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Mineralogical study and significance of the basalt-hosted Carlin-type Au deposits in southwestern Guizhou Province,China
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作者 Yuhong Yang Shen Liu +3 位作者 Jianzhong Liu Zepeng Wang Bingqiang Zhang Chengfu Yang 《Acta Geochimica》 EI CAS CSCD 2024年第6期1241-1254,共14页
The Jiadi and Damaidi gold deposits in southwest Guizhou Province are the largest basalt-hosted Carlintype gold deposits recently discovered in China.This study uses the Tescan Integrated Mineral Analyzer,supported by... The Jiadi and Damaidi gold deposits in southwest Guizhou Province are the largest basalt-hosted Carlintype gold deposits recently discovered in China.This study uses the Tescan Integrated Mineral Analyzer,supported by detailed field investigations,regional geological data,and extensive sample collections,including mineralized ore,altered wall rock,and unaltered basalt samples,for orebearing and geochemical analyses.Comparative analysis between altered and unaltered basalt samples revealed a mineral assemblage of sericite,quartz,and pyrite.This mineral composition forms through the hydrothermal alteration of unaltered basalt,originally containing feldspar,pyroxene,and ilmenite.The wall rock primarily features sericite,quartz,and hematite.During the alteration process,major,trace,and rare earth elements notably migrate.In the Jiadi deposit,K_(2)O,Rb,Au,and REE significantly increase,while Na_(2)O,CaO,MgO,and MnO decrease.SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3)levels remain relatively stable.In the Damaidi deposit,K_(2)O,Rb,and Au enrich,contrasting with the depletion of Na_(2)O,CaO,MgO,and MnO,while SiO_(2),Fe_(2)O_(3),Al_(2)O_(3),TiO_(2),and REE show no significant changes.In the wall rock,TiO_(2),Al_(2)O_(3),K_(2)O,and REE increase,while Na_(2)O,CaO,MgO,and MnO decrease;SiO_(2)and Fe_(2)O_(3)content remains unchanged.The mineralization process likely originated from mid-to low-temperature,reductive magmatic hydrothermal fluids rich in CO_(2),CH_(4),N_(2),H^(+),S^(2-),HS^(-),H_(3)AsO_(3),and[Au(HS_(2)]^(-).These fluids migrated to tectonically weak zones in the Lianhuashan area,where Emeishan basalts are present.They reacted with Fe-bearing minerals in the basalt,such as ferro-hornblende and ilmenite,forming pyrite,arsenic-bearing pyrite,and arsenopyrite,thus enriching Au in these minerals.Additionally,K^(+)and H^(+)in the fluid reacted with plagioclase in the basalt,forming sericite and quartz.As the fluid entered the wall rock from structural weak zones,its oxidation increased,leading to the complete or partial reaction of Fe-bearing minerals in the wall rock,resulting in the formation of hematite or magnetite.This mineralization process is similar to that observed in carbonate-hosted Carlin-type gold deposits in southwest Guizhou,with the primary distinction being the iron source.In carbonate deposits,iron originates from ferridolomite within the wall rock,while in basalt-hosted deposits,it derives from ferripyroxene and ilmenite. 展开更多
关键词 BasALTIC Ore-bearing rocks CARLIN-TYPE au deposit Mineralogy Mineral assemblage Element migration
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Alloy gene Gibbs energy partition function and equilibrium holographic network phase diagrams of Au_3Cu-type sublattice system 被引量:3
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作者 谢佑卿 聂耀庄 +2 位作者 李小波 彭红建 刘心笔 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第1期211-240,共30页
Taking Au3Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to hinder the progress of metal materials science is that today’s researchers do not understand that... Taking Au3Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to hinder the progress of metal materials science is that today’s researchers do not understand that the Gibbs energy function of an alloy phase should be derived from Gibbs energy partition function constructed of alloy gene sequence and their Gibbs energy sequence. Second, the six rules for establishing alloy gene Gibbs energy partition function have been discovered, and it has been specially proved that the probabilities of structure units occupied at the Gibbs energy levels in the degeneracy factor for calculating configuration entropy should be degenerated as ones of component atoms occupied at the lattice points. Third, the main characteristics unexpected by today’s researchers are as follows. There exists a single-phase boundary curve without two-phase region coexisting by the ordered and disordered phases. The composition and temperature of the top point on the phase-boundary curve are far away from those of the critical point of the Au3Cu compound; At 0 K, the composition of the lowest point on the composition-dependent Gibbs energy curve is notably deviated from that of the Au3Cu compounds. The theoretical limit composition range of long range ordered Au3Cu-type alloys is determined by the first jumping order degree. 展开更多
