Lubricant is harmful to the mechanical properties of the sintered materials. Die wall lubrication was applied on warm compaction powder metallurgy in the hope of reducing the concentration level of the admixed lubrica...Lubricant is harmful to the mechanical properties of the sintered materials. Die wall lubrication was applied on warm compaction powder metallurgy in the hope of reducing the concentration level of the admixed lubricant. Iron based samples were prepared by die wall lubricated warm compaction at 175 ℃, using a compacting pressure of 550 MPa. Emulsified polytetrafluoroethylene(PTFE) was used as die wall lubricant. Admixed lubricant concentration ranging from 0 to 0.5% was tested. Extremely low admixed lubricant contents were used. Results show that in addition to the decrease in ejection forces, the green density of the compacts increases with the decrease of admixed lubricant content until it reaches the maximum at 0.06% of lubricant content, then decreases with the decrease of admixed lubricant content. The mechanical properties of the sintered compacts that contain more than 0.06% admixed lubricant are better than those of the samples that contain lesser lubricant. No scoring was observed in all die wall lubricated experiments.展开更多
Carbide precipitates in Thin Wall Ductile Iron (TWDI) used for automotive applications needs to be eliminated or reduced for improved strength, ductility, crack propagation resistance and good machinability. Ductile i...Carbide precipitates in Thin Wall Ductile Iron (TWDI) used for automotive applications needs to be eliminated or reduced for improved strength, ductility, crack propagation resistance and good machinability. Ductile iron thin section profiles (≤3 mm) present danger of massive carbide precipitations in the as-cast sample. Precipitated carbide phase is brittle and negatively affects the mechanical properties of the iron matrix. The suppression of carbide formation is associated with the nucleating properties of the nodularizer and innoculant alloys. This treatment is vital in ensuring that carbide precipitation, flake graphite structure and non-nodular graphite phases are reduced or completely eliminated in the TWDI castings. Therefore, the temperature and technique of treatment would influence the yield of the process, and ultimately the mechanical properties. In this study, the effect of nodularization and inoculation treatment temperature on the microstructure and mechanical properties of TWDI castings is examined. The results indicate that good nodularity and nodule count with better percent elongations are achieved using low treatment temperatures in descending order of 1490°C, 1470°C and 1450°C, but have negative effect at lower treatment temperature of 1430°C. However, TWDI castings have superior properties in terms of nodule counts and nodularity at 1450°C. Treatment temperature does not produce significant influence on ultimate tensile strength (UTS) and hardness of TWDI castings. TWDI castings show poor nodularity, nodule count and ductility at higher inoculation treatment temperatures of 1550°C, 1530°C and 1510°C.展开更多
Improving the performance of anode is a crucial step for increasing output power of marine sediment microbial fuel cells(MSMFCs)to drive marine monitor to work for a long term on the ocean floor.A pyrolyzed iron phtha...Improving the performance of anode is a crucial step for increasing output power of marine sediment microbial fuel cells(MSMFCs)to drive marine monitor to work for a long term on the ocean floor.A pyrolyzed iron phthalocyanine modified multi-walled carbon nanotubes composite(FePc/MWCNTs)has been utilized as a novel nodified anode in the MSMFC.Its structure of the composite modified anode and electrochemical performance have been investigated respectively in the paper.There is a substantial improvement in electron-transfer efficiency from the bacteria biofilm to the modified anode via the pyrolyzed FePc/MWCNTs composite based on their cyclic voltammetry(CV)and Tafel curves.The electron transfer kinetic activity of the FePc/MWCNTs-modified anode is 1.86 times higher than of the unmodified anode.The maximum power density of the modified MSMFC was 572.3±14 m W m^-2,which is 2.6 times larger than the unmodified one(218.3±11 m W m^-2).The anodic structure and cell scale would be greatly minimized to obtain the same output power by the modified MSMFC,so that it will make the MSMFC to be easily deployed on the remote ocean floor.Therefore,it would have a great significance for us to design a novel and renewable long term power source.Finally,a novel molecular synergetic mechanism is proposed to elucidate its excellent electrochemical performance.展开更多
