The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method. Here, we design and fabricate novel 36-nm-thick Ag-Au composite layers alternately deposited on three...The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method. Here, we design and fabricate novel 36-nm-thick Ag-Au composite layers alternately deposited on three-dimensional （3D） periodic SiO2 nanogrids as surface-enhanced Raman scattering （SERS） probes. The SERS effects of the probes depend mainly on the positions and intensities of their localized surface plasmon resonance （LSPR） peaks, which is confirmed by the absorption spectra from finite-difference time-domain （FDTD） calculations. By optimizing the structure and material to maximize the intrinsic electric field enhancement based on the design method of 3D periodic SERS probes proposed, high performance of the Ag-Au/SiO2 nanogrid probes is achieved with the stability further enhanced by annealing. The optimized probes show the outstanding stability with only 4.0% SERS intensity change during 10-day storage, the excellent detection uniformity of 5.78% （RSD）, the detection limit of 5.0 × 10-12 M （1 ppt）, and superior selectivity for Hg ions. The present study renders it possible to realize the rapid and reliable detection of trace heavy metal ions by developing high- performance 3D periodic structure SERS probes by designing novel 3D structure and optimizing plasmonic material.展开更多
Self-consistent calculations of energy loss for a Ga ion moving in hot Au plasmas are made under the assumption of wide ranges of the projectile energy and the plasma temperature with all important mechanisms consider...Self-consistent calculations of energy loss for a Ga ion moving in hot Au plasmas are made under the assumption of wide ranges of the projectile energy and the plasma temperature with all important mechanisms considered in detail.The relevant results are found to be quite different from those of an a particle or a proton.One important reason for this is the rapid increasing of the charge state of a Ga ion at plasma temperature.This reason also leads to the inelastic stopping which does not always decrease with the increase of plasma temperature,unlike the case of an a particle.The nuclear stopping becomes very important at high enough plasma temperature due to the heavy reduced mass of a Ga and an Au ion and the above-mentioned reason.The well-known binary collision model[Phys.Rev.126(1962)1]and its revised one[Phys.Rev.A 29(1984)2145]are not working or unsatisfactory in this case.展开更多
Au ion beam was demanded at the 320 kV HV platform for multi-discipline research with highly charged ionsin 2014.The oven technique was used to produce Au ions with 14.5 GHz ECR ion source at the 320 kV HV platform.Ov...Au ion beam was demanded at the 320 kV HV platform for multi-discipline research with highly charged ionsin 2014.The oven technique was used to produce Au ions with 14.5 GHz ECR ion source at the 320 kV HV platform.Oven technique is one of the popular methods for producing ions from a solid material at present. In many cases,this technique is the most appropriate method to produce metal ion beams. It is simple in use and dose not causecarbon contamination. However, the main problem relating to this method is the operation temperature.展开更多
利用金属蒸发真空多弧离子源（MEVVA源）注入机,将Au离子注入到高纯石英玻璃衬底中来制备Au纳米颗粒,Au离子注入的加速电压分别为20、40和60 k V,注入剂量为1×1017ions/cm2,随后将注入样品在普通管式退火炉中700~1000℃退火处理。...利用金属蒸发真空多弧离子源（MEVVA源）注入机,将Au离子注入到高纯石英玻璃衬底中来制备Au纳米颗粒,Au离子注入的加速电压分别为20、40和60 k V,注入剂量为1×1017ions/cm2,随后将注入样品在普通管式退火炉中700~1000℃退火处理。研究了注入条件和热退火参数对Au纳米颗粒的形成、生长、分布以及光学性能的影响。采用光学吸收谱、扫描电子显微镜和透射电子显微镜对注入样品的光学性能、表面形貌和微观结构进行了测试和表征。实验结果表明,采用该低压离子注入结合热退火工艺的方法,所制备的Au纳米颗粒具有很强的局域表面等离子体共振特性,同时该方法也为制备尺寸和分布可控的Au纳米颗粒提供了一些新的参考途径。展开更多
An experimental apparatus for studies of MeV ion beam modification of materials has been established on a 3 MV tandem accelerator at Fudan university. A system of X-Y electrostatic scanning implantation of MeV heavy i...An experimental apparatus for studies of MeV ion beam modification of materials has been established on a 3 MV tandem accelerator at Fudan university. A system of X-Y electrostatic scanning implantation of MeV heavy ions and in situ Rutherford. backscattering analysis was included in it. The uniformity of scanning implantation was checked by the RBS measurement of a Si wafer implanted with 1 MeV Au ions. MeV ion beam mixing of Au/Si, Au/Ge and Ag/Si systems was preliminarily studied. The samples were irradiated by certain fluences of 1 MeV Ag ions at room temperature. The mixed layers were analyzed in situ using the glancing RBS technique with 2 MeV 4He+ ions. For Au/Si system, a uniformly mixed layer with a defined composition is obtained, and the intermixing is much less for Ag/Si system than for Au/Si system.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFA0207104)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA09040101)+2 种基金the National Natural Science Foundation of China(Grant No.Y6061111JJ)the Youth Innovation Promotion Association of Chinese Academy of Sciences(Grant No.2015030)the Key Technology Talent Program of Chinese Academy of Sciences(Grant Nos.Y8482911ZX and Y7602921ZX)