关键词 au3Cu compound au3Cu-type sublattice system alloy gene Gibbs energy partition function equilibrium holographic network phase diagrams systematic metal materials science
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Gold and antimony metallogenic relations and ore-forming process of Qinglong Sb(Au) deposit in Youjiang basin, SW China: Sulfide trace elements and sulfur isotopes 被引量:10
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作者 Jun Chen Zhi-Long Huang +2 位作者 Rui-Dong Yang Li-Juan Du Ming-Yang Liao 《Geoscience Frontiers》 SCIE CAS CSCD 2021年第2期605-623,共19页
In the northwestern margin of the Youjiang basin(NWYB)in SW China,many Carlin-like gold deposits are highly antimony(Sb)-rich,and many vein-type Sb deposits contain much Au.These deposits have similar ages,host rocks,... In the northwestern margin of the Youjiang basin(NWYB)in SW China,many Carlin-like gold deposits are highly antimony(Sb)-rich,and many vein-type Sb deposits contain much Au.These deposits have similar ages,host rocks,ore-forming temperatures,ore-related alterations and ore mineral assemblages,but the Au and Sb metallogenic relations and their ore-forming process remain enigmatic.Here we investigate the large Qinglong Sb deposit in the NWYB,which has extensive sub-economic Au mineralization,and present a new metallogenic model based on in-situ trace elements(EPMA and LA-ICP-MS)and sulfur isotopes(NanoSIMS and fs-LA-MC-ICPMS)of the ore sulfides.At Qinglong,economic Sb ores contain coarse-grained stibnite,jasperoid quartz and fluorite,whilst the sub-economic Au–Sb ores comprise dominantly veined quartz,arsenian pyrite and fine-grained stibnite.Three generations of ore-related pyrite(Py1,Py2 and Py3)and two generations of stibnite(Stb1 and Stb2)are identified based on their texture,chemistry,and sulfur isotopes.The pre-ore Py1 is characterized by the lower ore element(Au,As,Sb,Cu and Ag)contents(mostly below the LA-ICP-MS detection limit)and Co/Ni ratios(average 0.31)than the ore-stage pyrites(Py2 and Py3),implying a sedimentary/diagenetic origin.The Py2 and Py3 have elevated ore element abundance(maximum As=6500 ppm,Au=22 ppm,Sb=6300 ppm,Cu=951 ppm,Ag=77 ppm)and Co/Ni ratios(average 1.84),and have positive As vs.Au–Sb–Cu–Ag correlations.Early-ore Stb1 has lower As(0.12–0.30 wt.%)than late-ore Stb2(0.91–1.20 wt.%).These features show that the progressive As enrichment in ore sulfides is accompanied by increasing Au,Sb,Cu and Ag with the hydrothermal evolution,thereby making As a good proxy for Au.As-rich,As-poor and As-free zones are identified via NanoSIMS mapping of the Au-bearing pyrite.The As-rich zones in the Qinglong Au-bearing pyrites(Py2 and Py3)and ore stibnites(Stb1 and Stb2)have narrowδ^(34)SH_(2)S ranges(-8.9‰to +4.1‰,average-3.1‰)and-2.9‰to +6.9‰,average + 1.3‰),respectively,indicating that the Au-rich and Sb-rich fluids may have had the same sulfur source.Published in-situ sulfur isotopic data of pyrite As-rich zones from other Carlin-like Au deposits(Shuiyindong,Taipingdong,Nayang,Getang and Lianhuashan)in the NWYB have similar ore-fluidδSH_(2)S values(-4.5‰to +6.7‰,average-0.6‰)to those of Qinglong.Therefore,we infer that the sulfur of both Au and Sb mineralization was derived from the same magmatic-related source(0±5‰)in the NWYB.Moreover,the core of pyrites(Py1)has variable S isotope fractionation(-18.9‰to +18.1‰,mostly +3‰to +12‰),suggesting that the higher-^(34)S H_(2)S was produced by bacterial sulfate reduction(BSR).The hydrothermal pyrite(Py2 and Py3)δ^(34)S values gradually decrease with increasing As concentrations,and ultimately,within the restricted range(-5‰to +5‰)in As-rich zones.This variation implies that the As-rich pyrite was formed through ongoing interactions of the magmatic-hydrothermal fluid with pre-existing sedimentary pyrites,causing the progressive decreasing δ^(34)S values with As content increase,Hence,the fluid/mineral interaction may have generated the observed variation in δ^(34)S and As contents.Overall,comparing the Au and Sb deposits in the NWYB,we favor a magmatic-related source for the Au–Sb–As-rich fluids,but the Au-and Sb-ore fluids were likely evolved at separate stages in the ore-forming system. 展开更多
