Upper atmosphere composition data were obtained for the last half year with a quadruple mass spectrometer on board spacecraft "SZ-2" launched on 10 Jan uary 2001. Based on the analysis of these data, the var...Upper atmosphere composition data were obtained for the last half year with a quadruple mass spectrometer on board spacecraft "SZ-2" launched on 10 Jan uary 2001. Based on the analysis of these data, the variations of atmospheric compositions in solar and geomagnetic quiet conditions are reported first, then a detailed discussion on the atmospheric composition variations under the so lar and geomagnetic disturbed conditions is given. The results show that near the altitude of 400 km the variations of main atmospheric compositions corre sponding to solar disturbances are more remarkable in the sunlit area than in the shade area. On the contrary, in geomagnetic disturbance events the corre sponding variations are more obvious in the shade area, an evident increase of N2 density at relatively higher latitudes was observed.展开更多
The chemical composition of atmospheric aerosols has been investigated. Contributions ofsulfate and soot in aerosols to the atmospheric extinction are studied. Discussions are made on the problems of aerosol emitted f...The chemical composition of atmospheric aerosols has been investigated. Contributions ofsulfate and soot in aerosols to the atmospheric extinction are studied. Discussions are made on the problems of aerosol emitted from volcano, forest fires in northern China, 1987 and oil field fires in Kuwait, 1991. It is indicated that the changes in concentration, particle size, and chemical composition of aerosol after those events could have impacts on the climate change either regionally or globally and that the impact of aerosol particles on climate change could compensate for some temperature increase caused by greenhouse gases and the increase of surface intensity of ultraviolet radiation due to ozone layer depletion.展开更多
A global two-dimensional zonally averaged chemistry model is developed to study the chemi-cal composition of atmosphere. The region of the model is from 90°S to 90°N and from the ground to the altitude of 20...A global two-dimensional zonally averaged chemistry model is developed to study the chemi-cal composition of atmosphere. The region of the model is from 90°S to 90°N and from the ground to the altitude of 20 km with a resolution of 5° x 1 km. The wind field is residual circulation calcu-lated from diabatic rate. 34 species and 104 chemical and photochemical reactions are considered in the model. The sources of CH4, CO and NOx, which are divided into seasonal sources and non-seasonal sources, are parameterized as a function of latitude and time. The chemical composi-tion of atmosphere was simulated with emission level of CH4, CO and NOx in 1990. The results are compared with observations and other model results, showing that the model is successful to simu-late the atmospheric chemical composition and distribution of CH4. Key words Global two-dimensional chemistry model - Atmospheric composition - Emission This work was supported by the State Key Program for basic research “ Climate Dynamics and Cli-mate Prediction Theory” (Pandeng-yu-21).The authors would like to express their thanks to the National Oceanic and Atmospheric Administration (NOAA), Climate Monitoring and Diagnostics Laboratory (CMDL), Carbon Cycle Group for providing the observational data of CO and CH4.展开更多
The paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide-n...The paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide-nickel-chromium(WC/Ni-Cr)catalytic additive and without it.The cracking is carried out in an autoclave at 500℃for 30 min.The addition of the WC/Ni-Cr additive promotes the deepening of reactions of destruction not only of resins and asphaltenes,but also high molecular weight naphthene-aromatic compounds of the atmospheric residue.It is shown that the content of low molecular weight C9-C17 n-alkanes and C9-C10 alkylbenzenes rose sharply in the products of cracking with addition of WC/Ni-Cr in comparison with those produced without the additive.Alkyl-and naphthene-substituted aromatic hydrocarbons of benzene,naphthalene,phenanthrene series,polyarenes,benzo-and dibenzothiophenes are identified.展开更多
