Antistatic polymer fibers were investigated by using carbon nanotubes (CNTs) to enhance the antistatic ability of inner antistatic agents based on the mechanism of attracting moisture by polar radical groups. It is ...Antistatic polymer fibers were investigated by using carbon nanotubes (CNTs) to enhance the antistatic ability of inner antistatic agents based on the mechanism of attracting moisture by polar radical groups. It is indicated that the antistatic ability of the fibers filled with composite antistatic agents that contain CNTs and organic antistatic agents was superior to that of the fibers filled either with pure organic antistatic agents or pure CNTs. The antistatic ability of the composite antistatic agent fabricated by an in situ process was superior to that of the composite antistatic agent fabricated by direct dispersing CNTs in the antistatic agent carrier. Moreover, the heat-treated CNTs could further enhance the antistatic effect compared with the initial CNTs. The antistatic effect is significantly influenced by the content of CNTs in the composite antistatic agent.展开更多
In order to improve the electrical conductivity of nylon 6(PA6)and avoid misfires and explosions caused by static charge accumulation,a quaternary ammonium salt polyionic liquid(PIL)antistatic agent was synthesized in...In order to improve the electrical conductivity of nylon 6(PA6)and avoid misfires and explosions caused by static charge accumulation,a quaternary ammonium salt polyionic liquid(PIL)antistatic agent was synthesized in this paper.The surface resistance of PA6 was reduced to 10~8Ωwith the addition of 2 wt%antistatic agent,and the mechanical properties and aging resistance of the substrate were improved.Meanwhile,the morphology and crystallinity of PIL/PA6 composites were further characterized by scanning electron microscope(SEM),energy dispersion spectrometer(EDS)and X-ray diffraction(XRD).It is worth noting that the quaternary ammonium salt polyionic liquid antistatic agent synthesized in this paper has the advantages of excellent antistatic effect,durability,low cost,and simple reaction condition,so it has a broad application prospect in the antistatic aspect of PA6.展开更多
基金This work was financially supported by the Major State Basic Research Development Program of China (No.10332020)
文摘Antistatic polymer fibers were investigated by using carbon nanotubes (CNTs) to enhance the antistatic ability of inner antistatic agents based on the mechanism of attracting moisture by polar radical groups. It is indicated that the antistatic ability of the fibers filled with composite antistatic agents that contain CNTs and organic antistatic agents was superior to that of the fibers filled either with pure organic antistatic agents or pure CNTs. The antistatic ability of the composite antistatic agent fabricated by an in situ process was superior to that of the composite antistatic agent fabricated by direct dispersing CNTs in the antistatic agent carrier. Moreover, the heat-treated CNTs could further enhance the antistatic effect compared with the initial CNTs. The antistatic effect is significantly influenced by the content of CNTs in the composite antistatic agent.
基金supported by the Natural Science Foundation of Guangdong Province(Project No.2021A1515010140)the Natural Science Foundation of Shandong Province(Project No.ZR2020ME065)
文摘In order to improve the electrical conductivity of nylon 6(PA6)and avoid misfires and explosions caused by static charge accumulation,a quaternary ammonium salt polyionic liquid(PIL)antistatic agent was synthesized in this paper.The surface resistance of PA6 was reduced to 10~8Ωwith the addition of 2 wt%antistatic agent,and the mechanical properties and aging resistance of the substrate were improved.Meanwhile,the morphology and crystallinity of PIL/PA6 composites were further characterized by scanning electron microscope(SEM),energy dispersion spectrometer(EDS)and X-ray diffraction(XRD).It is worth noting that the quaternary ammonium salt polyionic liquid antistatic agent synthesized in this paper has the advantages of excellent antistatic effect,durability,low cost,and simple reaction condition,so it has a broad application prospect in the antistatic aspect of PA6.