关键词 Pyrite STIBNITE LA-ICP-MS and NanoSIMS Sulfur isotopes au and Sb deposits Youjiang basin
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Improved charge transfer by size-dependent plasmonic Au on C_3N_4 for efficient photocatalytic oxidation of RhB and CO_2 reduction 被引量:9
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作者 Xin Li Chongyang Liu +3 位作者 Dongyao Wu JinZe Li Pengwei Huo Huiqin Wang 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第6期928-939,共12页
A series of Au/g-C3N4(Au/CN)nanocomposites were successfully prepared,where g-C3N4 nanosheets(CN NSs)served as a substrate for the growth of different sized Au nanoparticles(Au NPs)using the constant temperature bath-... A series of Au/g-C3N4(Au/CN)nanocomposites were successfully prepared,where g-C3N4 nanosheets(CN NSs)served as a substrate for the growth of different sized Au nanoparticles(Au NPs)using the constant temperature bath-reduction method.The effect of Au NP size on electron transfer efficiency between the interfaces of the nanocomposite was studied.The three-dimensional finite-difference time-domain results revealed that larger Au NPs showed increased strength of the localized surface plasmon resonance effect.An increased number of high-energy electrons were available for transfer from Au NPs to CN under the visible light irradiation,inhibiting electron transfer from CN to Au NPs.Photoelectrochemical performance analysis showed that smaller Au NPs exhibited higher separation efficiency of the electron-hole pairs photo-generated with reasonable distribution density.These results are favorable for the improvement of photocatalytic performance.Compared to other nanocomposites,the 3-Au/CN sample(prepared using 3 mL HAuCl4 solution)with reasonable distribution density and small Au NPs exhibited the best photodegradation activity(92.66%)of RhB in 30 min under the visible light irradiation and photoreduction performance of CO2 to CO and CH4 with yields of 77.5 and 38.5μmol/g,respectively,in 8 h under UV light irradiation.Considering the experimental results in the context of the literature,a corresponding size-dependent photocatalytic mechanism was proposed. 展开更多
关键词 au/g-C3N4 NANOSHEET Size dependence CO2 photoreduction Photocatalyst
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Effects of crystallinity, {001}/{101} ratio, and Au decoration on the photocatalytic activity of anatase TiO_2 crystals 被引量:7
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作者 Jiangyan Wang Baoshun Liu Kazuya Nakata 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第3期403-412,共10页
Anatase TiO2 nanocrystals and sub-microcrystals with truncated octahedral bipyramidal morphologies were prepared by direct calcination of TiOF2 precursors. The as-prepared TiO2 samples were thoroughly characterized by... Anatase TiO2 nanocrystals and sub-microcrystals with truncated octahedral bipyramidal morphologies were prepared by direct calcination of TiOF2 precursors. The as-prepared TiO2 samples were thoroughly characterized by X-ray diffraction, Raman spectroscopy, field-emission scanning electron microscopy, N2 adsorption-desorption isotherms, X-ray photoelectron spectroscopy, and UV-visible diffuse spectroscopy. It was found that the crystallinity, grain size, and {001}/{101} ratio of the samples can be increased by raising the calcination temperature from 500 to 800℃. The higher crystallinity and {001}/{101} facet ratio resulted in an increase in both aqueous and gas-phase photocatalytic activities, by inhibiting the recombination and separation of electrons and holes. After selecting two TiO2 samples with high crystallinity and {001}/{101} ratio, Au nanoparticles were decorated on their surfaces, and the photocatalytic activity of the resulting samples under visible light illumination was studied. It was found that the visible light-induced photocatalytic activity increased by 2.6 and 4.8 times, respectively, upon Au decoration of the samples prepared by calcination of TiOF2 at 700 and 800℃. 展开更多
关键词 High crystallinity Anatase TiO2 High energy facets au decoration Photocatalysis
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Structure–performance relationship of Au nanoclusters in electrocatalysis:Metal core and ligand structure
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作者 Bowen Li Lianmei Kang +3 位作者 Yongfeng Lun Jinli Yu Shuqin Song Yi Wang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第8期63-89,共27页
