni content on the dry sliding wear behavior of the prepared compos-ites was investigated through sliding tests at 25 and 350℃.Results indicated that theθ-Al_(2)Cu phase gradually diminished and eventually disappeared as the Ni content increased from 0wt%to 3wt%.This change was accompanied by the formation and increase inδ-Al_(3)CuNi andε-Al_(3)Ni phases in microstructures.The hardness and ultimate tensile strength of the as-cast composites improved,and the wear rates of the composites decreased from 5.29×10^(−4)to 1.94×10^(−4)mm^(3)/(N∙m)at 25℃and from 20.2×10^(−4)to 7×10^(−4)mm^(3)/(N∙m)at 350℃with the increase in Ni content from 0wt%to 2wt%.The enhancement in performance was due to the presence of strengthening network structures and additional Ni-containing phases in the composites.However,the wear rate of the 3Ni composite was approximately two times higher than that of the 2Ni composite due to the fracture and debonding of theε-Al_(3)Ni phase.Abrasive wear,delamination wear,and oxidation wear were the predominant wear mechanisms of the investigated composites at 25℃,whereas delamination wear and oxid-ation wear were dominant during sliding at 350℃.展开更多
We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surf...We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters.展开更多
Based on the purpose of solving the"secondary absorption"of adjacent nanowires and the lateral emission in the Ga N nanowire arrays(NWAs)cathode,an exponential-doping and graded Al compositional Ga N NWAs ph...Based on the purpose of solving the"secondary absorption"of adjacent nanowires and the lateral emission in the Ga N nanowire arrays(NWAs)cathode,an exponential-doping and graded Al compositional Ga N NWAs photocathode is proposed,which could generate internal electric field to increase the quantum efficiency(QE)of top surface,and the introduction of an external electric field promote the side-emission electrons to shift toward the collecting side.The QE and collection efficiency(CE)of exponential-doping and graded compositional Ga N NWAs under different array structure parameters,incident angles and external electric field intensities are analyzed.The results show that although the collection ratio of emitted electrons in the exponential-doping Ga N NWAs is higher,the graded Al compositional photocathode with a stronger built-in electric field can obtain better CE under the application of an external electric field,and the peak value can reach 33.2%in a specific structure.External electric field has a more significant effect on the CE of uniform-doping Ga N NWAs.The solutions provided in this study can make the Ga N NWAs photocathode more suitable for the strict requirements of vacuum electron sources.展开更多
In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HE...In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HEA layer was prepared by magnetron sputtering onto the Al layer.The influence of the HEA layer thickness and pouring temperature on interface evolution was investigated based on SEM observation and thermodynamic analysis.Results indicate that the sluggish diffusion effect of HEA can effectively inhibit the interfacial diffusion between Al and Mg,which is conducive to the formation of solid solution,especially when the thickness of HEA is 800 nm.With the increase of casting temperature from 720 ℃ to 730 ℃,740℃,and 750 ℃,α-Al(Mg),α-Al(Mg)+Al3Mg2,Al3Mg2+Al12Mg17,and Al12Mg17+δ-Mg are formed at the interface of Ti/Mg bimetal,respectively.When the thickness of the HEA layer is 800 nm and the pouring temperature is 720 ℃,the bonding strength of the Ti/Mg bimetal can reach the maximum of 93.6 MPa.展开更多
Al7075-Cu composite joints were prepared by the squeeze overcast process.The effects of melt temperature,die temperature,and squeeze pressure on hardness and ultimate tensile strength(UTS)of squeeze overcast Al7075-Cu...Al7075-Cu composite joints were prepared by the squeeze overcast process.The effects of melt temperature,die temperature,and squeeze pressure on hardness and ultimate tensile strength(UTS)of squeeze overcast Al7075-Cu composite joints were studied.The experimental results depict that squeeze pressure is the most significant process parameter affecting the hardness and UTS.The optimal values of UTS(48 MPa)and hardness(76 HRB)are achieved at a melt temperature of 800℃,a die temperature of 250℃,and a squeeze pressure of 90 MPa.Scanning electron microscopy(SEM)shows that fractured surfaces show flatfaced morphology at the optimal experimental condition.Energy-dispersive spectroscopy(EDS)analysis depicts that the atomic weight percentage of Zn decreases with an increase in melt temperature and squeeze pressure.The optimal mechanical properties of the Al7075-Cu overcast joint were achieved at the Al2Cu eutectic phase due to the large number of copper atoms that dispersed into the aluminum melt during the solidification process and the formation of strong intermetallic bonds.Gray relational analysis integrated with the Taguchi method was used to develop an optimal set of control variables for multi-response parametric optimization.Confirmatory tests were performed to validate the effectiveness of the employed technique.The manufacturing of squeeze overcast Al7075-Cu composite joints at optimal process parameters delivers a great indication to acknowledge a new method for foundry practitioners to manufacture materials with superior mechanical properties.展开更多