The microprobe EDXRF equipment was used for analysis of the major and trace elements in glaze layer-transitive layer-body layer of the celadon from the Altar Yao （Kiln） and Laohudong Yao in the Southern Song Dynasty...The microprobe EDXRF equipment was used for analysis of the major and trace elements in glaze layer-transitive layer-body layer of the celadon from the Altar Yao （Kiln） and Laohudong Yao in the Southern Song Dynasty （1127-1279 A.D.）, Zhejiang, China. The K values of the discriminant factor for the celadon wares are larger than 8, which means the celadon of the Altar Yao and Laohudong Yao are different from that of the Longquan Yao. The former two belong to the Guan Yao system （the Chinese imperial kilns）, but the latter to the Min Yao system （the Chinese popular kilns）. The principle component analysis shows their relationship between the Altar and Laohudong wares with provenance postulation. The thickness of the transitive layer in the Altar and Laohudong wares is obviously different, which reveals the microstructure characteristics of the celadon even though both kinds of wares belong to the imperial kiln system.展开更多
In order to know the particle size distribution and mineral compositions of dust in Maiji town, Tianshui City, Gansu Province, size distribution and physical compositions of atmosphere natural dropping dust have been ...In order to know the particle size distribution and mineral compositions of dust in Maiji town, Tianshui City, Gansu Province, size distribution and physical compositions of atmosphere natural dropping dust have been analyzed. Based on the natural dropping dust ζ potential and the mass percentage of main mineral compositions in dust fall, we present two models (calculation method and hybrid method) for the zeta potential of atmospheric dust fall in pure water. The results illustrated that the natural dropping dust in Maiji town belongs to inhalable particles. The main mineral compositions and contents of the dust are quartz (57.08%), calcite (27.79%), albite (10.29%), muscovite (4.84%). Atmospheric dust fall in pure water is electronegativity and ζ potential decreased with increasing pH. There are some differences exist in the two modeling ways, but have a similar tendency. The zeta potential differences between natural dropping dust and modeling dust reflects the zeta potential contribution rate of main mineral particles in dust and the effect of trace polarity organic pollutants or other minerals.展开更多
Galvanic, compatibility between graphite epoxy composite materials (GECM) and LY12CZ aluminum alloy was evaluated in different atmospheric corrosion environments and by laboratory electrochemical measurements. Open ci...Galvanic, compatibility between graphite epoxy composite materials (GECM) and LY12CZ aluminum alloy was evaluated in different atmospheric corrosion environments and by laboratory electrochemical measurements. Open circuit potential electrochemical measurements showed a relatively large potential difference about 1 volt between the GECM and LY12CZ aluminum alloy, and this difference provided the driving force for galvanic corrosion of the LY12CZ aluminum alloy as an anode. Having been exposed for 1, 3 or 5 years in Beijing, Tuandao and Wanning station, GECM/LY12CZ couples showed significant losses of strength and elongation. Protective coatings and non-conductive barriers breaking the galvanic corrosion circuit were evaluated under the same atmospheric corrosive conditions. Epoxy primer paint, glass cloth barriers and LY12CZ anodizing were effective in galvanic corrosion control for GECM/LY12CZ couples.展开更多
A genetic algorithm based multi-objective coordinative optimization strategy is developed to optimize the operation of a binary feed atmospheric and vacuum distillation system, in which the objective functions cover t...A genetic algorithm based multi-objective coordinative optimization strategy is developed to optimize the operation of a binary feed atmospheric and vacuum distillation system, in which the objective functions cover the economic benefit, the furnace energy consumption and the CO_2 emissions, and meanwhile the simultaneous effect of binary feed composition is also investigated. A cross-call integration of software is developed to implement the optimization algorithm,and once the maximum economic benefit, the minimum furnace energy consumption and the minimum CO_2 emissions are obtained, the Pareto-optimal solution set is worked out, with the practical problems of the refinery being solved. The optimization result shows that under the same furnace energy consumption and the CO_2 emissions as the existing working condition, the economic benefit still allows for a considerable potential of increment by adjusting the heavy oil proportion of the binary feed crude oil.展开更多