The effects of alloying elements on the as-cast microstructures and mechanical properties of heavy section ductile cast iron were investigated to develop press die material having high strength and high ductility. Mea...The effects of alloying elements on the as-cast microstructures and mechanical properties of heavy section ductile cast iron were investigated to develop press die material having high strength and high ductility. Measurements of ultimate tensile strength, 0.2% proof strength, elongation and unnotched Charpy impact energy are presented as a function of alloy amounts within 0.25 to 0.75 wt pct range. Hardness is measured on the broken tensile specimens. The small additions of Mo, Cu, Ni and Cr changed the as-cast mechanical properties owing to the different as-cast matrix microstructures. The ferrite matrix of Mo and Ni alloyed cast iron exhibits low strength and hardness as well as high elongation and impact energy. The increase in Mo and Ni contents developed some fractions of pearlite structures near the austenite eutectic cell boundaries, which caused the elongation and impact energy to drop in a small range. Adding Cu and Cr elements rapidly changed the ferrite matrix into pearlite matrix, so strength and hardness were significantly increased. As more Mo and Cr were added, the size and fraction of primary carbides in the eutectic cell boundaries increased through the segregation of these elements into the intercellular boundaries.展开更多
A foundry research project has been recently initiated at RTIT in order to better understand the fabrication of as-cast heavy section DI parts meeting high impact energy requirements at low temperatures.The experiment...A foundry research project has been recently initiated at RTIT in order to better understand the fabrication of as-cast heavy section DI parts meeting high impact energy requirements at low temperatures.The experimental castings have the following dimensions 180 mm x 180 mm x 190 mm.The achieved as-cast Charpy impact strengths were as follows:17 J (RT),16 J (-20℃) and 11 J (-40℃).The foundry process,the chemical composition and the microstructure of this experimental casting are compared to the ones of various examples in order to show the detrimental effects of residual elements,microshrinkage and microcarbide on the impact properties.Finally,quality index empirical models (based on casting chemical compositions) are used to analyse the impact tests results.This paper illustrates that an adequate nodule count can contribute to reducing the detrimental effects of the residual elements and microsegregation.展开更多
This paper reports a simple and efficient chemical method to decorate multi-walled carbon nano- tubes（MWCNTs） with iron oxide nanoparticles. The TEM, FTIR, Raman and UV analysis demonstrate that iron oxide nanoparti...This paper reports a simple and efficient chemical method to decorate multi-walled carbon nano- tubes（MWCNTs） with iron oxide nanoparticles. The TEM, FTIR, Raman and UV analysis demonstrate that iron oxide nanoparticles were well deposited on the outer walls of MWCNTs. The size of the nanoparticles ranges from 30 to 50 nm. The sorption property of MWCNTs/Fe3O4 composites for the removal of 2,4-dichlorophenol（2,4-DCP） and Cu2＋ ions from aqueous solution was explored. The results present that MWCNTs decorated with Fe3O4 possessed higher sorption capability for removing 2,4-DCP and Cu2＋ ions, which favour the highly potential applications for pollutants removal from water.展开更多
Iron-based powder metallurgy material was prepared by warm compaction at 125 ℃ using a compacting pressure of 700 MPa. Sintering temperature ranging from 1 100 ℃ to 1 300 ℃ and sintering time ranging from 40 min to...Iron-based powder metallurgy material was prepared by warm compaction at 125 ℃ using a compacting pressure of 700 MPa. Sintering temperature ranging from 1 100 ℃ to 1 300 ℃ and sintering time ranging from 40 min to 80 min were used to study the effects of sintering parameters on the compacts. Die wall lubrication polytetrafluoroethylene(PTFE) emulsion was also applied in combination with warm compaction in hope to increase the compact density and the mechanical properties of the sintered material. Green and sintered density, spring back effect and sinter shrinkage were measured. Mechanical properties of both as-sinter and heat treated samples were also measured. Results show that mechanical properties of the sintered compacts increase with the increase of sintering temperature and sintering time. Sample prepared by die wall lubricated warm compaction always shows higher density and mechanical properties.展开更多