Remarkable progress has characterized the field of electrocatalysis in recent decades,driven in part by an enhanced comprehension of catalyst structures and mechanisms at the nanoscale.Atomically precise metal nanoclu... Remarkable progress has characterized the field of electrocatalysis in recent decades,driven in part by an enhanced comprehension of catalyst structures and mechanisms at the nanoscale.Atomically precise metal nanoclusters,serving as exemplary models,significantly expand the range of accessible structures through diverse cores and ligands,creating an exceptional platform for the investigation of catalytic reactions.Notably,ligand‐protected Au nanoclusters(NCs)with precisely defined core numbers offer a distinct advantage in elucidating the correlation between their specific structures and the reaction mechanisms in electrocatalysis.The strategic modulation of the fine microstructures of Au NCs presents crucial opportunities for tailoring their electrocatalytic performance across various reactions.This review delves into the profound structural effects of Au NC cores and ligands in electrocatalysis,elucidating their underlying mechanisms.A detailed exploration of the fundamentals of Au NCs,considering core and ligand structures,follows.Subsequently,the interaction between the core and ligand structures of Au NCs and their impact on electrocatalytic performance in diverse reactions are examined.Concluding the discourse,challenges and personal prospects are presented to guide the rational design of efficient electrocatalysts and advance electrocatalytic reactions. 展开更多
关键词 au nanoclusters CORE electrocatalytic performance LIGand STRUCTURES
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Experimental Study of the Distribution of Au and Cu in Aqueous Vapor Phase at High Temperatures and Its Role on Ore-forming Transportation 被引量:3
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作者 ZHANG Ronghua HU Shumin ZHANG Xuetong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第4期875-883,共9页
This study focuses on experiments of Au and Cu dissolved in vapor phase in hydrothermal fluids. Experiments prove that Au and Cu can re-distribute in vapor phase and liquid phase during separation of Au- and Cu-bearin... This study focuses on experiments of Au and Cu dissolved in vapor phase in hydrothermal fluids. Experiments prove that Au and Cu can re-distribute in vapor phase and liquid phase during separation of Au- and Cu-bearing supercritical fluids to vapor and liquid phases. These experimental results can illustrate some ore geneses, where boiling phenomena of ore fluids were found. Au- and Cubearing NaHCO3-HCl solutions were heated up to more than 350℃ in the main vessel, and then passed through a phase separator in a temperature range from 250℃ to 300℃, separated into vapor and liquid phases. We collected and analyzed the liquid and vapor samples separately, and found that Au and Cu dissolved and distributed in vapor phase. In some cases, the concentrations of Au and Cu in vapor are higher than those in liquid phase. Those experiments are used to interpret field observations of fluid inclusion data of some Au and Cu deposits, and demonstrate that some Au and Cu ore deposits are derived from metals transportation in vapor phase. 展开更多
关键词 au and Cu in vapor phase ore genesis boiling phenomena liquid and vapor phase separation metal transportation in gases
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Unravelling the role of the combined effect of metallic charge transfer channel and SiO_(x) overlayer in the Zr/Si-Fe_(2)O_(3):Au:SiO_(x) nanorod arrays to boost photoelectrochemical water splitting
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作者 Tae Sik Koh Periyasamy Anushkkaran +5 位作者 Love Kumar Dhandole Mahadeo A.Mahadik Weon-Sik Chae Hyun Hwi Lee Sun Hee Choi Jum Suk Jang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期370-379,I0009,共11页