Al2 O3-Si-Al composite specimens with the size of 25 mm × 25 mm × 125 mm were prepared using fused alumina （as aggregates and fines）,ultra-fine α-Al2O3,Si and Al powders as starting materials,liquid pheno...Al2 O3-Si-Al composite specimens with the size of 25 mm × 25 mm × 125 mm were prepared using fused alumina （as aggregates and fines）,ultra-fine α-Al2O3,Si and Al powders as starting materials,liquid phenol formaldehyde resin as the binder,pressing and heating at 800-1 500 ℃ for 3 h under carbon embedded condition.Evolution of phase composition and microstructure of Al2 O3-Si-Al composite during heating from 800 to 1 500 ℃ under carbon embedded condition were studied.The results show that：（1） Al4 C3,AlN and SiC are initially formed at 800-900 ℃ due to reactions of Al and Si with C or CO and N2 ; （2） at 1 000-1 300 ℃,the amounts of Al4C3,AlN and SiC increase with temperature rising and their crystals grow; （3） at 1 400-1 500 ℃,Al4 C3 and AlN disappear,and minor SiAlON crystals are observed; the nonoxide crystals develop well and they are interlaced in the corundum skeleton structure,which creates strengthening and toughening展开更多
Hekou ancient town,Qianshan County,Jiangxi Province,is one of the famous towns in the south of Jiangxi Province in the Qing Dynasty.It is on a par with Jingdezhen Town,Zhangshu Town and Wucheng Town,and they are known...Hekou ancient town,Qianshan County,Jiangxi Province,is one of the famous towns in the south of Jiangxi Province in the Qing Dynasty.It is on a par with Jingdezhen Town,Zhangshu Town and Wucheng Town,and they are known as the four famous towns in Jiangxi Province.Because of the late development,people s understanding of it is still very limited.Based on the phenomenology of architecture and the place theory of Norberg-Schulz,this paper makes a comprehensive analysis of the composition of Hekou ancient town,in order to have a more comprehensive understanding of Hekou ancient town and provide some reference for the protection and renewal of Hekou ancient town.展开更多
Study of atmospheric remnants in the low Earth orbit region (~200 km altitude) using Global Models, with application to electric thrusters of in situ resources utilization type.
Wavelike perturbations in the ionosphere of Titan,the largest satellite of Saturn,are explored based on the Cassini Ion Neutral Mass Spectrometer(INMS)measurements.Strong wavelike perturbations are identified for more...Wavelike perturbations in the ionosphere of Titan,the largest satellite of Saturn,are explored based on the Cassini Ion Neutral Mass Spectrometer(INMS)measurements.Strong wavelike perturbations are identified for more than twenty ion species,from simple ones such as N^(+)and CH_(4)^(+)to complex ones such as C_(2)H_(3)CNH^(+)and C_(4)H_(7)^(+).Simultaneous wavelike perturbations in background N_(2),indicative of atmospheric gravity waves,are also observed,motivating us to speculate that the INMS-derived ion perturbations are wave-driven.The amplitudes of the ion perturbations are found to be larger than that of the N_(2)perturbations.Clear compositional variation is revealed by the data:heavier ion species exhibit greater amplitudes.Such observations might be understood based on considerations either of force balance or chemical loss in Titan’s ionosphere.展开更多
文摘Upper atmosphere composition data were obtained for the last half year with a quadruple mass spectrometer on board spacecraft "SZ-2" launched on 10 Jan uary 2001. Based on the analysis of these data, the variations of atmospheric compositions in solar and geomagnetic quiet conditions are reported first, then a detailed discussion on the atmospheric composition variations under the so lar and geomagnetic disturbed conditions is given. The results show that near the altitude of 400 km the variations of main atmospheric compositions corre sponding to solar disturbances are more remarkable in the sunlit area than in the shade area. On the contrary, in geomagnetic disturbance events the corre sponding variations are more obvious in the shade area, an evident increase of N2 density at relatively higher latitudes was observed.
文摘The chemical composition of atmospheric aerosols has been investigated. Contributions ofsulfate and soot in aerosols to the atmospheric extinction are studied. Discussions are made on the problems of aerosol emitted from volcano, forest fires in northern China, 1987 and oil field fires in Kuwait, 1991. It is indicated that the changes in concentration, particle size, and chemical composition of aerosol after those events could have impacts on the climate change either regionally or globally and that the impact of aerosol particles on climate change could compensate for some temperature increase caused by greenhouse gases and the increase of surface intensity of ultraviolet radiation due to ozone layer depletion.