苍绎铁矿带会宝岭铁矿床为大型隐伏沉积变质岩型铁矿床,矿山涌水量大、排水成本高,且对矿山安全生产构成了威胁。治水前,矿山正常涌水量约530 m 3/h,其中已探明的封闭不良钻孔涌水量163.5 m 3/h,占矿山涌水的重要组成部分。本文针对封...苍绎铁矿带会宝岭铁矿床为大型隐伏沉积变质岩型铁矿床,矿山涌水量大、排水成本高,且对矿山安全生产构成了威胁。治水前,矿山正常涌水量约530 m 3/h,其中已探明的封闭不良钻孔涌水量163.5 m 3/h,占矿山涌水的重要组成部分。本文针对封闭不良钻孔的涌水量、水压、充水水源等特征进行分析,首次在深隐伏铁矿床中提出了孔底点注浆、分段泄压注浆、截水墙注浆止水3种井下注浆止水技术,建立了隐伏铁矿床封闭不良钻孔井下注浆止水体系,并取得了较好的止水效果,对类似矿山的封闭不良钻孔的止水工作具有重要指导意义。展开更多
文摘Lubricant is harmful to the mechanical properties of the sintered materials. Die wall lubrication was applied on warm compaction powder metallurgy in the hope of reducing the concentration level of the admixed lubricant. Iron based samples were prepared by die wall lubricated warm compaction at 175 ℃, using a compacting pressure of 550 MPa. Emulsified polytetrafluoroethylene(PTFE) was used as die wall lubricant. Admixed lubricant concentration ranging from 0 to 0.5% was tested. Extremely low admixed lubricant contents were used. Results show that in addition to the decrease in ejection forces, the green density of the compacts increases with the decrease of admixed lubricant content until it reaches the maximum at 0.06% of lubricant content, then decreases with the decrease of admixed lubricant content. The mechanical properties of the sintered compacts that contain more than 0.06% admixed lubricant are better than those of the samples that contain lesser lubricant. No scoring was observed in all die wall lubricated experiments.
文摘Carbide precipitates in Thin Wall Ductile Iron (TWDI) used for automotive applications needs to be eliminated or reduced for improved strength, ductility, crack propagation resistance and good machinability. Ductile iron thin section profiles (≤3 mm) present danger of massive carbide precipitations in the as-cast sample. Precipitated carbide phase is brittle and negatively affects the mechanical properties of the iron matrix. The suppression of carbide formation is associated with the nucleating properties of the nodularizer and innoculant alloys. This treatment is vital in ensuring that carbide precipitation, flake graphite structure and non-nodular graphite phases are reduced or completely eliminated in the TWDI castings. Therefore, the temperature and technique of treatment would influence the yield of the process, and ultimately the mechanical properties. In this study, the effect of nodularization and inoculation treatment temperature on the microstructure and mechanical properties of TWDI castings is examined. The results indicate that good nodularity and nodule count with better percent elongations are achieved using low treatment temperatures in descending order of 1490°C, 1470°C and 1450°C, but have negative effect at lower treatment temperature of 1430°C. However, TWDI castings have superior properties in terms of nodule counts and nodularity at 1450°C. Treatment temperature does not produce significant influence on ultimate tensile strength (UTS) and hardness of TWDI castings. TWDI castings show poor nodularity, nodule count and ductility at higher inoculation treatment temperatures of 1550°C, 1530°C and 1510°C.
基金supported by the National Defense Science and Technology Innovation Zone Project (Nos. 17H863-05-ZT-002-040-001 and 18-H863-05-ZT-002-01301
文摘Improving the performance of anode is a crucial step for increasing output power of marine sediment microbial fuel cells(MSMFCs)to drive marine monitor to work for a long term on the ocean floor.A pyrolyzed iron phthalocyanine modified multi-walled carbon nanotubes composite(FePc/MWCNTs)has been utilized as a novel nodified anode in the MSMFC.Its structure of the composite modified anode and electrochemical performance have been investigated respectively in the paper.There is a substantial improvement in electron-transfer efficiency from the bacteria biofilm to the modified anode via the pyrolyzed FePc/MWCNTs composite based on their cyclic voltammetry(CV)and Tafel curves.The electron transfer kinetic activity of the FePc/MWCNTs-modified anode is 1.86 times higher than of the unmodified anode.The maximum power density of the modified MSMFC was 572.3±14 m W m^-2,which is 2.6 times larger than the unmodified one(218.3±11 m W m^-2).The anodic structure and cell scale would be greatly minimized to obtain the same output power by the modified MSMFC,so that it will make the MSMFC to be easily deployed on the remote ocean floor.Therefore,it would have a great significance for us to design a novel and renewable long term power source.Finally,a novel molecular synergetic mechanism is proposed to elucidate its excellent electrochemical performance.