Hematite(α-Fe_(2)O_(3)) based photoanodes have been extensively studied due to various intriguing features that make them viable candidates for a photoelectrochemical(PEC) water splitting photoanode.Herein,we propose... Hematite(α-Fe_(2)O_(3)) based photoanodes have been extensively studied due to various intriguing features that make them viable candidates for a photoelectrochemical(PEC) water splitting photoanode.Herein,we propose a Zr-doped Fe_(2)O_(3) photoanode decorated with facilely spin-coated Au nanoparticles(NPs) and microwave-assisted attached Si co-doping in conjunction with a SiO_(x) overlayer that displayed a remarkable photocurrent density of 2.01 mA/cm^(2) at 1.23 V vs.RHE.The kinetic dynamics at the photoelectrode/-electrolyte interface was examined by employing systematic electrochemical investigations.The Au NPs played a dual role in increasing PEC water splitting.First,the Schottky interface that was formed between Au NPs and Zr-Fe_(2)O_(3) lectrode ensured the prevention of electron flow from the photoanode to the metal,increasing the number of available charges as well as suppressing surface charge recombination.Second,Au extracted photoholes from the bulk of the Zr-Fe_(2)O_(3) and transported them to the outer SiO_(x) overlayer,while the SiO_(x) overlayer efficiently collected the photoholes and promoted the hole injection into the electrolyte.Further,Si co-doping enhanced bulk conductivity by reducing bulk charge transfer resistance and improving charge carrier density.This study outlines a technique to design a metallic charge transfer path with an overlayer for solar energy conversion. 展开更多
关键词 HEMATITE Microwave attachment au nanoparticles SiO_(x) overlayer Water splitting
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Nano-Au-decorated hierarchical porous cobalt sulfide derived from ZIF-67 toward optimized oxygen evolution catalysis:Important roles of microstructures and electronic modulation
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作者 Hongyu Gong Guanliang Sun +6 位作者 Wenhua Shi Dongwei Li Xiangjun Zheng Huan Shi Xiu Liang Ruizhi Yang Changzhou Yuan 《Carbon Energy》 SCIE EI CAS CSCD 2024年第5期1-14,共14页
Enhancing both the number of active sites available and the intrinsic activity of Co-based electrocatalysts simultaneously is a desirable goal.Herein,a ZIF-67-derived hierarchical porous cobalt sulfide decorated by Au... Enhancing both the number of active sites available and the intrinsic activity of Co-based electrocatalysts simultaneously is a desirable goal.Herein,a ZIF-67-derived hierarchical porous cobalt sulfide decorated by Au nanoparticles(NPs)(denoted as HP-Au@CoxSy@ZIF-67)hybrid is synthesized by low-temperature sulfuration treatment.The well-defined macroporous-mesoporous-microporous structure is obtained based on the combination of polystyrene spheres,as-formed CoxSy nanosheets,and ZIF-67 frameworks.This novel three-dimensional hierarchical structure significantly enlarges the three-phase interfaces,accelerating the mass transfer and exposing the active centers for oxygen evolution reaction.The electronic structure of Co is modulated by Au through charge transfer,and a series of experiments,together with theoretical analysis,is performed to ascertain the electronic modulation of Co by Au.Meanwhile,HP-Au@CoxSy@ZIF-67 catalysts with different amounts of Au were synthesized,wherein Au and NaBH4 reductant result in an interesting“competition effect”to regulate the relative ratio of Co^(2+)/Co^(3+),and moderate Au assists the electrochemical performance to reach the highest value.Consequently,the optimized HP-Au@CoxSy@ZIF-67 exhibits a low overpotential of 340 mV at 10 mA cm^(-2)and a Tafel slope of 42 mV dec-1 for OER in 0.1 M aqueous KOH,enabling efficient water splitting and Zn-air battery performance.The work here highlights the pivotal roles of both microstructural and electronic modulation in enhancing electrocatalytic activity and presents a feasible strategy for designing and optimizing advanced electrocatalysts. 展开更多
关键词 au nanoparticles cobalt sulfide electronic modulation hierarchical porous structure oxygen evolution reaction
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Green synthesis of MIL⁃101/Au composite particles and their sensitivity to Raman detection of thiram
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作者 LIU Huihui ZHAO Baichuan +2 位作者 WANG Chuanhui WANG Zhi ZHANG Congyun 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第10期2021-2030,共10页
Metal⁃organic framework(MOF)MIL⁃101 and surface plasmon polariton(SPP)supported gold nanoparti⁃cles(Au NPs)hybrid systems were developed as a highly sensitive and reproducible surface⁃enhanced Raman scat⁃tering(SERS)d... Metal⁃organic framework(MOF)MIL⁃101 and surface plasmon polariton(SPP)supported gold nanoparti⁃cles(Au NPs)hybrid systems were developed as a highly sensitive and reproducible surface⁃enhanced Raman scat⁃tering(SERS)detection platform,in which a green electrostatic self⁃assembly technology was adopted to construct the substrate.In an aqueous solution,the electronegativity of the particles can be used to prepare the composite sub⁃strate without any surface modifier.Due to the enrichment capacity of MIL⁃101 and the electromagnetic enhance⁃ment from Au NPs,the well⁃designed MIL⁃101/Au composites possessed ultrahigh sensitivity with the detection limit of Rhodamine 6G(R6G)as low as 10^(-10) mol·L^(-1).Meanwhile,the substrate exhibits high stability,excellent reproduc⁃ibility,and recyclability.Additionally,the novel substrate can be explored for direct capture,and sensitively detect pesticide residues such as thiram. 展开更多
