Low-temperature Sintering of FeCuCo based Pre-alloyed Powder for Diamond Bits

We studied the effects of sintering temperature on FeCuCo based pre-alloyed powder for diamond bits.The FeCuCo composite was fabricated by co-precipitation method.With the addition of tungsten carbide（WC）,sintering under different temperatures was investigated.Mechanical properties of the FeCuCo based matrix were systematically studied.The structure of the composite was evaluated by X-ray diffraction（XRD） and scanning electron microscope（SEM） was used to analyze the surface of the powder and matrix.The suitable sintering temperature was determined through differential scanning calorimeter（DSC）.Micro drilling experiments were performed,and 820 ℃ was identified to be the ideal sintering temperature,at which the matrix shows the best mechanical properties and drilling performance.

Preparation and Arc Erosion Characteristics of Ultrafine Crystalline CuCr50 Alloy by MA-SPS

The ultrafine crystalline CuCr50（Cr 50 wt%） alloys were fabricated by a combination of mechanical alloying and spark plasma sintering process. The effects of milling time on crystallite size and solid solubility of the CuCr50 composite powders were investigated. The results showed that crystallite size of powders decreases gradually and solid solubility of Cr in Cu was extended with increasing milling time. The minimal crystallite size about 10 nm and the maximum solid solubility about 8.4 at%（i e, 7 wt%） were obtained at 60 h. The microstructure of ultrafine crystalline CuCr50 alloy was analyzed by SEM and TEM, which contains two kinds of size scale Cr particles of 2 μm and 50-150 nm, distributing homogeneously in matrix, respectively. The arc erosion characteristics of ultrafine crystalline CuCr50 alloy were investigated by the vacuum contact simulation test device in low D.C. voltage and low current（24 V/10 A）. A commercial microcrystalline CuCr50 alloy was also investigated for comparison. Experiments indicate that the cathode mass loss of ultrafine crystalline CuCr50 contact material is higher than that of microcrystalline CuCr50 material, but its eroded surface morphology by the arc is uniform without obvious erosion pits. While the surface of microcrystalline CuCr50 contact is seriously eroded in local area by the arc, an obvious erosion pit occurred in the core part. Therefore, the ability of arc erosion resistance of ultrafine crystalline CuCr50 alloy is improved compared to that of microcrystalline CuCr50 material.

THE RELATION BETWEEN THE TEMPERING EFFECTS AND THE INTRINSIC COERCIVITY OF SINTERED SmCo5 ALLOY AT 750℃

The relation between the tempering effects of sinterd SmCo^(5)alloy at 750℃and its intrinsic coercivity(i^(Hc))has been studied by the use of photoelectron energy spectrum.X-ray diffraction and high-voltage electron microscope.The result is that the cause of iHc dropping seriously for sintered SmCo_(5)alloy tempered at 750 t is not the eutectoid decomposition of SmCo_(5)and the increase of oxygen.In fact,iHcdropping is caused by that some defect-rich regions in Sm_(2)Co_(17)decomposed form SmC0_(5)from nucleation centers in reversed magnetization course.

Effect of cerium/lanthanum addition on microstructure and mechanical properties of Al7075 alloy via mechanical alloying and sintering

The effect of the Al-6Ce-3La（ACL） on the microstructural behavior of the Al7075 was investigated. Materials were synthesized by mechanical alloying with variation in the ACL content and milling time. Products were characterized and studied in the as-milled condition and mechanically evaluated after sintering. The synergetic effect of milling time and ACL content in the modified materials led to a reduction in the particle size. Results from electron microscopy showed a homogeneous dispersion of Ce/La phases up to 20 wt.% of ACL content after 10 h of milling. Mechanical evaluation under compressive test showed an improved performance for those alloys reinforced with 0.2 wt.% and 0.5 wt.% of ACL.

Microstructures and properties of CuZrAl and CuZrAlTi medium entropy alloys prepared by mechanical alloying and spark plasma sintering

Equiatomic CuZrAl and CuZrAlTi medium entropy alloys were designed and synthesized by mechanical alloying and spark plasma sintering technique.The alloying behavior,phase evolutions,microstructures and properties of samples were investigated by X-ray diffraction,differential scanning calorimetry,field emission scanning electron microscopy,microscopy/Vickers hardness testing and electrochemical polarization measurement.The results indicate that the final products of as-milled alloys consist of amorphous phases.Ti addition improves the glass forming ability of as-milled alloys.The as-sintered CuZrAl alloy contains face-centered cubic（fcc）solid solution,Al_（1.05）Cu_（0.95） Zr and AlZr_2 phases at different sintering temperatures.With Ti addition,the as-sintered sample is only composed of intermetallics at 690°C,while fcc1,fcc2 and CuTi3phases are formed at 1100°C.CuZrAlTi-1100°C alloy exhibits the highest hardness value of 1173HV0.2owing to the high sintering density,solid solution strengthening and homogeneous precipitation of nano-size crystalline phase.CuZrAlTi-690°C alloy presents a similar corrosion resistance with304 Lstainless steel in seawater solution and further possesses the lower corrosion rate.

Preparation and properties of W–Cu–Zn alloy with low W–W contiguity

The W–Cu–Zn alloy with a-brass matrix and low W–W contiguity was prepared by method of electroless copper plating combined with spark plasma sintering（SPS） method.The effects of process and parameters on the microstructure and mechanical properties of the alloy were investigated.The W–Cu–Zn alloy with a relative density of 96 % and a W–W contiguity of about 10 % was prepared by original fine tungsten particles combined with wet mixing method and SPS solid-state sintering method at 800℃ for 10 min.The microstructure analysis shows that Cu–Zn matrix consists of nano-sized a-brass grains,and the main composition is Cu3Zn electride.The nano-sized Cu was coated on the surface of tungsten particles by electroless copper plating method,and the fairly low consolidation temperature and short solid-state sintering time result in the nano-sized matrix phase.The dynamic compressive strength of the W–Cu–Zn alloy achieves to1000 MPa,but the alloy shows poor ductility due to the formation of the hard and brittle Cu3Zn electrides.The fine-grain strengthening and the solution strengthening of the Cu–Zn matrix phase are responsible for the high Vickers microhardness of about 300 MPa for W–Cu–Zn alloy.

Effects of Chromium Addition on Preparation and Properties of Bulk Cementite

Bulk cementites with the Cr contents of 0,3.01,6.03,8.22,and 11.51mass% were prepared by mechanical alloying（MA）and spark plasma sintering（SPS）.The results indicated that when the Cr content was low（3.01mass%）,the phases were composed of cementite with a small amount ofα-Fe at a sintering temperature of 1 173 K,but the microstructure became single-phase alloyed cementite as the Cr content was further increased.It showed that microaddition of Cr was beneficial for promoting the formation of cementite.Furthermore,the mechanical performance of cementite can be greatly affected by the variation of Cr content.The hardness,elastic modulus and elastic recovery presented a remarkably increasing tendency with the addition of Cr,and the maximum micro-hardness and elastic modulus values reached 1 070.74 HV and 199.32 GPa,respectively,which were similar to the precipitation phase（cementite）obtained by melting and casting techniques.Moreover,when the Cr content was below 11.51mass%,the crystal structure of Fe3C-type cementite would not change with increasing the Cr content.A Cr atom replaced an Fe atom in the lattice of the cementite,and voids appeared when Cr was doped into the cementite at content of about11.51mass%,causing the relative density to decrease.