Mixed Al-Si and Al-Cu powders were investigated as insert layers to reactive diffusion bond SiCp/6063 metal matrix composite (MMC). The results show that SiCp/6063 MMC joints bonded by the insert layers of the mixed...Mixed Al-Si and Al-Cu powders were investigated as insert layers to reactive diffusion bond SiCp/6063 metal matrix composite (MMC). The results show that SiCp/6063 MMC joints bonded by the insert layers of the mixed Al-Si and Al-Cu powders have a dense joining layer of high quality. The mass transfer between the bonded materials and insert layers during bonding leads to the hypoeutectic microstructure of the joining layers bonded by both the mixed Al-Si and Al-Cu powders with eutectic composition. At fixed bonding time (temperature), the shear strength of the joints by both insert layers of the mixed Al-Si and Al-Cu powders increases with increasing the bonding temperature (time), but get maxima at bonding temperature 600℃ (time 90 min).展开更多
Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as ra...Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as rapid tool wear,high specific cutting force,and poor surface integrity.Instead,a promising method for solving these problems is laser-induced oxidation-assisted milling(LOAM):under laser irradiation,the local workpiece material reacts with oxygen,thus forming loose and porous oxides that are easily removed.In the present work,the oxidation mechanism of SiCp/Al irradiated by a nanosecond pulsed laser is studied to better understand the laser-induced oxidation behavior and control the characteristics of the oxides,with laser irradiation experiments performed on a 65%SiCp/Al composite with various laser parameters and auxiliary gases(oxygen,nitrogen,and argon).With increasing laser pulse energy density,both the ablated groove depth and the width of the heat-affected zone increase.When oxygen is used as the auxiliary gas,an oxide layer composed of SiO_(2)and Al2O3 forms,and CO_(2)is produced and escapes from the material,thereby forming pores in the oxides.However,when nitrogen or argon is used as the auxiliary gas,a recast layer is produced that is relatively difficult to remove.Under laser irradiation,the sputtered material reacts with oxygen to form oxides on both sides of the ablated groove,and as the laser scanning path advances,the produced oxides accumulate to form an oxide layer.LOAM and conventional milling are compared using the same milling parameters,and LOAM is found to be better for reduced milling force and tool wear and improved machined surface quality.展开更多
The high temperature compression test of Be/2024Al composites with 62wt%Be was conducted at 500–575℃ and strain rate of0.003–0.1 s^(-1).The strain-compensated Arrhenius model and modified Johnson–Cook model were i...The high temperature compression test of Be/2024Al composites with 62wt%Be was conducted at 500–575℃ and strain rate of0.003–0.1 s^(-1).The strain-compensated Arrhenius model and modified Johnson–Cook model were introduced to predict the hot deformation behavior of Be/2024Al composites.The result shows that the activation energy of Be/2024Al composites was 363.364 k J·mol^(-1).Compared with composites reinforced with traditional ceramics,Be/2024Al composites can be deformed with ultra-high content of reinforcement,attributing to the deformable property of Be particles.The average relative error of the two models shows that modified Johnson–Cook model was more suitable for low temperature condition while strain-compensated Arrhenius model was more suitable for high temperature condition.The processing map was generated and a hot extrusion experiment was conducted according to the map.A comparation of the microstructure of Be/2024Al composites before and after extrusion shows that the Be particle deformed coordinately with the matrix and elongated at the extrusion direction.展开更多
As a typical energetic composite,polytetrafluoroethylene(PTFE)/aluminum(Al)has been widely applied in explosives,pyrotechnics,and propellants due to its ultra-high energy density and intense exothermic reaction.In thi...As a typical energetic composite,polytetrafluoroethylene(PTFE)/aluminum(Al)has been widely applied in explosives,pyrotechnics,and propellants due to its ultra-high energy density and intense exothermic reaction.In this work,the radial gradient(RG)structure of PTFE/Al cylinders with three different PTFE morphologies(200 nm and 5μm particles and 5μm fiber)and content changes are prepared by 3D printing technology.The effect of radial gradient structure on the pressure output of PTFE/Al has been studied.Compared with the morphology change of PTFE,the change of component content in the gradient structure has an obvious effect on the pressure output of the PTFE/Al cylinder.Furthermore,the relationships of the morphology,content of PTFE and the combustion reaction of the PTFE/Al cylinder reveal that the cylinder shows a more complex flame propagation process than others.These results could provide a strategy to improve the combustion and pressure output of PTFE/Al.展开更多
The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased i...The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased implantation time(dose),and more like a parabola at the low implantation pulse voltage.When implantation pulse voltage is increased,the implantation depth increased with the nitrogen distribution peak being deepened,widened and lowered somewhat.TiN,TiN+Ti 2N,or Ti 2N second phases were formed in the implanted layer.The relative percentage of nitrogen content in the form of TiN increases when going deeper into the implanted(TiN formed) layer.The increase of implantation pulse width and/or time is favourable for the formation of TiN rather than Ti 2N.It is unfavourable for formation of any nitrides when implantation pulse voltage is decreased to 30kV or less.Tiny crystalline particles (made mainly of Ti 2N and a smaller percentage of TiO 2 phases) of regular shapes such as triangle and tetragon, etc .(about 20 nm) are found distrbuted dispersively in the near surface region of samples implanted at the high implantation pulse voltage (75kV).展开更多