文摘The hazard of Hg ion pollution triggers the motivation to explore a fast, sensitive, and reliable detection method. Here, we design and fabricate novel 36-nm-thick Ag-Au composite layers alternately deposited on three-dimensional （3D） periodic SiO2 nanogrids as surface-enhanced Raman scattering （SERS） probes. The SERS effects of the probes depend mainly on the positions and intensities of their localized surface plasmon resonance （LSPR） peaks, which is confirmed by the absorption spectra from finite-difference time-domain （FDTD） calculations. By optimizing the structure and material to maximize the intrinsic electric field enhancement based on the design method of 3D periodic SERS probes proposed, high performance of the Ag-Au/SiO2 nanogrid probes is achieved with the stability further enhanced by annealing. The optimized probes show the outstanding stability with only 4.0% SERS intensity change during 10-day storage, the excellent detection uniformity of 5.78% （RSD）, the detection limit of 5.0 × 10-12 M （1 ppt）, and superior selectivity for Hg ions. The present study renders it possible to realize the rapid and reliable detection of trace heavy metal ions by developing high- performance 3D periodic structure SERS probes by designing novel 3D structure and optimizing plasmonic material.
基金This work was supported by the Foundation for the Development of Science and Technology of the Chinese Academy of Engeering Physics under grant No.2014B09036,National Natural Science Foundation of China(Grants Nos.11574034,U1530142,11104017,11371218,11474031,and 11474033)the National Basic Research Program of China under grant No.2013CB922200.
文摘Self-consistent calculations of energy loss for a Ga ion moving in hot Au plasmas are made under the assumption of wide ranges of the projectile energy and the plasma temperature with all important mechanisms considered in detail.The relevant results are found to be quite different from those of an a particle or a proton.One important reason for this is the rapid increasing of the charge state of a Ga ion at plasma temperature.This reason also leads to the inelastic stopping which does not always decrease with the increase of plasma temperature,unlike the case of an a particle.The nuclear stopping becomes very important at high enough plasma temperature due to the heavy reduced mass of a Ga and an Au ion and the above-mentioned reason.The well-known binary collision model[Phys.Rev.126(1962)1]and its revised one[Phys.Rev.A 29(1984)2145]are not working or unsatisfactory in this case.
文摘Au ion beam was demanded at the 320 kV HV platform for multi-discipline research with highly charged ionsin 2014.The oven technique was used to produce Au ions with 14.5 GHz ECR ion source at the 320 kV HV platform.Oven technique is one of the popular methods for producing ions from a solid material at present. In many cases,this technique is the most appropriate method to produce metal ion beams. It is simple in use and dose not causecarbon contamination. However, the main problem relating to this method is the operation temperature.
文摘利用金属蒸发真空多弧离子源（MEVVA源）注入机,将Au离子注入到高纯石英玻璃衬底中来制备Au纳米颗粒,Au离子注入的加速电压分别为20、40和60 k V,注入剂量为1×1017ions/cm2,随后将注入样品在普通管式退火炉中700~1000℃退火处理。研究了注入条件和热退火参数对Au纳米颗粒的形成、生长、分布以及光学性能的影响。采用光学吸收谱、扫描电子显微镜和透射电子显微镜对注入样品的光学性能、表面形貌和微观结构进行了测试和表征。实验结果表明,采用该低压离子注入结合热退火工艺的方法,所制备的Au纳米颗粒具有很强的局域表面等离子体共振特性,同时该方法也为制备尺寸和分布可控的Au纳米颗粒提供了一些新的参考途径。
基金The Project Supported by National Natural Science Foundation of China
文摘An experimental apparatus for studies of MeV ion beam modification of materials has been established on a 3 MV tandem accelerator at Fudan university. A system of X-Y electrostatic scanning implantation of MeV heavy ions and in situ Rutherford. backscattering analysis was included in it. The uniformity of scanning implantation was checked by the RBS measurement of a Si wafer implanted with 1 MeV Au ions. MeV ion beam mixing of Au/Si, Au/Ge and Ag/Si systems was preliminarily studied. The samples were irradiated by certain fluences of 1 MeV Ag ions at room temperature. The mixed layers were analyzed in situ using the glancing RBS technique with 2 MeV 4He+ ions. For Au/Si system, a uniformly mixed layer with a defined composition is obtained, and the intermixing is much less for Ag/Si system than for Au/Si system.