文摘A global two-dimensional zonally averaged chemistry model is developed to study the chemi-cal composition of atmosphere. The region of the model is from 90°S to 90°N and from the ground to the altitude of 20 km with a resolution of 5° x 1 km. The wind field is residual circulation calcu-lated from diabatic rate. 34 species and 104 chemical and photochemical reactions are considered in the model. The sources of CH4, CO and NOx, which are divided into seasonal sources and non-seasonal sources, are parameterized as a function of latitude and time. The chemical composi-tion of atmosphere was simulated with emission level of CH4, CO and NOx in 1990. The results are compared with observations and other model results, showing that the model is successful to simu-late the atmospheric chemical composition and distribution of CH4. Key words Global two-dimensional chemistry model - Atmospheric composition - Emission This work was supported by the State Key Program for basic research “ Climate Dynamics and Cli-mate Prediction Theory” (Pandeng-yu-21).The authors would like to express their thanks to the National Oceanic and Atmospheric Administration (NOAA), Climate Monitoring and Diagnostics Laboratory (CMDL), Carbon Cycle Group for providing the observational data of CO and CH4.
文摘The paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide-nickel-chromium(WC/Ni-Cr)catalytic additive and without it.The cracking is carried out in an autoclave at 500℃for 30 min.The addition of the WC/Ni-Cr additive promotes the deepening of reactions of destruction not only of resins and asphaltenes,but also high molecular weight naphthene-aromatic compounds of the atmospheric residue.It is shown that the content of low molecular weight C9-C17 n-alkanes and C9-C10 alkylbenzenes rose sharply in the products of cracking with addition of WC/Ni-Cr in comparison with those produced without the additive.Alkyl-and naphthene-substituted aromatic hydrocarbons of benzene,naphthalene,phenanthrene series,polyarenes,benzo-and dibenzothiophenes are identified.
文摘The microprobe EDXRF equipment was used for analysis of the major and trace elements in glaze layer-transitive layer-body layer of the celadon from the Altar Yao （Kiln） and Laohudong Yao in the Southern Song Dynasty （1127-1279 A.D.）, Zhejiang, China. The K values of the discriminant factor for the celadon wares are larger than 8, which means the celadon of the Altar Yao and Laohudong Yao are different from that of the Longquan Yao. The former two belong to the Guan Yao system （the Chinese imperial kilns）, but the latter to the Min Yao system （the Chinese popular kilns）. The principle component analysis shows their relationship between the Altar and Laohudong wares with provenance postulation. The thickness of the transitive layer in the Altar and Laohudong wares is obviously different, which reveals the microstructure characteristics of the celadon even though both kinds of wares belong to the imperial kiln system.
文摘In order to know the particle size distribution and mineral compositions of dust in Maiji town, Tianshui City, Gansu Province, size distribution and physical compositions of atmosphere natural dropping dust have been analyzed. Based on the natural dropping dust ζ potential and the mass percentage of main mineral compositions in dust fall, we present two models (calculation method and hybrid method) for the zeta potential of atmospheric dust fall in pure water. The results illustrated that the natural dropping dust in Maiji town belongs to inhalable particles. The main mineral compositions and contents of the dust are quartz (57.08%), calcite (27.79%), albite (10.29%), muscovite (4.84%). Atmospheric dust fall in pure water is electronegativity and ζ potential decreased with increasing pH. There are some differences exist in the two modeling ways, but have a similar tendency. The zeta potential differences between natural dropping dust and modeling dust reflects the zeta potential contribution rate of main mineral particles in dust and the effect of trace polarity organic pollutants or other minerals.
基金The authors gratefully acknowledge the financial support from National Key Basic Research and Development Programme of China (No. G1999065004).
文摘Galvanic, compatibility between graphite epoxy composite materials (GECM) and LY12CZ aluminum alloy was evaluated in different atmospheric corrosion environments and by laboratory electrochemical measurements. Open circuit potential electrochemical measurements showed a relatively large potential difference about 1 volt between the GECM and LY12CZ aluminum alloy, and this difference provided the driving force for galvanic corrosion of the LY12CZ aluminum alloy as an anode. Having been exposed for 1, 3 or 5 years in Beijing, Tuandao and Wanning station, GECM/LY12CZ couples showed significant losses of strength and elongation. Protective coatings and non-conductive barriers breaking the galvanic corrosion circuit were evaluated under the same atmospheric corrosive conditions. Epoxy primer paint, glass cloth barriers and LY12CZ anodizing were effective in galvanic corrosion control for GECM/LY12CZ couples.
