Influences of Al3+ concentration on hydrothermally synthesized xonotlite whiskers were researched in this paper. The crystal phase composition and morphology of the products were analyzed and characterized using XRD a...Influences of Al3+ concentration on hydrothermally synthesized xonotlite whiskers were researched in this paper. The crystal phase composition and morphology of the products were analyzed and characterized using XRD and SEM techniques. The results indicate that Al3+ concentration have great impact on the crystal phase composition and morphology of the xonotlite whiskers in CaO-SiO2-H2O system under the condition of initial CaO/SiO2 mol ratio of 1.0, reactant concentration of 0.05 mol·L-1 , at 225 ℃ for 15 h. The main crystal phase of hydrothermally synthesized products had a phase transition from xonotlite to tobermorite, and the morphology changed from fibrous to tabular with increasing the concentration of Al3+ ion. At last, in order to prepare the pure xonotlite whiskers via hydrothermal synthesis in CaO-SiO2-H2O system, the Al2O3 contents in raw materials should be less than 1%.展开更多
基金financially supported by the National Basic Research Program of China(973 Program,2010CB226901,2013CB934100)the National Natural Science Foundation of China(U1463206)~~
基金Doctor Start-up Foundation of Guizhou University (2010-041)Team Foundation of Green Chemical Engineering in Guizhou Province(2009-4002)Science Technology Foundation of Guizhou (20092052)
文摘Influences of Al3+ concentration on hydrothermally synthesized xonotlite whiskers were researched in this paper. The crystal phase composition and morphology of the products were analyzed and characterized using XRD and SEM techniques. The results indicate that Al3+ concentration have great impact on the crystal phase composition and morphology of the xonotlite whiskers in CaO-SiO2-H2O system under the condition of initial CaO/SiO2 mol ratio of 1.0, reactant concentration of 0.05 mol·L-1 , at 225 ℃ for 15 h. The main crystal phase of hydrothermally synthesized products had a phase transition from xonotlite to tobermorite, and the morphology changed from fibrous to tabular with increasing the concentration of Al3+ ion. At last, in order to prepare the pure xonotlite whiskers via hydrothermal synthesis in CaO-SiO2-H2O system, the Al2O3 contents in raw materials should be less than 1%.
