This study explores the potential of LDH flakes decorated with metallic oxide nanoparticles to function as both anti-corrosion barriers against chloride anions and heterogeneous photocatalysts for tetracycline degrada...This study explores the potential of LDH flakes decorated with metallic oxide nanoparticles to function as both anti-corrosion barriers against chloride anions and heterogeneous photocatalysts for tetracycline degradation under visible light.The process involves modifying the primarily MgO-based inorganic porous film by growing a MgFe LDH film,followed by the individual and dual incorporation of SnO_(2)and WO_(3)nanoparticles.The dual incorporation of these nanoparticles into the LDH matrix leads to synergistic interactions,effectively sealing pre-existing defects within LDH flakes and facilitating the in-situ formation of catalytic sites through oxidation and the induction of surface oxygen vacancy defects,which synergistically contribute to the enhancement of both electrochemical and photocatalytic activities.The enhanced electrochemical stability is reflected in a significant reduction in corrosion current density by 4 orders of magnitude compared to unmodified porous film.Additionally,the decorated film demonstrates sustained photocatalytic functionality,achieving significant degradation(95.5%)of tetracycline within two hours.This study presents a novel approach,highlighting the dual effectiveness of LDHs decorated by dual metal oxides as an anti-corrosive agent and photocatalyst,with promising implications for environmental remediation and wastewater purification.展开更多
A Zn‐based coating with durable hydrophobicity and good corrosion resistance was formed on a mild steel substrate,which involves electroplating Zn from a non‐aqueous electrolyte,followed by passivation in an oleic a...A Zn‐based coating with durable hydrophobicity and good corrosion resistance was formed on a mild steel substrate,which involves electroplating Zn from a non‐aqueous electrolyte,followed by passivation in an oleic acid(OA)solution.The electrodeposited Zn coatings were porous,which facilitated the formation of a chemical conversion layer of Zn oleate(ZO)during OA passivation.The Zn coating after passivation had a twolayer structure,which included an outer layer of ZO with a thickness of~26μm and an inner layer of Zn with a thickness of~6μm.The outer layer ZO is a type of metal soap with a smooth surface and durable hydrophobicity,such that water droplets can easily slip off its surface.Corrosion testing and electrochemical measurements in 3.5 wt.%NaCl aqueous solution indicate that the Zn coating after OA passivation exhibits outstanding anti‐corrosion properties compared with those exhibited by pure Zn coating.The corrosion products and mechanism of the two‐layer coating were explored.This study shows that smooth metal oleate coatings can provide hydrophobicity and corrosion resistance simultaneously to mild steel substrates.展开更多
基金supported by the National Research Foundation of Korea(NRF)funded by the Korean government(MSIT)(no.2022R1A2C1006743)。
文摘This study explores the potential of LDH flakes decorated with metallic oxide nanoparticles to function as both anti-corrosion barriers against chloride anions and heterogeneous photocatalysts for tetracycline degradation under visible light.The process involves modifying the primarily MgO-based inorganic porous film by growing a MgFe LDH film,followed by the individual and dual incorporation of SnO_(2)and WO_(3)nanoparticles.The dual incorporation of these nanoparticles into the LDH matrix leads to synergistic interactions,effectively sealing pre-existing defects within LDH flakes and facilitating the in-situ formation of catalytic sites through oxidation and the induction of surface oxygen vacancy defects,which synergistically contribute to the enhancement of both electrochemical and photocatalytic activities.The enhanced electrochemical stability is reflected in a significant reduction in corrosion current density by 4 orders of magnitude compared to unmodified porous film.Additionally,the decorated film demonstrates sustained photocatalytic functionality,achieving significant degradation(95.5%)of tetracycline within two hours.This study presents a novel approach,highlighting the dual effectiveness of LDHs decorated by dual metal oxides as an anti-corrosive agent and photocatalyst,with promising implications for environmental remediation and wastewater purification.
基金Zhejiang University K.P.Chao's High Technology Development Foundation。
文摘A Zn‐based coating with durable hydrophobicity and good corrosion resistance was formed on a mild steel substrate,which involves electroplating Zn from a non‐aqueous electrolyte,followed by passivation in an oleic acid(OA)solution.The electrodeposited Zn coatings were porous,which facilitated the formation of a chemical conversion layer of Zn oleate(ZO)during OA passivation.The Zn coating after passivation had a twolayer structure,which included an outer layer of ZO with a thickness of~26μm and an inner layer of Zn with a thickness of~6μm.The outer layer ZO is a type of metal soap with a smooth surface and durable hydrophobicity,such that water droplets can easily slip off its surface.Corrosion testing and electrochemical measurements in 3.5 wt.%NaCl aqueous solution indicate that the Zn coating after OA passivation exhibits outstanding anti‐corrosion properties compared with those exhibited by pure Zn coating.The corrosion products and mechanism of the two‐layer coating were explored.This study shows that smooth metal oleate coatings can provide hydrophobicity and corrosion resistance simultaneously to mild steel substrates.