文摘The effects of alloying elements on the as-cast microstructures and mechanical properties of heavy section ductile cast iron were investigated to develop press die material having high strength and high ductility. Measurements of ultimate tensile strength, 0.2% proof strength, elongation and unnotched Charpy impact energy are presented as a function of alloy amounts within 0.25 to 0.75 wt pct range. Hardness is measured on the broken tensile specimens. The small additions of Mo, Cu, Ni and Cr changed the as-cast mechanical properties owing to the different as-cast matrix microstructures. The ferrite matrix of Mo and Ni alloyed cast iron exhibits low strength and hardness as well as high elongation and impact energy. The increase in Mo and Ni contents developed some fractions of pearlite structures near the austenite eutectic cell boundaries, which caused the elongation and impact energy to drop in a small range. Adding Cu and Cr elements rapidly changed the ferrite matrix into pearlite matrix, so strength and hardness were significantly increased. As more Mo and Cr were added, the size and fraction of primary carbides in the eutectic cell boundaries increased through the segregation of these elements into the intercellular boundaries.
文摘A foundry research project has been recently initiated at RTIT in order to better understand the fabrication of as-cast heavy section DI parts meeting high impact energy requirements at low temperatures.The experimental castings have the following dimensions 180 mm x 180 mm x 190 mm.The achieved as-cast Charpy impact strengths were as follows:17 J (RT),16 J (-20℃) and 11 J (-40℃).The foundry process,the chemical composition and the microstructure of this experimental casting are compared to the ones of various examples in order to show the detrimental effects of residual elements,microshrinkage and microcarbide on the impact properties.Finally,quality index empirical models (based on casting chemical compositions) are used to analyse the impact tests results.This paper illustrates that an adequate nodule count can contribute to reducing the detrimental effects of the residual elements and microsegregation.
基金Supported by the National Natural Science Foundation of China(No.50878061)the National High Technology Research and Development Program of China(No.2007AA06Z303)+1 种基金State Key Lab of Urban Water Resource and Environment Fund (No.ESK200801)Scientific Research Foundation of Harbin City,China(No.2007RFXXS022)
文摘This paper reports a simple and efficient chemical method to decorate multi-walled carbon nano- tubes（MWCNTs） with iron oxide nanoparticles. The TEM, FTIR, Raman and UV analysis demonstrate that iron oxide nanoparticles were well deposited on the outer walls of MWCNTs. The size of the nanoparticles ranges from 30 to 50 nm. The sorption property of MWCNTs/Fe3O4 composites for the removal of 2,4-dichlorophenol（2,4-DCP） and Cu2＋ ions from aqueous solution was explored. The results present that MWCNTs decorated with Fe3O4 possessed higher sorption capability for removing 2,4-DCP and Cu2＋ ions, which favour the highly potential applications for pollutants removal from water.
文摘Iron-based powder metallurgy material was prepared by warm compaction at 125 ℃ using a compacting pressure of 700 MPa. Sintering temperature ranging from 1 100 ℃ to 1 300 ℃ and sintering time ranging from 40 min to 80 min were used to study the effects of sintering parameters on the compacts. Die wall lubrication polytetrafluoroethylene(PTFE) emulsion was also applied in combination with warm compaction in hope to increase the compact density and the mechanical properties of the sintered material. Green and sintered density, spring back effect and sinter shrinkage were measured. Mechanical properties of both as-sinter and heat treated samples were also measured. Results show that mechanical properties of the sintered compacts increase with the increase of sintering temperature and sintering time. Sample prepared by die wall lubricated warm compaction always shows higher density and mechanical properties.
文摘苍绎铁矿带会宝岭铁矿床为大型隐伏沉积变质岩型铁矿床,矿山涌水量大、排水成本高,且对矿山安全生产构成了威胁。治水前,矿山正常涌水量约530 m 3/h,其中已探明的封闭不良钻孔涌水量163.5 m 3/h,占矿山涌水的重要组成部分。本文针对封闭不良钻孔的涌水量、水压、充水水源等特征进行分析,首次在深隐伏铁矿床中提出了孔底点注浆、分段泄压注浆、截水墙注浆止水3种井下注浆止水技术,建立了隐伏铁矿床封闭不良钻孔井下注浆止水体系,并取得了较好的止水效果,对类似矿山的封闭不良钻孔的止水工作具有重要指导意义。