关键词 MIL⁃101 au nanoparticle surface⁃enhanced Raman scattering THIRAM
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Controllable Synthesis of Au NRs and Its Flexible SERS Optical Fiber Probe with High Sensitivity
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作者 熊文豪 WANG Wenbo +1 位作者 LONG Yuting 李宏 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期7-16,共10页
The surface-enhanced Raman scattering(SERS) optical fiber probes were successfully prepared by self-assembling on polyelectrolyte multilayers. Gold nanorods(Au NRs) were used as SERS enhancement material to give excel... The surface-enhanced Raman scattering(SERS) optical fiber probes were successfully prepared by self-assembling on polyelectrolyte multilayers. Gold nanorods(Au NRs) were used as SERS enhancement material to give excellent biological affinity and stability to the SERS optical fiber probes. Au NRs were synthesized by seed growth method. The synergistic effect between AgNO_(3) and surfactant was investigated, and the highest yield was found when AgNO_(3) was 500 uL. Meanwhile, different SERS optical fiber probes were obtained by selecting silane coupling agent, polyelectrolyte multilayer and graphene oxide(GO) to treat quartz fiber. It was found that the SERS optical fiber probes obtained by the self-assembled on polyelectrolyte multilayers method performed better than those by other methods. In addition, Mapping was combined with finite element simulation to analyze the electromagnetic field distribution at the fiber end face.The electromagnetic field distribution of Au NRs was investigated, the difference of electromagnetic field intensity around the Au NRs with different arrangements was compared, the strongest signal was obtained when the Au NRs were head-to-head. Finally, sensitivity of the optimized SERS optical fiber probes could reach 10^(-9)mol/L, with excellent stability and repeatability. 展开更多
关键词 surface-enhanced Raman scattering(SERS) optical fiber probe gold nanorods(au NRs) polyelectrolyte multilayers controllable synthesis
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基于Au1200的NAND Flash启动技术研究与实现
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作者 阎峰 鄢萍 +1 位作者 胡新元 易润忠 《机电一体化》 2008年第11期37-40,共4页
提出了基于MIPS架构的Aul200 CPU上直接从NAND Flash启动系统的方案。介绍了NAND Flash存储器与NOR Flash的区别,分析了已有的系统从NAND Flash启动系统的一般模式,根据NAND Flash启动原理设计了三级启动加载方案,并且详细阐述了每一级... 提出了基于MIPS架构的Aul200 CPU上直接从NAND Flash启动系统的方案。介绍了NAND Flash存储器与NOR Flash的区别,分析了已有的系统从NAND Flash启动系统的一般模式,根据NAND Flash启动原理设计了三级启动加载方案,并且详细阐述了每一级的功能及在NAND Flash中的位置,最后给出了硬件电路图和关键启动代码。成功地在所在硬件平台上得以实现。 展开更多
关键词 Nand FLasH MIPS 三级启动加载 au1200 CACHE
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Absorption Range and Energy Shift of Surface Plasmon in Au Monomer and Dimer 被引量:2
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作者 赵晓坤 姚湲 +4 位作者 郎佩琳 郭红莲 沈希 王岩国 禹日成 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第2期97-101,共5页
The resonance behaviors of local surface plasmon resonance in Au monomer and dimer are characterized sys- temically by electron energy loss spectroscopy in a scanning transmission electron microscope. The measured abs... The resonance behaviors of local surface plasmon resonance in Au monomer and dimer are characterized sys- temically by electron energy loss spectroscopy in a scanning transmission electron microscope. The measured absorption range is about 20nm larger than the physical size of the Au nanoparticles and the resonance peak energy shows a red shift when the electron beam passes off the nanoparticles. The Au dimer displays similar behaviors. Numerical simulation also reproduces those experimental results. 展开更多
关键词 of or on Absorption Range and Energy Shift of Surface Plasmon in au Monomer and Dimer EELS in
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Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review
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作者 Shi-min Zhen Da-zhao Wang +2 位作者 Zhong-jian Zha Hai-jun Bai Jiang Wang 《China Geology》 CAS CSCD 2024年第3期533-550,共18页
