The new catalytic kinetic spectrophotometric method for Au（III） determination was developed and validated. It was based on the catalytic effect of gold on the oxidation of sudan red III by ammonium peroxodisulfate ...The new catalytic kinetic spectrophotometric method for Au（III） determination was developed and validated. It was based on the catalytic effect of gold on the oxidation of sudan red III by ammonium peroxodisulfate （（NH4）2S2O8） with nitrilo triacetic acid as an activator in microemulsion and H2SO4 medium. Under optimum conditions, there was the linearity of the calibration curve in the concentration range from 0 to 20 μg/L Au（Ⅲ） at 520 nm. The relative standard deviation was 3.0% with a correlation coefficient of 0.9986. The detection limit achieved was 9.75 × 10^-5 μg/mL. A new method using a column packed with sulfhydryl dextrose gel （SDG） as a solid-phase extractant has been developed for the preconcentration and separation of Au（Ⅲ） ions. The method has been applied to the determination of trace gold with satisfactory results.展开更多
In view of the limitation of the difference method,the adjustment model of CPⅢprecise trigonometric leveling control network based on the parameter method was proposed in the present paper.The experiment results show...In view of the limitation of the difference method,the adjustment model of CPⅢprecise trigonometric leveling control network based on the parameter method was proposed in the present paper.The experiment results show that this model has a simple algorithm and high data utilization,avoids the negative influences caused by the correlation among the data acquired from the difference method and its accuracy is improved compared with the difference method.In addition,the strict weight of CPⅢprecise trigonometric leveling control network was also discussed in this paper.The results demonstrate that the ranging error of trigonometric leveling can be neglected when the vertical angle is less than 3 degrees.The accuracy of CPⅢprecise trigonometric leveling control network has not changed significantly before and after strict weight.展开更多
文摘The new catalytic kinetic spectrophotometric method for Au（III） determination was developed and validated. It was based on the catalytic effect of gold on the oxidation of sudan red III by ammonium peroxodisulfate （（NH4）2S2O8） with nitrilo triacetic acid as an activator in microemulsion and H2SO4 medium. Under optimum conditions, there was the linearity of the calibration curve in the concentration range from 0 to 20 μg/L Au（Ⅲ） at 520 nm. The relative standard deviation was 3.0% with a correlation coefficient of 0.9986. The detection limit achieved was 9.75 × 10^-5 μg/mL. A new method using a column packed with sulfhydryl dextrose gel （SDG） as a solid-phase extractant has been developed for the preconcentration and separation of Au（Ⅲ） ions. The method has been applied to the determination of trace gold with satisfactory results.
基金National Natural Science Foundation of China(No.41661091)。
文摘In view of the limitation of the difference method,the adjustment model of CPⅢprecise trigonometric leveling control network based on the parameter method was proposed in the present paper.The experiment results show that this model has a simple algorithm and high data utilization,avoids the negative influences caused by the correlation among the data acquired from the difference method and its accuracy is improved compared with the difference method.In addition,the strict weight of CPⅢprecise trigonometric leveling control network was also discussed in this paper.The results demonstrate that the ranging error of trigonometric leveling can be neglected when the vertical angle is less than 3 degrees.The accuracy of CPⅢprecise trigonometric leveling control network has not changed significantly before and after strict weight.