基金supported financially by the Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province (Grant No. BS2014NJ010)the National Natural Science Foundation of China (Grant No. 21506255)
文摘A genetic algorithm based multi-objective coordinative optimization strategy is developed to optimize the operation of a binary feed atmospheric and vacuum distillation system, in which the objective functions cover the economic benefit, the furnace energy consumption and the CO_2 emissions, and meanwhile the simultaneous effect of binary feed composition is also investigated. A cross-call integration of software is developed to implement the optimization algorithm,and once the maximum economic benefit, the minimum furnace energy consumption and the minimum CO_2 emissions are obtained, the Pareto-optimal solution set is worked out, with the practical problems of the refinery being solved. The optimization result shows that under the same furnace energy consumption and the CO_2 emissions as the existing working condition, the economic benefit still allows for a considerable potential of increment by adjusting the heavy oil proportion of the binary feed crude oil.
基金financially supported by Henan Scientific and Technological Research Projects ( 112102210095 )Science Fund for Distinguished Young Scholars of Henan Province ( 124100510019)the Education Department of Henan Province Foundation ( 14A430030)
文摘Al2 O3-Si-Al composite specimens with the size of 25 mm × 25 mm × 125 mm were prepared using fused alumina （as aggregates and fines）,ultra-fine α-Al2O3,Si and Al powders as starting materials,liquid phenol formaldehyde resin as the binder,pressing and heating at 800-1 500 ℃ for 3 h under carbon embedded condition.Evolution of phase composition and microstructure of Al2 O3-Si-Al composite during heating from 800 to 1 500 ℃ under carbon embedded condition were studied.The results show that：（1） Al4 C3,AlN and SiC are initially formed at 800-900 ℃ due to reactions of Al and Si with C or CO and N2 ; （2） at 1 000-1 300 ℃,the amounts of Al4C3,AlN and SiC increase with temperature rising and their crystals grow; （3） at 1 400-1 500 ℃,Al4 C3 and AlN disappear,and minor SiAlON crystals are observed; the nonoxide crystals develop well and they are interlaced in the corundum skeleton structure,which creates strengthening and toughening
基金Supported by Project of Humanities and Social Sciences in Colleges and Universities in Jiangxi Province(YS18126)
文摘Hekou ancient town,Qianshan County,Jiangxi Province,is one of the famous towns in the south of Jiangxi Province in the Qing Dynasty.It is on a par with Jingdezhen Town,Zhangshu Town and Wucheng Town,and they are known as the four famous towns in Jiangxi Province.Because of the late development,people s understanding of it is still very limited.Based on the phenomenology of architecture and the place theory of Norberg-Schulz,this paper makes a comprehensive analysis of the composition of Hekou ancient town,in order to have a more comprehensive understanding of Hekou ancient town and provide some reference for the protection and renewal of Hekou ancient town.
文摘Study of atmospheric remnants in the low Earth orbit region (~200 km altitude) using Global Models, with application to electric thrusters of in situ resources utilization type.
基金supported by the B-type Strategic Priority Program No. XDB41000000funded by the Chinese Academy of Sciences and the pre-research projects on Civil Aerospace Technologies No.s D020105 and D020103+1 种基金funded by China’s National Space Administrationsupport from the National Science Foundation of China through grants 42030201, 41904154 and 42104170
文摘Wavelike perturbations in the ionosphere of Titan,the largest satellite of Saturn,are explored based on the Cassini Ion Neutral Mass Spectrometer(INMS)measurements.Strong wavelike perturbations are identified for more than twenty ion species,from simple ones such as N^(+)and CH_(4)^(+)to complex ones such as C_(2)H_(3)CNH^(+)and C_(4)H_(7)^(+).Simultaneous wavelike perturbations in background N_(2),indicative of atmospheric gravity waves,are also observed,motivating us to speculate that the INMS-derived ion perturbations are wave-driven.The amplitudes of the ion perturbations are found to be larger than that of the N_(2)perturbations.Clear compositional variation is revealed by the data:heavier ion species exhibit greater amplitudes.Such observations might be understood based on considerations either of force balance or chemical loss in Titan’s ionosphere.