The matrix accumulative roll bonding technology (MARB) can improve the matrix performance of metal composite and strengthen the bonding quality of the interface./n this research, for the fwst time, the technology of...The matrix accumulative roll bonding technology (MARB) can improve the matrix performance of metal composite and strengthen the bonding quality of the interface./n this research, for the fwst time, the technology of MARB was proposed. A sound Cu/AI bonding composite was obtained using the MARB process and the bonding characteristic of the interface was studied using scanning electricity microscope (SEM) and energy-dispersive spectroscopy (EDS). The result indicated that accumulation cycles and diffusion annealing temperature were the most important factors for fabricating a Cu/AI composite material. The substrate aluminum was strengthened by MARB, and a high quality Cu/AI composite with sound interface was obtained as well.展开更多
This paper evaluated the protection effect of the cerium conversion coatings on the SiCp/5A06 Al composite and the 5A06 Al alloy.Electrochemical impedance spectroscopy(EIS) was employed to examine the variation of the...This paper evaluated the protection effect of the cerium conversion coatings on the SiCp/5A06 Al composite and the 5A06 Al alloy.Electrochemical impedance spectroscopy(EIS) was employed to examine the variation of the electrochemical variables of the samples treated and immersed in 3.5% NaCl solution at 35 °C for 1 h,which showed the enhancement of charge transfer resistance(Rt) and coating film resistance(Rc),i.e.,the corrosion resistance of the conversion coated samples was improved.The best protection ef...展开更多
TiC/Ni_3Al composites have been prepared using upward infiltration method. The densification was performed by both Ni_3Al melt filling and TiC sintering during the infiltration. The dissolution of TiC in liquid Ni_3A...TiC/Ni_3Al composites have been prepared using upward infiltration method. The densification was performed by both Ni_3Al melt filling and TiC sintering during the infiltration. The dissolution of TiC in liquid Ni_3Al has been evidenced by finding Ni_3(Al,Ti)C after fast cooling in the TiC/Ni_3Al composites. The dissolution may be responsible for the infiltration and sintering. Compared with downward infiltration, the upward infiltration brought about higher strength and fracture toughness and shorter infiltration time. TiC/20 vol. pct Ni_3Al composite processed by upward infiltration had a flexural strength of 1476 MPa with a statistic Weibull modulus of 20.2 and a fracture toughness of 20.4 MPa . Better mechanical properties may be attributed to melt unidirectional movement in upward infiltration.展开更多
A ceramic layer was prepared on the surface of Al2O3f/ZL109 composites by means of micro-arc oxidation (MAO) technique. The surface morphology and phase constituent of the ceramic layer were analyzed using scanning ...A ceramic layer was prepared on the surface of Al2O3f/ZL109 composites by means of micro-arc oxidation (MAO) technique. The surface morphology and phase constituent of the ceramic layer were analyzed using scanning electron microscope and X-ray diffraction. The polarization curves of the composites before and after MAO treatment were measured and analyzed. The results showed that after Al2O3f/ZL109 composites were treated using MAO technique in silicate solution, the ceramic layer formed, and it was composed of Al, Si, and mullite phase. Al and Si came from Al alloy matrix of the composites, and the mullite phase formed in process of MAO. Al2O3 fiber in the composites affects the electric conductivity of the composites, the MAO reaction is promoted, and the cera- mic layer forming on the composite material side is slightly thicker than that on the Al alloy side. After Al2O3f/ZL109 composites were treated using MAO technique, the corro- sion resistance of the composites is significantly improved.展开更多
A study has been made on diffusion bonding of SiCp/2024Ai composites by means of pure Al interlayer. In the condition of TB=843 K, PB=16 MPa, tB= 60 min, the diffusion bonded joint, with a shear strength of 235 MPa, w...A study has been made on diffusion bonding of SiCp/2024Ai composites by means of pure Al interlayer. In the condition of TB=843 K, PB=16 MPa, tB= 60 min, the diffusion bonded joint, with a shear strength of 235 MPa, was obtained when a 15 μm thick interlayer was used. The results of the shear testing and SEM indicate that fracture of the joint presented characteristics of ductile rupture.展开更多
In the present study, by adding SiC particles into Al-Si-Mg melt, Mg2Si and SiC particles hybrid reinforced Al matrix composites were fabricated through the Mg2Si in situ synthesis in melt combined with the SiC ex sit...In the present study, by adding SiC particles into Al-Si-Mg melt, Mg2Si and SiC particles hybrid reinforced Al matrix composites were fabricated through the Mg2Si in situ synthesis in melt combined with the SiC ex situ stir casting. The as-cast microstructure containing primary Mg2Si and SiC particles that distribute homogenously in Al matrix was successfully achieved. The effects of SiC particle addition on the microstructure of Mg2Si/Al composites were investigated by using scanning electron microscopy(SEM) and XRD. The results show that, with increasing the fraction of the SiC particles from 5wt.% to 10wt.%, the morphologies of the primary Mg2Si particulates in the prepared samples remain polygonal, but the size of the primary phase decreases slightly. However, when the SiC particle addition reaches 15wt.%, the morphologies of the primary Mg2Si particulates change partially from polygonal to quadrangular with a decrease in size from 50 μm to 30 μm. The size of primary Al dendrites decreases with increasing fraction of the SiC particles from 0wt.% to 15wt.%. The morphology of the eutectic Mg2Si phase changes from a fi ber-form to a short fi ber-form and/or a dot-like shape with increasing fraction of the SiC particles. Furthermore, no signifi cant change in dendrite arm spacing(DAS) was observed in the presence of SiC particles.展开更多