The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization origi... The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit. 展开更多
关键词 Mineralization and alteration Alkaline intrusion au deposit Physicochemical conditions Metallogenic model Oxygen fugacity Sulfur fugacity Mechanisms of mineral precipitation Fluid boiling Fluorine-enriched fluid Dongping gold deposit North China Craton Mineral exploration engineering
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Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au(Sb) deposits in southern Anhui: a case study and review 被引量:1
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作者 Qing Hu Huangling Gu +3 位作者 Xiaoyong Yang Yisu Ren Ergen Gao Zhangxing Nie 《Acta Geochimica》 EI CAS CSCD 2018年第3期360-383,共24页
Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au(Sb) deposit and Au deposits at Zhaojialing, Wuxi,and... Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au(Sb) deposit and Au deposits at Zhaojialing, Wuxi,and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au(Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods(144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au(Cu) in the process. Integrated with theresults of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui. 展开更多
关键词 Yanshannian magmatism Subduction-modified lithosphere au (Sb) DEPOSITS SOUTHERN ANHUI South China
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Effects of Au nanoparticle size and metal-support interaction on plasmon-induced photocatalytic water oxidation 被引量:1
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作者 Shengyang Wang Bin Zeng Can Li 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第7期1219-1227,共9页
Plasmonic photocatalysis with tunable light absorption has aroused significant attention in so-lar-to-chemical energy conversion.However,the energy conversion efficiency of plasmonic photo-catalysts is impeded by inef... Plasmonic photocatalysis with tunable light absorption has aroused significant attention in so-lar-to-chemical energy conversion.However,the energy conversion efficiency of plasmonic photo-catalysts is impeded by ineffective charge separation and the lack of highly active sites for redox reactions.In this work,the Au nanoparticle size and Au-TiO2 interaction of the Au/TiO2 plasmonic photocatalyst were adjusted simultaneously using a post-calcination treatment.The visi-ble-ight-induced water oxidation activity exhibited a volcano-like relationship with the calcination temperature;the treated photocatalyst at 600°C manifested the highest activity.Characterization with UV-visible spectra,XRD,SEM,and XPS revealed that the effect of the Au nanoparticle size and Au-TiO2 interaction were both responsible for the increase in plasmon-induced water oxidation activity. 展开更多
关键词 au/TIO2 Water oxidation Plasmonic photocatalysis Size effect Metal-semiconductor interaction
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Chemial Bond and Stability of Adsorption of [Au(AsS_3)]^(2-)on the Surface of Kaolinite 被引量:1
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作者 闵新民 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2004年第1期5-8,共4页
Density function theory and discrete variation method (DFT-DVM) were used to study the adsorption of [Au(AsS 3)] 2- on the surface of kaolinite.The correlation among structure,chemical bond and stability was discuss... Density function theory and discrete variation method (DFT-DVM) were used to study the adsorption of [Au(AsS 3)] 2- on the surface of kaolinite.The correlation among structure,chemical bond and stability was discussed.Several models were selected with [Au(AsS 3)] 2- in different directions and sites.The results show that the models with gold on the edge of kaolinite basal layer contain pincerlike bond among gold and several oxygen atoms and form strong Au-O covalent bond,so these models are more stable than those with gold above or under the layer.The models with gold near to [AlO 2(OH) 4] octahedra are more stable than those with gold near to the vacancy without aluminium.These two stable tendencies in kaolinite-[Au(AsS 3)] 2- are stronger than that in kaolinite-Au systems.The interaction between [Au(AsS 3)] 2- and kaolinite is stronger than that between gold and kaolinite,and this interaction is strong enough to form the surface complexes. 展开更多
关键词 kaolinite-[au(asS 3)] 2- structure chemical bond STABILITY quantum chemistry calculation
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Characteristics and Genesis of Fine-Clastic Rock-Type Au Deposits in the Liaodong Rift 被引量:1