β-SiC nanoparticle reinforced A1 matrix (nano-SiCp/A1) composite was prepared by a multi- step powder metallurgy strategy including presureless sintering, hot compacting process and hot extrusion. The microstructur...β-SiC nanoparticle reinforced A1 matrix (nano-SiCp/A1) composite was prepared by a multi- step powder metallurgy strategy including presureless sintering, hot compacting process and hot extrusion. The microstructures of the as-prepared composites were observed by scanning electronic microscopy (SEM), and the mechanical properties were characterized by tensile strength measurement and Brinell hardness test. The experimental results revealed that the tensile strength of the composite with the addition of 5wt%/3-SIC nanoprtieles could be increased to 215 MPa, increasing by 110% compared with pure A1 matrix. Comparative experiments reflected that theβ-SIC nanoprticles showed significant reinforcement effect than traditional a-SiC micro-sized particles. The preparation process and sintering procedure were investigated to develop a cost effective preparation strategy to fabricate nano-SiCp/A1 composite.展开更多
Aluminum-matrix boron carbide (B4Cp/Al) is a kind of neutron absorbing material widely used in nuclear spent fuel storage. In order to improve the tensile property of B4Cp/Al composites, a new type of nano-Al2O3 parti...Aluminum-matrix boron carbide (B4Cp/Al) is a kind of neutron absorbing material widely used in nuclear spent fuel storage. In order to improve the tensile property of B4Cp/Al composites, a new type of nano-Al2O3 particle (Al2O3np) reinforced B4Cp/Al + Al2O3np composites were prepared by powder metallurgy method. The Monte Carlo particle transport program (MCNP) was used to determine the influence of Al2O3np on the thermal neutron absorptivity of composites. The universal material testing machine and scanning electron microscope (SEM) were used to study the mechanical properties, microstructure and fracture morphology of B4Cp/Al composites. The results indicated that the neutron absorption properties of B4Cp/Al composites were not affected by the addition of nano-Al2O3 particles in the range of 1 wt%-15 wt%. The addition of Al2O3np can obviously reduce the grain size of B4Cp/Al matrix metals thus improve the tensile strength of the composites. The addition threshold of Al2O3np is about 2.5 wt%. Both B4Cp and Al2O3np change the fracture characteristics of the composites from toughness to brittleness, and the latter is more important.展开更多
An Al 50wt%TiC composite was directly synthesized by self propagating high temperature synthesis (SHS) technology,and then was used as a grain refining master alloy for commercially pure aluminum.The microstructure...An Al 50wt%TiC composite was directly synthesized by self propagating high temperature synthesis (SHS) technology,and then was used as a grain refining master alloy for commercially pure aluminum.The microstructure and grain refining performance of the synthesized master alloy were emphatically investigated.The SHS master alloy only contained submicron TiC particles except for Al matrix.Moreover,TiC particles were relatively free of agglomeration. Grain refining tests show that adding only 0.1 wt% of the master alloys to the aluminum melt could transform the structure of the solidified samples from coarse columnar grains to fine equiaxed grains (average grain size 120μm),and that this grain refining effectiveness could be maintained for almost 1.5h at 1003K. Therefore,it is concluded that the SHS master alloy is an effective grain refiner for aluminum and its alloys, and that it is highly resistant to the grain refining fading encountered with most grain refiners.展开更多
文摘Aluminum(Al)powder is widely used in solid propellants.In particular,nano-Al has attracted extensive scholarly attention in the field of energetic materials due to its higher reactivity than micro-Al.However,the existence of aluminum oxide film on its surface reduces the heat release performance of the aluminum powder,which greatly limits its application.Hence,this paper used iron,a component of solid propellant,to coat micron-Al and nano-Al to improve the heat release efficiency and reactivity of Al powder.SEM,TEM,EDS,XRD,XPS,and BET were used to investigate the morphological structure and properties of pure Al and Fe/Al composite fuels of different sizes.The results show that Fe was uniformly coated on the surface of Al powder.There was no reaction between Fe and Al,and Fe/Al composite fuels had a larger specific surface area than pure Al,which could better improve the reactivity of pure Al.Besides,the catalytic effects of pure Al and Fe/Al composite fuels of different sizes on ammonium perchlorate and ammonium nitrate were explored.The results show that the catalysis of pure Al powder could be greatly improved by coating Fe on the surface of Al powder.Especially,the micron-Fe/Al composite fuel had a higher catalytic effect than the pure nano-Al powder.Hence,Fe/Al composite fuels are expected to be widely used in solid propellants.
基金the financial support from Ningbo Institute of Technology, Beihang University
文摘In recent years,the addition of Ni has been widely acknowledged to be capable of enhancing the mechanical properties of Al-Si alloys.However,the effect of Ni on the wear behaviors of Al-Si alloys and Al matrix composites,particularly at elevated temperat-ures,remains an understudied area.In this study,Al-Si-Cu-Mg-Ni/20wt%SiC particles(SiCp)composites with varying Ni contents were prepared by using a semisolid stir casting method.The effect of Ni content on the dry sliding wear behavior of the prepared compos-ites was investigated through sliding tests at 25 and 350℃.Results indicated that theθ-Al_(2)Cu phase gradually diminished and eventually disappeared as the Ni content increased from 0wt%to 3wt%.This change was accompanied by the formation and increase inδ-Al_(3)CuNi andε-Al_(3)Ni phases in microstructures.The hardness and ultimate tensile strength of the as-cast composites improved,and the wear rates of the composites decreased from 5.29×10^(−4)to 1.94×10^(−4)mm^(3)/(N∙m)at 25℃and from 20.2×10^(−4)to 7×10^(−4)mm^(3)/(N∙m)at 350℃with the increase in Ni content from 0wt%to 2wt%.The enhancement in performance was due to the presence of strengthening network structures and additional Ni-containing phases in the composites.However,the wear rate of the 3Ni composite was approximately two times higher than that of the 2Ni composite due to the fracture and debonding of theε-Al_(3)Ni phase.Abrasive wear,delamination wear,and oxidation wear were the predominant wear mechanisms of the investigated composites at 25℃,whereas delamination wear and oxid-ation wear were dominant during sliding at 350℃.
基金Supported by Innovation and Technology Fund (No.ITP/045/19AP)Commercial Research&Development (CRD) Funding Supported by Hong Kong Productivity Council (No.10008787)。
文摘We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters.
基金supported by Qing Lan Project of Jiangsu Province-China(Grant No.2017-AD41779)the Fundamental Research Funds for the Central Universities-China(Grant No.30916011206)the Six Talent Peaks Project in Jiangsu ProvinceChina(Grant No.2015-XCL-008)。
文摘Based on the purpose of solving the"secondary absorption"of adjacent nanowires and the lateral emission in the Ga N nanowire arrays(NWAs)cathode,an exponential-doping and graded Al compositional Ga N NWAs photocathode is proposed,which could generate internal electric field to increase the quantum efficiency(QE)of top surface,and the introduction of an external electric field promote the side-emission electrons to shift toward the collecting side.The QE and collection efficiency(CE)of exponential-doping and graded compositional Ga N NWAs under different array structure parameters,incident angles and external electric field intensities are analyzed.The results show that although the collection ratio of emitted electrons in the exponential-doping Ga N NWAs is higher,the graded Al compositional photocathode with a stronger built-in electric field can obtain better CE under the application of an external electric field,and the peak value can reach 33.2%in a specific structure.External electric field has a more significant effect on the CE of uniform-doping Ga N NWAs.The solutions provided in this study can make the Ga N NWAs photocathode more suitable for the strict requirements of vacuum electron sources.
基金financial supports from the National Natural Science Foundation of China (No. 51875062)China Postdoctoral Science Foundation (No. 2021M700567)。
文摘In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HEA layer was prepared by magnetron sputtering onto the Al layer.The influence of the HEA layer thickness and pouring temperature on interface evolution was investigated based on SEM observation and thermodynamic analysis.Results indicate that the sluggish diffusion effect of HEA can effectively inhibit the interfacial diffusion between Al and Mg,which is conducive to the formation of solid solution,especially when the thickness of HEA is 800 nm.With the increase of casting temperature from 720 ℃ to 730 ℃,740℃,and 750 ℃,α-Al(Mg),α-Al(Mg)+Al3Mg2,Al3Mg2+Al12Mg17,and Al12Mg17+δ-Mg are formed at the interface of Ti/Mg bimetal,respectively.When the thickness of the HEA layer is 800 nm and the pouring temperature is 720 ℃,the bonding strength of the Ti/Mg bimetal can reach the maximum of 93.6 MPa.