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作者 YANG Dejiang 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2000年第3期570-576,共7页
Gold deposits occurring in the Liaodong rift are located in interlayered carbonate rocks and fine-clastic rocks, belonging to the middle and upper parts of the lower Proterozoic. Compared with the Carlin-type Au depos... Gold deposits occurring in the Liaodong rift are located in interlayered carbonate rocks and fine-clastic rocks, belonging to the middle and upper parts of the lower Proterozoic. Compared with the Carlin-type Au deposits abroad and gold deposits in Yunnan-Guizhou-Guangxi, Qinling and western Sichuan Province, they are similar in many respects. This paper discusses the geological features of ore-bearing formations and ore-filling structures and metallogenetic characteristics. Through the discussion on the sources of ores, heat and water, it points out that the Au deposits belong to vadose reworked hydrothermal deposits. This conforms to the principle of “mineralization in the neighbouring areas”, i.e., the deposits are formed in nearby ore-bearing layers, and the latest hydrothermal event was the main factor in forming the Au deposits. 展开更多
关键词 LIAODONG fine-clastic rock-type au deposit vadose reworked hydrothermal deposit
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Low-mass vector meson production at forward rapidity in p+p and d+Au collisions at (~SNN)^(1/2)=200 GeV from a multiphase transport model
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作者 Yi-Fei Xu Yong-Jin Ye +3 位作者 Jin-Hui Chen Yu-Gang Ma Song Zhang Chen Zhong 《Nuclear Science and Techniques》 SCIE CAS CSCD 2016年第4期78-82,共5页
Low-mass vector meson(ρ, ω, and Ф) production at forward rapidity in p+p and d+Au collisions at (~SNN)^(1/2)=200 Ge V is studied within the framework of a multiphase transport model(AMPT). Detailed investigations, ... Low-mass vector meson(ρ, ω, and Ф) production at forward rapidity in p+p and d+Au collisions at (~SNN)^(1/2)=200 Ge V is studied within the framework of a multiphase transport model(AMPT). Detailed investigations, including the transverse momentum and the rapidity dependence of low-mass vector meson production in the AMPT model, show that the hadron interaction process is important for a quantitative description of the ρ and ω data.But for the Ф meson, the strange quark production in the AMPT model with the string melting scenario describes the data reasonably well, while the default AMPT model under-predicts the data. The N(Ф)=N(ρ+ω) ratio from the AMPT model with the string melting scenario perfectly describes the data in p+p collisions. For the d+Au collisions, an increased trend of this ratio vs. transverse momentum and the number of participants are observed from the AMPT model. Our results indicate that a precise measurement of the N(Ф)=N(ρ+ω) ratio in d+Au and Au+Au collisions will shed more light on the strangeness production and its dynamics in quark–gluon plasma. 展开更多
关键词 生产速度 矢量介子 输运模型 低质量 SRT 碰撞 au 多相
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Microstructure and UV Fluorescence of Amorphous I/Au Composite Nanofilms Based on LVDCS Method
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作者 ZHAI Xiaoyu DING Yufeng +7 位作者 KANG Yixin LI Siqi PAN Liangliang ZHANG Dapeng HE Huimei JIANG Xinhua WANG Yun MENG Qingyun 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2019年第6期1254-1258,共5页
The amorphous I/Au composite nanofilms were prepared by low vacuum direct current sputtering(LVDCS) method. The optimized preparation technologies contain growth pressure, time, gaseous environment and annealing condi... The amorphous I/Au composite nanofilms were prepared by low vacuum direct current sputtering(LVDCS) method. The optimized preparation technologies contain growth pressure, time, gaseous environment and annealing conditions. The maximum fluorescence emission(λemmax) of I/Au nanofilms was observed at wavelength of 375 nm, and the intensity of fluorescence emission peak of annealed I/Au films was smaller than that of unannealed one due to fewer amorphous Au nanoparticles, caused by annealing treatment. In the UV-Vis absorption spectra, the intensity of UV-Vis absorption peak of annealed I/Au nanofilms is larger than that of the unannealed one. This work also developed a new way to grow I/Au composite fluorescent thin films. 展开更多
关键词 LVDCS method AMORPHOUS I/au nanofilms FLUORESCENCE
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