文摘Al7075-Cu composite joints were prepared by the squeeze overcast process.The effects of melt temperature,die temperature,and squeeze pressure on hardness and ultimate tensile strength(UTS)of squeeze overcast Al7075-Cu composite joints were studied.The experimental results depict that squeeze pressure is the most significant process parameter affecting the hardness and UTS.The optimal values of UTS(48 MPa)and hardness(76 HRB)are achieved at a melt temperature of 800℃,a die temperature of 250℃,and a squeeze pressure of 90 MPa.Scanning electron microscopy(SEM)shows that fractured surfaces show flatfaced morphology at the optimal experimental condition.Energy-dispersive spectroscopy(EDS)analysis depicts that the atomic weight percentage of Zn decreases with an increase in melt temperature and squeeze pressure.The optimal mechanical properties of the Al7075-Cu overcast joint were achieved at the Al2Cu eutectic phase due to the large number of copper atoms that dispersed into the aluminum melt during the solidification process and the formation of strong intermetallic bonds.Gray relational analysis integrated with the Taguchi method was used to develop an optimal set of control variables for multi-response parametric optimization.Confirmatory tests were performed to validate the effectiveness of the employed technique.The manufacturing of squeeze overcast Al7075-Cu composite joints at optimal process parameters delivers a great indication to acknowledge a new method for foundry practitioners to manufacture materials with superior mechanical properties.
基金the National Natural Science Foundation of China under grant No.50175004
文摘Mixed Al-Si and Al-Cu powders were investigated as insert layers to reactive diffusion bond SiCp/6063 metal matrix composite (MMC). The results show that SiCp/6063 MMC joints bonded by the insert layers of the mixed Al-Si and Al-Cu powders have a dense joining layer of high quality. The mass transfer between the bonded materials and insert layers during bonding leads to the hypoeutectic microstructure of the joining layers bonded by both the mixed Al-Si and Al-Cu powders with eutectic composition. At fixed bonding time (temperature), the shear strength of the joints by both insert layers of the mixed Al-Si and Al-Cu powders increases with increasing the bonding temperature (time), but get maxima at bonding temperature 600℃ (time 90 min).
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.NT2021020)。
文摘Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as rapid tool wear,high specific cutting force,and poor surface integrity.Instead,a promising method for solving these problems is laser-induced oxidation-assisted milling(LOAM):under laser irradiation,the local workpiece material reacts with oxygen,thus forming loose and porous oxides that are easily removed.In the present work,the oxidation mechanism of SiCp/Al irradiated by a nanosecond pulsed laser is studied to better understand the laser-induced oxidation behavior and control the characteristics of the oxides,with laser irradiation experiments performed on a 65%SiCp/Al composite with various laser parameters and auxiliary gases(oxygen,nitrogen,and argon).With increasing laser pulse energy density,both the ablated groove depth and the width of the heat-affected zone increase.When oxygen is used as the auxiliary gas,an oxide layer composed of SiO_(2)and Al2O3 forms,and CO_(2)is produced and escapes from the material,thereby forming pores in the oxides.However,when nitrogen or argon is used as the auxiliary gas,a recast layer is produced that is relatively difficult to remove.Under laser irradiation,the sputtered material reacts with oxygen to form oxides on both sides of the ablated groove,and as the laser scanning path advances,the produced oxides accumulate to form an oxide layer.LOAM and conventional milling are compared using the same milling parameters,and LOAM is found to be better for reduced milling force and tool wear and improved machined surface quality.
基金National Natural Science Foundation of China(Nos.52171136,51871072,51871073)the Excellent Youth Scholars project of Natural Science Foundation of Heilongjiang Province(No.YQ2021E 016)Heilongjiang Touyan Team Program。
文摘The high temperature compression test of Be/2024Al composites with 62wt%Be was conducted at 500–575℃ and strain rate of0.003–0.1 s^(-1).The strain-compensated Arrhenius model and modified Johnson–Cook model were introduced to predict the hot deformation behavior of Be/2024Al composites.The result shows that the activation energy of Be/2024Al composites was 363.364 k J·mol^(-1).Compared with composites reinforced with traditional ceramics,Be/2024Al composites can be deformed with ultra-high content of reinforcement,attributing to the deformable property of Be particles.The average relative error of the two models shows that modified Johnson–Cook model was more suitable for low temperature condition while strain-compensated Arrhenius model was more suitable for high temperature condition.The processing map was generated and a hot extrusion experiment was conducted according to the map.A comparation of the microstructure of Be/2024Al composites before and after extrusion shows that the Be particle deformed coordinately with the matrix and elongated at the extrusion direction.
基金supported by the National Natural Science Foundation of China(Grant Nos.11872341 and 22075261)。
文摘As a typical energetic composite,polytetrafluoroethylene(PTFE)/aluminum(Al)has been widely applied in explosives,pyrotechnics,and propellants due to its ultra-high energy density and intense exothermic reaction.In this work,the radial gradient(RG)structure of PTFE/Al cylinders with three different PTFE morphologies(200 nm and 5μm particles and 5μm fiber)and content changes are prepared by 3D printing technology.The effect of radial gradient structure on the pressure output of PTFE/Al has been studied.Compared with the morphology change of PTFE,the change of component content in the gradient structure has an obvious effect on the pressure output of the PTFE/Al cylinder.Furthermore,the relationships of the morphology,content of PTFE and the combustion reaction of the PTFE/Al cylinder reveal that the cylinder shows a more complex flame propagation process than others.These results could provide a strategy to improve the combustion and pressure output of PTFE/Al.
文摘The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased implantation time(dose),and more like a parabola at the low implantation pulse voltage.When implantation pulse voltage is increased,the implantation depth increased with the nitrogen distribution peak being deepened,widened and lowered somewhat.TiN,TiN+Ti 2N,or Ti 2N second phases were formed in the implanted layer.The relative percentage of nitrogen content in the form of TiN increases when going deeper into the implanted(TiN formed) layer.The increase of implantation pulse width and/or time is favourable for the formation of TiN rather than Ti 2N.It is unfavourable for formation of any nitrides when implantation pulse voltage is decreased to 30kV or less.Tiny crystalline particles (made mainly of Ti 2N and a smaller percentage of TiO 2 phases) of regular shapes such as triangle and tetragon, etc .(about 20 nm) are found distrbuted dispersively in the near surface region of samples implanted at the high implantation pulse voltage (75kV).
基金the National Natural Science Foundation of China (No. 50375019).
文摘The matrix accumulative roll bonding technology (MARB) can improve the matrix performance of metal composite and strengthen the bonding quality of the interface./n this research, for the fwst time, the technology of MARB was proposed. A sound Cu/AI bonding composite was obtained using the MARB process and the bonding characteristic of the interface was studied using scanning electricity microscope (SEM) and energy-dispersive spectroscopy (EDS). The result indicated that accumulation cycles and diffusion annealing temperature were the most important factors for fabricating a Cu/AI composite material. The substrate aluminum was strengthened by MARB, and a high quality Cu/AI composite with sound interface was obtained as well.
基金supported by Higher Education Commission of Pakistan
文摘This paper evaluated the protection effect of the cerium conversion coatings on the SiCp/5A06 Al composite and the 5A06 Al alloy.Electrochemical impedance spectroscopy(EIS) was employed to examine the variation of the electrochemical variables of the samples treated and immersed in 3.5% NaCl solution at 35 °C for 1 h,which showed the enhancement of charge transfer resistance(Rt) and coating film resistance(Rc),i.e.,the corrosion resistance of the conversion coated samples was improved.The best protection ef...
文摘TiC/Ni_3Al composites have been prepared using upward infiltration method. The densification was performed by both Ni_3Al melt filling and TiC sintering during the infiltration. The dissolution of TiC in liquid Ni_3Al has been evidenced by finding Ni_3(Al,Ti)C after fast cooling in the TiC/Ni_3Al composites. The dissolution may be responsible for the infiltration and sintering. Compared with downward infiltration, the upward infiltration brought about higher strength and fracture toughness and shorter infiltration time. TiC/20 vol. pct Ni_3Al composite processed by upward infiltration had a flexural strength of 1476 MPa with a statistic Weibull modulus of 20.2 and a fracture toughness of 20.4 MPa . Better mechanical properties may be attributed to melt unidirectional movement in upward infiltration.
基金financially supported by the National University Student Innovation Program (No. 101011202)
文摘A ceramic layer was prepared on the surface of Al2O3f/ZL109 composites by means of micro-arc oxidation (MAO) technique. The surface morphology and phase constituent of the ceramic layer were analyzed using scanning electron microscope and X-ray diffraction. The polarization curves of the composites before and after MAO treatment were measured and analyzed. The results showed that after Al2O3f/ZL109 composites were treated using MAO technique in silicate solution, the ceramic layer formed, and it was composed of Al, Si, and mullite phase. Al and Si came from Al alloy matrix of the composites, and the mullite phase formed in process of MAO. Al2O3 fiber in the composites affects the electric conductivity of the composites, the MAO reaction is promoted, and the cera- mic layer forming on the composite material side is slightly thicker than that on the Al alloy side. After Al2O3f/ZL109 composites were treated using MAO technique, the corro- sion resistance of the composites is significantly improved.
基金the National Advanced Technology "863" Project of China with !No.715-005-0800
文摘A study has been made on diffusion bonding of SiCp/2024Ai composites by means of pure Al interlayer. In the condition of TB=843 K, PB=16 MPa, tB= 60 min, the diffusion bonded joint, with a shear strength of 235 MPa, was obtained when a 15 μm thick interlayer was used. The results of the shear testing and SEM indicate that fracture of the joint presented characteristics of ductile rupture.
基金supported by the National Natural Science Foundation of China(No.50671044)the Sci-tech Development Project of Jilin Province of China(No.20070506)
文摘In the present study, by adding SiC particles into Al-Si-Mg melt, Mg2Si and SiC particles hybrid reinforced Al matrix composites were fabricated through the Mg2Si in situ synthesis in melt combined with the SiC ex situ stir casting. The as-cast microstructure containing primary Mg2Si and SiC particles that distribute homogenously in Al matrix was successfully achieved. The effects of SiC particle addition on the microstructure of Mg2Si/Al composites were investigated by using scanning electron microscopy(SEM) and XRD. The results show that, with increasing the fraction of the SiC particles from 5wt.% to 10wt.%, the morphologies of the primary Mg2Si particulates in the prepared samples remain polygonal, but the size of the primary phase decreases slightly. However, when the SiC particle addition reaches 15wt.%, the morphologies of the primary Mg2Si particulates change partially from polygonal to quadrangular with a decrease in size from 50 μm to 30 μm. The size of primary Al dendrites decreases with increasing fraction of the SiC particles from 0wt.% to 15wt.%. The morphology of the eutectic Mg2Si phase changes from a fi ber-form to a short fi ber-form and/or a dot-like shape with increasing fraction of the SiC particles. Furthermore, no signifi cant change in dendrite arm spacing(DAS) was observed in the presence of SiC particles.
基金Funded by the Research Collaborative Innovation Project of Jiangsu Province,China(BY2009129)the Science and Technology Project of Suzhou,China(SYG0905)
文摘β-SiC nanoparticle reinforced A1 matrix (nano-SiCp/A1) composite was prepared by a multi- step powder metallurgy strategy including presureless sintering, hot compacting process and hot extrusion. The microstructures of the as-prepared composites were observed by scanning electronic microscopy (SEM), and the mechanical properties were characterized by tensile strength measurement and Brinell hardness test. The experimental results revealed that the tensile strength of the composite with the addition of 5wt%/3-SIC nanoprtieles could be increased to 215 MPa, increasing by 110% compared with pure A1 matrix. Comparative experiments reflected that theβ-SIC nanoprticles showed significant reinforcement effect than traditional a-SiC micro-sized particles. The preparation process and sintering procedure were investigated to develop a cost effective preparation strategy to fabricate nano-SiCp/A1 composite.
基金Funded by Natural National Science Foundation of China(NSFC)(No.11305149)National High-Tech R&D Program(863 Program)(No.2013AA030704)。
文摘Aluminum-matrix boron carbide (B4Cp/Al) is a kind of neutron absorbing material widely used in nuclear spent fuel storage. In order to improve the tensile property of B4Cp/Al composites, a new type of nano-Al2O3 particle (Al2O3np) reinforced B4Cp/Al + Al2O3np composites were prepared by powder metallurgy method. The Monte Carlo particle transport program (MCNP) was used to determine the influence of Al2O3np on the thermal neutron absorptivity of composites. The universal material testing machine and scanning electron microscope (SEM) were used to study the mechanical properties, microstructure and fracture morphology of B4Cp/Al composites. The results indicated that the neutron absorption properties of B4Cp/Al composites were not affected by the addition of nano-Al2O3 particles in the range of 1 wt%-15 wt%. The addition of Al2O3np can obviously reduce the grain size of B4Cp/Al matrix metals thus improve the tensile strength of the composites. The addition threshold of Al2O3np is about 2.5 wt%. Both B4Cp and Al2O3np change the fracture characteristics of the composites from toughness to brittleness, and the latter is more important.
文摘An Al 50wt%TiC composite was directly synthesized by self propagating high temperature synthesis (SHS) technology,and then was used as a grain refining master alloy for commercially pure aluminum.The microstructure and grain refining performance of the synthesized master alloy were emphatically investigated.The SHS master alloy only contained submicron TiC particles except for Al matrix.Moreover,TiC particles were relatively free of agglomeration. Grain refining tests show that adding only 0.1 wt% of the master alloys to the aluminum melt could transform the structure of the solidified samples from coarse columnar grains to fine equiaxed grains (average grain size 120μm),and that this grain refining effectiveness could be maintained for almost 1.5h at 1003K. Therefore,it is concluded that the SHS master alloy is an effective grain refiner for aluminum and its alloys, and that it is highly resistant to the grain refining fading encountered with most grain refiners.